CN1300665A - Process for preparing microcrystal glass-ceramic compounded decorative plate - Google Patents
Process for preparing microcrystal glass-ceramic compounded decorative plate Download PDFInfo
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- CN1300665A CN1300665A CN 00136831 CN00136831A CN1300665A CN 1300665 A CN1300665 A CN 1300665A CN 00136831 CN00136831 CN 00136831 CN 00136831 A CN00136831 A CN 00136831A CN 1300665 A CN1300665 A CN 1300665A
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- glass
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Abstract
A process for preparing microcrystal glass-ceramics composite decorative plate includes such steps of pouring ceramic powder of ordinary floor tile into mould, adding said ceramic powder and one or more kinds of crystalline glass dregs to the mould until the needed thickness is reached, pressing, baking, sintering, grinding edges and fine polishing. Its advantages are simple technology, low cost and better lustre saturability.
Description
The present invention relates to a kind of preparation method of microcrystal glass-ceramic compounded decorative plate, belong to building material field.
Along with improving constantly of living standards of the people, it is more and more higher that the demand of ornament materials is that quantity or quality all become.Though the designs and varieties of traditional in recent years ceramic decoration sheet material constantly update, because pottery self makes its decorative pattern color and luster be difficult to compare favourably with natural granite.That microcrystalline glass decorative plate has is bright in luster, glossiness is high, corrosion-resistant, good characteristic such as wearability is good, but the complex manufacturing of microcrystal glass plate, production cost are higher.
The objective of the invention is to propose a kind of preparation method of microcrystal glass-ceramic compounded decorative plate, with the process equipment of producing the traditional ceramics floor, but require to add the glass slag body of the crystallization of different styles or tone according to pattern on the ceramic body surface, utilize the stove of sintered ceramic, the preparation microcrystal glass-ceramic compounded decorative plate.
The preparation method of the microcrystal glass-ceramic compounded decorative plate that the present invention proposes may further comprise the steps:
(1) cloth: the general floorings ceramic powder is injected mould to 3/5～4/5 of required gross thickness; With ceramic powder with carry out the cloth second time after but the glass slag charge of one or more crystallization mixes in 1: 0.05～0.6 ratio, reach till the required gross thickness.
(2) under the pressure of 20～40MPa, mould is forced into the blank forming desired density.
(3) oven dry: base substrate is dried between 150～300 ℃.
(4) sintering: utilize roller kilns Fast Sintering ceramic body, simultaneously, glass slag crystallization.Cooling is immediately come out of the stove.
(5) corase grind polishing: after the ceramic idiosome that will come out of the stove was thrown through edging, essence, devitrified glass showed distinctive color and light.
Microcrystal glass-ceramic compounded decorative plate with method preparation of the present invention has the structure of ceramic matrix+devitrified glass.Devitrified glass can distribute in pelletized form, also can be certain pattern.Used ceramic powder can be any general floorings ceramic powder, but used glass slag charge comprises one or more crystallized glass slag charges that present different color.Can carry out cloth for the third time at the skin of ceramic material-glass dregs mixing material, obtain ceramic to ceramic devitrified glass-nucleated glass gradient material, it is honorable to present devitrified glass ground after sintering, the grinding.In concrete preparation process, the order of first, second, third cloth or the reversed order of first, second time cloth can be come.In order to improve the aesthetic effect of decorative panel, can be after oven dry before the sintering, according to the decorative pattern glazing of design.The microcrystal glass-ceramic compounded plate technology of the present invention's preparation is simple, with low cost.The microcrystal glass-ceramic compounded plate of manufacturing of the present invention has good color and luster saturation degree, and the designs and varieties adjustability is good.
Further specify below in conjunction with embodiment.
Embodiment 1:
But the glass slag charge of crystallization (weight %) composed as follows:
SiO
2 60 Al
2O 35 Na
2O 4 K
2O 3 ZnO 7 CaO 12 MgO 1
BaO 2 TiO
2 Cu
2O?0.3 SnO 0.7
The distribution of particles of above-mentioned slag charge is the 2-200 order.
