CN1308559C - Human body fluid soluble inorganic ceramic fiber sound absorption board and process of production - Google Patents
Human body fluid soluble inorganic ceramic fiber sound absorption board and process of production Download PDFInfo
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- CN1308559C CN1308559C CNB200310105699XA CN200310105699A CN1308559C CN 1308559 C CN1308559 C CN 1308559C CN B200310105699X A CNB200310105699X A CN B200310105699XA CN 200310105699 A CN200310105699 A CN 200310105699A CN 1308559 C CN1308559 C CN 1308559C
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- dissolves
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- 239000000835 fiber Substances 0.000 title claims abstract description 98
- 238000000034 method Methods 0.000 title claims abstract description 10
- 238000010521 absorption reaction Methods 0.000 title claims description 23
- 210000001124 body fluid Anatomy 0.000 title claims description 17
- 239000010839 body fluid Substances 0.000 title claims description 17
- 239000000919 ceramic Substances 0.000 title abstract description 3
- 238000004519 manufacturing process Methods 0.000 title description 4
- 239000000463 material Substances 0.000 claims abstract description 40
- 238000005520 cutting process Methods 0.000 claims abstract description 17
- 238000002360 preparation method Methods 0.000 claims abstract description 14
- 238000004049 embossing Methods 0.000 claims abstract description 12
- 239000007788 liquid Substances 0.000 claims abstract description 9
- 238000001035 drying Methods 0.000 claims abstract description 8
- 239000002002 slurry Substances 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 26
- 239000002893 slag Substances 0.000 claims description 22
- 238000005469 granulation Methods 0.000 claims description 16
- 230000003179 granulation Effects 0.000 claims description 16
- 229910052909 inorganic silicate Inorganic materials 0.000 claims description 14
- 230000003014 reinforcing effect Effects 0.000 claims description 14
- 235000019362 perlite Nutrition 0.000 claims description 13
- 229920000742 Cotton Polymers 0.000 claims description 12
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 12
- 239000004327 boric acid Substances 0.000 claims description 11
- 239000003365 glass fiber Substances 0.000 claims description 11
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 10
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 10
- 229920002472 Starch Polymers 0.000 claims description 10
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims description 10
- 230000018044 dehydration Effects 0.000 claims description 10
- 238000006297 dehydration reaction Methods 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 10
- 235000019698 starch Nutrition 0.000 claims description 10
- 239000008107 starch Substances 0.000 claims description 10
- 210000002268 wool Anatomy 0.000 claims description 10
- HCJLVWUMMKIQIM-UHFFFAOYSA-M sodium;2,3,4,5,6-pentachlorophenolate Chemical compound [Na+].[O-]C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl HCJLVWUMMKIQIM-UHFFFAOYSA-M 0.000 claims description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 8
- 238000000465 moulding Methods 0.000 claims description 8
- 239000012188 paraffin wax Substances 0.000 claims description 8
- 239000010451 perlite Substances 0.000 claims description 8
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 235000012239 silicon dioxide Nutrition 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 238000005507 spraying Methods 0.000 claims description 7
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 6
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 6
- 239000003814 drug Substances 0.000 claims description 6
- 229940079593 drug Drugs 0.000 claims description 6
- 238000002347 injection Methods 0.000 claims description 6
- 239000007924 injection Substances 0.000 claims description 6
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 5
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 239000007767 bonding agent Substances 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- 125000005619 boric acid group Chemical group 0.000 claims description 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 241000658379 Manihot esculenta subsp. esculenta Species 0.000 claims 1
- 238000007493 shaping process Methods 0.000 abstract 1
- 238000004381 surface treatment Methods 0.000 abstract 1
- 238000003556 assay Methods 0.000 description 9
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 9
- 230000004927 fusion Effects 0.000 description 9
- 239000000499 gel Substances 0.000 description 7
- 239000011490 mineral wool Substances 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 5
- 240000003183 Manihot esculenta Species 0.000 description 4
- 239000010425 asbestos Substances 0.000 description 4
- 229910052895 riebeckite Inorganic materials 0.000 description 4
- 230000009970 fire resistant effect Effects 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 235000019354 vermiculite Nutrition 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000010455 vermiculite Substances 0.000 description 2
- 229910052902 vermiculite Inorganic materials 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 1
- SEGBQNJGOCXIGC-FHERZECASA-N benzyl n-[(2s)-1-[(4-hydroxyoxolan-3-yl)amino]-4-methyl-1-oxopentan-2-yl]carbamate Chemical group N([C@@H](CC(C)C)C(=O)NC1C(COC1)O)C(=O)OCC1=CC=CC=C1 SEGBQNJGOCXIGC-FHERZECASA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000009982 effect on human Effects 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 231100000003 human carcinogen Toxicity 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Landscapes
- Ceramic Products (AREA)
- Building Environments (AREA)
Abstract
The present invention relates to an inorganic ceramic fiber sound-absorbing panel capable of dissolving in body liquid of human bodies and a preparation method thereof. The present invention is characterized in that the sound-absorbing panel comprises the main components of the proportion by weight percentage: 30 to 60% of soluble fiber, 10 to 20% of inorganic bonds, 3 to 5% of organic bonds, 10 to 40% of stuffing and 3 to 9% of other material. The preparation method comprises the steps that the soluble fiber is used as the main body material and granulated; the bonds with the proportioning are added for slurry preparation; the product is prepared by processing via procedures of shaping, drying, surface treatment, cutting, embossing, fine cutting, etc. The soluble fiber sound-absorbing panel of the present invention uses the soluble fiber capable of dissolving in body liquid of human bodies as the main material to ensure that the influence of the product on human health is reduced to the minimum; moreover, besides the technical order is equal to or superior to that of a common sound-absorbing panel, the fire proof use temperature (can reach 1000 DEG C) of the sound-absorbing panel can be greatly enhanced.
