CN1306412A - Hair conditioning compsn. comprising poly & Alpha,-olefin oil - Google Patents
Hair conditioning compsn. comprising poly & Alpha,-olefin oil Download PDFInfo
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- CN1306412A CN1306412A CN98814102.7A CN98814102A CN1306412A CN 1306412 A CN1306412 A CN 1306412A CN 98814102 A CN98814102 A CN 98814102A CN 1306412 A CN1306412 A CN 1306412A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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Abstract
Disclosed is a conditioning shampoo composition comprising by weight: poly α-olefin oils derived from 1-alkene monomers having from about 6 to about 16 carbons, the poly & alpha;-olefin oils having a viscosity of from about 1 to about 35,000 cst, a molecular weight of from about 200 to about 60,000, and a polydispersity of no more that about 3; an additional conditioning agent selected from the group consisting of hydrophilically substituted cationic surfactants, amines, high melting point compounds, and mixtures thereof, and an aqueous carrier.
Description
Technical field
The present invention relates to Wo 2008069000, this Wo 2008069000 comprises selected poly ﹠ Alpha ,-olefin oil and additional conditioner.
Background of invention
Because hair contacts with surrounding and the scalp sebum secreted, so that people's hair can become is dirty.The dirty of hair makes it have dirty and oily sensation, brings the outward appearance that lacks captivation.Dirty the needing regularly of hair washed hair.
Hair washing is cleaned hair by removing excessive dirt and sebum.But hair washing can make hair be in wet, disorderly and be difficult to the state handled usually.In case hair has been done, will make hair be in drying, thick groove, tarnish or rolled state owing to the natural oil of hair and other natural conditioning and moistening composition are removed.In addition, because the dry static content of hair that makes increases, this can hinder combs one's hair and makes hair be in the state of alleged " hair flies upward (fly-away hair) " usually; Perhaps bring a kind of undesirable " terminal fork (split ends) " phenomenon, especially true to long hair.
For alleviating these hair washings problem afterwards, various methods have been developed.These methods are used hair conditioner such as leave (leave-on) and wash type (rinse-off) product after hair washing, extremely lean on single product to clean hair conditioning shampoo with conditioning hair simultaneously.Although some consumers like comprising conditioner shampoo easily and convenience, the more conventional conditioner dosage form of hair is liked being used for step by step by most of consumer, it uses after hair washing usually.Conditioner preparation can be the form of wash type product or leave product, can be the form of Emulsion, cream, gel, spray and mousse.The convenience that those like the consumer of conventional conditioner dosage form to pay attention to higher relatively conditioning effect or nurse one's health quantity according to the situation or the section change of hair.
The conventional method that is of value to conditioning hair is to use hair conditioner, as cationic surfactant and polymer, silicone conditioning agent, hydrocarbon ils and aliphatic alcohol.
Known cationic surfactant, polymer, hydrocarbon ils and aliphatic alcohol can strengthen the gloss of hair, for hair provides humidity, flexibility and antistatic behaviour.But these components are also brought to hair and are clamminess or the sensation of greasy or waxiness, and are especially true when dry right overhead.Know that also silicone conditioning agent can bring conditioning benefit such as smooth and be easy to combing, this is because the surface tension of silicone compounds is low.But silicone conditioning agent can bring exsiccant sensation of hair or disorderly state again, when dry right overhead especially like this.
Based on foregoing, a kind of Wo 2008069000 need be provided, this Wo 2008069000 not only all can provide improved conditioning benefit in the hair damp-arthralgia but also when hair is done.Specifically, when dry right overhead, need provide long-term moistening sensation, smooth sensation and the processing controls (manageability control) that continues to hair, and not make hair feel greasy.
There is not prior art that whole advantage of the present invention and benefit can be provided.
Summary of the invention
The present invention relates to a kind of Wo 2008069000, said composition comprises:
(1) poly ﹠ Alpha ,-olefin oil is derived to the 1-olefinic monomer of about 16 carbon atoms by having about 6; This poly alpha olefin oil viscosity is about 1 to about 35000 centistokes (cst), and molecular weight is about 200 to about 60000, and polydispersity (polodispersity) is no more than about 3;
(2) additional conditioner is selected from cationic surfactant, amine, high melting compound that hydrophiling replaces, and their mixture; With
(3) aqueous carrier.
Of the present invention open by reading, those skilled in the art can clearly understand these and other feature of the present invention, characteristics and advantage.
Detailed Description Of The Invention
Although description of the present invention finishes with claims, requirement of the present invention is pointed out and clearly stated to these claims especially, can believe, will be better understood the present invention by following description.
The document of all references is all introduced the present invention as a reference in full.Quoting of any document is not to admit that the document can be as any decision of prior art of the present invention.
In the present invention, except as otherwise noted, " comprising " is meant and can adds other step and other composition that does not influence final result.This term comprised term " by ... form " and " basically by ... composition ".
Except as otherwise noted, all percent, umber and ratio all is based on the gross weight of compositions of the present invention.When relating to the composition of listing, therefore all these weight do not comprise the carrier or the by-product that may comprise in the industrial materials all by live vol.
Characteristics of the present invention and the embodiment stated in this file have lot of advantages.Care composition for example of the present invention provides long-term moistening sensation, smooth sensation and the processing controls that continues when hair is done, and does not make hair feel greasy.The product type that Wo 2008069000 of the present invention is suitable for remaining on the hair or falls from the hair upper punch.
Poly ﹠ Alpha ,-olefin oil
Wo 2008069000 of the present invention comprises poly ﹠ Alpha ,-olefin oil.In the present invention, poly ﹠ Alpha ,-olefin oil provides conditioning benefit when hair is done, as moistening sensation, smooth sensation and processing controls, and do not make hair feel greasy.
By weight, the content of the poly ﹠ Alpha ,-olefin oil in the present composition is preferably about 0.1% to about 20%, is preferably about 0.2% to about 10%, more preferably about 0.5% to about 5%.
Among the present invention used poly ﹠ Alpha ,-olefin oil be by the 1-olefinic monomer derive and come those, wherein the 1-olefinic monomer have about 6 to about 16 carbon atoms, preferably have about 6 to about 12 carbon atoms.The non-limiting example of the 1-olefinic monomer that the preparation poly ﹠ Alpha ,-olefin oil is used comprises 1-hexene, 1-octene, 1-decene, 1-dodecylene, tetradecene, cetene, the isomer of collateralization such as 4-methyl-1-pentene, and their mixture.The used 1-olefinic monomer of preferred preparation poly ﹠ Alpha ,-olefin oil is 1-octene, 1-decene, 1-dodecylene, tetradecene, cetene, and their mixture.In addition, used poly alpha olefin oil viscosity is about 1 to about 35000 centistokes among the present invention, and molecular weight is about 200 to about 60000, and polydispersity is no more than about 3.
In the present invention, to be at least about 800 poly ﹠ Alpha ,-olefin oil be useful to molecular weight.Be sure of that these high-molecular weight poly ﹠ Alpha ,-olefin oils can make hair have the long-term moistening sensation that continues.In the present invention, molecular weight is that to be lower than about 800 poly ﹠ Alpha ,-olefin oil be useful.Be sure of that these low-molecular-weight poly ﹠ Alpha ,-olefin oils can make hair have sensation smooth, bright, cleaning.
In the present invention, useful especially poly ﹠ Alpha ,-olefin oil comprises the poly decene of the commodity PURESYN 6 by name of number-average molecular weight about 500, the poly decene of the commodity PURESYN 300 by name of the poly decene of the commodity of number-average molecular weight about 3000 PURESYN 100 by name and number-average molecular weight about 6000 can obtain from Mobil Chemical company.
Additional conditioner
Compositions of the present invention comprises additional conditioner, and this conditioner is selected from cationic surfactant, amine, high melting compound and their mixture that hydrophiling replaces.
In the present invention, described additional conditioning agents be generally based on composition weight at least about 1%, preferred about 1% to about 20%, more preferably from about 1% to about 10%.
The cationic surfactant that hydrophiling replaces
In the present invention, the cationic surfactant of hydrophiling replacement is useful.The cationic surfactant that hydrophiling of the present invention replaces comprises that those comprise the cationic surfactant of two hydrophilic segments at least, wherein at least one substituent group in the molecule is selected from ether-ether, amide groups or the amino part of aromatics, and at least one substituent group is selected from alkoxyl (preferred C
1-C
3Alkoxyl), polyoxyalkylene (preferred C
1-C
3Polyoxyalkylene), alkylamidoalkyl, hydroxy alkyl and alkyl group.The cationic surfactant that hydrophiling of the present invention replaces preferably comprises 2 to about 10 nonionic hydrophilic segments.
In the present invention, the cationic surfactant that hydrophiling replaces provides conditioning benefit, as it is smooth that hair feel is got up, and is especially true when hair is done.Believe that the cationic surfactant by hydrophiling is replaced combines with above-mentioned high molecular ester oil, can obtain a kind of care composition, this care composition when hair is wet and hair the conditioning benefit of improvement all can be provided when dried.
