CN1275323A - Germicide composition - Google Patents

Germicide composition Download PDF

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Publication number
CN1275323A
CN1275323A CN 00111059 CN00111059A CN1275323A CN 1275323 A CN1275323 A CN 1275323A CN 00111059 CN00111059 CN 00111059 CN 00111059 A CN00111059 A CN 00111059A CN 1275323 A CN1275323 A CN 1275323A
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weight percentage
microbicide compositions
soil
aliette
fungicide
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CN 00111059
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Chinese (zh)
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胡耐冬
孔昭国
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Individual
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Abstract

A fungicide composite contains systemic fungicide fosely-aluminium, contact fungicide thiram and ziram and mancozeb and soil fungicide etridiazole and fenaminosulf and hymexazol, in which the weight portion ratio of active components is 1 : 30 to 30 : 1 and 1 : 6 to 6 : 1, and the weight percentage content of active components is 0.5-95%, and the said composite at least containes two kinds of carriers, and at least one kind is surfactant. It can be extensively used for controlling crops diseases and pests, can be used as seed and soil treating agent and spray fungicide for plant stem and foliage, and its application can adopt the processes of pouring, ejecting, spraying, powdering and smoking,etc..

Description

Microbicide compositions
Microbicide compositions of the present invention belongs to the preparation of compositions method and the application of crops systemic fungicide, contact bactericide, soil fungicides.
Many different compounds are as interior absorption and contact and soil fungicides in the prior art, and this compounds is to have bought on the market, and it is write by the Ministry of Chemical Industry's agricultural chemicals central information facility and " finds in the external pesticide species handbook.In soil-borne disease in seedling stage such as cotton, peanut, paddy rice, cucumber, capsicum, eggplant, tomato such as the yellow fusarium wilt of cotton, peanut root rot and stem rot, melon damping off, damping off, bakanae disease of rice, damping off are difficult with control, and the loss that these diseases cause is very serious.Bactericide aliette (triethyl group phosphoric acid aluminium) is mainly used in prevents and treats the microbial disease of Oomycete cause of disease, second phosphorus companion and mancozeb (complex compound of ethylenebis (curing carbamic acid) manganese and zinc salt) are used the control that the Oomycete pathogen is caused disease with, and these medicaments are to the effect of above-mentioned crops soil-borne disease in the seedling stage use that do not appear in the newspapers.
The purpose of microbicide compositions of the present invention, providing a kind of microbicide compositions has special control efficiency to soil-borne disease in seedling stage such as cotton, peanut, paddy rice, cucumber, capsicum, eggplant, tomato, also microbial disease of Oomycete cause of disease etc. is also had good active.Microbicide compositions: closed a kind of systemic fungicide and be aliette and a kind of contact bactericide and a kind of soil fungicides.Wherein the contact bactericide be tmtd (two (dimethylamino thiocarbonyl group) two sulphur), ziram (two (dimethyl disulfide carbonyl) zinc), mancozeb (ethylenebis (aminodithioformic acid) manganese and zinc salt complex compound), maneb (ethylidene dithiocarbamate manganese), zineb (ethylenebis (aminodithioformic acid) zinc), for woods ammonium (ethylenebis (aminodithioformic acid) ammonium); Soil fungicides be Grandox fumigant (5-ethyoxyl-3-trichloromethyl-1,2,4-thiadiazoles), enemy can pine (4-dimethylamino benzene diazosulfonic acid sodium), dislike mould spirit (5-methyl-isoxazole-3-alcohol).Microbicide compositions of the present invention is mainly used in the control cotton, wheat, paddy rice, soybean, peanut, grape, tobacco, lupulus, millet, potato, tomato, Chinese cabbage, beet, wild cabbage, capsicum, eggplant, garlic, onion, shallot, cucumber, pumpkin, lettuce and other vegetables, and rubber, pineapple, lichee, citrus, apple, avocado, cocoa, rose, carnation and other ornamental plants disease: (Huang) fusarium wilt, root rot, stem rot, stem wilt, damping off, bakanae disease, black stem, damping off, anthracnose, smut, apple scab, downy mildew, late blight, the frost eqpidemic disease, rotten mildew, canker, white blister, (millet) poliosis; Wherein soil-borne disease in seedling stage such as cotton, peanut, paddy rice, cucumber, capsicum, eggplant, tomato there is special efficacy.
