CN1152760A - Adhesive-stick type label - Google Patents

Adhesive-stick type label Download PDF

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Publication number
CN1152760A
CN1152760A CN96112797A CN96112797A CN1152760A CN 1152760 A CN1152760 A CN 1152760A CN 96112797 A CN96112797 A CN 96112797A CN 96112797 A CN96112797 A CN 96112797A CN 1152760 A CN1152760 A CN 1152760A
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CN
China
Prior art keywords
adhesive
stick type
type label
adhesive phase
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN96112797A
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Chinese (zh)
Other versions
CN1122250C (en
Inventor
山田敏数
月田达也
今和弘
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Lintec Corp
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Lintec Corp
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Publication of CN1152760A publication Critical patent/CN1152760A/en
Application granted granted Critical
Publication of CN1122250C publication Critical patent/CN1122250C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/08Fastening or securing by means not forming part of the material of the label itself
    • G09F3/10Fastening or securing by means not forming part of the material of the label itself by an adhesive layer
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/023Adhesive

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Adhesive Tapes (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention provides a tacky adhesive label which is easily peelable by contact with water, such as, for washing. This tacky adhesive label 1 is composed of a base material layer 2 and a tacky adhesive layer 3. This base material layer 2 is composed of materials, such as various kinds of paper, woven fabrics, non-woven fabrics and porous resin films, having water permeability. This tacky adhesive layer 3 is composed of a tacky adhesive of an emulsion system contg. about 2.0 to 20wt.% surfactant. Its tacky adhesive power is decreased by contact with the water. The tacky adhesive layer 3 has the characteristic of bringing about peeling from an adherend within 180 seconds when the hot water of 70 DEG C is continuously brought into collision against the label under 5kg/cm<2> water pressure.

