CN1272501C - Process file for manufacturing wet type synthetic leather - Google Patents
Process file for manufacturing wet type synthetic leather Download PDFInfo
- Publication number
- CN1272501C CN1272501C CNB031082661A CN03108266A CN1272501C CN 1272501 C CN1272501 C CN 1272501C CN B031082661 A CNB031082661 A CN B031082661A CN 03108266 A CN03108266 A CN 03108266A CN 1272501 C CN1272501 C CN 1272501C
- Authority
- CN
- China
- Prior art keywords
- film
- synthetic leather
- wet type
- resin layer
- matrix
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/06—Interconnection of layers permitting easy separation
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C08J2367/03—Polyesters derived from dicarboxylic acids and dihydroxy compounds the dicarboxylic acids and dihydroxy compounds having the hydroxy and the carboxyl groups directly linked to aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2461/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2461/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2461/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C08L67/03—Polyesters derived from dicarboxylic acids and dihydroxy compounds the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Laminated Bodies (AREA)
Abstract
A wet process film for synthetic leather production is obtained by providing a release layer composed of a polyolefin-based resin whose release is controlled on at least one side of a base composed of a synthetic resin film. To provide a wet process film for production of a synthetic leather not causing release of a urethane layer in a urethane resin coagulating tank and having adequate release characteristics capable of readily releasing the process film from the urethane layer in a releasing step.
Description
Technical field
The present invention relates to a kind of operation film that in the synthetic leather wet type is made, uses, in particular, relating to a kind of being difficult in the forming process of urethane resin layer peels off this urethane resin layer and the operation film that can easily peel off under the situation of not destroying urethane resin layer, use from the operation film in the synthetic leather wet type is made stripping process.
Background technology
Up to the present, the surface of synthetic leather usually forms urethane resin layer with dry process, but this urethane resin layer does not have water vapo(u)r transmission, and promptly so-called aeration is low.By contrast, the urethane resin layer that forms with damp process does not have the problems referred to above, and because manufacture process can be simplified, has therefore become main flow gradually.
In using the synthetic leather manufacture method of this damp process, at first be on matrix, to be coated with polyurethane resin, make in coagulating basin that it solidifies, film forming, thereby form urethane resin layer.Subsequently, wash, drying, peel off matrix then, carry out various fine finishining as required, produce synthetic leather.
In the synthetic leather manufacture method of using this damp process, the matrix utilization that has been coated with polyurethane resin fills the coagulating basin of the dimethyl formamide aqueous solution and polyurethane resin is solidified, form urethane resin layer, because and then will be by the tank that is used to wash, therefore require its matrix to have resistance to water, for example, when using with paper to the operation paper of base material on matrix, this operation paper produces rough sledding such as crimping.
Therefore, have resistance to water in order to make matrix, for example, the spy opens and discloses a kind of synthetic leather wet type manufacturing operation paper that is pressed with thermoplastic resin film at least on the single face upper strata of resistance to water paper such as synthetic paper in the flat 10-168761 communique.
But coating will become the polyurethane resin of synthetic leather on this operation paper, when the polyurethane resin in making solidification layer solidifies, or when in tank, washing, difference according to circumstances, urethane resin layer might or stick out from operation paper, or produces and peel off.
On the other hand, in order to prevent the generation of above-mentioned situation, if on operation paper surface adhesive layer is set, then operation paper becomes and is difficult to peel off, and when the peeling strength polyurethane resin layer, has the problem of polyurethane resin fault rupture.
Therefore, wish to have a kind of wet type synthetic leather manufacturing operation paper always, its characteristics are: in coagulating basin or in the tank, urethane resin layer does not stick out from operation paper, do not produce and peel off, and in washing, dried stripping process, under the situation of not destroying urethane resin layer, have fissility than the appropriateness that is easier to peel off.
Summary of the invention
The object of the present invention is to provide a kind of in coagulating basin or the tank that is being used for washing, urethane resin layer does not stick out from the operation film, do not produce yet and peel off, and in stripping process, the wet type synthetic leather manufacturing operation film that the operation film is easy to peel off from this urethane resin layer with appropriate fissility.