Microbicide compositions of the present invention takes following technical scheme to realize, microbicide compositions is: containing a kind of systemic fungicide is aliette and a kind of contact bactericide and a kind of soil fungicides.Wherein the contact bactericide is tmtd, ziram, mancozeb, maneb, zineb, ambam; Soil fungicides be Grandox fumigant, enemy can pine, dislike mould spirit.Preferable microbicide compositions is by systemic fungicide aliette and contact bactericide tmtd, systemic fungicide aliette and contact bactericide mancozeb, systemic fungicide aliette and soil fungicides are disliked mould spirit, and contact bactericide tmtd and soil fungicides are disliked mould spirit and formed.The amount of application of compound when the amount that contains active component in the product of microbicide compositions of the present invention depends on independent the use, the ratio of a kind of compound and another kind of compound and the degree of synergistic effect, the while is relevant with the target fungi.The ratio of systemic fungicide and contact bactericide and soil fungicides is 1: 30 to 30: 1 based on the parts by weight of active component, and preferable ratio is that the ratio of systemic fungicide and contact bactericide and soil fungicides is 1: 6 to 6: 1 based on the parts by weight of active component.Microbicide compositions of the present invention by systemic fungicide and contact bactericide and soil fungicides with three components or the combination of many components.Active component is 0.5% to 95% of a gross weight in the composition, and concrete usage ratio is that aliette: 100-2500PPM, preferable consumption are 150-1000PPM; Tmtd, ziram, mancozeb, maneb, zineb, ambam: 100-3000PPM, preferable consumption are 150-1500PPM; Grandox fumigant, enemy can pines, dislike mould spirit: 100-2000PPM, preferable consumption 150-1500PPM.Microbicide compositions comprises carrier, and carrying is solid or liquid, comprises that being generally gas compression back is the material of liquid, and any carrier that is generally used for preparing microbicide compositions all can use.Active component and carrier are mixed with the place that is easy to use processing, and crops, seed and soil are easy to store, transportation or loading and unloading.Microbicide compositions is mixed with pulvis, paste, wetting powder, soluble powder, water dispersion granule, dust agent, liquor, emulsifiable concentrate, suspending agent, aqueous suspension, microemulsion, aqueous emulsion, fumicants, sustained release agent, aerosol.Use is included in solution and the powder in the polymer capsule, the natural or synthetic material or the carrier of dipping active substance.The preparation preparation adopts universal method, and active substance is mixed with liquid flux and solid carrier, and adding surfactant simultaneously is emulsifier, dispersant, stabilizing agent, wetting agent, adds adhesive and dyestuff and odorant.The preparation method of microbicide compositions, water is as solvent or thinner, and organic solvent is as attached cosolvent or antifreeze additive, and organic solvent comprises benzene, dimethylbenzene, toluene, alkylbenzene, Fluhyzon and the chlorination virtue stem of aromatic hydrocarbons; The chloro aliphatic hydrocarbon is chlorobenzene, vinyl chloride, trichloroethanes, carrene, chloroform, carbon tetrachloride and many chloroethanes; Aliphatic hydrocarbon, petroleum distillate, cyclohexane, light mineral oil, paraffin and coal; The polar solvent alcohols is isopropyl alcohol, butanols, ethylene glycol, phenmethylol, furfuryl alcohol and ring ethanol, and ether and ester; Ketone is acetone, MEK, methyl iso-butyl ketone (MIBK), ring ethyl ketone, fourth propyl ester, and dimethyl formamide, dimethyl alum and N-methyl-pyrrolidones.Mixtures of different liquids often is suitable for.The solid carrier that is fit to comprises natural or synthetic clay and silicate, natural silica and diatomite; Magnesium silicate is talcum for example; Magnesiumaluminumsilicate is active soil and vermiculite for example; Alumina silicate is kaolinite, montmorillonite and go mother for example; Calcium carbonate; Ammonium sulfate; Synthetic hydrated silica and synthetic calcium silicates or alumina silicate; Element is carbon and sulphur for example; Natural and synthetic resin is cumarone resin, polyvinyl chloride for example, styrene polymer and copolymer; Solid polystream phenol; Pitch; Paraffin; Solid fertilizer, for example phosphate.The solid carrier that is applicable to pulvis comprises rock dust, montmorillonite, the diatomite of natural formation, for example microdispersed silicic acid of the synthetic mineral matter that grinds or aluminium oxide; The particulate vector that is fit to comprises for example synthetic particle made of calcite, marble, float stone, sepiolite and dolomite and organic and inorganic powder of broken and natural rock classification.Particle prepares from organic material, for example wood chip, peanut shell, maize cob fiber and dry tobacco rods.
