CN1301059C - Method for preparing inorganic material clad silver loaded nanometer SiO2 antibacterial agent - Google Patents
Method for preparing inorganic material clad silver loaded nanometer SiO2 antibacterial agent Download PDFInfo
- Publication number
- CN1301059C CN1301059C CNB2005100377244A CN200510037724A CN1301059C CN 1301059 C CN1301059 C CN 1301059C CN B2005100377244 A CNB2005100377244 A CN B2005100377244A CN 200510037724 A CN200510037724 A CN 200510037724A CN 1301059 C CN1301059 C CN 1301059C
- Authority
- CN
- China
- Prior art keywords
- silver
- antibacterial agent
- inorganic material
- antibacterial
- material clad
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a method for preparing a silver carried nano SiO2 antibacterial agent with an inorganic clad structure. The present invention is characterized in that silver carried nano SiO2 antibacterial powder is prepared into a water suspension, and then, chemical cladding treatment is carried out. The present invention comprises steps: butyl titanate is hydrolyzed into anatase TiO2, and anatase TiO2 is clad on the surfaces of silver carried nano SiO2 particles to form antibacterial particles with a clad structure. The silver carried nano SiO2 antibacterial agent with an inorganic cladding structure has good whiteness, good optical stability and good antibacterial durability; the antibacterial rate for colibacillus and staphylococcus aureus is over 99%.
Description
Technical field:
The present invention relates to a kind of preparation method of novel inorganic clad structure antibacterial agent.Especially relate to a kind of inorganic material clad silver loaded nanometer SiO
2The preparation method of antibacterial agent.The preparing technical field that belongs to antibacterial agent.
Background technology:
At present, the antibacterial agent that is used for colibacillus, staphylococcus aureus has nanometer SiO
2The silver of carrier is antimicrobial powder, and it mainly has the following disadvantages:
1, whiteness is relatively poor
2, photostability is relatively poor
3, antibiotic persistence is relatively poor
Therefore its sterilizing rate to colibacillus, staphylococcus aureus is lower, generally only be? %.
Summary of the invention:
The objective of the invention is to overcome above-mentioned deficiency, a kind of better whiteness that has is provided, better photostability and antibiotic persistent inorganic material clad silver loaded nanometer SiO
2The preparation method of antibacterial agent.
The object of the present invention is achieved like this: a kind of inorganic material clad silver loaded nanometer SiO
2The preparation method of antibacterial agent is characterized in that it being with silver-carrying nano SiO
2Antibiotic powder is mixed with water suspension, carries out chemistry again and coats processing.
The present invention generates anatase titanium dioxide TiO with the butyl titanate hydrolysis
2, be coated on silver-carrying nano SiO
2The surface of particle, the antimicrobial particle of formation clad structure.This antibacterial agent whiteness is good, and optical stability and antibiotic persistence are good.Its sterilizing rate to colibacillus, staphylococcus aureus is more than 99%.
Embodiment:
Embodiment 1:
With 10g nano silver-carrying SiO
2Powder adds in the 250ml beaker, adds 100ml water, and 2000r/min stirs 15min, makes suspended substance A, and suspended substance A is transferred in the 250ml there-necked flask, stirs and is warming up to 80 ℃ of insulations.In the 50ml beaker, add simultaneously 20ml butyl titanate, 15ml ethanol and 1ml glacial acetic acid, stir faint yellow transparent system B.B slowly is added dropwise among the A, dripped off in 2.5 hours, under 80 ℃, be incubated 1 hour, filter, 120 ℃ of dry products that get.
Embodiment 2:
With 10g nano silver-carrying SiO
2Powder adds in the 250ml beaker, adds 150ml water, and 1900r/min stirs 20min, makes suspended substance A, and suspended substance A is transferred in the 250ml there-necked flask, stirs and is warming up to 85 ℃ of insulations.In the 50ml beaker, add simultaneously 10ml butyl titanate, 20ml ethanol and 1ml glacial acetic acid, stir faint yellow transparent system B.B slowly is added dropwise among the A, dripped off in 3 hours, under 85 ℃, be incubated 1 hour, filter, 120 ℃ of dry products that get.
Claims (2)
1, a kind of inorganic material clad silver loaded nanometer SiO
2The preparation method of antibacterial agent is with silver-carrying nano SiO
2Antibiotic powder is mixed with water suspension, carries out chemistry again and coats processing, it is characterized in that: the butyl titanate hydrolysis is generated anatase titanium dioxide TiO
2, be coated on silver-carrying nano SiO
2The surface of particle, the antimicrobial particle of formation clad structure.