Description

Adhesive-stick type label
The present invention relates to adhesive-stick type label, particularly be attached to the adhesive-stick type label that uses on the body that is attached for washing.
For example, packing milk, bottled beer, bread etc. are contained in transportation in the plastic case (box), keeping, but in the circulation stage, in order to discern content kind, number transmission destination etc., are pasting the adhesive-stick type label of representing these contents on chest.
In the past,, used solvent type acrylic adhesives usually, stipulated that its adhesion intensity of force is peeled off, come off etc. with unlikely generation in course of conveying was standard as the bonding agent of this adhesive-stick type label.
Yet, said vesse, therefore usually be repeatedly used, when re-using, must stick corresponding adhesive-stick type label, and chest is when using once again, wash chest with automatic washer, because the clinging power of adhesive-stick type label is strong, adhesive-stick type label is not peeled off in this washing but as mentioned above,, therefore, need be with the operation that manually the rubberizing label is torn it down from chest.
Yet, this method needs a lot of labours to be engaged in the operation that adhesive-stick type label is peeled off, therefore when chest uses once again, overlapping new adhesive-stick type label carries out what is called and heavily pastes on rubberizing label last time, but in this case, the outward appearance that has the damage chest, and, because thickness increases problems such as number that counterweight pastes is also restricted.
The object of the present invention is to provide a kind of by with for example the washing and so on water contact the adhesive-stick type label that just can be easy to peel off.
In order to achieve the above object, adhesive-stick type label of the present invention is characterised in that it has base material layer and adhesive phase, and above-mentioned adhesive phase is to be made of the latex class bonding agent that contains surfactant, by with contacting of water its clinging power being reduced.
Adhesive-stick type label of the present invention with above formation can not produce when adhesive-stick type label uses and run counter to peeling off of original idea, and by just contacting and can peel off at an easy rate with the water that for example is used to wash.
Therefore particularly, when being attached to chest and so on as mentioned above, can wash, peel off and remove adhesive-stick type label, can avoid being used for work already to peel off the miscellaneous of adhesive-stick type label along with it for being used on the adherend of washing.
The content of the above-mentioned surfactant in the above-mentioned adhesive phase preferably sets at 2.0~20wt%.
Above-mentioned surfactant is preferably formed by the material based on non-ionic surfactant.
The clinging power of above-mentioned adhesive phase when drying preferably sets at 300~2000g/25mm.
Above-mentioned base material layer preferably is made up of the material with water permeability.
Above-mentioned adhesive-stick type label preferably is attached to for being attached on the body of washing and uses.
The feature of adhesive-stick type label of the present invention is that also it has base material layer and adhesive phase, above-mentioned adhesive phase have with 70 ℃ warm water with 5kg/cm 2Hydraulic pressure bump the time, can be from being attached the characteristic that body strips down in 180 seconds.
Adhesive-stick type label of the present invention with above formation can not produce when adhesive-stick type label uses and run counter to peeling off of original idea, but by contacting then and can peel off at an easy rate with the water that for example is used to wash.
Particularly, be attached to chest and so on as mentioned above, can wash, peel off and remove adhesive-stick type label, therefore can avoid operation by hand to peel off the miscellaneous of adhesive-stick type label along with it for being attached when using on the body of washing.
The clinging power of above-mentioned adhesive phase when drying preferably sets at 300~2000g/25mm.
Above-mentioned base material layer is preferably formed by the material with water permeability.
Above-mentioned adhesive-stick type label preferably is attached to for being attached on the body of washing and uses.
Other purpose of the present invention constitutes and effect, can be from learning based on following examples record content of accompanying drawing and experimental example explanation.
Fig. 1 is the sectional view of expression adhesive-stick type label embodiment of the present invention.
Fig. 2 is the sectional view of expression adhesive-stick type label embodiment of the present invention.
Below the preferred embodiment shown in reference to the accompanying drawings describes adhesive-stick type label of the present invention in detail.
Fig. 1 is the sectional view of expression adhesive-stick type label embodiment of the present invention.Adhesive-stick type label 1 of the present invention is attached to the state that is attached on the body 4 shown in this figure.Adhesive-stick type label 1 is made of base material layer 2 and adhesive phase 3.
The constituent material of base material layer 2 in the present embodiment, there is not special qualification, for example can be by various resins such as polypropylene, tygon, polyester, polyamide, polyimide or, metal formings such as aluminium foil constitute, but peel off for the water that is fed into easily on the aftermentioned adhesive phase 3, preferably have the material of water permeability (especially water wettability).
As this base material layer 2, for example can enumerate various stationeries such as good quality paper, coated paper, heat-sensitive paper, the porous matter resin molding of weaving cloth, nonwoven fabrics, porous matter polypropylene screen and so on water permeability.
Base material layer 2 is not limited to individual layer, also can be made of the layered product more than 2 layers.
On the face of the side opposite of base material layer 2, for example can stamp marks such as literal, mark, figure, bar code (printing etc.) as required with adhesive phase 3.
Adhesive phase 3 is to be made of the latex class bonding agent that contains surfactant.
As bonding agent (stickability composition), can be that rubber adhesive, acrylic adhesives, type siloxane bonding agent etc. are any, but wherein especially preferably based on acrylic adhesives.
As acrylic adhesives, it is main monomer composition by the low Tg that gives cementability, give the comonomer composition of the high Tg of cementability and cohesiveness, the polymkeric substance or the multipolymer that contain monomer component for the functional group that improves crosslinked and cementability and be principal ingredient are formed.