Microbicide compositions of the present invention is mixed with various preparations usually, is diluted by the user before use.Exist a spot of supporting surfactant to help dilution.At least a carrier is a surfactant in composition, and for example composition contains at least two kinds of carriers, and wherein at least a is surfactant.Surfactant is respectively emulsifier, dispersant, wetting agent; Nonionic and ionic.Surfactant comprises the sodium salt and the calcium salt of polyacrylic acid and lignin sulfonic acid; Contain the fatty acid of at least 12 carbon atoms and the polycondensation product of fatty amine and acid amides, oxirane and expoxy propane in the molecule; The fatty acid ester of glycerine, sorbierite, sucrose, pentaerythrite; At least contain the sulfuric acid of 10 carbon atoms and the alkali metal and the alkali salt of sulfonic acid in molecule, preferable is sodium salt, the sodium salt of lauryl sodium sulfate, Teepol, sulfonated castor oil, alkylaryl sodium sulfonate, neopelex; And the copolymer of polymers of ethylene oxide and oxirane and expoxy propane.Following material emulsifier and wetting agent; Nonionic emulsifier, polyoxyethylene fatty acid fat, polyoxyethylene aliphatic alcohol ether, polyoxyethylene fatty amine, ethoxy castor oil, anion emulsifier, cellulose acid and that derive is made dispersant.Adhesive is in powder, particle or the latex shape adding preparations such as synthetic carbonyl methylol, polyvinyl alcohol and polyvinyl acetate or natural water-soluble polymer, gum Arabic.Contain toner in the preparation, inorganic pigment iron oxide, titanium oxide, Prussia orchid; Organic dyestuff alizarin, azo dyes, metal phthalocyanine, kiton colors; Also contain odorant natural aromatic oil.According to type, in solid pharmaceutical preparation, contain 5% to 85% active substance by weight, be 20-80% preferably, in pharmaceutical solutions, contain 10-50% active substance by weight, contain the active substance of 10-60% by weight at suspension preparation.Wetting powder contains the active component of 10-85% usually, except solid inert carrier, contains the dispersant of 3-10% usually, contains stabilizing agent and other additive, bleeding agent and the sticker of 0-10%.Pulvis is mixed with the powder concentrate usually, and it and wetting powder have similar composition, does not contain dispersant, and pulvis is contained the composition of 0.5-10%W active substance usually in the fields by other solid carrier dilution.Granule is made 10-100 international standard sieve mesh 1.676-0.152mm particle usually, by reuniting or soaking into the method preparation, usually granule contains the active component of 0.5-75% and the additive of 0-10%W, stabilizing agent, surfactant, slow release regulator and adhesive.Dry flowable pulvis is made up of smaller containing than the particle of higher concentration active ingredient.Missible oil except containing solvent, contains outside the cosolvent usually when needed, contains the 10-50%W/V active component, other additive of 2-20%W/V emulsifier and 0-20%W/V, stabilizing agent, bleeding agent and corrosion inhibitor.Suspending concentrate need stir usually, to obtain the stable non-deposition product that can flow, it contains the active component of 10-75%W usually, the dispersant of 0.5-15%W, the suspending agent of 0.1-10%W, other additive of protection glue and thixotropic agent, 0-10%W, defoamer, corrosion inhibitor, stabilizing agent, bleeding agent and sticker, water and organic liquid, wherein active component is undissolved basically; Some organic solid or mineral salt are dissolved in the preparation, to help to prevent deposition or as the antifreezing agent of water.The dispersion liquid and the emulsion that contain water, the wetting powder of dilute with water or concentrate obtain composition.Emulsion is water-in-oil type or oil-in-water type, can have dense thick pulpous state denseness.