Description
Technical field
The present invention relates to a kind of inorganic silicate fiber sound absorption plate that dissolves in human body fluid and preparation method thereof.
Background technology
Traditional architecture acoustical board product serves as the main adhesive that adds proper proportion with raw material such as asbestos, rock wool, mineral wool, expanded perlite, vermiculites mainly, processes through operations such as moulding, drying, cutting, embossing, facings.
There is following problem in the acoustical board product of above manufacture of materials:
Though the acoustical board price of using asbestos to produce is comparatively cheap and since proved asbestos produce and use in, the dust of generation has the human carcinogen is acted on, and is limited or stops using.
Using rock wool, mineral wool, expanded perlite, vermiculite only is about 450 ℃-600 ℃ as the acoustical board product serviceability temperature of main raw material(s) production, is difficult to the requirement that reaches fire-resistant.
Summary of the invention
The objective of the invention is by adopting soluble fibre to replace manufacture of materials soluble fibre acoustical boards such as traditional asbestos, rock wool, mineral wool, expanded perlite, vermiculite, because soluble fibre has enough solubility in human body fluid, the time of staying of fiber in human body can be shortened, fiber is reduced to the infringement of human body minimum, thereby make the soluble fibre plate become the product that does not harm human body.
The technical solution used in the present invention is: develop a kind of inorganic silicate fiber sound absorption plate that dissolves in human body fluid, it is characterized in that this acoustical board predominant quantity percentage composition is:
Soluble fibre 30～60%
Inorganic bonding agent 10～20%
Organic bond 3～5%
Filler 10～40%
Other materials 3～9%.
The above-mentioned inorganic silicate fiber sound absorption plate that dissolves in human body fluid, soluble fibre wherein is the inorganic silicate fiber that dissolves in human body fluid, the weight percent of this fiber consists of:
SiO
2 56～85％
CaO+MgO 11～40％
B
2O
3 1～2％
Al
2O
3 0～1％
Fe
2O
3 0～0.5％
Na
2O+K
2O 0～0.5％。
Above-mentioned inorganic bonding agent is silicon dioxide gel, alumina sol, silicate of soda and/or aluminum sulfate; Above-mentioned organic bond is starch, polyvinyl alcohol, carboxymethyl cellulose, cassava and/or acorn nut powder; Above-mentioned filler is clay, kieselguhr and/or expanded perlite;
Above-mentioned other materials is reinforcing fibre, anti-blushing agent and anticorrisive agent; Wherein: reinforcing fibre is string and/or short glass fiber; Anti-blushing agent is that solid paraffin and/or rosin acid are received; Anticorrisive agent is boric acid, sodium pentachlorophenate and/or bisnaphthol.
