CN1315132A - Composition of hexadecamacrolide-type antibiotic miticiding insecticide and pyridine-type insecticide - Google Patents
Composition of hexadecamacrolide-type antibiotic miticiding insecticide and pyridine-type insecticide Download PDFInfo
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- CN1315132A CN1315132A CN 00112179 CN00112179A CN1315132A CN 1315132 A CN1315132 A CN 1315132A CN 00112179 CN00112179 CN 00112179 CN 00112179 A CN00112179 A CN 00112179A CN 1315132 A CN1315132 A CN 1315132A
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- acetamiprid
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Abstract
A composition of hexadecamacrolide antibiotic-type miticiding insecticides and pyridine-type pesticides is disclosed, and features that it contains abamectin (0.05-2.5%) and acetamipid (0.05-10%). Its advantages include broad spectrum, low dosage and cost, solving the problem of pest's resistance to drug, and high synergistic action to lepidopterous pests.
Description
The present invention relates to the composition of a kind of ten former powder of hexa-atomic macrolides agricultural chemicals (cream) and the former powder of pyridine farm chemical.It has obvious synergistic effect.Add pesticides new formulation---the microemulsion that becomes ultra-fine grain diameter, stable storage with emulsifier, dispersant, proportion conditioning agent, thickener, bleeding agent, antifreezing agent and water through the homogeneous dispersible formulation.
Now have missible oil, microemulsion and the wetting powder of the single agent of acetamiprid (Avermectin); Wetting powder, microemulsion and the missible oil of the agent of Acetamiprid list.Its shortcoming is: the agent of acetamiprid list is the biological species insecticidal/acaricidal agent, and Insecticiding-miticiding quick-acting is poor, and is poor slightly to Semiptera insect preventive effect in addition; The agent of Acetamiprid list is to Semiptera insect special efficacy, doublely controls Lepidoptera, wing order insect slightly.
The objective of the invention is to avoid above-mentioned weak point of the prior art and a kind of ten hexa-atomic macrolide antibiotics agent for killing mite and pest and pyridines insecticides are provided, insecticidal spectrum is enlarged; And in the content range that the present invention comprises, Lepidoptera insects such as (diamond-back moth, cotton bollworms) there is the notable synergistic effect; Thoroughly solved the resistance problem of single agent to some insect; Reduce the independent usage amount of two single agent, reduced the mu cost.
Purpose of the present invention can reach by following measure:
A kind of ten hexa-atomic macrolide antibiotics agent for killing mite and pest and pyridines insecticides is characterized in that said composition contains 0.05-2.5% (m/m) acetamiprid and 0.05-10% (m/m) Acetamiprid.
Purpose of the present invention can also reach by following measure:
A kind of ten hexa-atomic macrolide antibiotics agent for killing mite and pest and pyridines insecticides, it is characterized in that the microemulsion that said composition is made contains: 0.05-2.5% (m/m) acetamiprid and 0.05-10% (m/m) Acetamiprid, 12-20% (m/m) emulsifier is OX901, OX902, OX903, DNP-18,500
#, 1600
#, 2000
#In three kinds of compositions, 2-5% (m/m) dispersant is a kind of in NNO, OX2000, sodium lignin sulfonate, calcium lignosulfonate, the penetrant t, 1-5% (m/m) bleeding agent is two kinds in azone, polysorbate 80, the penetrant t, 2-6% (m/m) proportion conditioning agent, 1-5% (m/m) thickener, the water of 1-5% (m/m) antifreezing agent and equivalent;
Emulsifier adopts OX903,500
#, 2000
#Three kinds of compositions are best;
It is best that dispersant adopts OX2000;
The used proportion conditioning agent of microemulsion is one of following kind: isopropyl alcohol, propane diols, urea, cyclohexanone, ethylenediamine, ethylene glycol;
The used thickener of microemulsion is two kinds of following kind: polyvinyl alcohol, CMC, xanthans, bentonite, white carbon;
The used antifreezing agent of microemulsion is one of following kind: ethylene glycol, polyethylene glycol, glycerine;
Microemulsion is to adopt homogeneous blender high degree of dispersion production technology and make;
Said composition also can be made into emulsifiable concentrate, missible oil, wetting powder.
