CN1268489A - Drinking water containing several mineral nutrients, its preparation method and application - Google Patents
Drinking water containing several mineral nutrients, its preparation method and application Download PDFInfo
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Abstract
The present invention relates to a nutritive water containing multi-minerals, its main components include different drinking water as carrier and effective quantity of microelements which are in the form of acetates, chlorides, sodium selenite (or sodium selenate), calcium gluconate, calcium lactate, L-calcium threonate, VC calcium and calcium salt of amino acids. It can supplement macroelements such as Ca, P, Mg and microelements such as Se, Mn, Zn, Co, Mo, Sr, Fe, Si etc.
Description
The invention relates to a kind of novel drinkable water, more particularly can effectively replenish drinking water containing several mineral nutrients of human body beneficial's element and its production and use about a kind of.
Mineral element is one of human body six big nutritive factors of growing.14 kinds of essential trace elements of The World Health Organization's affirmation at present have zinc, copper, iron, iodine, selenium, chromium, cobalt, manganese, molybdenum, vanadium, fluorine, nickel, strontium, tin.Mineral element, particularly trace element play omnibearing effect in human body grows, comprise construction, reparation from body tissue, to physiological metabolism, to raise immunity, even the effect of directly preventing and curing diseases are arranged.
Calcium be human life this, the cell of each organ all contains certain calcium, and the inside and outside calcium ion concn difference of cell walls be must keep one to one ten thousand ratio the time, the function of cell and organ could be normally; Otherwise cell and organ dysfunction are undesired will be sick.Calcium is the maximum mineral element of in-vivo content, 1.5~2% of about percentage of liveweight, and wherein 99% in bone and tooth, and 1% presents ionic state in blood and soft tissue, keeps running balance with bone calcium.Though ion state calcium is few, and important physiological function such as nerve conduction, Muscle contraction, heart are normally beated, human thinking are arranged.Because calcium participates in metabolism, has every day hundreds of milligrams of calcium to excrete, so need constantly to replenish.General per day for adults need be taken in 800 milligrams of calcium, 400~600 milligrams of children, 1000~1500 milligrams of pregnant woman.Because the common food calcium content is low, specific absorption only 20~30%, in addition the adult absorb calcium ability with the increase at age reason such as minimizing, take in the calcium amount and often be difficult to reach standard, form the calcium deficiency phenomenon.
Solve calcifames, can eat rich calcium food, more as bean product, dairy products etc.; But the most simple and effective way is still replenished the calcium with calcium preparation, or the edible food of strengthening with the calcium agent.As developed country in recent years " eating calcium heat " appears, people even the calcium agent is considered as controlling osteopathy, anti-cancer, hypotensive, so that the anti-ageing treasure of health care.Yet general calcium agent belongs to the molecular calcium agent, and institute's calcic is atomic state and can not goes out with physical method for separation; And be insoluble in water, need to decompose and the help of vitamins D through hydrochloric acid in gastric juice, the calcium atom that the big activity of radius is little just can be converted into the little activity of radius big can be by the calcium ion of intestinal absorption.If the hydrochloric acid in gastric juice deficiency, then effect of supplemented calcium is just desirable not to the utmost, and causes that toward the contact meeting constipation and vitamins D assemble and intoxicating phenomenon gradually.Therefore, how safely and effectively for the mankind replenish the calcium, remain medical circle, the right difficult problem in trophology interface for a long time.
Magnesium is the activator of many enzymes.Magnesium-ATP (Triphosaden) mixture is the reaction substrate of all enzymes.Magnesium participates in the ATP hydrolysis of cardiac muscle fibre in cardiac muscle.The combination of muscle and each organ calcium and release, cardiac motion, keep nerve, blood vessel and cardiac system normal function, promote the synthetic all relevant of genetic material with magnesium.The general every order of grownup need be taken in 300~350 milligrams in magnesium, and containing the many vegetables of chlorophyll, millet, wheat, meat, sea-food etc. all is the good source of magnesium; But specific absorption is low, so that common people take the photograph magnesium is on the low side.Moreover, if long-term chronic diarrhoea causes the excessive discharge of magnesium, magnesium deficiency can appear.