By weight, the content of the cationic surfactant that included hydrophiling replaces in the present composition is preferably about 0.1% to about 20%, is preferably about 0.2% to 10%, more preferably about 1% to about 5%.
The cationic surfactant that suitable hydrophiling replaces comprises the cationic surfactant of following formula II to the hydrophiling replacement of (VIII):
N wherein
1Be 8 to about 28; m
1+ m
2Be 2 to about 40; Z
1Be short-chain alkyl, preferred C
1-C
3Alkyl, more preferably methyl or (CH
2CH
2O)
M3H, wherein m
1+ m
2+ m
3Be up to 60; X is for becoming salt ion, as is selected from the one-tenth salt ion of halogen (as chlorine, bromine), acetate, citrate, lactate, glycolic root, phosphate radical, nitrate anion, sulfonate radical, sulfate radical, alkyl sulfate and alkyl azochlorosulfonate;
N wherein
2Be 1 to 5; R
105, R
106And R
107In one or more be C independently
1-C
30Alkyl, that remaining is CH
2CH
2OH; R
108, R
109And R
110In one or two be C independently
1-C
30Alkyl, that remaining is CH
2CH
2OH; X is as mentioned above the same, for becoming salt ion;
Wherein, for formula IV and formula (V), Z
2Be alkyl independently, preferred C
1-C
3Alkyl, more preferably methyl; Z
3Be the short chain hydroxyalkyl independently, preferred methylol or ethoxy; n
3And n
4Be 2 to 4 integer (containing 2 and 4) independently, preferred 2 to 3 integer (containing 2 and 3), more preferably integer 2; R
111And R
112Independently for replace or unsubstituted alkyl, C
12-C
20Alkyl or alkenyl; X is as defined above, for becoming salt ion;
R wherein
113Be alkyl, preferred C
1-C
3Alkyl, more preferably methyl; Z
4And Z
5Be short-chain hydrocarbon group independently, preferred C
2-C
4Alkyl or alkenyl, more preferably ethyl; m
4Be 2 to about 40, preferred about 7 to about 30; X is as defined above, for becoming salt ion;
R wherein
114And R
115Be C independently
1-C
3Alkyl, preferable methyl; Z
6Be C
12-C
22Alkyl, alkyl-carbonyl or alkylamidoalkyl; A is a protein, preferred collagen protein, keratin, cow's milk protein silkworm silk, soybean protein, wheat protein or their hydrolysed form; X is as defined above, for becoming salt ion;
N wherein
5Be 2 or 3; R
116And R
117Be C independently
1-C
3Alkyl, preferable methyl; X is as defined above, for becoming salt ion.The non-limiting example that can be used for the cationic surfactant of hydrophiling replacement of the present invention comprises the material with following CTFA title: quaternium-16, quaternium-26, quaternium-27, quaternium-30, quaternium-33, quaternium-43, quaternium-52, quaternium-53, quaternium-56, quaternium-60, quaternium-61, quaternium-62, quaternium-70, quaternium-71, quaternium-72, quaternium-75, the quaternium-76 hydrolytic collagen, quaternium-77, quaternium-78, the quaternium-79 hydrolytic collagen, the quaternium-79 hydrolysis of keratin, the quaternium-79 lactoalbumin hydrolysate, the quaternium-79 hydrolyzed-silk, quaternium-79 hydrolyzed soybean protein and quaternium-79 hydrolyzed wheat protein, quaternium-80, quaternium-81, quaternium-82, quaternium-83, quaternium-84 and their mixture.
The cationic surfactant that particularly preferred hydrophiling replaces comprises dialkyl amide base ethyl-hydroxyethyl methyl ammonium salt (dialkylamido ethyl hydroxyethylmonnium salt), dialkyl amide base ethyl dimethyl ammonium (dialkylamidoethyl dimonium salt), two alkanoyl ethyl-hydroxyethyl methyl ammonium salts, two alkanoyl ethyl dimethyl ammoniums and their mixture; Following industrial goods of trade name for example: the VARISOFT 110 that originates from Witco Chemical, VARISOFT 222, VARIQUATK1215 and VARIQUAT638, originate from the MACKPROKLP of Mclntyre, MACKPROWLW, MACKPRO MLP, MACKPRO NSP, MACKPRO NLW, MACKPRO WWP, MACKPRO NLP and MACKPRO SLP, originate from the ETHOQUAD 18/25 of Akzo, ETHOQUAD O/12PG, ETHOQUAD C/25, ETHOQUAD S/25 and ETHODUOQUAD, originate from the DEHYQUAT SP of Henkel, and the ATLAS G265 that originates from ICI Americas.
Amine
Amine can be used as a kind of additional conditioning agents.The primary, the second month in a season and uncle's fatty amine are useful.Teritary amide base amine with alkyl group of about 12 to 22 carbon is useful especially.Exemplary teritary amide base amine comprises: stearamidopropyldime.hylamine, stearoyl amido propyl group diethylamide, stearoyl amido ethyl diethylamide, stearoyl amido ethyl dimethyl amine, palmityl amido propyl-dimethyl amine, palmityl amido propyl group diethylamide, palmityl amido ethyl diethylamide, palmityl amido ethyl dimethyl amine, two lauroyl amido propyl-dimethyl amines, two lauroyl amido propyl group diethylamides, two lauroyl amido ethyl diethylamides, two lauroyl amido ethyl dimethyl amines, Semen arachidis hypogaeae amidopropyl dimethyl amine, Semen arachidis hypogaeae amidopropyl diethylamide, Semen arachidis hypogaeae amido-ethyl diethylamide, Semen arachidis hypogaeae amido-ethyl dimethyl amine, diacetylamino ethyl stearmide.Also useful (with 5 moles oxirane) stearylamine, dihydroxy ethyl stearic amine and Semen arachidis hypogaeae base docosyl amine that dimethyl stearic amine, dimethyl soybean-based amine, Semen sojae atricolor amine, Semen Myristicae amine, tridecyl amine, ethyl stearic amine, N-tallow propanediamine, ethoxylation are arranged.The US4275055 that authorizes people such as Nachtigal discloses useful in the present invention amine.
These amine can also and the acid use that combines, described acid has L-glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, fumaric acid, tartaric acid, citric acid, L-glutamic acid hydrochloride, maleic acid and their mixture; More preferably L-glutamic acid, lactic acid, citric acid.Amine of the present invention is preferably used any acid, is about 1: 0.3 to about 1: 2 by the mol ratio of amine and acid, more preferably partly neutralizes to about 1: 1 mol ratio by about 1: 0.4.
High melting compound
High melting compound can be used as a kind of additional conditioner.The fusing point of high melting compound of the present invention is at least about 25 ℃, and is selected from aliphatic alcohol, fatty acid, fatty alcohol derivative, derivative of fatty acid, hydrocarbon, steroid and their mixture.It will be obvious to those skilled in the art that at this a part of disclosed chemical compound of this description to be grouped into a more than apoplexy due to endogenous wind in some cases, for example some fatty alcohol derivatives also can belong to the derivative of fatty acid apoplexy due to endogenous wind.But given classification is not to plan concrete chemical compound is limited, and why does like this, just classification for convenience and name.In addition, those of ordinary skill in the art understands that also because the length of the number of two keys and position, side chain and position is different, some fusing point with chemical compound of definite carbon number may be lower than about 25 ℃.This part does not plan to comprise this low-melting compound.Can be at the 5th edition International CosmeticIngredient Dictionary in 1993 and the indefiniteness example of finding high melting compound of the present invention in 1992 among the 2nd edition the CTFA Cosmetic IngredientHandbook.
Believe that these high melting compounds cover the surface of hairs and reduce friction, therefore make hair feel get up smooth and be easy to combing.
By weight, the content of included high melting compound is preferably about 1% to about 14% in the present composition, and more preferably from about 3% to about 10%, and most preferably from about 4% to about 8%.
Here used is to have about 14 aliphatic alcohol to about 30 carbon atoms, preferred about 16 aliphatic alcohol to about 22 carbon atoms.These aliphatic alcohol can be straight chain or side chain also can be saturated or unsaturated.The indefiniteness example of aliphatic alcohol comprises hexadecanol, octadecanol, tadenan and their mixture.
In the present invention, useful aliphatic alcohol is that those have about 10 aliphatic alcohol to about 30 carbon atoms, preferred about 12 aliphatic alcohol to about 22 carbon atoms, more preferably from about 16 aliphatic alcohol to about 22 carbon atoms.These aliphatic alcohol can be straight chain or side chain also can be saturated or unsaturated.Comprise that also those meet the binary acid of requirement of the present invention, ternary acid and other polyprotic acid, also comprise the salt of these fatty acids here.The indefiniteness example of fatty acid comprises lauric acid, Palmic acid, stearic acid, behenic acid, decanedioic acid and their mixture.