The present invention has following advantage compared to existing technology:
The present invention has adopted microemulsion, emulsifiable concentrate thoroughly to solve problem of environmental pollution.By Toxicity Determination, determined the rational proportion of two effective ingredients, carried out the industrialness production test, product toxicity is measured, and has finished the present invention.It is the good agent for killing mite and pest of various crop such as control vegetables, fruit, melon beans, fruit tree, flowers, cotton, tobacco leaf, tea tree, accomplishes the end in view.
Microemulsion technical target of the product of the present invention is:
Project indicator acetamiprid content, % (m/m) 0.05-2.5 Acetamiprid content, the cold storage qualified stability in % (m/m) 0.05-10PH value 5-9 heat storage stability (54 ± 2 ℃, 14 days) %＜5
The microemulsion outward appearance is blueing optical transparency or outer transparency liquid, through 54 ± 2 ℃ of heat storages in 14 days, effective ingredient resolution ratio＜5%.
Toxicity Determination result:
After measured, two kinds of effective ingredients are in content range of the present invention, and composition has obvious synergistic function than two kinds of single agent.Subjects is lepidopterous diamond-back moth and cotton bollworm.
The measurement result of toxicity test and best proportioning sees Table 1, as can be seen from Table 1, acetamiprid and Acetamiprid by different proportionings composite after, diamond-back moth all there are to a certain degree addition or synergistic effect, wherein acetamiprid and Acetamiprid in proportion 0.2: 1.3 composite after, co-toxicity coefficient reaches 190.4, has significant synergies.
Acetamiprid is the GABA acceptor to the action target of insect, and Acetamiprid is the Ach acceptor to the action target of insect, and they have different mechanism of action, do not have cross resistance, therefore with they by best proportioning composite after, can improve control efficiency, the development of delaying drug resistance to diamond-back moth.
| Medicament | ?LD 50(μ g/ head) | The actual measurement toxicity index | Theoretical toxicity index | Co-toxicity coefficient CTC |
| Avermectin | 0.0500 | ????592.8 | ||
| Acetamiprid | 0.2964 | ????100 | ||
| Together+pyridine (0.1: 1.4) | 0.2081 | ????142.4 | ????132.8 | ????107.2 |
| Together+pyridine (0.2: 1.3) | 0.0939 | ????315.6 | ????165.7 | ????190.4 |
| Together+pyridine (0.3: 1.2) | 0.1169 | ????253.5 | ????198.5 | ????127.7 |
Embodiment 1:
Get 1.10 kilograms in the former powder of 92% acetamiprid, 3.15 kilograms of 93% Acetamiprids, emulsifier 500
#+ OX903+2000
#(1: 0.1-10: 0.1-10) 18 kilograms, 3.5 kilograms of dispersant OX2000,4 kilograms of proportion conditioning agent propane diols, 2 kilograms of thickener xanthans+polyvinyl alcohol, 4 kilograms of penetrant azone+penetrant ts, 6 kilograms of antifreeze glycols, 58.25 kilograms in water, with homogeneous, dispersion, test package are promptly formed microemulsion.
Annotate: OX series is Liaoyang, Liaoning Province gram difficult to understand chemicals Co., Ltd trade name.
Embodiment 2:
Get 23 kilograms of 4.3% acetamiprid cream, 3 kilograms of 93% Acetamiprids, emulsifier 500
#+ OX903+2000
#(1: 0.1-10: 0.1-10) 19 kilograms, 3.8 kilograms of dispersant OX2000,4 kilograms of proportion conditioning agent propane diols, 2 kilograms of thickener xanthans, 4 kilograms of penetrant azone+penetrant ts, 6 kilograms of antifreeze glycols, 35.2 kilograms in water is promptly made emulsifiable concentrate (aqueous emulsion) product through homogeneous dispersion, test package.
Embodiment 3:
Get 28 kilograms of 4.3% acetamiprid cream, 3.8 kilograms of 93% Acetamiprids, emulsifier 500
#+ OX903 (1: 0.1-10) 15 kilograms, 3 kilograms of antifreeze glycols, homogeneous disperses promptly to get the missible oil product.
Embodiment 4:
Get 1.5 kilograms in the former powder of 92% acetamiprid, 3.8 kilograms of 93% Acetamiprids, emulsifier 500
#+ OX903 (1: 0.1-10) 5 kilograms, dispersant NNO10 kilogram, 2 kilograms of white carbons, but mix, pulverize and promptly get the wet-milling product.