Potassium is positively charged ion the abundantest in the human body, accounts for 75~80%, is the important ionogen of cell; Can regulate heart, muscle, nervous function, keep the osmotic pressure and the acid base equilibrium of fluid of inside and outside cell, long-term potassium deficiency causes that easily neural system, muscle are unusual.The adult need take in 1875~5625 milligrams in potassium every day, and potassium is distributed widely in the various kinds of foods, but specific absorption is low.
Selenium is described as the jinx of cancer, and it is the constituent of Selenoperoxidase, and anti-peroxidation and reductive action are arranged, and the protection cell is not damaged, and can reach best anticancer effect; But anticoagulant also, preventing thrombosis forms; Remove the vessel wall inner cholesterol, prevent coronary heart disease.Appropriate supplement selenium can strengthen people's immunizing power, can prevent curing cancers, tumour, heart white muscle disease, Kaschin-Beck disease, cardiovascular and cerebrovascular disease, arrhythmia, hepatopathy, diabetes, cataract, children's retarded etc. more than 40 plant sick, and can delay senility, vision protection.The adult needs selenium 50~250 micrograms every day, and China lacks selenium in the area more than 90%.
Manganese is described as long-lived element, and it participates in superoxide-dismutase, can raise immunity, help the control of cancer, schizophrenia, diabetes; Can remove aging principal element-superoxide radical.Manganese deficiency easily causes nanism, anaemia, tumour, liver cancer, the esophageal carcinoma, hypertension.The adult needs 2.5~5 milligrams in manganese every day, and regional manganese deficiencies such as China's Delta of the Pearl River, Yangtze River Delta and northeast are comparatively serious.
Zinc is the flower of life, and participation carbonic acid enzyme, telomere (DNA) wait the component of hundreds of enzyme, keep cellularstructure and function, the booster immunization function.Scarce zinc causes easily that the sexual organ development is bad, sexual function reduction, oligospermia, menstruation is undesired or stop, fetal anomaly; Children's appetite is poor, growth retardation, short, stupid, near-sighted, immunologic hypofunction; Diseases such as adult's arteriosclerosis, coronary heart disease, hepatitis, renal insufficiency, leukemia, cancer, alopecia, early ageing.It is generally not enough that the adult needs 15 milligrams on zinc, Chinese people to take in zinc every day, especially with children for very.
Iron is the hematopoiesis element, and iron deficiency easily causes diseases such as anaemia, hypoimmunity, easy to catch cold, distraction, memory are strong, stomatitis, chronic gastritis, cancer of the stomach.The adult needs 20 milligrams of iron every day, and China's hypoferric anemia is more, especially with children for very.
Cobalt is the king of trace element, and it participates in the marrow hemopoiesis function, promotes erythrocytic growth and maturation, promotes nucleic acid and protein synthesis nucleoprotein, and is also relevant with cardiovascular growth and metabolism.Scarce cobalt easily causes diseases such as pernicious anemia, nerve degeneration, milk stop to secrete, become thin, asthma, cardiovascular diseases, myelitis, glaucoma, cataract, leukemia, cancer of the stomach.The adult needs cobalt 3~5 micrograms every day.
Molybdenum can help irony nutrition to store in vivo, also is to keep one of elastic essential material of arterial wall, is the composition of nitrite reductase etc., can make nitrous acid reduction ammonification and lose carcinogenic toxicity, so be cancerocidal substance.Scarce molybdenum easily causes diseases such as cardiovascular disorder, malnutritive syndromes, retardation of growth, sacroiliitis, the esophageal carcinoma, tumour, stomach ulcer, urinary stone disease, impotence, carious tooth.The adult needs molybdenum 150~500 micrograms every day.
Strontium is the component of bone and tooth, and cardiovascular disordeies such as energy preventing hypertension can be protected biomembranous stability, and calcium ion concn difference inside and outside safeguarding cytolemma is played an important role; Can replace the calcium ion in the urinary stone, calculus is diminished gradually and discharge; Scarce strontium easily causes diseases such as osteoporosis, calculus, carious tooth, cramp.The adult needs 2 milligrams in strontium every day.
The synergy of above element can play the effect of control to cancer, cardiovascular and cerebrovascular disease, diabetes etc., and can eliminate harmful free radicals, delays senility.