A kind of method for making that dissolves in the inorganic silicate fiber sound absorption plate of human body fluid, it is characterized in that soluble fibre is material of main part and granulation, the binding material that adds proportional quantity is joined slurry slurrying, operation such as cuts through moulding, drying, surfacing cutting, embossing, essence and processes;
The step of preparation method is as follows:
(1) fiber granulation: with the soluble fibre granulation, the granularity of granulated wool is 5～20mm, and its slag ball content is 0～5%;
(2) join slurry slurrying: granulated wool and binding material are mixed in required ratio, be stirred to slurry and be suspension, the cotton pulp ratio is≤10%;
(3) moulding: be molded on the fourdrinier and carry out, comprise approach flow, vacuum suction filter dehydration, suction press dehydration and liquid drugs injection cutting part;
(4) drying: the wet mat moisture content is 100～120%, dry 50～150min between 100～350 ℃;
(5) cutting, facing: machine cuts becomes slab, the surface plane planing, and surperficial sprayed coating,
(6) redrying: through the slab of surface spraying, at 100～120 ℃, dry 1～15min;
(7) embossing, machine cuts become accurate finished size, promptly.
The quality index of soluble fibre acoustical board of the present invention is as follows:
Bulk density: 220-600kg/m
3
Flexural strength: 0.7-1.0MPa
Moisture content: 0～3%
Flammable: the A level is not fired
Coefficient of thermal conductivity: normal temperature 0.035-0.0.042W/m.k
Average sound absorption coefficient (125HZ-4000HZ): 0.45-0.7
Solubility: 100-250mg/L
The invention has the advantages that compared with the prior art:
1. adopting the soluble fibre that mixes with human body fluid is main raw material(s), and it is minimum that effect on human health is reduced to.
2. can increase substantially the fire-resistant serviceability temperature (can reach 1000 ℃) of acoustical board,
The specific embodiment
Embodiment 1
One, solvable dimension part weight proportion (kg): SiO
285 parts, 11 parts of CaO+MgO, B
2O
32 parts, Al
2O
31 part, Fe
2O
30.5 part, Na
2O+K
20.5 part of O.
After the step above-mentioned raw materials of preparation method mixed, 1500～1800 ℃ were melt into liquid state in special resistance furnace (or electric arc furnaces, glass have a rest stove), utilized blowing process or got rid of a method (0.3～0.6Mpa blast) and carry out fiber production.
Existing resistance furnace is set up 3 groups of electrodes, because raw material changes, resistance is increased, and conductance reduces, and causes the fusing difficulty, for this increases by 3 groups of electrodes to existing resistance furnace, becomes 6 groups of electrodes, to improve the conductance of raw material.
The inorganic silicate fiber that dissolves in human body fluid that the present invention produces, softness and high resilience, average fibre diameter 1～5 μ m, fibre length is 30～150mm, slag ball content is 5～10%.
Fiber that the present invention obtains in PH7.3～7.5, soaks 24h in the meta-alkalescence solution that temperature is 37 ± 0.5 ℃, uses atomic absorption spectrometry, and its solubility is 100～250mg/L; And the conventional ceramic fiber solubility of contrast is 0mg/L.
Two, soluble fibre acoustical board part predominant quantity proportioning (kg):
60 parts of soluble fibres, 20 parts of silicate of soda or silicon dioxide gels, 5 parts of starch and/or polyvinyl alcohol, 10 parts of kieselguhr and/or expanded perlites, 5 parts of other materials.Other materials is reinforcing fibre (string); Anti-blushing agent (solid paraffin); Anticorrisive agent (boric acid and/or sodium pentachlorophenate)
The step of preparation method of the present invention is as follows;
1, fiber granulation: adopt comminutor to carry out, the granularity of granulated wool is at 10～20mm, and its slag ball content is 5%;
2, join slurry slurrying: granulated wool and binding material are mixed, stir in required ratio, and cotton pulp is than 10%;
3, moulding: on fourdrinier, carry out, comprise approach flow, vacuum suction filter dehydration or suction press dehydration and liquid drugs injection cutting part.Through the wet mat after the dehydration, its moisture content is generally 100～120%.
4, drying: at 100～350 ℃/50～150min, its moisture content of the dried goods of process is below 3%.
5, cutting: cutting comprises rip cutting, crosscut composition, all adopts machine cuts.
6, planing surface: cut, the slab after the crosscut, planish by surface plane.
7, surface spraying: the slab behind the planing surface, carry out surperficial flush coater, the coating for preparing (coating is made by polyvinyl alcohol, calcium carbonate superfine powder powder, titanium dioxide, calcite in powder, SPA202 defoamer etc.) by the pump weight feed, sprays glue with nozzle from the coating storage tank.
8, redrying: the slab through the surface spraying, enter the redrying stove, baking temperature is 100～120 ℃, drying time is at 1～15min.
9, embossing: embossing has several forms such as roll extrusion flower, mold pressing flower, heat embossing.
10, essence is cut: the plate that adopts the machine cuts method will be pressed with decorative pattern cuts into accurate finished size, and size is generally 300 * 300; 400 * 400; 600 * 600 (mm).