In the present invention, but useful fatty alcohol derivative and derivative of fatty acid comprise fatty acid that the alkyl ether of the alkyl ether of aliphatic alcohol, oxyalkylated aliphatic alcohol, alkoxy fatty alcohols, the ester of aliphatic alcohol, the fatty acid ester with chemical compound of esterified hydroxy groups, hydroxyl replace and their mixture.The indefiniteness example of fatty alcohol derivative and derivative of fatty acid comprises material such as methyl stearyl ether; Ceteth (ceteth) series compound, as ceteth-1 to ceteth-45, these chemical compounds are glycol ethers of hexadecanol, Digital ID is wherein represented the ethylene glycol number that exists; Octadecyl polyoxyethylene ether (steareth) series compound, as steareth-1 to steareth-10, these chemical compounds are glycol ethers of octadecanol, Digital ID is wherein represented the ethylene glycol number that exists; (16/octadecyl polyoxyethylene ether) ceteareth-1 to ceteareth-10, these chemical compounds are glycol ethers of 16/octadecanol (fatty alcohol mixture that promptly mainly contains hexadecanol and octadecanol), and Digital ID is wherein represented the ethylene glycol number that occurs; The C of the compound c eteth that had just described above, steareth and ceteareth
1-C
30Alkyl ether; The polyoxyethylene ether of tadenan; Ethyl stearte, the stearic acid hexadecyl ester, cetyl palmitate, stearyl stearate, myristyl myristate, polyoxyethylene palmityl ether stearate, polyoxyethylene octadecyl ether stearate, the polyoxyethylene lauryl ether stearate, ethylene glycol monostearate, polyoxyethylene monostearate, the polyoxyethylene distearate, propylene glycol monostearate, the propylene glycol distearate, the trimethylolpropane distearate, sorbitan stearate, poly-tristerin, glyceryl monostearate, glycerol distearate, glycerol tristearate and their mixture.
Used hydrocarbon comprises the chemical compound that has at least about 20 carbon atoms among the present invention.
Used steroid comprises as cholesteric chemical compound among the present invention.
Preferred single high pure compound is as high melting compound.The pure fat alcohol unification compound that is selected from pure hexadecanol, octadecanol and docosanol is particularly preferred.Here, it is about 90% that the meaning of " pure " is meant that the purity of chemical compound is at least, preferably at least about 95%.When consumer when the hair supernatant is washed compositions of the present invention, these highly purified unification compounds provide good rinsability.
Industrial available high melting compound used among the present invention comprises: originate from Shin NihonRika (Osaka, Japan) commodity are called the series of KONOL and originate from NOF (Tokyo, hexadecanol, octadecanol and the docosanol of the series of the NNA by name of commodity Japan); Originate from WAKO (Osaka, the pure docosanol of the 1-DOCOSANOL by name of commodity Japan); Originate from Akzo (ChicagoIllinois, USA) commodity NEO-FAT by name, originate from Witco company (Dublin Ohio, USA) commodity by name HYSTRENE's and originate from Vevy (Genova, Italy) the various fatty acids of commodity DERMA by name; And the cholesterol that originates from the commodity NIKKOL AGUASOME LA by name of Nikko.
Aqueous carrier
Compositions of the present invention comprises a kind of aqueous carrier.According to other characteristic of the compatibility of other component and desired product, select the consumption and the kind of described carrier.
Be used for the aqueous solution that carrier of the present invention comprises water and low-grade alkane alcohol and polyhydric alcohol.Here used low-grade alkane alcohol is the monohydric alcohol of 1 to 6 carbon atom, more preferably ethanol and isopropyl alcohol.Here used polyhydric alcohol comprises propylene glycol, hexanediol, glycerol and propane diol.
Preferred aqueous carrier mainly is a water.Preferably use deionized water.According to required product attribute, the natural water that contains inorganic cation also is operable.In general, compositions of the present invention contains 20% to about 95% the water of having an appointment, preferred about 30% to about 92% water, more preferably from about 50% to about 90% water.
Silicone compounds
Wo 2008069000 of the present invention can further comprise silicone compounds.Here used silicone compounds comprises soluble or insoluble silicone conditioning agent of volatile soluble or insoluble or fixedness." soluble " meaning is meant that this silicone compounds can be miscible to form a same part (homogeneous phase) mutually with the carrier of compositions." insoluble " meaning is meant that this silicone compounds forms a discontinuous phase that is independent of carrier, as the emulsion or the form of suspension of droplets of siloxane.The silicone compounds here can comprise that emulsion polymerization prepares by any suitable method as known in the art.Silicone compounds can also be sneaked into compositions of the present invention with the form of emulsion, wherein said emulsion is by means of the surfactant that is selected from anion surfactant, non-ionic surface active agent, cationic surfactant and their mixture, prepares by mechanical mixture; Or be in the emulsion of the synthesis phase of emulsion polymerisation.
Here the viscosity of used silicone compounds in the time of 25 ℃ is preferably about 1000 to about 2000000 centistokes, and more preferably from about 10000 to about 1800000 centistokes, and most preferably from about 100000 to about 1500000 centistokes.Can measure viscosity by glass capillary tube viscometer cited among the test method CTM0004 of Dow Corning company on July 20th, 1970.Can prepare high-molecular weight silicone compounds by emulsion polymerization.Suitable siloxanes liquid comprises poly-alkylsiloxane, poly-aryl siloxanes, polyoxyethylene alkyl aryl radical siloxane, polyether siloxane copolymer and their mixture.Other non-volatile siloxane chemical compound with conditioning performance also can use.
By weight, the content of included silicone compounds is preferably about 0.01% to about 20% in the compositions of the present invention, and more preferably from about 0.05% to about 10%.
Silicone compounds of the present invention also comprises poly-alkyl or the poly-aryl siloxanes with following array structure (I):
R wherein
123Be alkyl or aryl; X is about 7 to about 8000 integer.Z
8It is the group that is positioned at the siloxane chain end.If making the siloxanes that is produced at room temperature is liquid, it is dispersible to be, when being applied to hair not only nontoxic non-stimulated but also do not have nocuity, with compositions in other component compatibility, normal use and storage requirement under have chemical stability and can be deposited on the hair and conditioning hair, be replaced in (the R on the siloxane chain so
123) or (Z of siloxane chain end
8) the alkyl or aryl group can have any structure.Suitable Z
8Group comprises hydroxyl, methyl, methoxyl group, ethyoxyl, propoxyl group and aryloxy group.Two R on the silicon atom
123Group can be identical group or different groups.Preferred two R
123Group is identical group.Suitable R
123Group comprises methyl, ethyl, propyl group, phenyl, aminomethyl phenyl and phenyl methyl.Preferred silicone compounds is polydimethylsiloxane, poly-di-ethyl siloxane and PSI.Polydimethylsiloxane is also referred to as the poly dimethyl silicone, is particularly preferred.Spendable poly-alkylsiloxane comprises, for example, and polydimethylsiloxane.These silicone compounds are available, for example from the Viscasil of the General Electric Company and SF 96 series of products with from Dow Corning 200 series of products of Dow Corning.
Also can use polyoxyethylene alkyl aryl radical siloxane liquid to comprise for example PSI.These siloxanes are available, for example from the SF 1075 methylbenzene base fluids of the General Electric Company or from the 556 cosmetics-stage liquid of Dow Corning.
In order to strengthen the gloss characteristic of hair, the silicone compounds of special preferred heights arylation, as refraction index about 1.46 or higher, the poly-ethylsiloxane of refraction index about 1.52 or higher height phenylating particularly.When using the silicone compounds of these high refractive indexes, should be by they being mixed with spreading agent such as surfactant or silicone resin as described in following, to reduce the film forming ability of surface tension and reinforcing material.
Spendable silicone compounds also comprises, the polydimethylsiloxane of polypropylene oxide modification for example can certainly use the polydimethylsiloxane of the mixture modification of ethylene oxide or ethylene oxide and propylene oxide.The amount of ethylene oxide and propylene oxide is enough low, not hinder the dispersibility characteristic of siloxanes.These materials are also referred to as the alkoxylate polydimethylsiloxane.
Other silicone compounds comprises the amino siloxanes that replaces.The silicone compounds that suitable alkyl amino replaces comprises those with following array structure (II):
R wherein
124Be H, CH
3Or OH, p
1, p
2, q
1And q
2Be the integer that depends on molecular weight, mean molecule quantity is approximate between 5000 and 10000.This polymer is also referred to as " amodimethicone ".
Suitable amino replacement siloxanes liquid comprises those of following formula III representative:
(R
125)
aG
3-a-Si-(OSiG
2)
p3-(OSiG
b(R
125)
2-b)
p4-O-SiG
3-a(R
125)
a(Ⅲ)
Wherein G is selected from hydrogen, phenyl, OH, C
1-C
8Alkyl and preferable methyl; A represents 0 or 1 to 3 integer, and preferred 0; B represents 0 or 1 also preferably to equal 1; p
3With p
4Sum is 1 to 2000 number, and preferred 50 to 150, p
3Can represent 0 to 1999 integer and preferred 49 to 149, p
4Can represent 1 to 2000 integer and preferred 1 to 10; R
125For suc as formula C
Q3H
2q3The univalent perssad of L, wherein q
3Be 2 to 8 integer, L is selected from following group
-N(R
126)CH
2-CH
2-N(R
126)
2
-N(R
126)
2
-N(R
126)
3X′
-N(R
126)CH
2-CH
2-NR
126H
2X′；
R wherein
126Be selected from hydrogen, phenyl, benzyl, saturated alkyl, preferably contain the alkyl group of 1 to 20 carbon atom, and X ' expression halogen ion.