As from the foregoing, above-mentioned element is most important to HUMAN HEALTH longevity, and human body all will consume some amount every day, so that also should give every day is additional, could keep element balance.The mode of replenishing multielement is to provide with normal diet, and also available tonic or element preparation replenish.But because of need complementary element kind is many, also just must eat various food or preparation, do unavoidable inconvenience like this.Certainly the edible natural mineral water also can provide the beneficial element of certain kind, some amount, but just because be natural, the ratio between contained elementary composition and the element is changeless, so not necessarily meet the human body needs fully.Up to now, the contriver of this patent product still finds no commodity like this and bibliographical information.
One of purpose of the present invention provides a kind of prior art existing problems of overcoming, and is the drinking water containing several mineral nutrients that the mankind replenish multielement.
Two of purpose of the present invention provides is a kind ofly directly drinking or is doing meals, soup, beverage etc. when directly edible, can effectively replenish the main mineral element nutrition of needed by human body, control is these elements and the multiple chronic disease (as cancer, cardiovascular and cerebrovascular disease and diabetes etc.) that causes for want of, thus the drinking water containing several mineral nutrients that keeps fit and promote longevity.
Three of purpose of the present invention provides a kind of preparation method of drinking water containing several mineral nutrients.
These and other purpose of the present invention will further be illustrated by following detailed description and explanation.
Drinking water containing several mineral nutrients of the present invention, comprise various drinkable waters as carrier, also comprise acetate, muriate and Sodium Selenite (or sodium selenate), calglucon, calcium lactate, l threonic acid, VC calcium, the amino acid calcium of the magnanimity of significant quantity, particularly trace element etc., wherein water-content is 98~99.99 (WT) %; The element that adds in the described water can be calcium, potassium, magnesium, selenium, manganese, zinc, cobalt, molybdenum, strontium, iron, silicon etc., can add one or more separately.
Drinking water containing several mineral nutrients of the present invention contains calcium, manganese, zinc, iron, selenium, magnesium ion in drinking water containing several mineral nutrients, wherein, the content of above-mentioned ion in water is: (unit: mg/litre)
Calcium ion (Ca
2+): 78~400; Magnesium ion (Mg
2+): 4.5~60;
Mn ion (Mn
2+): 0.04~1.5; Zine ion (Zn
2+): 0.2~7.5;
Iron ion (Fe
2+): 0.26~10; Plasma selenium (Se
2-): 0.003~0.1.
Further, contain calcium, manganese, zinc, iron, selenium, magnesium ion in the drinking water containing several mineral nutrients of the present invention, wherein, the content of above-mentioned ion in water is: (unit: mg/litre)
Calcium ion (Ca
2+): 78~162; Magnesium ion (Mg
2+): 4.6~9.5;
Mn ion (Mn
2+): 0.04~0.1; Zine ion (Zn
2+): 0.2~0.4;
Iron ion (Fe
2+): 0.3~0.5; Plasma selenium (Se
2-): 0.003~0.005.
Be preferably, contain calcium, manganese, zinc, iron, selenium, magnesium ion in the drinking water containing several mineral nutrients of the present invention, wherein, the content of above-mentioned ion in water is: (unit: mg/litre)
Calcium ion (Ca
2+): 78~162; Magnesium ion (Mg
2+): 9~19;
Mn ion (Mn
2+): 0.08~0.2; Zine ion (Zn
2+): 0.4~1.0;
Iron ion (Fe
2+): 0.5~1.1; Plasma selenium (Se
2-): 0.005~0.011.
In the present invention, also can contain cobalt, molybdenum, potassium and strontium plasma in the drinking water containing several mineral nutrients.
Also can contain cobalt, molybdenum, potassium and strontium ion in the drinking water containing several mineral nutrients of the present invention, wherein, the content of above-mentioned ion in water is: (unit: mg/litre)
Cobalt ion (Co
2+): 0.004~0.2; Molybdenum ion (Mo
2+): 0.002~0.1;
Potassium ion (K
+): 26~1000; Strontium ion (Sr
2+): 0.1~1.0.