With pack into the mould of 800 * 800mm of ordinary white ceramic powder, addition is 4/5 of a required powder total amount; Glass particle with after ceramic powder mixes in 1: 9 ratio, is added mould equably, and addition is 1/5 of a required powder total amount.Add the blank that is pressed into 800 * 800 * 10mm.Glazing after 220 ℃ of oven dry.Blank was put into the roller kilns sintering 40 minutes, and maximum sintering temperature is 1180 ℃.Behind the kiln discharge,, promptly obtain the microcrystal glass-ceramic compounded plate beautiful in colour of punctation or striped with upper surface corase grind, polishing.
Embodiment 2:
But the glass slag charge of crystallization (weight %) composed as follows:
SiO
2 58 Al
2O
3 8 Na
2O 5 K
2O 5 ZnO 5 CaO 15
BaO 3 Fe
2O
3 1
The distribution of particles of above-mentioned slag charge is the 2-200 order.
With pack into the mould of 800 * 800mm of ordinary white ceramic powder, addition is 4/5 of a required powder total amount; Glass particle with after ceramic powder mixes in 1: 9 ratio, is added mould equably, and addition is 1/5 of a required powder total amount.Add the blank that is pressed into 800 * 800 * 10mm.Glazing after 220 ℃ of oven dry.Blank was put into the roller kilns sintering 40 minutes, and maximum sintering temperature is 1160 ℃.Behind the kiln discharge,, promptly obtain the saturated microcrystal glass-ceramic compounded plate of color and luster of black splotch or striped with upper surface corase grind, polishing
Embodiment 3
But the glass slag charge of crystallization (weight %) composed as follows:
SiO
2 62 Al
2O
3 5 Na
2O 4 K
2O 3 ZnO 7 CaO 14 ZrO
2 1
BaO 2 Cu
2O 0.5 SnO 0.5
The granularity of above-mentioned slag charge is the 2-200 order.
With pack into the mould of 800 * 800mm of ordinary white ceramic powder, addition is 3/5 of a required powder total amount; Glass particle with after ceramic powder mixes in 4: 6 ratio, is added mould equably, and addition is 1/5 of a required powder total amount; The glass slag is added mould uniformly, and addition is 1/5 of a required powder total amount.Add the blank that is pressed into 800 * 800 * 10mm.After 220 ℃ of oven dry, blank was put into the roller kilns sintering 50 minutes, maximum sintering temperature is 1180 ℃.Behind the kiln discharge,, promptly obtain red microcrystal glass-ceramic microcrystal glass-ceramic gradient composite plate beautiful in colour with upper surface corase grind, polishing.
Embodiment 4
But the glass slag charge of two kinds of crystallization is formed following (weight %) respectively:
Glass 1:SiO
260 Al
2O
35 Na
2O 4 K
2O 3 ZnO 7 CaO 12 MgO 1
BaO 2 TiO
2 Cu
2O?0.3 SnO?0.7
Glass 2:SiO
258 Al
2O
38 Na
2O 5 K
2O 5 ZnO 5 CaO 15
BaO 3 Fe
2O
3 1
The distribution of particles of above-mentioned slag charge is the 2-200 order, mixes stand-by with glass 2 in 7: 3 ratio glass 1.
With pack into the mould of 800 * 800mm of ecru ceramic powder, addition is 4/5 of a required powder total amount; Glass particle with after ceramic powder mixes in 2: 8 ratio, is added mould equably, and addition is 1/5 of a required powder total amount.Add the blank that is pressed into 150 * 150 * 10mm.Glazing after 220 ℃ of oven dry.Blank was put into the roller kilns sintering 40 minutes, and maximum sintering temperature is 1180 ℃.Behind the kiln discharge,, promptly obtain the microcrystal glass-ceramic compounded plate beautiful in colour of red or black patches with upper surface corase grind, polishing.