The effect of microbicide compositions of the present invention is the preparation of compositions and the application of a kind of systemic fungicide and a kind of contact bactericide and a kind of soil fungicides, finished product preparation respectively makes up material and mixes, composition composition preparation separately provides, in the bottle barrel cage, directly mix before using and use, concentrate mixes the concentration that obtains required active substance usually with water, have weeding, desinsection, kill the composition of mite, sterilization, nematocide, antivirotic, plant growth regulator, nutrient for plants liquid, soil conditioner mix.Extensively use cast, injection, spraying, dusting, scatter, be fuming.Microbicide compositions of the present invention is widely used in the control diseases and pests of agronomic crop, and crop seeds is handled, soil treatment.
The embodiment of microbicide compositions of the present invention, embodiment 1, the preparation of 50% wetting powder: the aliette weight percentage is 42%, the tmtd weight percentage is 8%, the lauryl sodium sulfate weight percentage is 2%, the sodium lignin sulfonate weight percentage is 8%, and the kaolin weight percentage is 40%.Each component is solid and mixes, and pulverizes in cracker, reaches standard value up to grain fineness.
Embodiment 2, the preparation of 50% wetting powder: the aliette weight percentage is 8%, the tmtd weight percentage is 42%, the lauryl sodium sulfate weight percentage is 2%, the sodium lignin sulfonate weight percentage is 10%, and the kaolin weight percentage is 38%, and each component is solid and mixes, in cracker, pulverize, reach standard value up to grain fineness.
Embodiment 3, the preparation of 60% wetting powder: the aliette weight percentage is 30%, the tmtd weight percentage is 30%, the lauryl sodium sulfate weight percentage is 2%, and the diatomite weight percentage is 20%, and the sodium lignin sulfonate weight percentage is 4%, the kaolin weight percentage is 14%, each component is solid and mixes, and pulverizes in cracker, reaches standard value up to grain fineness.
Embodiment 4, the preparation of 60% wetting powder: the aliette weight percentage is 10%, the tmtd weight percentage is 50%, the lauryl sodium sulfate weight percentage is 3%, the sodium lignin sulfonate weight percentage is 11%, and the kaolin weight percentage is 36%, and each component is solid and mixes, in cracker, pulverize, reach standard value up to grain fineness.
Embodiment 5, the preparation of 60% wetting powder: the aliette weight percentage is 50%, the tmtd weight percentage is 10%, the lauryl sodium sulfate weight percentage is 4%, the sodium lignin sulfonate weight percentage is 12%, and the kaolin weight percentage is 34%, and each component is solid and mixes, in cracker, pulverize, reach standard value up to grain fineness.
Embodiment 6, the preparation of 64% wetting powder: the aliette weight percentage is 32%, the tmtd weight percentage is 32%, the lauryl sodium sulfate weight percentage is 2%, and the diatomite weight percentage is 20%, and the sodium lignin sulfonate weight percentage is 4%, the kaolin weight percentage is 10%, each component is solid and mixes, and pulverizes in cracker, reaches standard value up to grain fineness.
Embodiment 7, the preparation of 64% wetting powder: the aliette weight percentage is 32%, the tmtd weight percentage is 32%, the lauryl sodium sulfate weight percentage is 4%, the sodium lignin sulfonate weight percentage is 12%, and the kaolin weight percentage is 20%, and each component is solid and mixes, in cracker, pulverize, reach standard value up to grain fineness.