Be preferably, also can contain cobalt, molybdenum, potassium and strontium ion in the drinking water containing several mineral nutrients of the present invention, wherein, the content of above-mentioned ion in water is: (unit: mg/litre)
Cobalt ion (Co
2+): 0.008~0.02; Molybdenum ion (Mo
2+): 0.004~0.008;
Potassium ion (K
+): 50~108; Strontium ion (Sr
2+): 0.14~0.3.
In the present invention, described many mineral ions can be selected from calcium acetate, calglucon, calcium lactate, l threonic acid, VC calcium, amino acid calcium, manganese acetate, Cobaltous diacetate, Sodium orthomolybdate, zinc acetate, iron protochloride, Sodium Selenite, Repone K, magnesium chloride etc.; Described water is a kind of of various drinkable waters, can be pure water, distilled water, deionized water, also can be rivers water, well water, spring, mineral water, tap water.
Drinking water containing several mineral nutrients of the present invention can prepare by the following method, comprises the steps:
A, take by weighing the multielement compound: (unit: gram/ton) in following ratio
Calcium acetate or other calcium agent 325~1668; Manganese acetate 0.2~7; Cobaltous diacetate 0.02~0.8;
Sodium orthomolybdate 0.004~0.2; Zinc acetate 0.7~25; Iron protochloride 0.9~36;
Sodium Selenite 0.007~0.2; Repone K 50~1907; Magnesium chloride 38~502.
B, in the agitator of excess water is arranged, press the precedence of sodium selenate, Sodium orthomolybdate, muriate, acetate and other calcium agent, the compound that has weighed up is slowly added, and fully stirs, make it be dissolved into colourless transparent solution, leave standstill about 1 hour;
C, be drinking water containing several mineral nutrients with pressure filter press filtration, filtrate;
D, be fed in the container, and seal, product;
The project check according to the pertinent regulations of state of E, product.
Be preferably, the preparation method of drinking water containing several mineral nutrients of the present invention comprises the steps:
A, take by weighing the multielement compound: (unit: gram/ton) in following ratio
Calcium acetate or other calcium agent 325~676; Manganese acetate 0.4~0.9; Cobaltous diacetate 0.03~0.08;
Sodium orthomolybdate 0.01~0.02; Zinc acetate 1.3~3.4; Iron protochloride 1.8~3.9;
Sodium Selenite 0.011~0.024; Repone K 95~206; Magnesium chloride 75~159.
B, in the agitator of excess water is arranged, press the precedence of sodium selenate, Sodium orthomolybdate, muriate, acetate and other calcium agent, the compound that has weighed up is slowly added, and fully stirs, make it be dissolved into colourless transparent solution, leave standstill about 1 hour;
C, be drinking water containing several mineral nutrients with pressure filter press filtration, filtrate;
D, sterilization, sterilization;
E, be fed in the container, and seal, product;
The project check according to the pertinent regulations of state of F, product.
Be underground water as the water that uses among the present invention, then water hardness is good with<4 and 4~8; The acid-basicity of water with pH value less than 5 to being good greater than 9, but best with 6~8; Water colorless is transparent, and nothing precipitation, opacity are no more than 5 mg/litre, boils the back odorless, and free from extraneous odour must not contain macroscopic aquatic organism and disgusting material; Cultivated 24 hours down at 37 ℃, total plate count is no more than 100/milliliter, and intestinal bacteria are no more than 3/liter.
It can be that food grade multielement calcium acetate also can be the acetate of simple food grade multiple beneficial magnanimity, particularly trace element and muriate and Sodium Selenite, sodium selenate, other calcium agent that the present invention carries the solvent that adds in the drinking water containing several mineral nutrients.
The system calcium acetate the calcium source be material calciferous, as natural mineral calcite, pearl, shell etc., they all are the mineral acid calcium salts, with the calcium acetate that generates after the acetic acid effect in the organic acid be calcium of organic acid normal salt, so calcium acetate ought to belong to organic calcium.