The present inventor has carried out various researchs in order to achieve the above object repeatedly, and it found that:
(1) a kind of wet type synthetic leather manufacturing operation film wherein, on the single face at least of the matrix that is made of synthetic resin film, is provided with the peel ply that is made of the vistanex that has carried out peeling off control.
(2) according to the wet type synthetic leather manufacturing operation film of above-mentioned (1) record, wherein, the said polyolefins resin is a polypropylene.
(3), wherein, above-mentionedly peel off that to control be to make the said polyolefins resin contain the terpenic series phenol resin according to the wet type synthetic leather manufacturing operation film of above-mentioned (1) or (2) record.
(4) according to the wet type synthetic leather manufacturing operation film of any one record in above-mentioned (1)～(3), wherein, above-mentioned to peel off control be that corona treatment is carried out on the peel ply surface that is made of vistanex.
(5), wherein, between above-mentioned matrix and the peel ply that constitutes by vistanex, be provided with the improved polyalkene layer according to the wet type synthetic leather manufacturing operation film of any one record in above-mentioned (1)～(4).
(6) according to the wet type synthetic leather manufacturing operation film of any one record in above-mentioned (1)～(5), wherein, above-mentioned synthetic resin film is the polyethylene terephthalate film.Can address the above problem, thereby finish the present invention.
The invention is characterized in: on the single face at least of the matrix that constitutes by synthetic resin film, be provided with the peel ply that constitutes by the vistanex that has carried out peeling off control.
In the present invention, must use synthetic resin film as matrix.Matrix is decided to be synthetic resin film, and its advantage is: be easy to choose the material with transparency, paintedly be easy to differentiate when uneven when urethane resin layer produces, with low price relatively such as synthetic paper.
In addition, will be heated to more than 150 ℃ during owing to drying, preferred substrate has heat resistance, and then, if the matrix softness then is difficult to urethane resin layer is peeled, the therefore preferred synthetic resin film that uses type with hardness.
As synthetic resin film, as long as satisfy the desired condition of above-mentioned matrix, there is no particular restriction, and it comprises the film of polyether-ether-ketone, polyether-ketone, polyimides, polyether sulfone and mylar etc.Wherein, as the polyethylene terephthalate film of polyester resin film, it not only has heat resistance, hard advantage, and has solvent resistance, and is therefore preferred.
In addition, the thickness of the matrix that is made of synthetic resin film is not particularly limited the scope of preferred 20～125 μ m.If matrix thickness is thinner than 20 μ m, when then making synthetic leather,, consequently might on urethane resin layer, produce fold because the stress that exists on the matrix is easy to generate stretching.On the other hand, not only uneconomical if matrix thickness surpasses 125 μ m, and also under the identical situation of width, thickness is big more, and it is short more that the length of operation film will become, so the replacing frequency of the used roller of operation film improves the operability variation.
Be used to form the vistanex of peel ply among the present invention, it comprises for example polyethylene, polypropylene, polystyrene, ethylene-propylene copolymer resin, polybutene resin etc., especially, considers optimization polypropylene from the viewpoint of heat resistance and fissility.
Secondly, peel off first method of control as vistanex among the present invention, this method is to make this vistanex contain the terpenic series phenol resin.
Here, containing the vistanex of terpenic series phenol resin, as long as for containing the material of terpenic series phenol resin and vistanex, can be the material that is mixed with these resins, also can be copolymer.
The terpenic series phenol resin is meant in appropriate solvent, in the presence of catalyst, makes the reaction of terpenes and phenol and the resin of manufacturing.As terpenes, it comprises monoterpene, sesquiterpene, two terpenes, セ ス terpenes, triterpene, tetraterpene etc., preferred monoterpene, and particularly, it comprises for example australene, nopinene, d-citrene etc.Here, phenol comprise replace or unsubstituted phenol and derivative, comprise the phenol that phenol that unsubstituted phenol, monoalkyl replaces and dialkyl group replace, for example adjacent, and p-Cresol, xylenols, octyl phenol, dioctyl phenol, nonyl phenol and dinonyl phenol.