Embodiment 8, the preparation of 64% wetting powder: the aliette weight percentage is 32%, the tmtd weight percentage is 32%, the lauryl sodium sulfate weight percentage is 4%, and the diatomite weight percentage is 4%, and the sodium lignin sulfonate weight percentage is 8%, the chalk weight percentage is 20%, each component is solid and mixes, and pulverizes in cracker, reaches standard value up to grain fineness.
Embodiment 9, the preparation of 80% wetting powder: the aliette weight percentage is 40%, the tmtd weight percentage is 40%, the lauryl sodium sulfate weight percentage is 4%, the sodium lignin sulfonate weight percentage is 8%, and the kaolin weight percentage is 8%, and each component is solid and mixes, in cracker, pulverize, reach standard value up to grain fineness.
Embodiment 10, the preparation of 50% wetting powder: the aliette weight percentage is 25%, the tmtd weight percentage is 25%, the sodium sulphate weight percentage is 4%, and the kaolin weight percentage is 30%, and the lauryl sodium sulfate weight percentage is 10%, the sodium lignin sulfonate weight percentage is 6%, each component is solid and mixes, and pulverizes in cracker, reaches standard value up to grain fineness.
Embodiment 11, the preparation of 30% wetting powder: the aliette weight percentage is 15%, the tmtd weight percentage is 15%, and the sodium sulphate weight percentage is 2%, and the kaolin weight percentage is 40%, the diatomite weight percentage is 12%, the lauryl sodium sulfate weight percentage is 10%, and the sodium lignin sulfonate weight percentage is 6%, and each component is solid and mixes, in cracker, pulverize, reach standard value up to grain fineness.
Embodiment 12, the preparation of 60% wetting powder: the aliette weight percentage is 50%, disliking mould clever weight percentage is 10%, the lauryl sodium sulfate weight percentage is 3%, the sodium lignin sulfonate weight percentage is 11%, and the kaolin weight percentage is 36%, and each component is solid and mixes, in cracker, pulverize, reach standard value up to grain fineness.
Embodiment 13, the preparation of 60% wetting powder: the tmtd weight percentage is 50%, disliking mould clever weight percentage is 10%, the sodium sulphate weight percentage is 6%, and the kaolin weight percentage is 16%, and the lauryl sodium sulfate weight percentage is 10%, the sodium lignin sulfonate weight percentage is 8%, each component is solid and mixes, and pulverizes in cracker, reaches standard value up to grain fineness.
Embodiment 14, the preparation of 20% suspending agent: the aliette weight percentage is 10%, the tmtd weight percentage is 10%, dodecyl alcohol polyethylene glycol phosphate weight percentage is 4%, ethyoxyl triglyceride weight percentage is 2%, the calcium dodecyl benzene sulfonate weight percentage is 1%, the epoxy first and second alkane epoxy propane copolymer weight percentages are 2%, the cyclohexanone weight percentage is 35%, alkylaryl cut (boiling point>200 ℃) weight percentage is 36%, tmtd is dissolved in 80% the cyclohexanone and alkylaryl cut, add dodecyl alcohol polyethylene glycol phosphate then, the ethyoxyl triglyceride, calcium dodecyl benzene sulfonate and the epoxy first and second alkane epoxy propane copolymers thoroughly stir mixture.After adding aliette, mixture is pulverized in ball mill (1mm pearl), adds remaining solvent again.
Embodiment 15, the preparation of 16% aqueous suspension: the aliette weight percentage is 8%, the tmtd weight percentage is 8%, lauryl sodium sulfate is 3%, the ethylene glycol weight percentage is 6%, the water weight percentage is 75%, and aliette and tmtd are pulverized in (1mm pearl) in ball mill with 60% water and lauryl sodium sulfate.Ethylene glycol is dissolved in remaining water, stirs down to add.