Human essential elements needs intake (RDA) every day, and " the human elementary daily intaking amount table " formulated according to The World Health Organization (WHO) is organized into table 1.In the drinking water containing several mineral nutrients of the present invention, adding amount of element is according to local water quality and the shortage situation of crowd to relevant element, and need take in the normal content of element everyone every day in conjunction with the grownup that the World Health Organization and China NI formulate, yet to consider simultaneously, the needed by human body mineral matter nutritional be from food (comprising foodstuff raw material) as rice, face, meat, dish etc. and two approach of drinkable water and obtaining.According to trophology and medical information, 5% of the total amount of the various trace elements of needed by human body is to derive from water.Therefore, each constituent content is a principle with this ratio at first also in the drinking water containing several mineral nutrients of this patent.But consider that this kind content only is general requirement, i.e. minimum requirements, concerning replenishing mineral element, effect is inevitable not obvious.If expanded to 2 times, promptly it 10% derives from water, and this moment, content increased, and has zinc, selenium, three in strontium to determine whether the requirement that touches the mark of element for mineral water, very is suitable for replenishing mineral matter nutritional; If expanded to 4 times, promptly it 20% derives from water, though then content increases, may some be higher, and easily cause side effect.Therefore, be good to select 10% ratio for use.Table 1
Human elementary daily intaking amount table milligram/day
Age | ??0-1 | ??2-9 | ??10-18 | The adult | The old man | The pregnant woman | Wet nurse |
Calcium Ca 2+ | ??400-600 | ??600- ??800 | ??1000- ??1200 | ??800- ??1200 | ??1500 | ??2000 | |
Magnesium Mg 2+ | ??50-70 | ??150-250 | ??350 | ??350 | ??450 | ??450 | |
Potassium K + | ??350- ??1275 | ??550- ??3000 | ??1525- ??4575 | ??1875- ??5625 | |||
Sodium Na + | ??115- ??750 | ??325- ??1800 | ??1800- ??2700 | ??1100- ??3300 | |||
Iron Fe 2+ | ??10 | ??10-12 | ??12-18 | ??12-18 | ??28 | ??28 | |
Cobalt Co 2+ | ??0.0003 | ??0.0009- ??0.0015 | ??0.002- ??0.003 | ??0.003- ??0.005 | ??0.003 | ??0.0025 | |
Zinc Zn 2+ | ??3-5 | ??10 | ??15 | ??15 | ??20 | ??25 | |
Iodine I - | ??40-50 | ??70-120 | ??150 | ??150 | ??175 | ??200 | |
Copper Cu 2+ | ??0.5-1.0 | ??1.5-2.5 | ??2.0-3.0 | ??2.0-3.0 | |||
Manganese Mn 2+ | ??0.5-1.0 | ??1.5-3.0 | ??2.5-5.0 | ??2.5-5.0 | |||
Chromium Cr 3+ | ??0.01- ??0.06 | ??0.02- ??0.2 | ??0.05- ??0.2 | ??0.05- ??0.2 | |||
Molybdenum Mo 2+ | ??0.03- ??0.08 | ??0.10- ??0.30 | ??0.15- ??0.50 | ??0.15- ??0.50 | |||
Selenium Se 2- | ??0.01- ??0.06 | ??0.02- ??0.20 | ??0.05- ??0.20 | ??0.05- ??0.20 | |||
Fluorine F - | ??0.1-1.0 | ??0.5-2.5 | ??1.5-2.5 | ??1.5-4.0 | |||
Chlorine Cl - | ??275- ??1400 | ??500- ??2775 | ??1400- ??4200 | ??1700- ??5100 | |||
Strontium Sr 2+ | ??2 |
According to table 1, each element daily intaking amount differs very great disparity.For example, being grown up everyone, to take in 1000 milligrams of calcium in average day be iron, manganese, zinc, cobalt, molybdenum, selenium summation 28 times unexpectedly.Therefore, lack the caused various syndromes of these elements, ought to be the most obvious with calcium deficiency, also discover easily and draw, thereby covered the symptom that lacks other elements.So, often also just easily people are merely replenished the calcium, mend other elements and look.In other words, calcium deficiency person's majority should also be simultaneously to lack other mineral elements person.Therefore, the concrete formulating of recipe of drinking water containing several mineral nutrients is with regard to the corresponding principle of other mineral elements of benefit of holding concurrently in calcium-enriched of taking.