As the main monomer composition, for example can enumerate alkyl acrylates such as ethyl acrylate, butyl acrylate, acrylic acid pentyl ester, 2-EHA, 2-ethyl hexyl acrylate, cyclohexyl acrylate, benzyl acrylate or, alkyl methacrylates such as butyl methacrylate, methacrylic acid 2-Octyl Nitrite, cyclohexyl methacrylate, benzyl methacrylate.
As the comonomer composition, can enumerate methyl acrylate, methyl methacrylate, Jia Jibingxisuanyizhi, vinyl acetate, styrene, vinyl cyanide etc.
As the monomer component that contains functional group, for example can enumerate acrylic acid, methacrylic acid, maleic acid, itaconic acid etc. contain carboxyl monomer or, 2-hydroxyethyl (methyl) acrylate, 2-hydroxypropyl (methyl) acrylate, N hydroxymethyl acrylamide etc. contain monomer, acrylamide, Methacrylamide, glycidyl methacrylate of hydroxyl etc.
The reason of preferred these materials be because, when clinging power, cohesiveness are good, owing to do not have unsaturated link in the polymkeric substance, thereby to the good stability of light and oxygen, and can obtain quality and characteristic arbitrarily according to purposes by the kind of monomer and the selection of molecular weight.
Above-mentioned bonding agent also can use any material of non-crosslinked type, cross-linking type.When using the latter, also can add various crosslinking chemicals as required.
In the adhesive phase 3, contain surfactant, therefore, the water wettability of adhesive phase 3 is improved, and when contacting with water, when washing particularly was provided, bonding agent lost activity, and peels off easily.
As this surfactant, for example can enumerate, the anionic surface active agent of sodium alkyl benzene sulfonate, alkyl diphenyl ether disulphonic acid sodium, NaLS, polyoxyethylene alkyl ether sodium sulphate and so on or, the non-ionics of NONIN HS 240, polyoxyethylene nonylplenyl ether, polyoxyethylene lauryl ether and so on etc. can be mixing uses more than a kind or 2 kinds wherein.Wherein, the reason less in view of hydrophobic group, that water wettability is higher is preferably based on the material of non-ionics.At this moment, as non-ionics, the big kind of especially preferred HLB (Hydrophilic-Lipophilic Balance, water wettability-hydrophobicity balance) value.
Surface-active contents in the adhesive phase 3 is higher.Just, the surface-active contents in the adhesive phase 3 is to be advisable in 2.0~20wt% (solid state component ratio) scope, and 3.0~18wt% (solid state component ratio) is better, and 4.0~15wt% (solid state component ratio) more preferably.If the content of surfactant very little, then the water wettability of adhesive phase 3 improves not enough, the very difficult contact with water promptly produces peeling off of adhesive phase 3, and, if the content of surfactant is too much, then can cause the performances such as cohesiveness of adhesive phase 3 to descend, also might produce bonding agent and ooze out or be impregnated in the base material layer and go.
Surfactant both can add in bonding agent manufacturing process, also can append after bonding agent is made.
In the adhesive phase 3, also can for example add plastifier, stickability imparting agent, thickening agent, filling agent, various adjuvants such as anti aging dope, antiseptic, mildewproof agent, dyestuff, pigment as required.
This adhesive phase 3 normally has necessity and enough clinging powers, reduces its clinging power by contacting with water.But with adhesive phase with following characteristic for well.
Adhesive phase 3 (contacts common state before) with water when drying clinging power is advisable preferred 500~1500g/25mm with 300~2000g/25mm.If this clinging power is low excessively, adhesive-stick type label such as (be attached body when carrying and during keeping) was easy to generate and runs counter to peeling off of original idea when then adhesive-stick type label used; If clinging power is too high,, might when contacting, be difficult to make adhesive phase 3 to produce and peels off with water then according to the conditions such as content of surfactant.
Adhesive phase 3 has, when bear 5kg/cm on adhesive-stick type label 1 2The warm water of 70 ℃ of hydraulic pressure continuous injections the time, in 180 seconds, more fortunately in 150 seconds, better 120 seconds with interior from peeled off the characteristic of (or losing clinging power) by adherend.
Have under the adhesive case of this specific character, for example plastic this class of chest of pasting adhesive-stick type label 1 is by adherend 4, when washing is provided, when especially washing with automatic washer, can be before washing finishes during automatically from being peeled off and remove adhesive-stick type label by adherend 4.
The thickness of adhesive phase 3 (dry film thickness) does not have special qualification, but be attached to for the washing used on the adherend 4 time, be advisable preferred 5~50 μ m with 3~100 μ m.
More than this adhesive-stick type label 1, contain bonding agent and surfactant, its manufacture method is, adjusted coating fluid directly is coated on the base material layer 2 in accordance with regulations, forms adhesive phase 3 by drying, perhaps, the duplicating that same coating fluid is coated on regulation is with on the plate, and dry back forms adhesive phase 3, this adhesive phase 3 is duplicated on the one side of base material layer 2 again.
Adhesive-stick type label of the present invention can also paste the release sheet (not shown) on adhesive phase 3.This release sheet, can use any material, for example the film formed of various resins such as polyethylene terephthalate, polybutylene terephthalate, polycarbonate, polyene propyl ester or, with paper woods such as polyethylene layer platen, the paper that is coated with carclazyte, viscose papers as matrix material, on the composition surface of the adhesive phase 3 of this matrix material, form release coating (siloxane layer etc.).
Adhesive-stick type label 1 of the present invention, preferably being attached to provides washing, especially with washing being used on the adherend 4 of (cleansing solution being water, aqueous alkali etc.) automatically.This by the representative of adherend 4, for example can enumerate the plastics system chest (box) of foods such as accommodating packing milk, bottled beer, bread etc.
Certainly, among the present invention by adherend 4, be not limited in these.
As shown in Figure 1, by the label veneer 5 of adherend 4, can be even surface, but as shown in Figure 2, for example preferably form and have small concavo-convex 6 face (uneven surface) by embossing.Label veneer 5 is under the situation of asperities, and the clinging power of the adhesive phase 3 relative with label veneer 5 reduces, and is immersed moisture by adherend 4 recess by asperities when the washing, and adhesive phase 3 contacts with water easily, so can peel off easilier.