The technical indicator of soluble fibre acoustical board of the present invention is as follows:
Bulk density: 220-600kg/m
3
Flexural strength: 0.7-1.0MPa
Moisture content: 0～3%
Flammable: the A level is not fired
Coefficient of thermal conductivity: normal temperature 0.035-0.0.042W/m.k
Average sound absorption coefficient (125HZ-4000HZ): 0.45-0.7
Solubility: 100-250mg/L
Soluble fibre acoustical board of the present invention is equal to except technical indicator or is better than the common acoustical board, can increase substantially the fire-resistant serviceability temperature (can reach 1000 ℃) of acoustical board.
Embodiment 2
One, soluble fibre part weight proportion (kg): SiO
256.5 part, 40 parts of CaO+MgO, B
2O
32 parts, Al
2O
31 part, Fe
2O
30.5 part;
The step of preparation method: 1800～2000 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 5～10 μ m; Length 90～250mm; Slag ball content 5～10%; Solubility 100～250mg/L.
Two, soluble fibre acoustical board part predominant quantity proportioning (kg):
30 parts of soluble fibres, 20 parts in silicate of soda and/or aluminum sulfate, 3 parts of starch and/or carboxymethyl celluloses, 40 parts of kieselguhr or expanded perlites, 7 parts of other materials.Other materials is reinforcing fibre (string and/or a short glass fiber); Anti-blushing agent (rosin acid is received); Anticorrisive agent (boric acid or sodium pentachlorophenate).
The step of preparation method: the soluble fibre granulation to granularity at 5～10mm, slag ball content is 0～1%; Granulated wool and binding material mix, stir in required ratio, and cotton pulp is than 9%; Net forming, vacuum suction filter dehydration, liquid drugs injection cutting on the fourdrinier spreading mass; Moisture content 100～120%, 100～150 ℃/100～150min, to moisture content 2%; Machine cuts, surface plane planing; (100～120 ℃/10～15min of surface spraying, redryings.), embossing, accurately become required finished size, packing.
The quality index of soluble fibre acoustical board: bulk density 220～600kg/m
3Flexural strength: 0.7～1.0Mpa; Moisture content: 0～3%; Flammable: the A level is not fired; Coefficient of thermal conductivity: normal temperature 0.035-0.042W/m.k; Average sound absorption coefficient (125HZ-4000HZ): 0.45～0.7; Solubility: 100～250mg/L (with the assay method of above-mentioned soluble fibre); All the other are with example 1.
Embodiment 3
Soluble fibre part weight proportion (kg): SiO
256 parts, 40 parts of CaO+MgO, B
2O
32 parts, Al
2O
31 part, Fe
2O
30.5 part, Na
2O+K
20.5 part of O; 1800～2000 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 1～6 μ m; Length 100～250mm; Slag ball content 5～8%; Solubility 190～250mg/L.
Soluble fibre acoustical board part predominant quantity proportioning (kg): 50 parts of soluble fibres, 20 parts in silicate of soda and/or aluminum sulfate, totally 24 parts of 3 parts of polyvinyl alcohol and/or carboxymethyl celluloses, kieselguhr and expanded perlite, 3 parts of other materials.Other materials is reinforcing fibre (string or a short glass fiber); Anti-blushing agent (solid paraffin); Anticorrisive agent (sodium pentachlorophenate or sodium pentachlorophenate).
The step of preparation method: soluble fibre granulation, granularity are at 8～15mm, and slag ball content is 1～2%; Granulated wool and binding material mix, stir by dosage, and cotton pulp is than 7.5%; Approach flow moulding, vacuum suction filter dehydration, liquid drugs injection cutting; Moisture content 100～110%, 200～250 ℃/100～120min, to moisture content 2%; Machine cuts, surface plane planing; (100～120 ℃/10～15min of surface spraying, redryings.), embossing, accurately become required finished size, packing.
The quality index of soluble fibre acoustical board: bulk density 220～300kg/m
3Flexural strength: 0.7～1.0Mpa; Moisture content: 0～3%; Flammable: the A level is not fired; Coefficient of thermal conductivity: normal temperature 0.035-0.042W/m.k; Average sound absorption coefficient (125HZ-4000HZ): 0.45～0.7; Solubility: 100～250mg/L (with the assay method of above-mentioned soluble fibre); All the other are with example 1.