The terpenic series phenol resin plays the effect of control urethane resin layer peeling force, and the content of terpenic series phenol resin is big more, and then the tendency of Chan Shenging is that the peeling force of peel ply becomes greatly.Therefore, the content by control terpenic series phenol resin can produce the operation film that is provided with peel ply, and this peel ply is made of the vistanex with required peeling force.
Consider above effect, for the vistanex of 100 weight portions, the content of terpenic series phenol resin is preferred 1～50 weight portion usually, and more preferably, its content is in the scope of 5～20 weight portions.In addition, by its content is defined in the scope of 1～50 weight portion, when the urethane resin layer that will become synthetic leather from the operation film is peeled off, can prevent to cross the destruction of the urethane resin layer that causes by force effectively owing to the adhesive strength of operation film and urethane resin layer.And then, if the content of terpenic series phenol resin in above-mentioned content range, its advantage is: the good fluidity of vistanex is coated with on matrix and becomes easy.
In addition, the number-average molecular weight of terpenic series phenol resin is preferred about 100～3,000, if in this scope, then effect is remarkable, and has easy-to-use advantage.
Secondly, peel off second method of control as vistanex among the present invention, this method is that corona treatment is carried out on the peel ply surface that is made of vistanex of film forming on matrix.That is, the operation film can be controlled and peeling force between the urethane resin layer of synthetic leather will be become by corona treatment.Particularly, if increase the power output of corona treatment, peeling force also increases, and therefore by the power output of control corona treatment, can make the operation film with required peeling force.The power output of corona treatment is generally 1～1.5kW, is generally 0.5～1.5 second in the processing time, and void pitch is to carry out corona treatment under 1～10mm.
And then the content control by making above-mentioned terpenic series phenol resin and the power output control combination of this corona treatment can realize the control that precision is higher.
By having carried out peel ply and the urethane resin layer that the above-mentioned vistanex of peeling off control constitutes, it is by the scope of the preferred 0.3～9.0N/3cm of peel strength of aftermentioned method mensuration.If peel strength is littler than 0.3N/3cm, then the manufacturing of wet type synthetic leather with the coagulating basin of operation in or the tank that is used for washing, urethane resin layer might stick out from the operation film, or generation is peeled off, if surpass 9.0N/3cm, when from the operation film urethane resin layer being peeled off, urethane resin layer might be out of shape, or fracture.
Peel ply that constitutes by the vistanex that contains above-mentioned terpenic series phenol resin and/or the peel ply that constitutes by the vistanex that has carried out above-mentioned corona treatment, the scope of preferred 10～150 μ m of its thickness.Its thickness preferably is because can bring into play better effect in this scope.
Peel ply by the vistanex that has carried out peeling off control constitutes can only be formed on the single face of matrix, also can be formed at two-sided on.
In addition, preferably, the peel ply that is made of this vistanex is implemented in order to produce the embossing processing of leather hand feeling.
And then, in the present invention,, preferably make and contain the improved polyalkene layer between the two in order to improve the cementability of matrix that constitutes by above-mentioned synthetic resin film and the peel ply that constitutes by the said polyolefins resin.So-called improved polyalkene is meant in polyethylene or polypropylene to import functional group, the material of the cementability of improvement and metal or plastics by copolymerization or reaction.It for example comprises Mitsui Chemicals (strain) system " ア De マ one " (trade name), and it is to make unsaturated acids or acid anhydrides etc. carry out the ethene that glycerol polymerization obtains and the copolymer of alpha-olefin.In addition, the scope of preferred 5～30 μ m of its thickness.If in the scope of 5～30 μ m, then can obtain the cementability of appropriateness.
In addition, owing to contain the improved polyalkene layer, the cementability of matrix and polyolefin resin layer improves, and its advantage is to use employed operation film among the present invention repeatedly.