" practical element medicine " report according to publication in 1999: sodium, chlorine, phosphorus, manganese, copper, chromium and molybdenum intake abundance in China's meals, satisfied specified requirement.China resident calcium, zinc and potassium intake are low excessively, and the intake of selenium and magnesium is also on the low side.Sideropenia and hypoferric anemia are still the harm women and the children's of current China important deficiency disease.Other essential trace elements are difficult to directly carry out hygienical evaluation owing to do not make the day feed rate hygienic standard of China as yet; But China's germanium, arsenic, vanadium, cobalt and fluorine intake also are on the low side in the world.
Above-mentioned situation is added element components and must be considered carefully when the preparation drinking water containing several mineral nutrients; But preparation at first will be studied local water quality and the resident situation that needs to element, and then required element components is added in decision.In water, cross the low interpolation of also can considering as some element.In addition, some element physiological function particularly important also can be considered to add, and for example: manganese is long-lived element, and longevo's hair manganese value is healthy people more than 2 times, and also can prevent curing cancers, so take the circumstances into consideration interpolation.
In the present invention, drinking water containing several mineral nutrients can prepare by the following method, and its processing step mainly comprises:
A, formulating of recipe:
When serving as main system drinking water containing several mineral nutrients with the multielement calcium acetate, needing needs to add the element kind according to aforementioned principle design earlier, calculates the prescription value of system multielement calcium acetate, and is worth with this and prepares required multielement calcium acetate, calculates the prescription value of respectively dividing into groups again.When system multielement calcium acetate, raw materials used can be the raw material of non-food grade, as natural mineral calcite (CaCO
3) etc.
Table 2
With required element compound weight of pure water preparation drinking water containing several mineral nutrients and prescription value design table
Annotate: need intake (mg) everyone every day of being grown up: calcium 800, manganese 3, cobalt 0.3, molybdenum 0.15, zinc 15, iron 20, selenium 0.2, potassium 2000, magnesium 350, strontium 2.Because China is calcium deficiency 300mg per capita, so calcium is 300mg in design 2.5 premium on currency, quite calcium acetate 1.3g contains strontium 0.546mg.Other elements 5% by providing in the water, i.e. the 2nd hurdle indication in the table.Make each constituent content of water (mg/l): calcium 120, manganese 0.06, cobalt 0.006, molybdenum 0.003, zinc 0.3 (reaching the mineral water index), iron 0.4, selenium 0.004, potassium 40, magnesium 7, strontium 0.22 (reaching the mineral water index).
Be example now with distilled water or the space water that does not contain any mineral element, and establish the general manganese deficiency of local resident, molybdenum is comparatively remarkable, design the combination of its element with this condition, and calculate needed weight, prescription value, prepare suitable multielement acetic acid calcium powder with this value of prescription again, as additive.In addition, also add Repone K, magnesium chloride and Sodium Selenite.Its combination sees Table grouping prescription value in 2.
B, calculate and weigh up the compound that need to add:
The all cpds weight that calculates the stainless steel vessel or the agitator Central Plains water weight of the former water of using as dissolving tank of Sheng and need to add, and accurately weigh up, be loaded in the container, be equipped with to add and dissolve and use.Calculation formula:
The drinking water containing several mineral nutrients weight of making (kilogram)=former water weight (kilogram) ÷ former moisture assembly side's value (%);
Drinking water containing several mineral nutrients weight (kilogram) * certain groups elements prescription value (%) certain compound purity of ÷ (%) of certain compound weight (kilogram) of need adding=make;
C, dissolving and sterilization: Jiang Yuanshui places stainless steel vessel or the agitator of using as dissolving tank, press the precedence of Sodium Selenite (or sodium selenate), Sodium orthomolybdate, muriate, polynary calcium acetate, the compound that has weighed up is slowly added, and fully stir, make it be dissolved into colourless transparent solution, left standstill 1 hour, with precipitation and sterilization, sterilizing agent is all cpds that is added.
D, pressure filter press filtration: filtrate water white transparency, i.e. drinking water containing several mineral nutrients.
E, be fed in the container, and seal, product.
F, check: product project according to the pertinent regulations of state can be made commodity selling after the assay was approved.