Embodiment 4
Soluble fibre (hereinafter to be referred as fiber) part weight proportion (kg): SiO
258 parts, 40 parts of CaO+MgO, B
2O
31 part, Fe
2O
30.5 part, Na
2O+K
20.5 part of O;
1800～2000 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 6～10 μ m; Length 150～250mm; Slag ball content 5～14%; Solubility 180～250mg/L.
Soluble fibre plate (hereinafter to be referred as plate) part proportioning (kg): 60 parts of soluble fibres, 10 parts of silicate of soda and/or silicon dioxide gels, 5 parts in cassava and/or acorn nut powder, 16 parts of kieselguhr or expanded perlites, 9 parts of other materials.
Other materials is reinforcing fibre (short glass fiber); Anti-blushing agent (rosin acid is received); Anticorrisive agent (boric acid or sodium pentachlorophenate).
The step of preparation method: soluble fibre granulation, granularity are at 10～15mm, and slag ball content is 2～3%; Granulated wool and binding material mix, stir by dosage, and cotton pulp is than 6.5%; Approach flow moulding, vacuum suction filter dehydration, liquid drugs injection cutting; Moisture content 100～110%, 200～250 ℃/100～120min, to moisture content 2%; Machine cuts, surface plane planing; (100～120 ℃/10～15min of surface spraying, redryings.), embossing, accurately become required finished size, packing.
The quality index of plate: bulk density 220～300kg/m
3Flexural strength: 0.7～1.0Mpa; Moisture content: 2.5%; Flammable: the A level is not fired; Coefficient of thermal conductivity: normal temperature 0.035-0.042W/m.k; Average sound absorption coefficient (125HZ-4000HZ): 0.45～0.7; Solubility: 100～250mg/L (with the assay method of above-mentioned soluble fibre); All the other are with example 1.
Embodiment 5
Fibre furnish (kg): SiO
260 parts, 38.5 parts of CaO+MgO, B
2O
31 part, Na
2O+K
20.5 part of O; 1800～2000 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 2～5 μ m: length 30～200mm; Slag ball content 5～15%; Solubility 100～200mg/L.
Plate proportioning (kg): 45 parts of soluble fibres, 20 parts in silicate of soda and/or aluminum sulfate, 5 parts in carboxymethyl cellulose and/or acorn nut powder, 21 parts in clay and/or kieselguhr, 9 parts of other materials.
Other materials is reinforcing fibre (short glass fiber); Anti-blushing agent (rosin acid is received); Anticorrisive agent (boric acid or sodium pentachlorophenate).
The soluble fibre granulation, granularity 10～15mm, slag ball content 2～3%; Granulated wool and binding material mix, stir by dosage, and cotton pulp is than 8.5%: moisture content 100～110%, 200～250 ℃/100～120min, do to moisture content 2%; 100～120 ℃/10～15min of redrying.
The quality of plate: bulk density 550～600kg/m
3Flexural strength: 0.7～1.0Mpa; Moisture content: 1.5%: combustibility: the A level is not fired; Coefficient of thermal conductivity: normal temperature 0.035-0.042W/m.k; Average sound absorption coefficient (125HZ-4000HZ): 0.45～0.7; Solubility: 100～250mg/L (with the assay method of above-mentioned soluble fibre); All the other are with example 2.
Embodiment 6
Soluble fibre weight proportion (kg): SiO
270 parts, 27.5 parts of CaO+MgO, B
2O
32 parts, Na
2O+K
20.5 part of O; 1500～1900 ℃ of fusions; 0.3～0.6Mpa blast: diameter 2～5 μ m; Length 90～250mm; Slag ball content 5～13%; Solubility 100～200mg/L.
Soluble fibre acoustical board part predominant quantity proportioning (kg): 55 parts of soluble fibres, 18 parts of silicate of soda and/or silicon dioxide gels, 5 parts of starch and/or polyvinyl alcohol, 13 parts of kieselguhr or expanded perlites, 9 parts of other materials.
Other materials is reinforcing fibre (short glass fiber); Anti-blushing agent (rosin acid is received); Anticorrisive agent (boric acid or sodium pentachlorophenate).
The soluble fibre granulation, granularity 15～20mm, slag ball content 2.5～3%; Cotton pulp is than 8.5%; Moisture content 100～110%, 200～250 ℃/100～120min are done to moisture content 1.5%; 100～120 ℃/10～15min of redrying.
The quality of plate: bulk density 500～550kg/m
3Flexural strength: 0.7～1.0Mpa; Moisture content: 1.5%; Flammable: the A level is not fired; Coefficient of thermal conductivity: normal temperature 0.035-0.042W/m.k; Average sound absorption coefficient (125HZ-4000HZ): 0.45～0.7; Solubility: 100～250mg/L (with the assay method of above-mentioned soluble fibre); All the other are with example 1.