Especially, when using the polyethylene terephthalate film, when using polypropylene, preferably be provided with the improved polyalkene layer at this two interlayer as the vistanex of peel ply as matrix.
In addition, in the present invention,,, preferably improved polyalkene is implemented to give the processing of resistance to water from requiring the resistance to water aspect in order to reach purpose of the present invention.
The specific embodiment
Below in conjunction with embodiment the present invention is described in more detail, but the present invention is not limited to these embodiment.
＜evaluation method 〉
1. urethane resin layer heaves, peels off evaluation
With Visual Confirmation in the coagulating basin of wet type synthetic leather manufacturing process and the urethane resin layer in the tank have on the operation of the having no way of film and heave, have or not and peel off, estimate with following benchmark.
Zero: urethane resin layer is not heaved from the operation film, and nothing is peeled off.
*: urethane resin layer is heaved, is peeled off from the operation film.
2. urethane resin layer peels off evaluation
The state of the urethane resin layer when just from the operation film urethane resin layer being peeled off is estimated with following benchmark.
Zero: urethane resin layer is peeled off from the operation film easily, and urethane resin layer does not have distortion or fracture.
△: urethane resin layer is peeled off from the operation film easily, but owing to heaving or peeling off, urethane resin layer produces distortion.
*: urethane resin layer is peeled off difficulty from the operation film, produces to extend or fracture.
3. the mensuration of peeling force
Estimate by peel strength mensuration shown below.
To step and draw (マ イ ラ one) adhesive tape to be attached to operation film (polyester adhesive tape, eastern electrician of day (strain) system, goods number No.31B) on, in 23 ℃, the thermostatic chamber of relative humidity 50%, placed 30 minutes, be cut into 3cm wide after, with the rate of extension that 1000mm/ divides, the peeling force when measuring 180 degree peel-strength polyurethane layers.
Embodiment 1
With thickness be the polyethylene terephthalate film of 75 μ m as matrix, use the legal coating improved polyalkene of extruding layer (Mitsui Chemicals (strain) system, trade name " ア De マ one SF731 ") in the above, make its bed thickness reach 15 μ m.In the above, acrylic resin (Japanese Port リ ケ system (strain) system " FL25T ") with respect to 100 weight portions, extrude contain 5 weight portion terpenic series phenol resin (ヤ ス Ha ラ ケ ミ カ Le (strain) system " マ イ テ イ one エ one ス G-150; " number-average molecular weight 770) resin, use laminated method, peel ply is set on matrix, makes bed thickness reach 35 μ m, thereby produce the operation film.
Then, with The tape casting on this operation film, be coated with polyurethane resin (big Japanese ink chemical industry (strain) system " Network リ ス ボ Application 7367SL; " 22 weight % dimethyl formamide solutions), it was flooded 5 minutes in using the coagulating basin of water management, make dimethyl formamide concentration reach 15 weight %, urethane resin layer is solidified.Subsequently, in tank, it is washed, then dry 120 seconds under 130 ℃ temperature.These samples are carried out the mensuration of peeling off evaluation and peel strength that evaluation, urethane resin layer are heaved, peeled off to urethane resin layer.The results are shown in table 1.
Embodiment 2～4
Except the terpenic series phenol resin content that makes copolymerization as shown in table 1 like that, all the other and embodiment 1 identical production process film are carried out the evaluation identical with embodiment 1.The results are shown in table 1.
Embodiment 5
With thickness be the PET film of 75 μ m as matrix, be coated with improved polyalkene (Mitsui Chemicals society system " ア De マ one SF731 ") in the above, make bed thickness reach 15 μ m.Extrude acrylic resin in the above, laminated on matrix with laminated method, make bed thickness reach 35 μ m, produce the operation film.
Using springtime motor (strain) system " AG1080B " as corona treatment then, is that 100m/ branch, void pitch are under the condition of 2mm in processing speed, presses the power output shown in the table 1, and corona treatment is implemented on the surface of vistanex.Identical with embodiment 1 then, make the urethane resin layer film forming, make sample, carry out the evaluation identical with embodiment 1.It the results are shown in table 1.