Below illustrate in greater detail the present invention by specific embodiment.
Embodiment 1
Preparation is used to form the coating fluid of adhesive phase by the following method, this coating fluid is coated on the face of base material layer, behind the dry formation adhesive phase, thereby on this adhesive phase, paste the adhesive-stick type label (size: vertical 100mm * horizontal 100mm) that release sheet forms the present invention
The preparation method of coating fluid
With 2-EHA and, butyl acrylate and, vinyl acetate and, acrylic acid and, surfactant (polyoxyethylene nonylplenyl ether) reacts by general emulsion polymerization prescription, the preparation coating fluid.
Make the condition of each layer in the adhesive-stick type label, as shown below.
1. base material layer
Constituent material: good quality paper
Thickness: 80 μ m
2. adhesive phase
[bonding agent]
2-EHA: 60 weight portions
Butyl acrylate: 32 weight portions
Vinyl acetate: 5 weight portions
Acrylic acid: 3 weight portions
Acrylic polymer
[surfactant]
Polyoxyethylene nonylplenyl ether (non-ionics): 60wt% (solid state component ratio)
Thickness: 20 μ m
3. release sheet
Constituent material: viscose paper, one side is carried out siloxane treated, thickness: 70 μ m
Embodiment 2
Except that the thickness with adhesive phase changes over 30 μ m, make adhesive-stick type label by the method identical with embodiment 1.
Embodiment 3
Except that with the surfactant in the adhesive phase by following the change, by making adhesive-stick type label with embodiment 1 same procedure.
[surfactant]
Polyoxyethylene nonylplenyl ether (non-ionics): 3wt% (solid state component ratio)
Embodiment 4
Except that with the surfactant in the adhesive phase by following the change, by making adhesive-stick type label with embodiment 1 same procedure.
[surfactant]
Polyoxyethylene nonylplenyl ether (non-ionics): 4wt% (solid state component ratio)
Sodium lauryl benzene sulfonate (anionic surface active agent): 2wt% (solid state component)
Embodiment 5
Except that with the bonding agent in the adhesive phase and surfactant by following the change, by making adhesive-stick type label with embodiment 1 same procedure.
[bonding agent]
Butyl acrylate: 62 weight portions
2-EHA: 30 weight portions
Vinyl acetate: 5 weight portions
Acrylic acid: 3 weight portions
Acrylic polymer
[surfactant]
Polyoxyethylene nonylplenyl ether (non-ionics): 4wt% (solid state component ratio)
Sodium lauryl benzene sulfonate (anionic surface active agent): 2wt% (solid state component ratio)
Embodiment 6
Except with base material layer, use instead outside the heat-sensitive paper that thickness is 80 μ m, by making adhesive-stick type label with embodiment 4 same procedure.
Embodiment 7
Except with base material layer, using thickness instead is outside the porous matter polypropylene film of 50 μ m, by making adhesive-stick type label with embodiment 1 same procedure.
Embodiment 8
Except base material layer being changed into the continuous cloth of plain weave wood that thickness is 150 μ m, by making adhesive-stick type label with embodiment 1 same procedure.
Comparative Examples 1
Preparation is used to form the coating fluid of adhesive phase by the following method, except form the adhesive phase of being made up of solvent type acrylic adhesives with this coating fluid, by making adhesive-stick type label with embodiment 1 same procedure
The preparation method of coating fluid
With 2-EHA: 60 weight portions and, butyl acrylate: 32 weight portions and, vinyl acetate: 5 weight portions and, acrylic acid: 3 weight portions, ethyl acetate as solvent, is reacted by general polymerization prescription, with respect to polymkeric substance 100 weight portions that obtain in this reaction, the コ mouth ネ one ト L (Japanese Port リ ウ レ ソ Co., Ltd. system) that adds 1 weight portion as crosslinking chemical, makes coating fluid.
Comparative Examples 2
Except base material layer being used instead the porous matter polypropylene film that thickness is 50 μ m, make adhesive-stick type label by Comparative Examples 1 same procedure.
Test
From the foregoing description 1~8, remove release sheet on each adhesive-stick type label of Comparative Examples 1,2, be attached to following A, B2 kind respectively by on the adherend with the adhesive phase that exposes
A. be the sheet material of polypropylene system, the label veneer is an even surface.
B. be the sheet material of polypropylene system, the label veneer is a uneven surface
(surfaceness Rmax=40 μ m)
Below, when pressing the clinging power of JIS Z 0237 each adhesive-stick type label of standard test, as decantation test, facing to labelling partly by adherend with 5kg/cm 2The warm water of 70 ℃ of hydraulic pressure continuous injections, measure time until adhesive-stick type label is peeled off, come off.These be the results are shown in the following table 1.
Can learn clearly that by result shown in the table 1 adhesive-stick type label of the present invention of embodiment 1~8 is compared with the adhesive-stick type label of Comparative Examples, in very short time just from being peeled off, split away off by adherend.
As mentioned above,, when adhesive-stick type label uses, can not produce and run counter to peeling off of original idea, but just contact and to peel off at an easy rate by water with for example washing and so on according to adhesive-stick type label of the present invention.
Therefore particularly, when being attached to chest and so on as mentioned above, can wash, peel off and remove adhesive-stick type label, can avoid operation by hand to peel off the miscellaneous of adhesive-stick type label along with it for being used on the adherend of washing.
The present invention is not limited to above-mentioned embodiment or embodiment, and its scope is only by following claim decision.
Table 1
Clinging power (g/25mm) Peel off the time (second) that comes off until adhesive-stick type label
By adherend A Embodiment 1 ????1200 ????30
Embodiment 2 ????1500 ????40
Embodiment 3 ????1200 ????90
Embodiment 4 ????1200 ????40
Embodiment 5 ????1300 ????35
Embodiment 6 ????1400 ????60
Embodiment 7 ????1200 ????120
Embodiment 8 ????1100 ????100
Comparative example 1 ????1500 Do not peel off and come off
Comparative example 2 ????1500 Do not peel off and come off
By adherend B Embodiment 1 ????600 ????15
Embodiment 2 ????700 ????20
Embodiment 3 ????600 ????40
Embodiment 4 ????600 ????20
Embodiment 5 ????700 ????20
Embodiment 6 ????700 ????30
Embodiment 7 ????600 ????60
Embodiment 8 ????600 ????60
Comparative example 1 ????800 ????300
Comparative example 2 ????800 ????300