Embodiment 7
Soluble fibre part weight proportion (kg down together): SiO
262 parts, 35.5 parts of CaO+MgO, B
2O
32 parts, Fe
2O
30.5 part; 1800～2000 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 4～7 μ m; Length 70～250mm; Slag ball content 5～8%; Solubility 200～250mg/L.
Soluble fibre acoustical board part predominant quantity proportioning (kg): 45 parts of soluble fibres, 20 parts of silicon dioxide gel and/or alumina sols, 5 parts of starch or polyvinyl alcohol, 27 parts of kieselguhr or expanded perlites, 3 parts of other materials.
Other materials is reinforcing fibre (short glass fiber); Anti-blushing agent (solid paraffin and rosin acid are received); Anticorrisive agent (boric acid and/or bisnaphthol).
The soluble fibre granulation, granularity 10～15mm, slag ball content 3.5～4%; Cotton pulp is than 5.5%; Moisture content 100～110%, 300～350 ℃/50～100min are done to moisture content 0.5%; 100～120 ℃/10～15min of redrying.
The quality of plate: bulk density 400～450kg/m
3Flexural strength: 0.7～1.0Mpa; Moisture content: 0.5%; Flammable: the A level is not fired; Coefficient of thermal conductivity: normal temperature 0.035-0.042W/m.k; Average sound absorption coefficient (125HZ-4000HZ): 0.45～0.7; Solubility: 100～250mg/L (with the assay method of above-mentioned soluble fibre); All the other are with example 1.
Embodiment 8
Soluble fibre weight proportion: SiO
258.5 part, 39.5 parts of CaO+MgO, B
2O
31 part, Al
2O
30.1 part, Fe
2O
30.5 part, Na
2O+K
20.4 part of O; 1800～2000 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 4～8 μ m; Length 30～200mm; Slag ball content 5～10%; Solubility 200～250mg/L.
Soluble fibre acoustical board part, predominant quantity proportioning (kg): 52 parts of soluble fibres, 18 parts of alumina sol and/or silicate of soda, 4 parts of starch and/or carboxymethyl celluloses, 23 parts of kieselguhr or clays, 3 parts of other materials.
Other materials is reinforcing fibre (short glass fiber); Anti-blushing agent (solid paraffin and rosin acid are received); Anticorrisive agent (boric acid and/or bisnaphthol).
The soluble fibre granulation, granularity 10～13mm, slag ball content 3～4%; Cotton pulp is than 7.5%; Moisture content 100～110%, 300～350 ℃/50～100min are done to moisture content 0.5%; 100～120 ℃/10～15min of redrying.
The quality of plate: bulk density 300～350kg/m
3Flexural strength: 0.7～1.0Mpa; Moisture content: 0.5%; Flammable: the A level is not fired; Coefficient of thermal conductivity: normal temperature 0.035-0.042W/m.k; Average sound absorption coefficient (125HZ-4000HZ): 0.45～0.7; Solubility: 100～250mg/L (with the assay method of above-mentioned soluble fibre); All the other are with example 1.
Embodiment 9
Soluble fibre weight proportion: SiO
257 parts, 40 parts of CaO+MgO, B
2O
32 parts, Al
2O
30.3 part, Fe
2O
30.3 part, Na
2O+K
20.4 part of O; 1900～2000 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 6～10 μ m; Length 150～250mm; Slag ball content 5～12%; Solubility 150～250mg/L.
53 parts of soluble fibres, 17 parts of silicon dioxide gel and/or silicate of soda, 5 parts starch and/or cassavas, 22 parts of expanded perlite or clays, 3 parts of other materials.
Other materials is reinforcing fibre (string and/or a short glass fiber); Anti-blushing agent (solid paraffin and/or rosin acid are received); Anticorrisive agent (boric acid and/or bisnaphthol).
The soluble fibre granulation, granularity 10～15mm, slag ball content 4～5%; Cotton pulp is than 6.5%; Moisture content 100～110%, 300～350 ℃/50～100min are done to moisture content 0.85%; 100～120 ℃/10～15min of redrying.
The quality of plate: bulk density 250～300kg/m
3Flexural strength: 0.7～1.0Mpa; Moisture content: 0.5%; Flammable: the A level is not fired; Coefficient of thermal conductivity: normal temperature 0.035-0.042W/m.k; Average sound absorption coefficient (125HZ-4000HZ): 0.45～0.7; Solubility: 100～250mg/L (with the assay method of above-mentioned soluble fibre); All the other are with example 1.