Particularly preferred amino corresponding to formula III replaces siloxanes, is known as " trimethylsilylamodimethicone " polymer, R wherein
124Be methyl.
Other the spendable amino siloxane polymer that replaces is suc as formula shown in (V):
R wherein
128Representative has the univalent hydrocarbyl group of 1 to 18 carbon atom, and preferred alkyl or kiki alkenyl group are as methyl; R
129The representation hydrocarbyl group, preferred C
1-C
18Kiki alkenyl group or C
1-C
18, more preferably C
1-C
8Alkenyloxy group; Q-is the halogen ion, preferred chloride ion; p
5Representative from 2 to 20 preferred 2 to 8 assembly averages; p
6Representative from 20 to 200 and preferred 20 to 50 assembly average.Such preferred polymer is called the polymer of " UCARSILICONE ALE 56 " from Union Carbide, name.
The list of references of open suitable nonvolatile dispersive silicone compounds comprises No. the 849433rd, the British patent that the US that authorizes Geen gave the US 3964500 of Drakoff, authorizes the US 4364837 of Pader and authorize Woolston on June 22 in 2826551,1976.PetrarchSystems company provides the inventory of (but be not exclusive) widely suitable silicone compounds in " Silicon Compounds (silicon compound) " of distribution in 1984.
Another kind of may useful especially nonvolatile dispersive siloxanes be silicone gum (siliconegum).Terminology used here " silicone gum " is meant a kind of polysiloxane material, its viscosity in the time of 25 ℃ more than or equal to 1000000 centistokes.Some is overlapping for silicone gum described herein as can be seen and aforesaid silicone compounds possibility.This overlapping be not to plan to any restriction the in these materials.Silicone gum is described in Petrarch and other document and comprises US 4152416 and the Noll that authorized people such as Spitzer on May 1st, 1979, the Chemistryand Technology of Silicones that Walter showed, New York:Academic Press 1968.General Electric Silicone Rubber Product Data SheetsSE30, SE33, SE54 and the SE76 in addition of silicone gum are described in addition.Typically the bulk molecule amount of " silicone gum " (massmolecular weight) surpass about 200000, generally between about 200000 to about 1000000.The instantiation of this material comprises polydimethylsiloxane, poly-(dimethyl siloxane, ethylene methacrylic radical siloxane) copolymer, poly-(dimethyl siloxane, diphenyl siloxane, ethylene methacrylic radical siloxane) copolymer and their mixture.
For the silicone resin (silicone resin) of highly cross-linked polymer siloxane system also is useful.This crosslinked be in making the process of silicone resin, by what trifunctional or four functional silane and simple function or two functional silane or simple function and two functional silane blending were introduced.Fine in the art understanding will change with sneaking into the unitary variation of silane specific in this silicone resin for obtaining the needed degree of cross linking of silicone resin.In general, have the trifunctional and the four functional silicone monomeric units of q.s, thereby have enough crosslinking degrees, just be considered to silicones so that become the silicone compositions of rigidity or hard thin film after the drying.For concrete silicone compositions, the oxygen atom wherein and the ratio of silicon atom are represented crosslinked level.Among the present invention, whenever have a silicon atom and be silicone resin usually with regard to the silicone compositions that has about 1.1 oxygen atoms at least.The preferred oxygen atom: the ratio of silicon atom was at least about 1.2: 1.0.Employed silane comprises monomethyl silane, dimethylsilane, trimethyl silane, single phenyl silane, diphenyl silane, aminomethyl phenyl silane, mono-vinyl silane, methyl ethylene chlorosilane and tetrachloro for silane when making silicone resin, and the most frequently used is methyl substituted silane.Preferred resin is GE SS4230 and the SS4267 that General Electric provides.Usually, commercially available silicone resin is to provide with the form of being dissolved into low viscous volatilization or non-volatile siloxanes liquid.Here used silicone resin provides and sneaks in the compositions of the present invention with this dissolved form, and this is clearly for the ordinary skill in the art.Be not limited to theory, can believe that silicone resin can strengthen the gloss that the deposition of other silicone compounds on hair also can strengthen hair with high refractive index.
Other useful silicone resin is the silicone resin powder, the material of the called after polymethylsilsequioxane that provides as CTFA, its on market by Toshiba Silicones with Tospearl
TMSell.
The method of making these silicone compounds is found in Encyclopedia of Polymer Scienceand Engineering, and Volume 15, Second Edition, PP.204-308, John Wiley﹠amp; Sons, Inc., 1989.
Especially, can discern silicone compositions and silicone resin easily, " MDTQ " nomenclature that those skilled in the art know that Here it is according to writing a Chinese character in simplified form nomenclature.In this nomenclature, this siloxanes is described according to the various siloxanyl monomers unit of existing this siloxanes of formation.Say that simply symbol M is represented simple function unit (CH
3)
3SiO
0.5D represents two functional unit (CH
3)
2SiO; T represents trifunctional units (CH
3) SiO
1.5Q represents four functional unit SiO
2Apostrophe on the unit symbol as the substituent group of M ', D ', T ' and the non-methyl of Q ' expression, and specifically defines when occurring at every turn.Typical alternative substituent group comprises vinyl, phenyl, amino, hydroxyl etc.In the MDTQ nomenclature, various unitary mol ratios, perhaps represent, perhaps represent, thereby finished description silicone compositions with concrete indicated ratio in conjunction with molal weight with footnote under the symbol of every kind of unit sum (or its average) in the expression siloxanes.In silicone resin, if T, Q, T ' and/or Q ' than the relative molecular weight height of D, D ', M and/or M ', just represent crosslinked level height.But, as previously mentioned, also can represent crosslinked aggregate level to the ratio of silicon with oxygen.
Here used silicone resin, preferred MQ, MT, MTQ, MQ and MDTQ resin.Therefore, preferred siloxanes substituent group is a methyl.The ratio of preferred especially MQ resin, wherein M: Q is about 0.5: 1.0 to about 1.5: 1.0, and the mean molecule quantity of this resin is about 1000 to about 10000.
Silicone compounds industrial goods used in the present invention comprise the polydimethylsiloxane of commodity D-130 by name, the cetyl polydimethylsiloxane of commodity DC2502 by name, octadecyl polydimethylsiloxane, commodity DC1664 by name and the emulsifying polydimethylsiloxane of DC1784 and the alkyl graft copolymerization silicone emulsion of commodity DC2-2845 by name that commodity are called DC2503; These materials all can obtain from Dow Corning company, and the polydimethylsiloxane of emulsion polymerisation can be applied for describedly obtaining from Toshiba Silicone like that by GB2303857.
Additional component
Wo 2008069000 of the present invention can contain multiple annexing ingredient, and these annexing ingredients can be selected according to the required characteristic of final products by those of ordinary skill in the art.Annexing ingredient comprises, for example dewatering cationic surfactant, cationic polymer, additional oiliness compound, non-ionic polymers and other annexing ingredient.
The dewatering cationic surfactant
Dewatering cationic surfactant used in the present invention is the known any dewatering cationic surfactant of those of ordinary skill in the art.
In the dewatering cationic surfactant, used in the present invention is dewatering cationic surfactant corresponding to following logical formula I:
R wherein
101, R
102, R
103And R
104In have at least one to be to be selected from aliphatic group or to have aromatic group, alkoxyl, polyoxyalkylene, alkylamidoalkyl, hydroxy alkyl, aryl or alkylaryl, remaining R up to about 22 carbon atoms with 8 to 30 carbon atoms
101, R
102, R
103And R
104Be independently selected from and have 1 to the aliphatic group of about 22 carbon atoms or have aromatic group, alkoxyl, polyoxyalkylene, alkylamidoalkyl, hydroxy alkyl, aryl or alkylaryl up to about 22 carbon atoms; And X is into salt anionic, as is selected from the one-tenth salt ion of halogen (as chlorine, bromine), acetate, citrate, lactate, glycolic root, phosphate radical, nitrate anion, sulfonate radical, sulfate radical, alkyl sulfate and alkyl azochlorosulfonate.Aliphatic group can also comprise ehter bond except that carbon atom and hydrogen atom and amino waits other group.The aliphatic group that chain is long, as have about 12 carbon atoms or more aliphatic group can be saturated also can be undersaturated.Preferred R
101, R
102, R
103And R
104Be C independently
1-C
22Alkyl.The non-limiting example of the dewatering cationic surfactant that the present invention is used comprises the material with following CTFA title: quaternium-8, quaternium-14, quaternium-18, quaternium-18 methyl ester sulfate (methosulfate), quaternium-24, and their mixture.