Drinking water containing several mineral nutrients of the present invention also can prepare by the following method, and its processing step comprises:
A, formulating of recipe: with the human essential elements compound, as food grade acetate, muriate and Sodium Selenite (or sodium selenate), calglucon, calcium lactate, l threonic acid, VC calcium, amino acid calcium, when directly making drinking water containing several mineral nutrients, need design at first as required to need to add the element kind, calculate various element compound individual event prescription values, this law and preceding method do not have difference in essence, but this law compound used therefor is a food grade.
B, calculate and weigh up the compound that need to add:
Calculation formula: the drinking water containing several mineral nutrients weight of making (kilogram)=
Former water weight (kilogram) ÷ former water individual event prescription value (%); Drinking water containing several mineral nutrients weight (kilogram) * certain element individual event prescription value (%) of certain compound weight (kilogram) of need adding=make
Certain compound purity of ÷ (%);
C, dissolving and sterilization: Jiang Yuanshui places stainless steel vessel or agitator, press the precedence of Sodium Selenite (or sodium selenate), Sodium orthomolybdate, muriate, acetate and other calcium salts, the compound that has weighed up is slowly added, and fully stir, make it be dissolved into colourless transparent solution, left standstill 1 hour, and made it precipitation, sterilization, sterilizing agent is all cpds that is added.
D, pressure filter press filtration: the filtrate water white transparency is drinking water containing several mineral nutrients.
E, be fed in the container, and seal, product.
F, check: project just can be made commodity selling after the assay was approved according to the pertinent regulations of state.
According to above-mentioned two kinds method, the processing requirements that prepare drinking water containing several mineral nutrients, be the calcium source with calcium acetate now, distilled water (or pure water) is manufactured experimently the drinking water containing several mineral nutrients that becomes to be fit to common people's needs for former water, its element theory value content is according to relevant data in the table 2, and the proportion of establishing water is 1 (1 milligram/1 milliliter), can derive calculation formula:
Single-element theoretical content (mg/litre) in the drinking water containing several mineral nutrients=
From water, need to take in amount of element (milligram) ÷ everyone every day
Drinking water containing several mineral nutrients volume (liter);
Formula can calculate each element theory content in the drinking water containing several mineral nutrients in view of the above.
As dislike this content higher, but thin up to needs content, every liter of dilution needs amount of water to calculate as follows:
Dilution needs amount of water (liter)=former content ÷ to need content-1 liter.
Standard for Natural Mineral Waters according to country's formulation: strontium, zinc are 0.2~5 mg/litre, and selenium is 0.01~0.05 mg/litre.In view of the above, strontium in the above-mentioned drinking water containing several mineral nutrients, zinc, three on selenium are up to standard, so can be referred to as " artificial mineralized water ".
Above-mentioned element theory value content is similar substantially to Guangzhou test center measured value.
Former water per ton need add the compound Weight Calculation: press above-mentioned formula:
1 ton of former water can be made into drinking water containing several mineral nutrients (kilogram)=
1000 kilograms of former water prescriptions of ÷ of former water value 99.93306%=1000.6698 kilogram
Drinking water containing several mineral nutrients per ton needs compound weight: calcium acetate=1000.6698 * 0.050019% ÷ 94.04%=532.2469 gram manganese acetate=1000.6698 * 0.000027% ÷ 99.0%=0.2729 gram cobalt acetate=1000.6698 * 0.000003% ÷ 99.5%=0.0301 gram sodium molybdate=1000.6698 * 0.0000006% ÷ 99.0%=0.0061 gram zinc acetate=1000.6698 * 0.0001006% ÷ 99.0%=1.0168 gram frerrous chloride=1000.6698 * 0.0001423% ÷ 99.0%=1.4383 gram sodium selenite=1000.6698 * 0.0000008% ÷ 97.0%=0.0082 gram potassium chloride=1000.6698 * 0.007622% ÷ 99.0%=77.0414 gram magnesium chloride=1000.6698 * 0.005851% ÷ 99.0%=59.1405 gram
More than be calculated as far as possible accurately, so it is more to get decimal digits.