Embodiment 10
Fibre furnish (kg): SiO
280 parts, 17 parts of CaO+MgO, B
2O
32 parts, Fe
2O
30.5 part, Na
2O+K
2O0.5 part; 1900～2000 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 3～6 μ m; Length 100～250mm; Slag ball content 5～14%; Solubility 100～240mg/L.
Plate proportioning: 53 parts of soluble fibres, 12 parts of silicon dioxide gels, 3 parts of starch and/or polyvinyl alcohol, 5 parts starch and/or cassavas, 23 parts of expanded perlite or clays, 4 parts of other materials.
Other materials is reinforcing fibre (string and/or a short glass fiber); Anti-blushing agent (solid paraffin and/or rosin acid are received); Anticorrisive agent (boric acid and/or bisnaphthol).
The soluble fibre granulation, granularity 16～20mm, slag ball content 3～4%; Cotton pulp is than 9.5%; Moisture content 100～110%, 300～350 ℃/50～100min are done to moisture content 0.5%; 100～120 ℃/10～15min of redrying.
The quality of plate: bulk density 300～350kg/m
3Flexural strength: 0.7～1.0Mpa; Moisture content: 0.5%; Flammable: the A level is not fired; Coefficient of thermal conductivity: normal temperature 0.035～0.042W/m.k; Average sound absorption coefficient (125HZ-4000HZ): 0.45～0.7; Solubility: 100～250mg/L (with the assay method of above-mentioned soluble fibre); All the other are with example 1.
Claims (6)
1. inorganic silicate fiber sound absorption plate that dissolves in human body fluid is characterized in that:
(1) this acoustical board predominant quantity percentage composition is:
Soluble fibre 30～60%
Inorganic bonding agent 10～20%
Organic bond 3～5%
Filler 10～40%
Other materials 3～9%;
(2) described soluble fibre is the inorganic silicate fiber that dissolves in human body fluid, and the weight percent of this fiber consists of:
SiO
2 56～85％
CaO+MgO 11～40％
B
2O
3 1～2％
Al
2O
3 0～1％
Fe
2O
3 0～0.5％
Na
2O+K
2O 0～0.5％。
2. according to the described inorganic silicate fiber sound absorption plate that dissolves in human body fluid of claim 1, it is characterized in that described inorganic bonding agent is silicon dioxide gel, alumina sol, silicate of soda and/or aluminum sulfate.
3. according to the described inorganic silicate fiber sound absorption plate that dissolves in human body fluid of claim 1, it is characterized in that described organic bond is starch, polyvinyl alcohol, carboxymethyl cellulose, cassava and/or acorn nut powder.
4. according to the described inorganic silicate fiber sound absorption plate that dissolves in human body fluid of claim 1, it is characterized in that described filler is clay, kieselguhr and/or expanded perlite.
5. according to the described inorganic silicate fiber sound absorption plate that dissolves in human body fluid of claim 1, it is characterized in that described other materials is reinforcing fibre, anti-blushing agent and anticorrisive agent; Wherein: reinforcing fibre is string and/or short glass fiber; Anti-blushing agent is that solid paraffin and/or rosin acid are received; Anticorrisive agent is boric acid, sodium pentachlorophenate and/or bisnaphthol.