Embodiment 16, the preparation of 20% aqueous suspension: the aliette weight percentage is 10%, the tmtd weight percentage is 10%, the sodium methylene bis-naphthalene sulfonate weight percentage is 5%, the ethylene glycol weight percentage is 8%, the penetrant t weight percentage is 2%, and the water weight percentage is 65%, and aliette and tmtd are pulverized in the 1mm pearl in ball mill with 70% water and sodium methylene bis-naphthalene sulfonate.Other components dissolved stirs other component of adding then in remaining water.
Embodiment 17, indoorly the cucumber fusarium wilt is given birth to test test, and in the greenhouse 64% wetting powder of embodiment 7 preparations and 20% tolelofos-methyl and 10% " shuang xiao ling " relatively done biologic test.Conventional method is adopted in experiment.Experimental result is as follows: bactericide: 64% wetting powder 3.1246EC of embodiment 7 preparations 50(PPM), 20% tolelofos-methyl 4.7621EC 50(PPM), 10% " shuang xiao ling " 23.7140EC 50(PPM).
Embodiment 18, and indoor cucumber sudden routine diease occurrence in seedling stage is tested tested, and in the greenhouse 50% wetting powder and 77.2% general the making every effort to overcome of embodiment 10 preparations relatively done biologic test.Conventional method is adopted in experiment.Experimental result is as follows: bactericide: 50% wetting powder 1.4260EC of embodiment 10 preparations 50(PPM), 77.2%, Pu Like 5.7421EC 50(PPM).
Embodiment 19, indoorly rice seedling blight is given birth to test test, and in the greenhouse 60% wetting powder of embodiment 3 preparations relatively done biologic test with the mould spirit of 15% evil.Conventional method is adopted in experiment.Experimental result is as follows: bactericide: 50% wetting powder 2.2160EC of embodiment 3 preparations 50(PPM), 15% dislike mould clever 2.9817EC 50(PPM).
Embodiment 20, indoorly cotton wilt is given birth to test test, and in the greenhouse 30% wetting powder and 20% tolelofos-methyl of embodiment 11 preparations relatively done biologic test.Conventional method is adopted in experiment.Experimental result is as follows: bactericide: 50% wetting powder 3.7453EC of embodiment 3 preparations 50(PPM), 20% tolelofos-methyl 6.3375EC 50(PPM).
Embodiment 21, the test of control in field cotton spoting verticillium wilt, 64% wetting powder of bactericide: embodiment 6 preparations, (bucket mixes 64% wetting powder, 50% thiram wettable powder of buying on the market and 40% or 80% or 90% aliette wetting powder or soluble powder mix the mixture that obtains 64% wetting powder in 1: 1 (active ingredient) direct bucket of proportioning: wherein contain 32% aliette with active ingredient), 10% tolelofos-methyl wetting powder, 10% dislikes mould Lingshui Spring agent.Test is handled: a.64% wetting powder (embodiment 6) is 1000 times; B.64% wetting powder (bucket mixes) is 1000 times; C.10% the tolelofos-methyl wetting powder is 500 times; D.10% dislike 500 times of mould Lingshui Spring agent; E. blank.
Test method: 1.2 mu of examination areas, their early stage carries out soil with above-mentioned medicament and the basal part of stem spraying is handled, and spouting liquid is 70 liters/mu, and every processing repeats for 4 times.9 days intervals of dispenser amount to medication 3 times, investigate in 9 days after the medication the last time.Every sub-district is selected 25 strains at random during investigation, calculates the incidence of disease and proofreaies and correct preventive effect.This plot is that historical blight is retransmitted the district, and is therefore blank heavier according to district's morbidity.