Embodiment 6,7
Except such power output that changes corona treatment as shown in table 1,, carry out the evaluation identical with embodiment 1 with embodiment 5 identical making samples.It the results are shown in table 1.
Embodiment 8
With the method identical the operation film of making is similarly to Example 1 carried out corona treatment, produce sample, carry out the evaluation identical with embodiment 1 with embodiment 5.It the results are shown in table 1.
Comparative example 1
The terpenic series phenol resin in not using embodiment 1,, carry out the evaluation identical with embodiment 1 with embodiment 1 identical production process film.It the results are shown in table 1.
Table 1
| Terpenic series phenol resin (weight portion) | The power output of corona treatment (kW) | Evaluation is heaved, peeled off to urethane resin layer | Urethane resin layer peel off evaluation | Peel strength (N/3cm) | |
| Embodiment 1 | 5 | - | ○ | ○ | 0.4 |
| Embodiment 2 | 10 | - | ○ | ○ | 1.2 |
| Embodiment 3 | 15 | - | ○ | ○ | 2.7 |
| Embodiment 4 | 20 | - | ○ | ○ | 5.1 |
| Embodiment 5 | - | 0.1 | ○ | ○ | 0.5 |
| Embodiment 6 | - | 0.5 | ○ | ○ | 1.7 |
| Embodiment 7 | - | 4.0 | ○ | ○ | 2.1 |
| Embodiment 8 | 5 | 0.1 | ○ | ○ | 1.5 |
| Comparative example 1 | - | - | × | △ | 0.2 |
Operation film of the present invention, it contains the content of terpenic series phenol resin in the vistanex of terpenic series phenol resin or the power output of corona treatment by control, can be with from the peel strength control of the layer of polyurethane of this operation film within the specific limits.
In the present invention, on the single face at least of the matrix that constitutes by synthetic resin film, the wet type synthetic leather manufacturing of the peel ply that setting is made of the vistanex that contains the terpenic series phenol resin is with the operation film and/or the vistanex surface has been carried out the wet type synthetic leather manufacturing operation film of corona treatment, it is in the polyurethane resin coagulating basin, layer of polyurethane is not peeled off, and in stripping process, the operation film is peeled off from this layer of polyurethane easily, has the fissility of appropriateness.
Claims (5)
1. wet type synthetic leather manufacturing operation film is characterized in that, on the single face at least of the matrix that is made of synthetic resin film, is provided with the peel ply that is made of vistanex that contains the terpenic series phenol resin or the surperficial vistanex that has carried out corona treatment.
2. according to the wet type synthetic leather manufacturing operation film of claim 1 record, it is characterized in that the said polyolefins resin is a polypropylene.
3. according to the wet type synthetic leather manufacturing operation films of claim 1 or 2 records, it is characterized in that the polyolefin layer that be provided with glycerol polymerization between above-mentioned matrix and the peel ply that is made of said polyolefins resin unsaturated acids or acid anhydrides obtains.
4. according to the wet type synthetic leather manufacturing operation film of claim 1 or 2 records, it is characterized in that above-mentioned synthetic resin film is the polyethylene terephthalate film.