Claims (9)
1, a kind of ten hexa-atomic macrolide antibiotics agent for killing mite and pest and pyridines insecticides is characterized in that said composition contains 0.05-2.5% (m/m) acetamiprid and 0.05-10% (m/m) Acetamiprid.
2, according to claim 1 ten hexa-atomic macrolide antibiotics agent for killing mite and pest and pyridines insecticides, it is characterized in that the microemulsion that said composition is made contains: 0.05-2.5% (m/m) acetamiprid and 0.05-10% (m/m) Acetamiprid, 12-20% (m/m) emulsifier is OX901, OX902, OX903, DNP-18,500#, 1600
#, 2000
#In three kinds of compositions, 2-5% (m/m) dispersant is a kind of in NNO, OX2000, sodium lignin sulfonate, calcium lignosulfonate, the penetrant t, 1-5% (m/m) bleeding agent is two kinds in azone, polysorbate 80, the penetrant t, 2-6% (m/m) proportion conditioning agent, 1-5% (m/m) thickener, the water of 1-5% (m/m) antifreezing agent and equivalent.
3, composition according to claim 2 is characterized in that emulsifier adopts OX903,500
#, 2000
#Three kinds of compositions are best.
4, composition according to claim 2 is characterized in that dispersant adopts OX2000 for best.
5, composition according to claim 2 is characterized in that the used proportion conditioning agent of microemulsion is one of following kind: isopropyl alcohol, propane diols, urea, cyclohexanone, ethylenediamine, ethylene glycol.
6, composition according to claim 2 is characterized in that the used thickener of microemulsion is two kinds of following kind: polyvinyl alcohol, CMC, xanthans, bentonite, white carbon.
7, composition according to claim 2 is characterized in that the used antifreezing agent of microemulsion is one of following kind: ethylene glycol, polyethylene glycol, glycerine.
8, composition according to claim 2 is characterized in that microemulsion is to adopt homogeneous blender high degree of dispersion production technology and make.
9, composition according to claim 1 is characterized in that said composition also can be made into emulsifiable concentrate, missible oil, wetting powder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00112179 CN1315132A (en) | 2000-03-28 | 2000-03-28 | Composition of hexadecamacrolide-type antibiotic miticiding insecticide and pyridine-type insecticide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00112179 CN1315132A (en) | 2000-03-28 | 2000-03-28 | Composition of hexadecamacrolide-type antibiotic miticiding insecticide and pyridine-type insecticide |
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| Publication Number | Publication Date |
|---|---|
| CN1315132A true CN1315132A (en) | 2001-10-03 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 00112179 Pending CN1315132A (en) | 2000-03-28 | 2000-03-28 | Composition of hexadecamacrolide-type antibiotic miticiding insecticide and pyridine-type insecticide |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100588320C (en) * | 2008-03-14 | 2010-02-10 | 中国农业科学院郑州果树研究所 | Acetamiprid and pirimicarb pesticidal composition for controlling erisosma lanigerum hausmann and aphis citricola |
| WO2010092031A3 (en) * | 2009-02-11 | 2011-05-05 | Basf Se | Pesticidal mixtures |
| WO2010092028A3 (en) * | 2009-02-11 | 2011-07-14 | Basf Se | Pesticidal mixtures |
| CN106305714A (en) * | 2016-07-28 | 2017-01-11 | 尹正平 | Fruit fly attractant concentrated solution and matched fruit fly attractant thereof |
| CN107027800A (en) * | 2017-05-26 | 2017-08-11 | 河北威远生化农药有限公司 | A kind of Pesticidal combination containing avermectin B2a |
-
2000
- 2000-03-28 CN CN 00112179 patent/CN1315132A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100588320C (en) * | 2008-03-14 | 2010-02-10 | 中国农业科学院郑州果树研究所 | Acetamiprid and pirimicarb pesticidal composition for controlling erisosma lanigerum hausmann and aphis citricola |
| WO2010092031A3 (en) * | 2009-02-11 | 2011-05-05 | Basf Se | Pesticidal mixtures |
| WO2010092028A3 (en) * | 2009-02-11 | 2011-07-14 | Basf Se | Pesticidal mixtures |
| CN106305714A (en) * | 2016-07-28 | 2017-01-11 | 尹正平 | Fruit fly attractant concentrated solution and matched fruit fly attractant thereof |
| CN107027800A (en) * | 2017-05-26 | 2017-08-11 | 河北威远生化农药有限公司 | A kind of Pesticidal combination containing avermectin B2a |
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