In having the dewatering cationic surfactant of logical formula I, preferably contain at least in those molecules one minimum be the cationic surfactant of the alkyl chain of 16 carbon.The non-limiting example of these preferred dewatering cationic surfactants comprises INCROQUAT TMC-80 ECONOL TM22, as originate from Croda commodity INCROQUAT TMC-80 by name product and originate from the product of the commodity ECONOL TM22 by name of Sanyo Kasei; Hexadecyltrimethylammonium chloride, as originate from the product of the commodity CA-2350 by name of Nikko Chemical; The hydrogenated tallow alkyl trimethyl ammonium chloride; dialkyl group (14-18) alkyl dimethyl ammonium chloride; two tallow alkyl alkyl dimethyl ammonium chlorides; dihydro tallow alkyl alkyl dimethyl ammonium chloride; VARISOFT TA100; two cetyl alkyl dimethyl ammonium chlorides; two (docosyl/Semen arachidis hypogaeae base) alkyl dimethyl ammonium chloride; two (docosyl) alkyl dimethyl ammonium chloride; the stearyl dimethyl benzyl ammonium chloride; stearyl propylene glycol phosphate ester alkyl dimethyl ammonium chloride; stearoyl amido propyl-dimethyl benzyl ammonium chloride; stearoyl amido propyl-dimethyl (acetic acid myristin) ammonium chloride, and N-(stearyl gallbladder carbamyl ylmethyl) pyridinium chloride.
Cationic polymer
Wo 2008069000 of the present invention can comprise one or more cationic polymers.Here employed term " polymer " " will both comprise the material of the monomer polymerization manufacturing by a type, comprise the material of two kinds (they being copolymer) or polytype monomer polymerization manufacturing again.
Preferably this cationic polymer is water miscible cationic polymer." water miscible " cationic polymer is meant such polymer, and this polymer can fully be dissolved in water, and forms concerning naked eyes clear solutions basically in the time of 25 ℃ in water (distilled water or the water suitable with distilled water) under the concentration 0.1%.Preferred polymer will fully dissolve and form clear solutions basically under 0.5% concentration, more preferably form clear solutions basically under 1.0% concentration.
Thus, it is about 5000 that the weight average molecular weight of this cationic polymer generally is at least, and representationally is at least approximately 10000, and is lower than about 10000000.Preferably, molecular weight is about 100000 to about 2000000.Usually this cationic polymer has nitrogenous cationic moiety, as quaternary ammonium or cation amino part, and their mixture.
Cationic charge density is preferably at least about 0.1 milliequivalent/gram (meq/gram), more preferably at least about 1.5 milliequivalent/grams, even more preferably at least about 1.1 milliequivalent/grams, most preferably at least about 1.2 milliequivalent/grams.Can measure the cationic charge density of cationic polymer by the Kjeldahl method.Those of ordinary skill in the art can know, the charge density of amido polymer will change with the variation of the isoelectric point, IP of pH and this amino group.Under the pH that expection is used, charge density should be within above-mentioned scope.
As long as meet the water-soluble criterion, can use any anionic counter ion.Suitable counter ion comprises halogen ion (as Cl, Br, I or F, preferred Cl, Br or I), sulfate radical and methylsulfate.Can use other gegenion, enumerating here is not exclusive yet.
As the part of whole monomeric units of cationic hair conditioning polymer, nitrogenous cationic moiety occurs with substituent form usually.Therefore, cationic polymer can comprise monomeric unit that quaternary ammonium or cationic amine replace and other is called the unitary bipolymer of the unitary non-cationic of spacer monomers, terpolymer etc. here.In the art, this polymer be known and most of can be in the 3rd edition of the CTFA cosmetic ingredient dictionary of editing by Estrin, Crosley and Haynes (CosmeticIngredient Dictionary) (The Cosmetic, Toiletry, and FragranceAssociation, Inc., Washington, D.C., 1982) find.
Suitable cationic polymer comprises, for example, have the vinyl monomer of cationic amine or quaternary ammonium functional group and the copolymer of water solublity spacer monomers, this water solublity spacer monomers can be acrylamide, Methacrylamide, alkyl and dialkyl group acrylamide, alkyl and dialkyl methyl acrylamide, alkyl acrylate, alkyl methacrylate, vinyl caprolactone and vinyl pyrrolidone.This alkyl and dialkyl group substituted monomer preferably have C
1-C
7Alkyl group more preferably has C
1-C
3Alkyl group.Other suitable spacer monomers comprises vinyl esters, vinyl alcohol (by the hydrolysis preparation of polyvinyl acetate), maleic anhydride, propylene glycol and ethylene glycol.
This cationic amine can be primary, secondary, tertiary amine, and this depends on the concrete kind and the pH of compositions.In general, preferred secondary amine and tertiary amine, particularly tertiary amine.
The vinyl monomer that amine replaces can amine the form polymerization, can randomly change into ammonium then by quaterisation; Equally also can amine is quaternized, and then form polymer.For example, tertiary amine functional group can by with formula R
118The reactant salt of X and quaternized, wherein R
118Be short-chain alkyl, preferred C
1-C
7Alkyl, more preferably C
1-C
3Alkyl, and X is a kind of one-tenth salt anionic as defined above.
Suitable cation amino and quaternary ammonium monomer comprise, for example, vinyl compound by following replacement: propenoic acid dialkyl aminoalkyl ester, the methacrylic acid dialkyl aminoalkyl ester, acrylic acid one alkylaminoalkyl, methacrylic acid one alkylaminoalkyl, trialkyl methacryloxy alkylammonium salt, trialkyl acryloxyalkyl ammonium salt, the diallyl quaternary ammonium salt, and has a vinyl quaternary ammonium compound of cationic nitrogenous ring, cation contains azo-cycle as pyridine, the cyclic cationic nitrogenous ring of imidazoles and quaternized ketopyrrolidine, for example alkyl vinyl imidazoles, alkylvinylpyridines, alkyl vinyl ketopyrrolidine salt.These monomeric moieties are preferably as C
1-C
3The low alkyl group of alkyl, more preferably C
1And C
2Alkyl.Be applicable to that amine substituted ethylene base monomer of the present invention comprises propenoic acid dialkyl aminoalkyl ester, methacrylic acid dialkyl aminoalkyl ester, dialkyl aminoalkyl acrylamide and dialkyl aminoalkyl Methacrylamide, the preferred C of alkyl group wherein
1-C
7Alkyl, more preferably C
1-C
3Alkyl.
Cationic polymer of the present invention can comprise and is derived from amine-and/or the mixture of the monomeric unit of the monomer of quaternary ammonium-substituted and/or suitable spacer monomers.
Suitable cationic hair conditioning polymer for example comprises: the copolymer of l-vinyl-2-pyrrolidone and 1-vinyl-3-methylimidazole salt (as chloride salt) is (in the industry by the Cosmetic, Toiletryand Fragrance Association, " CTFA " is called Polyquaternium-16), as originate from (the Parsippany of BASFWyandotte company, NJ, those (for example LUVIQUAT FC 370) of the LUVIQUAT by name of commodity USA); The copolymer (CTFA is called Polyquaternium-11 in the industry) of l-vinyl-2-pyrrolidone and dimethylaminoethyl acrylate methyl base amino-ethyl ester, as originate from (the Wayne of Gaf company, NJ, those (for example GAFQUAT 755N) of the GAFQUAT by name of commodity USA); The cationic polymer that contains the diallyl quaternary ammonium, comprise that (CTFA) is called as Polyquaternium 6 and Polyquaternium 7 respectively in the industry as the homopolymer of dimethyl diallyl ammonium chloride and the copolymer of acrylamide and dimethyl diallyl ammonium chloride; And the inorganic acid salt of the amino-Arrcostab of the homopolymer of unsaturated carboxylic acid and copolymer, this unsaturated carboxylic acid has 3-5 carbon atom as described in the US 4009256.
The both sexes ter-polymers that other suitable cationic polymer is made up of acrylic acid, methacryl amido oxypropyl trimethyl ammonium chloride and acrylic acid methyl ester., its structure is as follows, and (CTFA) is called as Polyquaternium 47 in the industry.The example of suitable commercially available material is the MERQUAT 200l that Calgon company provides, ratio n wherein
6: n
7: n
8It is 45: 45: 10.
Operable other cationic polymer comprises polysaccharide polymer, as cationic cellulose derivative and cationic starch derivative.
Be applicable to cationic polysaccharide polymeric material of the present invention, comprise polysaccharide polymer with following structural formula:
Wherein: Z
7Be the dewatered grape saccharide residue, as starch or cellulose dewatered grape saccharide residue; R
119Be alkylidene oxygen base alkylidene, polyoxy alkylidene or hydroxy alkylidene group, or their combination; R
120, R
121And R
122Be alkyl, aryl, alkylaryl, aryl alkyl, alkoxyalkyl or alkoxy aryl group independently, each group contains about 18 carbon atoms of as many as, and the total number of carbon atoms of each cationic moiety (is R
120, R
121, and R
122In the carbon number sum) preferably be about 20 or lower; X is into salt anionic as previously mentioned.