Claims (1)
1, a kind of preparation method of microcrystal glass-ceramic compounded decorative plate is characterized in that this method may further comprise the steps:
(1) cloth: the general floorings ceramic powder is injected mould to 3/5～4/5 of required gross thickness; With ceramic powder with carry out the cloth second time after but the glass slag charge of one or more crystallization mixes in 1: 0.05～0.6 ratio, reach till the required gross thickness;
(2) under the pressure of 20～40MPa, mould is forced into the blank forming desired density;
(3) oven dry: base substrate is dried between 150～300 ℃;
(4) sintering: utilize roller kilns Fast Sintering ceramic body, simultaneously, glass slag crystallization.Cooling is immediately come out of the stove;
(5) corase grind polishing: after the ceramic idiosome that will come out of the stove was thrown through edging, essence, devitrified glass showed distinctive color and light.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00136831 CN1108905C (en) | 2000-12-29 | 2000-12-29 | Process for preparing microcrystal glass-ceramic compounded decorative plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00136831 CN1108905C (en) | 2000-12-29 | 2000-12-29 | Process for preparing microcrystal glass-ceramic compounded decorative plate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1300665A true CN1300665A (en) | 2001-06-27 |
| CN1108905C CN1108905C (en) | 2003-05-21 |
Family
ID=4597525
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 00136831 Expired - Fee Related CN1108905C (en) | 2000-12-29 | 2000-12-29 | Process for preparing microcrystal glass-ceramic compounded decorative plate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1108905C (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101337826B (en) * | 2007-07-06 | 2010-07-28 | 中国地质大学（武汉） | Technique of preparing microcrystalline glass-ceramic composite board by one-step firing process |
| CN101538114B (en) * | 2001-08-02 | 2011-07-13 | 3M创新有限公司 | Article comprising metal oxide glasses and method of making same |
| CN101613217B (en) * | 2008-06-26 | 2011-12-07 | 广东科达机电股份有限公司 | Method for one-time sintering of ceramic-microcrystalline glass composite board |
| CN102092946B (en) * | 2009-12-09 | 2012-06-20 | 沈阳临德陶瓷研发有限公司 | Method for preparing microcrystalline glass-ceramic composite decorating plate by using ceramic polishing waste |
| CN102729315A (en) * | 2012-07-16 | 2012-10-17 | 潮州市三元陶瓷(集团)有限公司 | Primary formation process of glass ceramic kettle body |
| CN112408800A (en) * | 2020-11-25 | 2021-02-26 | 江西璞晶新材料股份有限公司 | Method for preparing marble-like colored microcrystalline glass by using ceramic pigment |
-
2000
- 2000-12-29 CN CN 00136831 patent/CN1108905C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101538114B (en) * | 2001-08-02 | 2011-07-13 | 3M创新有限公司 | Article comprising metal oxide glasses and method of making same |
| CN101417860B (en) * | 2001-08-02 | 2012-01-18 | 3M创新有限公司 | Method of making articles from glass and glass ceramic articles so produced |
| CN101337826B (en) * | 2007-07-06 | 2010-07-28 | 中国地质大学（武汉） | Technique of preparing microcrystalline glass-ceramic composite board by one-step firing process |
| CN101613217B (en) * | 2008-06-26 | 2011-12-07 | 广东科达机电股份有限公司 | Method for one-time sintering of ceramic-microcrystalline glass composite board |
| CN102092946B (en) * | 2009-12-09 | 2012-06-20 | 沈阳临德陶瓷研发有限公司 | Method for preparing microcrystalline glass-ceramic composite decorating plate by using ceramic polishing waste |
| CN102729315A (en) * | 2012-07-16 | 2012-10-17 | 潮州市三元陶瓷(集团)有限公司 | Primary formation process of glass ceramic kettle body |
| CN102729315B (en) * | 2012-07-16 | 2015-12-09 | 潮州市三元陶瓷(集团)有限公司 | Glass ceramics kettle body one-shot forming technique |
| CN112408800A (en) * | 2020-11-25 | 2021-02-26 | 江西璞晶新材料股份有限公司 | Method for preparing marble-like colored microcrystalline glass by using ceramic pigment |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1108905C (en) | 2003-05-21 |
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Granted publication date: 20030521 Termination date: 20121229 |