6. according to the described preparation method that dissolves in the inorganic silicate fiber sound absorption plate of human body fluid of claim 1, it is characterized in that soluble fibre is material of main part and granulation, the binding material that adds proportional quantity is joined slurry slurrying, processes through moulding, drying, surfacing cutting, embossing, smart cutting process;
The step of preparation method is as follows:
(1) fiber granulation: with the soluble fibre granulation, the granularity of granulated wool is 5～20mm, and its slag ball content is 0～5%;
(2) join slurry slurrying: granulated wool and binding material are mixed in required ratio, be stirred to slurry and be suspension, cotton pulp is than≤10%;
(3) moulding: be molded on the fourdrinier and carry out, comprise approach flow, vacuum suction filter dehydration or suction press dehydration and liquid drugs injection cutting part;
(4) drying: the wet mat moisture content is 100～120%, dry 50～150min between 100～350 ℃;
(5) cutting, facing: machine cuts becomes slab, the surface plane planing, and surperficial sprayed coating,
(6) redrying: through the slab of surface spraying, at 100～120 ℃, dry 1～15min;
(7) embossing, machine cuts become accurate finished size, promptly.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200310105699XA CN1308559C (en) | 2003-11-24 | 2003-11-24 | Human body fluid soluble inorganic ceramic fiber sound absorption board and process of production |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200310105699XA CN1308559C (en) | 2003-11-24 | 2003-11-24 | Human body fluid soluble inorganic ceramic fiber sound absorption board and process of production |
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| CN1544771A CN1544771A (en) | 2004-11-10 |
| CN1308559C true CN1308559C (en) | 2007-04-04 |
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| JP5022512B1 (en) * | 2011-12-01 | 2012-09-12 | ニチアス株式会社 | Amorphous composition |
| CN104562701A (en) * | 2015-01-05 | 2015-04-29 | 芜湖环瑞汽车内饰件有限公司 | Ferric oxide-polyurethane composite emulsion-coated polypropylene-based non-woven sound-absorbing material for automotive interiors |
| CN107434371A (en) * | 2016-05-25 | 2017-12-05 | 北新集团建材股份有限公司 | A kind of mineral wool sound absorption board of anti-electromagnetic radiation and preparation method thereof |
| CN107986768B (en) * | 2017-12-12 | 2020-12-11 | 山东鲁阳节能材料股份有限公司 | Soluble fiber, soluble fiber board and preparation method thereof |
| CN111807857A (en) * | 2020-07-06 | 2020-10-23 | 山东民烨耐火纤维有限公司 | Novel porous composite silicate heat-insulating material and preparation method thereof |
| CN112608123A (en) * | 2020-12-16 | 2021-04-06 | 山东鲁阳节能材料股份有限公司 | Biological environment-friendly inorganic board and preparation method thereof |
| CN116334957A (en) * | 2021-12-15 | 2023-06-27 | 山东鲁阳节能材料股份有限公司 | Soluble fiber paper and preparation method thereof |
| CN115679746B (en) * | 2022-11-02 | 2024-04-05 | 山东鲁阳节能材料股份有限公司 | Soluble fiber paper and preparation method thereof |
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|---|---|---|---|---|
| JPH0482712A (en) * | 1990-07-25 | 1992-03-16 | Aisin Takaoka Ltd | Sound-insulating material |
| US5122559A (en) * | 1990-09-13 | 1992-06-16 | Basf Aktiengesellschaft | Lightweight building board |
| CN1160624A (en) * | 1996-03-28 | 1997-10-01 | 刘清明 | Production method of composite color fibreboard |
| EP0878589A2 (en) * | 1997-05-14 | 1998-11-18 | Arne Petersohn | Method for manufactoring a sound absorbing element for buildings |
| CN1267646A (en) * | 1999-12-23 | 2000-09-27 | 崔申 | Multifunctional sound-absorbing expanded perlite board and its production process |
| CN1340480A (en) * | 2000-09-01 | 2002-03-20 | 山东鲁阳股份有限公司 | Mechanically made ceramic fibre plate |
| CN1385388A (en) * | 2002-06-06 | 2002-12-18 | 山东鲁阳股份有限公司 | Ceramic fibre thermal-insulating boara and making method thereof |
-
2003
- 2003-11-24 CN CNB200310105699XA patent/CN1308559C/en not_active Expired - Lifetime
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0482712A (en) * | 1990-07-25 | 1992-03-16 | Aisin Takaoka Ltd | Sound-insulating material |
| US5122559A (en) * | 1990-09-13 | 1992-06-16 | Basf Aktiengesellschaft | Lightweight building board |
| CN1160624A (en) * | 1996-03-28 | 1997-10-01 | 刘清明 | Production method of composite color fibreboard |
| EP0878589A2 (en) * | 1997-05-14 | 1998-11-18 | Arne Petersohn | Method for manufactoring a sound absorbing element for buildings |
| CN1267646A (en) * | 1999-12-23 | 2000-09-27 | 崔申 | Multifunctional sound-absorbing expanded perlite board and its production process |
| CN1340480A (en) * | 2000-09-01 | 2002-03-20 | 山东鲁阳股份有限公司 | Mechanically made ceramic fibre plate |
| CN1385388A (en) * | 2002-06-06 | 2002-12-18 | 山东鲁阳股份有限公司 | Ceramic fibre thermal-insulating boara and making method thereof |
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| Publication number | Publication date |
|---|---|
| CN1544771A (en) | 2004-11-10 |
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Address after: 256120 Shandong city of Zibo province Yiyuan County Yi River Road No. 11 Patentee after: LUYANG ENERGY-SAVING MATERIALS Co.,Ltd. Address before: 256120 Shandong city of Zibo province Yiyuan County Yi River Road No. 11 Patentee before: Shandong Luyang Share Co.,Ltd. |
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