Cationic cellulose can be from Amerchol company (Edison, NJ, series of polymers product P olymer JR USA)
And LR
In obtain, be the salt of the hydroxyethyl-cellulose crossed of the epoxide reaction that replaces with trimethyl ammonium, (CTFA) is called Polyquaternium 10 in the industry.The cationic cellulose of another kind of type comprises the polymeric quaternary ammonium salts of the hydroxyethyl-cellulose of crossing with the epoxide reaction of lauryl dimethyl ammonium replacement, and (CTFA) is called Polyquaternium 24 in the industry.These materials can (Edison, NJ USA) obtain, and commodity are called Polymer LM-200 from Amerchol company
Operable other cationic polymer comprises cationic guar derivative, and as guar gum hydroxypropyl-trimethyl ammonium chloride (guar hydroxypropyltrimonium chloride), industrial goods are the Jaguar R series of products that originate from Celanese company.Other material comprises the 3962418 described cellulose ether of quaternary nitrogen and the copolymers of described etherified cellulose of US3958518 and starch of containing as US.
Among the present invention, useful especially cationic polymer comprises Polyquaterniun-7, Polyquaterniun-10, Polyquaterniun-24, Polyquaterniun-39, Polyquaterniun-47, and their mixture.
Additional oiliness compound
Among the present invention, useful additional oiliness compound comprises aliphatic alcohol and derivant, fatty acid and derivant thereof and hydro carbons.This useful additional oiliness compound can be volatile also can be nonvolatile, and its fusing point is no more than about 25 ℃.Be not limited to theoretical restriction, can believe that this additional oiliness compound can be penetrated in the hair and modifies the hydroxyl bond of hair, thereby make hair have flexibility and elasticity.Additional oiliness compound of this part and aforesaid high melting compound are distinguishing.The non-limiting example of this additional oiliness compound can and be found in the 2nd edition CTFA cosmetic composition handbook (CTFA Cosmetic Ingredient Handbook) at the 5th edition international cosmetic ingredient dictionary (International Cosmetic Ingredient Dictionary) in 1993 in 1992.
Used aliphatic alcohol comprises that those have about 10 to about 30 carbon atoms among the present invention, and preferred about 12 to about 22 carbon atoms, most preferably from about 16 aliphatic alcohol to about 22 carbon atoms.These aliphatic alcohol can be straight chain also can be side chain, can be saturated also can be undersaturated, preferred undersaturated aliphatic alcohol.The non-limiting example of these chemical compounds comprises oleyl alcohol, Palmitoleyl alcohol, isooctadecanol, different spermol, undecyl alcohol, octyl dodecanol, octyl group decanol, octyl group alcohol, capryl alcohol, decanol and lauryl alcohol.
Used fatty acid comprises that those have about 10 to about 30 carbon atoms among the present invention, and preferred about 12 to about 22 carbon atoms, most preferably from about 16 fatty acids to about 22 carbon atoms.These fatty acids can be straight chain also can be side chain, can be saturated also can be undersaturated.For instance, Shi Yi fatty acid comprises oleic acid, linoleic acid, isostearic acid, linolenic acid, ethyl linolenic acid, arachidonic acid and castor oil acid.Here derivative of fatty acid that is limited and fatty alcohol derivative comprise the alkyl ether of aliphatic alcohol ester, alkoxy fatty alcohols, aliphatic alcohol, the alkyl ether of alkoxy fatty alcohols and the ester oil (bulky ester oil) of large volume, as pentaerythritol ester oil, trihydroxy methyl ester oil, citric acid ester oil, glyceride oil, and their mixture.For instance, the non-limiting example of derivative of fatty acid and fatty alcohol derivative comprises methyl linoleate, Ethyl linoleate, the linoleic acid isopropyl ester, Ceraphyl 140A, acid isopropyl, ethyl oleate, oleic acid octyl group ten diester, oleic acid oil base ester, decyl oleate, butyl oleate, methyl oleate, stearic acid octyl group ten diester, isostearic acid octyl group ten diester, different Palmic acid octyl group ten diester, different octyl pelargonate, octyl pelargonate, the own ester of isostearic acid, the isostearic acid isopropyl ester, different isodecyl pelargonate, the isostearic acid isopropyl ester, the isostearic acid ethyl ester, isostearic acid methyl ester and Oleth-2.Here the ester oil of employed large volume is lower than approximately 800 as the molecular weight of pentaerythritol ester oil, trihydroxy methyl ester oil, citric acid ester oil and glyceride oil, preferably be lower than about 500.
Hydrocarbon used in the present invention comprises the hydrocarbon of straight chain, cyclic and side chain, they can be saturated also can be undersaturated, as long as their fusing point is no more than about 25 ℃.These hydrocarbon have about 12 to about 40 carbon atoms, preferably have about 12 to about 30 carbon atoms, and most preferably from about 12 to about 22 carbon atoms.Here also comprise by alkenyl monomer (as C
2-6Alkenyl monomer) hydrocarbon that is polymerized.These polymer can be straight chain also can be side chain.The chain length of straight chain polymer is shorter relatively usually, and the total number of carbon atoms that has as mentioned above.Branch polymer can have in fact long chain length.The excursion of the number-average molecular weight of this material is very big, but often up to about 500, and preferred about 200 to about 400, and more preferably from about 300 to about 350.In addition, can also use various other mineral oil of level.Mineral oil is the liquid mixture of the hydrocarbon that obtains from oil.The instantiation of suitable hydrocarbon material has paraffin oil, mineral oil, dodecane, Fancol ID, hexadecane, 2-Methylpentadecane, eicosylene, different eicosylene, tridecane, the tetradecane, polybutene, polyisobutylene and their mixture.The preferred hydrocarbon that uses is selected from mineral oil, poly ﹠ Alpha ,-olefin oil among the present invention, as Fancol ID, 2-Methylpentadecane, polybutene, polyisobutylene and their mixture.
Commercially available aliphatic alcohol used in the present invention and derivant thereof comprise: originate from the oleyl alcohol of the commodity UNJECOL 90BHR by name of ShinNihon Rika, the various liquid ester that originate from the commodity SCHERCEMOL series by name of Scher, the own ester of isostearic acid of commodity HIS by name that originates from Kokyu Alcohol and the isostearic acid isopropyl ester of commodity ZPIS by name.Commercially available bulky ester oil used in the present invention comprises: trimethylolpropane tris caprylate/three decanoins that originate from the commodity MOBILESTER P43 by name of Mobil Chemical company.Commercially available hydrocarbon used in the present invention comprises: originate from Presperse (South Plainfield New Jersey, commodity USA) are called Fancol ID, 2-Methylpentadecane and the different eicosylene of PERMETHYL 99A, PERMETHYL 101A and PERMETHYL 1082; Originate from Amoco Chemical (Chicago Illinois, the isobutene. of the INDOPOL H-100 by name of commodity USA) and the copolymer of n-butene; And the commodity that originate from Witco are called the mineral oil of BENOL and originate from Exxon Chemical company (Houston Texas, the isoparaffin of the ISOPAR by name of commodity USA).
Non-ionic polymers
Non-ionic polymers used in the present invention comprises the cellulose derivative, ethylene oxide polymer of cellulose derivative, hydrophobically modified and is polymer based with the ethylene oxide/propylene oxide.Suitable non-ionic polymers is a cellulose derivative, comprise the methylcellulose of commodity BENECEL by name, the hydroxyethyl-cellulose of commodity NATROSOL by name, the hydroxypropyl cellulose of commodity KLUCEL by name, the cetyl hydroxyethyl cellulose of commodity POLYSURF 67 by name, all originate from Herculus.Other suitable non-ionic polymers be commodity CARBOWAX PEGs, POLYOX WASRs by name and UCON FLUIDS be polymer based with the ethylene oxide/propylene oxide, all originate from Amerchol.
Polyethylene Glycol
The feature of Polyethylene Glycol is to have following general formula:
R wherein
201Be selected from hydrogen, methyl and their mixture.Work as R
201During for hydrogen, these materials are the polymer of ethylene oxide, are also referred to as polyethylene glycol oxide, polyoxyethylene and Polyethylene Glycol.Work as R
201During for methyl, these materials are the polymer of propylene oxide, are also referred to as polypropylene oxide, polyoxypropylene and polypropylene glycol.Work as R in addition
201During for methyl, should know that may there be multiple position isomer in polymer product.
In the superincumbent structure, x
3Meansigma methods be about 1500 to about 25000, preferred about 2500 to about 20000, more preferably from about 3500 to about 15000.
Other useful polymer comprises the mixture of polypropylene glycol and Polyethylene Glycol and polypropylene glycol.
