CN1311783A - 具有链烯基取代基的磺酰基氨基(硫代)羰基三唑啉(硫)酮 - Google Patents

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Publication number

CN1311783A

CN1311783A CN99809054A CN99809054A CN1311783A CN 1311783 A CN1311783 A CN 1311783A CN 99809054 A CN99809054 A CN 99809054A CN 99809054 A CN99809054 A CN 99809054A CN 1311783 A CN1311783 A CN 1311783A

Authority

CN

China

Prior art keywords

alkyl

group

represent

fluorine

chlorine

Prior art date

1998-05-23

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

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• 125000003342 alkenyl group Chemical group 0.000 title claims abstract description 11
• BOXGRONENWXPJP-UHFFFAOYSA-N S(=O)(=O)=C1N(N=NC1)C(=O)SN Chemical compound S(=O)(=O)=C1N(N=NC1)C(=O)SN BOXGRONENWXPJP-UHFFFAOYSA-N 0.000 title abstract 2
• 150000001875 compounds Chemical class 0.000 claims abstract description 155
• 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 43
• 239000001257 hydrogen Substances 0.000 claims abstract description 43
• 238000000034 method Methods 0.000 claims abstract description 39
• NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 26
• 239000001301 oxygen Substances 0.000 claims abstract description 26
• 229910052760 oxygen Inorganic materials 0.000 claims abstract description 26
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 20
• 125000003545 alkoxy group Chemical class 0.000 claims abstract description 13
• 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract description 12
• 125000003118 aryl group Chemical group 0.000 claims abstract description 7
• 125000003710 aryl alkyl group Chemical group 0.000 claims abstract description 6
• 150000003839 salts Chemical class 0.000 claims abstract description 6
• 125000003282 alkyl amino group Chemical class 0.000 claims abstract description 4
• 125000000753 cycloalkyl group Chemical class 0.000 claims abstract description 4
• 125000005236 alkanoylamino group Chemical class 0.000 claims abstract description 3
• 125000003302 alkenyloxy group Chemical class 0.000 claims abstract description 3
• 125000001316 cycloalkyl alkyl group Chemical class 0.000 claims abstract description 3
• 125000001072 heteroaryl group Chemical class 0.000 claims abstract description 3
• 125000005017 substituted alkenyl group Chemical group 0.000 claims abstract description 3
• 239000000417 fungicide Substances 0.000 claims abstract 3
• YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 120
• 239000011737 fluorine Substances 0.000 claims description 120
• 229910052731 fluorine Inorganic materials 0.000 claims description 120
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 119
• 239000000460 chlorine Substances 0.000 claims description 119
• 229910052801 chlorine Inorganic materials 0.000 claims description 119
• -1 thiocarbamoyl Chemical group 0.000 claims description 116
• WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 70
• GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 69
• 229910052794 bromium Inorganic materials 0.000 claims description 69
• 238000002360 preparation method Methods 0.000 claims description 68
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• 238000006243 chemical reaction Methods 0.000 claims description 27
• 239000000203 mixture Substances 0.000 claims description 27
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• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 24
• 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 20
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• 239000003795 chemical substances by application Substances 0.000 claims description 13
• 239000013543 active substance Substances 0.000 claims description 12
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• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
• 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 claims description 10
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• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 9
• 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 9
• 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 8
• 150000003863 ammonium salts Chemical class 0.000 claims description 7
• 125000004104 aryloxy group Chemical group 0.000 claims description 7
• 125000003830 C1- C4 alkylcarbonylamino group Chemical group 0.000 claims description 6
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 6
• 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 claims description 6
• 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 claims description 6
• 159000000000 sodium salts Chemical class 0.000 claims description 6
• SMDGVPQREIZILS-UHFFFAOYSA-N $l^{1}-oxidanylmethylbenzene Chemical compound [O]CC1=CC=CC=C1 SMDGVPQREIZILS-UHFFFAOYSA-N 0.000 claims description 5
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• 125000000547 substituted alkyl group Chemical group 0.000 claims description 4
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• 229910052751 metal Inorganic materials 0.000 claims description 3
• 239000002184 metal Substances 0.000 claims description 3
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• 125000003320 C2-C6 alkenyloxy group Chemical group 0.000 claims description 2
• AYDQIZKZTQHYIY-UHFFFAOYSA-N OC(=O)C1(C)CC(C(O)=O)=CC=C1 Chemical compound OC(=O)C1(C)CC(C(O)=O)=CC=C1 AYDQIZKZTQHYIY-UHFFFAOYSA-N 0.000 claims description 2
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• 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 claims description 2
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• 150000003818 basic metals Chemical group 0.000 claims description 2
• 125000000480 butynyl group Chemical group [*]C#CC([H])([H])C([H])([H])[H] 0.000 claims description 2
• 159000000007 calcium salts Chemical class 0.000 claims description 2
• 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 claims description 2
• 125000006310 cycloalkyl amino group Chemical group 0.000 claims description 2
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• 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 claims description 2
• 125000005879 dioxolanyl group Chemical group 0.000 claims description 2
• 125000005982 diphenylmethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 2
• 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 2
• 125000006125 ethylsulfonyl group Chemical group 0.000 claims description 2
• 159000000003 magnesium salts Chemical class 0.000 claims description 2
• 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 2
• 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims description 2
• 239000001103 potassium chloride Substances 0.000 claims description 2
• 235000011164 potassium chloride Nutrition 0.000 claims description 2
• 125000004076 pyridyl group Chemical group 0.000 claims description 2
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• 125000004646 sulfenyl group Chemical group S(*)* 0.000 claims description 2
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• 125000005034 trifluormethylthio group Chemical group FC(S*)(F)F 0.000 claims description 2
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• 125000004786 difluoromethoxy group Chemical group [H]C(F)(F)O* 0.000 claims 1
• 125000006216 methylsulfinyl group Chemical group [H]C([H])([H])S(*)=O 0.000 claims 1
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• 125000000217 alkyl group Chemical class 0.000 abstract description 5
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