5. according to the wet type synthetic leather manufacturing operation film of claim 3 record, it is characterized in that above-mentioned synthetic resin film is the polyethylene terephthalate film.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP90772/2002 | 2002-03-28 | ||
| JP2002090772A JP3936219B2 (en) | 2002-03-28 | 2002-03-28 | Process film for manufacturing wet synthetic leather |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1448579A CN1448579A (en) | 2003-10-15 |
| CN1272501C true CN1272501C (en) | 2006-08-30 |
Family
ID=28786139
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB031082661A Expired - Lifetime CN1272501C (en) | 2002-03-28 | 2003-03-27 | Process file for manufacturing wet type synthetic leather |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP3936219B2 (en) |
| KR (1) | KR100936098B1 (en) |
| CN (1) | CN1272501C (en) |
| TW (1) | TWI278551B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6645787B2 (en) * | 2015-09-30 | 2020-02-14 | ユニチカ株式会社 | Process film |
| WO2018150502A1 (en) * | 2017-02-15 | 2018-08-23 | リンテック株式会社 | Roll |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2849409B2 (en) * | 1989-07-27 | 1999-01-20 | 株式会社日立製作所 | Spectral shift operation method and operation control device for boiling water reactor |
| JPH10168761A (en) * | 1996-12-10 | 1998-06-23 | Fuji Techno Kk | Process paper for producing synthetic leather by wet process and application processing |
| JP2000108264A (en) * | 1998-09-30 | 2000-04-18 | Nippon Polyolefin Kk | Process sheet and manufacture of the same |
| JP4569998B2 (en) * | 2000-09-11 | 2010-10-27 | 大日本印刷株式会社 | Release paper and synthetic leather produced using it |
-
2002
- 2002-03-28 JP JP2002090772A patent/JP3936219B2/en not_active Expired - Lifetime
-
2003
- 2003-03-26 KR KR1020030018750A patent/KR100936098B1/en active IP Right Grant
- 2003-03-26 TW TW092106715A patent/TWI278551B/en not_active IP Right Cessation
- 2003-03-27 CN CNB031082661A patent/CN1272501C/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| KR20030078679A (en) | 2003-10-08 |
| CN1448579A (en) | 2003-10-15 |
| JP3936219B2 (en) | 2007-06-27 |
| TW200305672A (en) | 2003-11-01 |
| TWI278551B (en) | 2007-04-11 |
| JP2003286664A (en) | 2003-10-10 |
| KR100936098B1 (en) | 2010-01-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2401149B1 (en) | Method for making multi-layer print media by extrusion coating | |
| CN1112782A (en) | Uniaxially oriented label film with compatibilizer | |
| CN1119988A (en) | Synthetic paper with multi-layer structure and excellent printing property | |
| CN1637086A (en) | Resin composition for use in release film and release film produced therefrom | |
| CN112770886A (en) | Craft paper for concrete decoration and press molding material for concrete decoration | |
| CN1152760A (en) | Adhesive-stick type label | |
| CN1272501C (en) | Process file for manufacturing wet type synthetic leather | |
| CN1302921C (en) | Method for producing multilayer coextrudate and film structure produced by this method | |
| KR100732222B1 (en) | Mold releasable composite material for wet production of polyurethane resin synthetic leather | |
| CN1717445A (en) | Release agent, layered pressure-sensitive adhesive product, and layered pressure-sensitive adhesive tape | |
| WO2016136478A1 (en) | Flexographic printing plate, method for manufacturing flexographic printing plate, and original plate of flexographic printing plate | |
| CN1202310C (en) | Paper backing and adhesive sheet using the same | |
| JP3149275B2 (en) | Release sheet and method of manufacturing the same | |
| JPH0834058A (en) | Production of decorative sheet | |
| JP4377924B2 (en) | Process film for manufacturing wet synthetic leather | |
| JP2002220798A (en) | Released paper | |
| KR101607403B1 (en) | Entry board for fabricating PCB hole | |
| JP2004156223A (en) | Panel for concrete form and manufacturing method therefor | |
| JP4229315B2 (en) | Translucent hard coat resin molding, laminate film and transfer film | |
| JP2000225665A (en) | Unevenly patterned electron beam curing resin decortive sheet and manufacture thereof | |
| CN1809458A (en) | Mold release film and process for producing flexible printed wiring board therewith | |
| JPS60236717A (en) | Manufacture of developer sheet | |
| JPH0117277B2 (en) | ||
| JPH0686042B2 (en) | Method for producing resin-impregnated wood | |
| CN1139624C (en) | Reproducing polyester film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| REG | Reference to a national code |
Ref country code: HK Ref legal event code: WD Ref document number: 1058220 Country of ref document: HK |
|
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20060830 |