Polyethylene glycol polymer used in the present invention has PEG-2M, R wherein
201Be hydrogen and x
3About 2000 (PEG-2M is also referred to as Polyox WSR N-10, originates from Union Carbide and is called PEG-2000) of meansigma methods; PEG-5M, R wherein
201Be hydrogen and x
3About 5000 (PEG-5M is also referred to as Polyox WSR N-35 and Polyox WSR N-80, and the two all originates from Union Carbide and is called PEG-5000 and Macrogol 3000 00) of meansigma methods; PEG-7M, R wherein
201Be about 7000 (PEG-7M is also referred to as Polyox WSR N-750, originates from UnionCarbide) of meansigma methods of hydrogen and x3; PEG-9M, R wherein
201Be hydrogen and x
3About 9000 (PEG-9M is also referred to as Polyox WSR N-3333, originates from Union Carbide) of meansigma methods; And PEG-14M, R wherein
201Be hydrogen and x
3About 14000 (PEG-14M is also referred to as Polyox WSR N-3000, originates from Union Carbide) of meansigma methods.
Other annexing ingredient
Compositions of the present invention can comprise other annexing ingredient, these annexing ingredients can be selected according to the desirable characteristics of final products by those of ordinary skill in the art, and are suitable for giving compositions at the acceptable of beauty treatment or aesthetic or for they provide other purposes.These other annexing ingredient generally all uses separately, and by the weight of compositions, its consumption is about 0.001% to about 10%, preferably up to about 5% consumption.
The kind that can be formulated into other annexing ingredient in the compositions of the present invention is a lot, comprise: other conditioner, as originate from the commodity Peptein 2000 by name of Hormel hydrolytic collagen, originate from the commodity Emix-d by name of Eisai vitamin E, originate from Roche pantothenylol, originate from general (alcohol) benzyl ethyl ether, hydrolysis of keratin, protein, plant extraction liquid and the nutrient of Roche; Hair fixing copolymer, as amphoteric amorphous polymer, cationic amorphous polymer, anionic amorphous polymer, nonionic amorphous polymer, and silicone grafted copolymer; Antiseptic is as benzylalcohol, methyl parahydroxybenzoate, propyl p-hydroxybenzoate and imidazolidinyl urea; PH adjusts agent, as citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate; Salt is typically potassium acetate and sodium chloride; Coloring agent is as any FD﹠amp; C or F﹠amp; The C dyestuff; Hair oxidation (bleaching) agent is as hydrogen peroxide, perborate and persulfate; The hair Reducing agent is as the mercaptoethanol hydrochlorate; Spice; And sequestering agent, as disodiumedetate; Ultraviolet and ultrared covering and absorbent are as ethylhexyl salicylate; Dandruff removing agent is as Zinc Pyrithione (zinc pyridinethione); And fluorescent whitening agent, as polystyrene-based stilbene (polystyrylstilbene), triazine stilbene (trizinstilbene), Hydroxycoumarin, aminocoumarin, triazole, pyrazoline, oxazole, pyrene, porphyrin, imidazoles and their mixture.
Embodiment
The following examples further describe and have confirmed embodiment of the present invention within the scope of the invention.Providing of these embodiment only is for illustrative purposes, and can not be construed to is limitation of the present invention, because under the situation that does not break away from the spirit and scope of the present invention, a lot of variations of the present invention all are possible.With chemical name or the various compositions of CTFA name identification, or make separate stipulations in the back.
Compositions of the present invention is suitable for wash type product or leave product, and is specially adapted to make the product of Emulsion, cream, gel, spray or mousse form.
Embodiment 1 to 6 is the Wo 2008069000s of the present invention that are specially adapted to the wash type product.Compositions
| Component | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Poly ﹠ Alpha ,-olefin oil-1 *1 | ?1.0 | ?1.0 | ?1.0 | ?2.0 | ||
| Poly ﹠ Alpha ,-olefin oil-2 *2 | ?1.0 | ?1.0 | ||||
| Poly ﹠ Alpha ,-olefin oil-3 *3 | ?0.1 | ?0.2 | ||||
| Spermol *4 | ?4.0 | ?4.0 | ?4.0 | ?4.0 | ?4.5 | ?4.5 |
| Stearyl alcohol *5 | ?2.0 | ?2.0 | ?2.0 | ?2.0 | ?2.5 | ?2.5 |
| Docosanol *6 | ?1.0 | ?1.0 | ?1.0 | ?1.0 | ?0.5 | ?0.5 |
| Dihydro Adeps Bovis seu Bubali amido-ethyl ethoxy methyl formate ammonium sulfate *7 | ?1.0 | ?1.0 | ?1.0 | |||
| Distearyl amido ethyl-hydroxyethyl methyl formate ammonium sulfate | ?1.0 | ?1.0 | ?1.0 | |||
| Stearamidopropyldime.hylamine *8 | ?2.0 | ?2.0 | ?1.5 | ?2.0 | ?2.0 | ?1.0 |
| L-glutamic acid *9 | ?0.64 | ?0.64 | ?0.8 | ?0.6 | ?0.64 | ?0.64 |
| Stearoyl amido CAB *10 | ?1.0 | ?1.0 | ||||
| Hydroxyethyl-cellulose *11 | ?0.1 | ?0.1 | ||||
| Polyoxyethylene (2000) *12 | ?0.1 | ?0.1 | ||||
| ?Polyquaternium-10 *13 | ?0.05 | ?0.05 | ||||
| ?Polyquaternium-7 *14 | ?0.05 | |||||
| Pentaerythritol tetraoctyl stearate *15 | ?1.0 | ?1.0 | ?0.5 |
| Tricarboxymethyl propane oleate *16 | ????1.0 | ????1.0 | ????0.5 | |||
| Citric acid three different cetyl *17 | ????0.5 | |||||
| Three glyceryl isostearates *18 | ????0.5 | |||||
| Antiseptic | ????0.04 | ????0.04 | ????0.04 | ????0.04 | ????0.04 | ????0.04 |
| Benzylalcohol | ????0.4 | ????0.4 | ????0.4 | ????0.4 | ????0.4 | ????0.4 |
| Spice | ????0.25 | ????0.25 | ????0.25 | ????0.25 | ????0.25 | ????0.25 |
| Mixture of siloxanes *19 | ????2.0 | ????2.5 | ????4.2 | ????2.5 | ????2.5 | ????2.5 |
| Silicone emulsion *20 | ????0.5 | ????0.5 | ????0.5 | |||
| Hydrolytic collagen *21 | ????0.01 | ????0.01 | ????0.01 | ????0.01 | ????0.01 | ????0.01 |
| Vitamin E *22 | ????0.01 | ????0.01 | ????0.01 | ????0.01 | ????0.01 | ????0.01 |
| Pantothenylol *23 | ????0.03 | ????0.03 | ????0.03 | ????0.03 | ????0.03 | ????0.03 |
| General (alcohol) benzyl ethyl ether *24 | ????0.25 | ????0.25 | ????0.25 | ????0.25 | ????0.25 | ????0.25 |
| Citric acid | Adjust the needed amount of pH 3-7 | |||||
| Deionized water | -add to 100%- | |||||
The regulation of component
*1 poly ﹠ Alpha ,-olefin oil-1: the Puresyn6 that derives from Mobil.
*2 poly ﹠ Alpha ,-olefin oils-2: the Puresyn100 that derives from Mobil.
*3 poly ﹠ Alpha ,-olefin oils-3: the Puresyn300 that derives from Mobil.
*4 spermols: the Konol series that derives from Shin NihonRika.
*5 stearyl alcohols: the Konol series that derives from Shin NihonRika.
*6 docosanols: the 1-Docosanol (97%) that derives from Wako.
*7 dihydro Adeps Bovis seu Bubali amido-ethyl ethoxy methyl formate ammonium sulfate: the Varisoft 110 that derives from Witco.
*8 stearamidopropyldime.hylamine: the amido amine MPS that derives from Nikko.
*9 L-glutamic acid: the L-glutamic acid (cosmetics-stage) that derives from Ajinomoto.
*10 stearoyl amido CAB: the Rikabion A-700 that derives from Shin Nihon Rika.
*11 hydroxyethyl-celluloses: derive from Aqualon.
*12 polyoxyethylene (2000): the WSRN-10 that derives from Amerchol.
*13 Polyquaternium-10: the UCARE Polymer LR400 that derives from Amerchol.
*14 Polyquaternium-7: the Merquat that derives from Calgon.
*15 pentaerythritol tetraoctyl stearates: the KAK PTI that derives from Kokyu alcohol.
*16 trimethylolpropane tris isostearates: the EnujerubuTP3SO that derives from Shin Nihon Rika.
*17 citric acids, three different cetyl: derive from Bernel.
*18 3 glyceryl isostearates: derive from Taiyo Kagaku.
*19 mixture of siloxanes: the SE 76 that derives from G.E..
*20 silicone emulsions: the X65-4829 that derives from Tosil/GE.
*21 hydrolytic collagen: the Peptein 2000 that derives from Hormel.
*22 vitamin Es: the Emix-d that derives from Eisai.
*23 pantothenylol: derive from Roche.
*24 general (alcohol) benzyl ethyl ether: derive from Roche.