2, a kind of inorganic material clad silver loaded nanometer SiO according to claim 1
2The preparation method of antibacterial agent is characterized in that silver-carrying nano SiO
2Powder 1: 10 by weight～15 adds in the entry, and 1900～2000r/min stirs 15～20min, makes suspended substance A, stirs to be warming up to 80 ℃～85 ℃ insulations; With butyl titanate, ethanol and glacial acetic acid by weight 10～20: 15～20: 1 mix stir faint yellow transparent system B; B is added dropwise among the A, dripped in 2.5～3 hours, under 80 ℃～85 ℃, be incubated 〉=1 hour, filter, the dry product that gets.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100377244A CN1301059C (en) | 2005-02-01 | 2005-02-01 | Method for preparing inorganic material clad silver loaded nanometer SiO2 antibacterial agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100377244A CN1301059C (en) | 2005-02-01 | 2005-02-01 | Method for preparing inorganic material clad silver loaded nanometer SiO2 antibacterial agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1663390A CN1663390A (en) | 2005-09-07 |
| CN1301059C true CN1301059C (en) | 2007-02-21 |
Family
ID=35034841
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100377244A Expired - Fee Related CN1301059C (en) | 2005-02-01 | 2005-02-01 | Method for preparing inorganic material clad silver loaded nanometer SiO2 antibacterial agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1301059C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101255254B (en) * | 2008-03-28 | 2010-06-23 | 浙江高峰控股集团有限公司 | Antibacterial polypropylene pipes and antibacterial composite master batch as well as manufacturing method thereof |
| CN114180991A (en) * | 2021-12-22 | 2022-03-15 | 湖南华联瓷业股份有限公司 | Production process of wear-resistant glaze and glaze |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4849223A (en) * | 1984-12-28 | 1989-07-18 | Johnson Matthey Public Limited Company | Antimicrobial compositions consisting of metallic silver combined with titanium oxide or tantalum oxide |
| CN1563183A (en) * | 2004-03-31 | 2005-01-12 | 华东理工大学 | Method for preparing antibiosis ABS products |
-
2005
- 2005-02-01 CN CNB2005100377244A patent/CN1301059C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4849223A (en) * | 1984-12-28 | 1989-07-18 | Johnson Matthey Public Limited Company | Antimicrobial compositions consisting of metallic silver combined with titanium oxide or tantalum oxide |
| CN1563183A (en) * | 2004-03-31 | 2005-01-12 | 华东理工大学 | Method for preparing antibiosis ABS products |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1663390A (en) | 2005-09-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TWI533806B (en) | Virus deactivator | |
| KR101233570B1 (en) | Antibacterial deodorant and method for producing the same | |
| CN1331400C (en) | Method for preparing composite photocatalytic germicide | |
| CN103167798B (en) | Comprise the antimicrobial of cuprous oxide and antiviral composition and preparation method thereof | |
| TWI592453B (en) | Antibacterial antiviral photocatalyst titanium oxide, and an antibacterial antiviral photocatalyst titanium oxide slurry dispersed in a neutral region, and the manufacturing method thereof | |
| JP6040021B2 (en) | Antibacterial antiviral composition and method for producing the same | |
| Hadavand et al. | Preparation of modified nano ZnO/polyester/TGIC powder coating nanocomposite and evaluation of its antibacterial activity | |
| JP2009024158A (en) | Specific nanostructured material as protective coating for metal surface | |
| EP2373748A1 (en) | Self-cleaning coating composition | |
| JP2010537809A (en) | Transparent and stable titanium dioxide sol | |
| CN1784974A (en) | Composite photocatalitic germicide | |
| CN1903948A (en) | In situ cladding technology of titanium dioxide nano-particle | |
| WO2018110173A1 (en) | Photocatalytic material and photocatalytic coating composition | |
| CN1086362C (en) | Preparation of composite nanometer titania-silica material | |
| CN1301059C (en) | Method for preparing inorganic material clad silver loaded nanometer SiO2 antibacterial agent | |
| KR20090108590A (en) | Method for producing coating agent exhibiting photocatalytic activity and coating agent obtained by the same | |
| JP4849778B2 (en) | Antibacterial deodorant and method for producing the same | |
| CN1597090A (en) | Preparation of photocatalyst without high temperature sintering treatment and its application | |
| KR100784137B1 (en) | Titanium Dioxide Photocatalyst and Its Coating Method | |
| CN105273443A (en) | Nanometer self-cleaning, anti-fog and sterilization glass coating and preparation method thereof | |
| CN1230079C (en) | Nanometer optical catalyst bactericidal composition and preparation thereof | |
| KR20130114686A (en) | Virus inactivator | |
| JP4964331B2 (en) | Method for producing antibacterial deodorant | |
| JP5574813B2 (en) | Manufacturing method of titanium oxide-based fine particles, antibacterial / deodorant using the titanium oxide-based fine particles, coating solution for forming antibacterial / deodorant coating, and substrate with antibacterial / deodorant coating | |
| CN1651534A (en) | Photocatalytic indoor wall surface spray coating agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Jiangyin Ruco Technology Co., Ltd. Assignor: Hua Mingyang Contract fulfillment period: 2009.4.10 to 2014.4.10 contract change Contract record no.: 2009320000797 Denomination of invention: Method for preparing inorganic material clad silver loaded nanometer SiO2 antibacterial agent Granted publication date: 20070221 License type: Exclusive license Record date: 2009.5.6 |
|
| LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.4.10 TO 2014.4.10; CHANGE OF CONTRACT Name of requester: JIANGYIN CITY NUOKE SCIENCE CO., LTD. Effective date: 20090506 |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070221 Termination date: 20160201 |