Interpretation of result: find out that from result of the test the morbidity of blank is that the incidence of disease of 85%, four chemicals treatment is respectively 3%, 6%, 11% and 23%, control efficiency is more satisfactory, wherein 64% wetting powder control efficiency the best of preparing with embodiment 6.Four kinds of bactericidal agent for preventing and treating cotton spoting verticillium wilt result of the tests are as follows: embodiment 6,64% Wettable powdered disinfectants, and 1000 times of using dosages, several 100 strains of investigation strain, the incidence of disease is 3%, proofreaies and correct preventive effect 95.5%; 64% wetting powder bucket mixes, and using dosage is 1000 times, investigates 100 strain numbers, and the incidence of disease is 6%, and proofreading and correct preventive effect is 92.9%; 10% tolelofos-methyl, 500 times of using dosages are investigated 100 strains, and the incidence of disease 11% is proofreaied and correct preventive effect 87.1%; 10%; Dislike mould spirit, using dosage is 500 times, investigates 100 strains, and the incidence of disease is 23%, and control efficiency is 72.9%; Blank is investigated 100 strains, and the incidence of disease is 85%.

Claims (8)

1, a kind of microbicide compositions is characterized in that: contain a kind of systemic fungicide and/or a kind of contact bactericide and/or a kind of soil fungicides in the composition.
2, microbicide compositions according to claim 1 is characterized in that: the ratio of interior absorption sterilization and/or contact bactericide and/or soil fungicides is 1: 30 to 30: 1 based on the parts by weight of active component.
3, according to claim 1 or 2 brown microbicide compositions, it is characterized in that: the ratio of systemic fungicide and/or contact bactericide and/or soil fungicides is 1: 6 to 6: 1 based on the parts by weight of active component.
4, microbicide compositions according to claim 1 is characterized in that: wherein systemic fungicide is aliette (a triethyl group phosphoric acid aluminium); Wherein the contact bactericide is tmtd (two (dimethylamino thiocarbonyl group) two sulphur), ziram (two (dimethylamino thiocarbonyl group) zinc), mancozeb (complex compound of ethylenebis (aminodithioformic acid) manganese and zinc salt), maneb (ethylidene dithiocarbamate manganese), zineb (ethylenebis (aminodithioformic acid) zinc), ambam (ethylenebis (aminodithioformic acid) ammonium); Wherein soil fungicides be Grandox fumigant (5-ethyoxyl-3-trichloromethyl-1,2,4-thiadiazoles), enemy can pine (4-dimethyl phenalgin diazosulfonic acid sodium), dislike mould spirit (5-methyl-isoxazole-3-alcohol).
5, microbicide compositions according to claim 4 is characterized in that: wherein systemic fungicide is aliette (a triethyl group phosphoric acid aluminium); Wherein the contact bactericide is tmtd (two (dimethylamino thiocarbonyl group) two sulphur) and mancozeb (complex compound of ethylenebis (aminodithioformic acid) manganese and zinc salt); Wherein soil fungicides is for disliking mould spirit (5-methyl-isoxazole-3-alcohol).
6, according to claim 1,2 or 3 described microbicide compositions, it is characterized in that: the active component weight percentage of composition is 0.5-95%.
7, microbicide compositions according to claim 1 is characterized in that: contain at least two kinds of carriers in the composition, wherein at least a is surfactant.
8, microbicide compositions according to claim 1 is characterized in that: the method for control diseases and pests of agronomic crop, handle at crop seeds, and soil treatment, the agent of cauline leaf sheet spray disinfection, and prevent and treat soil-borne disease.
CN 00111059 2000-05-27 2000-05-27 Germicide composition Pending CN1275323A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102228045A (en) * 2011-07-22 2011-11-02 天津市绿亨化工有限公司 Novel efficient agricultural bactericide compounded from hymexaxzol and thiram
CN106538522A (en) * 2015-09-22 2017-03-29 浙江嘉华化工有限公司 A kind of phosethyl-Al wettable powder compositionss
CN111513074A (en) * 2020-05-08 2020-08-11 许素红 Formula and method for preventing and treating tomato stem basal rot

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102228045A (en) * 2011-07-22 2011-11-02 天津市绿亨化工有限公司 Novel efficient agricultural bactericide compounded from hymexaxzol and thiram
CN106538522A (en) * 2015-09-22 2017-03-29 浙江嘉华化工有限公司 A kind of phosethyl-Al wettable powder compositionss
CN111513074A (en) * 2020-05-08 2020-08-11 许素红 Formula and method for preventing and treating tomato stem basal rot

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