Preparation method
The compositions of embodiment 1 to 6 as implied above can prepare by any conventional method well known in the art.They are suitable for being prepared as follows: if comprise polymeric material in the compositions, as hydroxyethyl-cellulose, polyoxyethylene, Polyquaternium-10 and Polyquaternium-7, just they at room temperature are scattered in the water, are prepared into polymer solution.Cationic surfactant, amine and above-mentioned polymer solution that high melting compound, hydrophiling replace are if exist, just with their mixing and be heated to more than 70 ℃.Such mixture that obtains is cooled to below 50 ℃, under agitation adds remaining component, and further be cooled to about 30 ℃.
As selection, high melting compound, teritary amide base amine and polymer solution are if exist, with mixed and be heated to more than 70 ℃.Such mixture that obtains is cooled to about 60 ℃, adds the surfactant that hydrophiling replaces.Such final mixture that obtains is cooled to below 50 ℃, under agitation adds remaining component, and further be cooled to about 30 ℃.
If composite material needs, each step all can be used SANYE blender (triblender) and/or mill.
Embodiment disclosed by the embodiment of front and representative has lot of advantages.For example, they can provide long-term moistening sensation, the slick sensation that continues and be easy to processing controls to hair in the time of dry hair, and do not stay oily sensation.
Be appreciated that embodiment as described herein and embodiment only are the purposes in order to explain, and under the situation that does not break away from the spirit and scope of the present invention, the person skilled in the art can carry out multiple modification or change according to the present invention.
Claims (8)
1. Wo 2008069000 comprises:
(1) derive and the poly ﹠ Alpha ,-olefin oil that comes to the 1-olefinic monomer of about 16 carbon atoms by having about 6, this poly alpha olefin oil viscosity is about 1 to about 35000 centistokes, and molecular weight is about 200 to about 60000, and polydispersity is no more than about 3;
(2) additional conditioner is selected from cationic surfactant, amine, high melting compound and their mixture that hydrophiling replaces; With
(3) aqueous carrier.
2. the Wo 2008069000 of claim 1 comprises the additional conditioning agents at least about 1% by weight.
3. the Wo 2008069000 of claim 2, wherein this less important grease separation is lower than about 800 poly ﹠ Alpha ,-olefin oil from molecular weight.
4. the Wo 2008069000 of claim 2, wherein this less important grease separation from molecular weight at least about 800 poly ﹠ Alpha ,-olefin oil.
5. claim 3 or 4 Wo 2008069000, wherein the cationic surfactant that replaces of this hydrophiling is selected from dialkyl amide base ethyl-hydroxyethyl methyl ammonium salt, dialkyl amide base ethyl dimethyl ammonium, two alkanoyl ethyl-hydroxyethyl methyl ammonium salts, two alkanoyl ethyl dimethyl ammoniums and their mixture.
6. claim 3 or 4 Wo 2008069000, wherein this amine is selected from teritary amide base amine, and it is about 12 alkyl to about 22 carbon atoms that described teritary amide base amine has chain length.
7. claim 3 or 4 Wo 2008069000, wherein this high melting compound is selected from spermol, stearyl alcohol, tadenan and their mixture.
8. claim 3 or 4 Wo 2008069000 wherein also comprise silicone compounds.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US1998/011784 WO1999062467A1 (en) | 1998-06-04 | 1998-06-04 | HAIR CONDITIONING COMPOSITION COMPRISING POLY α-OLEFIN OIL |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1306412A true CN1306412A (en) | 2001-08-01 |
Family
ID=22267263
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN98814102.7A Pending CN1306412A (en) | 1998-06-04 | 1998-06-04 | Hair conditioning compsn. comprising poly & Alpha,-olefin oil |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP1083864A1 (en) |
| JP (1) | JP2000515563A (en) |
| CN (1) | CN1306412A (en) |
| AU (1) | AU7955398A (en) |
| BR (1) | BR9815886A (en) |
| WO (1) | WO1999062467A1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104507450A (en) * | 2012-07-27 | 2015-04-08 | 荷兰联合利华有限公司 | Composition |
| CN105916484A (en) * | 2014-01-23 | 2016-08-31 | 荷兰联合利华有限公司 | Hair conditioning composition comprising a zwitterion or proteincaeous material |
| CN105916483A (en) * | 2014-01-23 | 2016-08-31 | 荷兰联合利华有限公司 | Use of a hair conditioning composition for styling the hair |
| CN105934235A (en) * | 2014-01-23 | 2016-09-07 | 荷兰联合利华有限公司 | Hair conditioning composition comprising benzyl alcohol as preservative |
| CN109893461A (en) * | 2012-07-27 | 2019-06-18 | 荷兰联合利华有限公司 | The method for being used to prepare improved conditioning composition |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2469099A (en) * | 1999-01-25 | 2000-08-07 | Procter & Gamble Company, The | Cleansing compositions |
| FR2795312B1 (en) * | 1999-06-23 | 2001-08-10 | Oreal | COMPOSITION CONTAINING AN OPACIFYING OR NACRANT AGENT AND AT LEAST TWO FATTY ALCOHOLS |
| US7056351B2 (en) | 2000-12-13 | 2006-06-06 | The Procter & Gamble Company | Oxidative hair dye composition containing polyakyleneglyco(n)alkylamine and a solid fatty compound |
| US6986886B2 (en) | 2000-12-13 | 2006-01-17 | The Procter & Gamble Company | Hair conditioning compositions and their use in hair coloring compositions |
| US6946122B2 (en) | 2001-03-09 | 2005-09-20 | The Procter & Gamble Company | Hair care composition containing a polyalkylene (n) alkylamine which provide hair volume reduction |
| EP1269974A1 (en) * | 2001-06-18 | 2003-01-02 | Unilever Plc | Hair styling compositions |
| DE10317781A1 (en) * | 2003-04-16 | 2004-11-04 | Cognis Deutschland Gmbh & Co. Kg | Cosmetic composition containing poly-alpha-olefin |
| JP5616609B2 (en) * | 2009-11-06 | 2014-10-29 | 花王株式会社 | Hair cosmetics |
| JP5710119B2 (en) * | 2009-11-20 | 2015-04-30 | 東邦化学工業株式会社 | Hair composition |
| JP5670131B2 (en) * | 2010-09-13 | 2015-02-18 | 東邦化学工業株式会社 | Hair composition |
| JP2019518014A (en) * | 2016-06-15 | 2019-06-27 | ダウ グローバル テクノロジーズ エルエルシー | Improved hair care composition |
| EP3471688A1 (en) * | 2016-06-15 | 2019-04-24 | Rohm and Haas Company | Synergistic hair care formulations |
| WO2023227304A1 (en) * | 2022-05-27 | 2023-11-30 | Unilever Ip Holdings B.V. | Concentrated conditioning compositions |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9208653D0 (en) * | 1992-04-22 | 1992-06-10 | Unilever Plc | Cosmetic composition and process for making it |
| FR2734720B1 (en) * | 1995-06-02 | 1997-07-18 | Oreal | DELAYED FOAM SHAVING GEL CONTAINING A MONOESTER OF C4-C10 ACID AND C16-C18 ALCOHOL |
| US6268431B1 (en) * | 1995-09-01 | 2001-07-31 | The Procter & Gamble Company | Hair styling shampoos containing low Tg latex polymer particles |
| KR20000005084A (en) * | 1996-03-27 | 2000-01-25 | 레이서 제이코버스 코넬리스 | Conditioning shampoo compositions containing polyalphaolefin conditioner |
-
1998
- 1998-06-04 WO PCT/US1998/011784 patent/WO1999062467A1/en not_active Application Discontinuation
- 1998-06-04 EP EP98930083A patent/EP1083864A1/en not_active Withdrawn
- 1998-06-04 JP JP11544706A patent/JP2000515563A/en not_active Ceased
- 1998-06-04 BR BR9815886-4A patent/BR9815886A/en unknown
- 1998-06-04 AU AU79553/98A patent/AU7955398A/en not_active Abandoned
- 1998-06-04 CN CN98814102.7A patent/CN1306412A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104507450A (en) * | 2012-07-27 | 2015-04-08 | 荷兰联合利华有限公司 | Composition |
| CN104507450B (en) * | 2012-07-27 | 2017-10-13 | 荷兰联合利华有限公司 | Composition |
| CN109893461A (en) * | 2012-07-27 | 2019-06-18 | 荷兰联合利华有限公司 | The method for being used to prepare improved conditioning composition |
| CN105916484A (en) * | 2014-01-23 | 2016-08-31 | 荷兰联合利华有限公司 | Hair conditioning composition comprising a zwitterion or proteincaeous material |
| CN105916483A (en) * | 2014-01-23 | 2016-08-31 | 荷兰联合利华有限公司 | Use of a hair conditioning composition for styling the hair |
| CN105934235A (en) * | 2014-01-23 | 2016-09-07 | 荷兰联合利华有限公司 | Hair conditioning composition comprising benzyl alcohol as preservative |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2000515563A (en) | 2000-11-21 |
| BR9815886A (en) | 2001-10-23 |
| EP1083864A1 (en) | 2001-03-21 |
| AU7955398A (en) | 1999-12-20 |
| WO1999062467A1 (en) | 1999-12-09 |
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