Claims (7)

1. adhesive-stick type label, it is a kind of adhesive-stick type label with base material layer and adhesive phase, it is characterized in that, described adhesive phase constitutes by containing surface-active latex class bonding agent, reduces its clinging power by contacting with water.
2. the adhesive-stick type label described in the claim 1, wherein, the described surface-active contents in the described adhesive phase is 2.0~20wt%.
3. claim 1 or 2 described adhesive-stick type labels, wherein, described surfactant is based on the nonionic Surfactant.
4. adhesive-stick type label, it is a kind of adhesive-stick type label with base material layer and adhesive phase, it is characterized in that, described adhesive phase has with 5kg/cm 2The warm water of 70 ℃ of hydraulic pressure continuous injections the time, at 180 seconds with interior characteristic from being stripped down by adherend.
5. each described adhesive-stick type label in the claim 1~4, wherein, the clinging power of described adhesive phase when drying is 300-2000g/25mm.
6. each described adhesive-stick type label in the claim 1~5, wherein, described base material layer has water permeability.
7. each described adhesive-stick type label in the claim 1~6 wherein, is to be attached to being used on the adherend for washing.
CN96112797A 1995-10-19 1996-10-18 Adhesive-stick type label Expired - Fee Related CN1122250C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP7296264A JPH09114382A (en) 1995-10-19 1995-10-19 Tacky adhesive label
JP296264/95 1995-10-19
JP296264/1995 1995-10-19

Publications (2)

Publication Number Publication Date
CN1152760A true CN1152760A (en) 1997-06-25
CN1122250C CN1122250C (en) 2003-09-24

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN96112797A Expired - Fee Related CN1122250C (en) 1995-10-19 1996-10-18 Adhesive-stick type label

Country Status (4)

Country Link
JP (1) JPH09114382A (en)
KR (1) KR100438076B1 (en)
CN (1) CN1122250C (en)
TW (1) TW327687B (en)

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CN103319968A (en) * 2008-03-13 2013-09-25 日东电工株式会社 Adhesive composition, adhesive layer, adhesive member and image display device, and also a method for detaching an optical film from an image display device
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Also Published As

Publication number Publication date
JPH09114382A (en) 1997-05-02
TW327687B (en) 1998-03-01
KR970022896A (en) 1997-05-30
CN1122250C (en) 2003-09-24
KR100438076B1 (en) 2004-08-31

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