Drinking water containing several mineral nutrients product of the present invention, above-mentioned each element of the important again and easy shortage of contained needed by human, as calcium, selenium, manganese, cobalt, molybdenum etc., when the edible water yield reaches 2.5 liters, can satisfy the adult and from water, need the intake standard everyone every day, children reduce by half, and the child reduces by half again, can reach standard basically.To add the compound gross weight be 1675 milligrams, only account for 0.07%, the overwhelming majority or water account for 99.93%, artificial salinity=1.675 grams/2.5 liters=0.7 grams per liter.Water colorless, transparent, odorless, sanitary index meet the requirements, and press the salinity classification of water, belong to fresh water, pH value 7.6.This water can be made daily drinkable water and use, can be loaded on and make commodity in the Plastic Bottle and drink as mineral water, also can add carbonic acid gas and seasonings and make carbonated drink and sell, also can be loaded in the big plastic tank and make commodity, it is edible to make beverage, soup, meals for family and unit.But it should be noted that, because of this Shuifu County contains various positively charged ions and acetate, cl anion, to electronegative colloidal solution, can produce the static neutralization as milk, soya-bean milk etc., destroy the colloid environment, calcium plasma and protein bound are inner complex, form flocculation and deposited phenomenon, make milk become the milk flower, make soya-bean milk become uncongealed beancurd.But the variation that this can not influence nutrition makes the easier absorption of calcium on the contrary; Do not influence proteinic absorption yet.With this bubble tea time, underwater gold belongs to ion can be combined into materials such as insoluble tannic acid calcium with composition such as tannic acid in the tea, and tea flavour is changed to some extent, and the erosion of mixing phenomenon is arranged, but this only loses some calcium compositions and does not have any toxic side effect.
Often edible this drinking water containing several mineral nutrients can replenish the various mineral nutrients of needed by human body more comprehensively, and the various diseases that these mineral matter nutritionals are for want of caused has certain prevention and assisting therapy (dietotherapy) to act on.Contained a large amount of acetate anion can play the same plurality of health care functions of vinegar.Moreover the strontium acetate of association not only can be mended strontium in the calcium acetate, but also is good insect repellent, can prevent and treat roundworm, oxyuriasis.Simultaneously, owing to contain the very strong various ions of chemically reactive, this water also has certain sterilization, disinfection.Therefore, this drinking water containing several mineral nutrients should be more satisfactory novel drinkable water, and bigger development prospect is arranged, and will obtain bigger society and economic benefit.With the processing step of other these water of calcium agent system similarly.
If not refer in particular in the present invention, all parts, amount are the weight unit based on gross weight.
Below further specify the present invention by specific embodiment, but embodiment only be used for the explanation, can not limit the scope of the invention.
Embodiment 1
With eastern suburb, Guangzhou gold hole spring (well water) system drinking water containing several mineral nutrients.This is in 24 kilometers of new east station of Guangzhou NATO, and one along the ring road in the urban district.This place is the hilly country, there is geochemistry of Yanshanian granitoids to distribute, one east northeast is arranged to zone of fracture, form water-bearing zone, have many places spring to distribute at this zone of fracture, the water source is very abundant, and water quality is good, 0.079 milligram/L of salinity, 40.71 milligrams/L of metasilicic acid content, reach metasilicic acid mineral water standard, can make the water source of drinking water containing several mineral nutrients.According to another data, Delta of the Pearl River area liver cancer is how relevant with local area drinkable water manganese deficiency, and the esophageal carcinoma is relevant with scarce molybdenum, so when local area system drinking water containing several mineral nutrients, suitably manganese addition and molybdenum are to prevent and treat this two kinds of diseases and rich man disease.Now adopt the mode of directly adding to prepare drinking water containing several mineral nutrients with various relevant element compounds.Its technology, step are as follows:
A, formulating of recipe see Table 3
Table 3
It is required to prepare drinking water containing several mineral nutrients with Guangzhou Jin Keng metasilicic acid mineral water
Element compound weight and prescription value design table
Element | Need to add this element compound | ||||||||
Title | Be grown up and from water, need intake (milligram) everyone every day | 2.5 rise content in the former water (milligram) | 2.5 rise and need addition (milligram) in the former water | Title | Constituent content % | Weight (milligram) | Make the prescription value % of polynary calcium | Single prescription value % | Grouping prescription value % |
Calcium | ?300 | ??17.80 | ??282.2 | Calcium acetate | ??23.9749 | ????1177.0643 | ????93.1275 | ??0.04705 | Polynary calcium 0.0505212 |
Manganese | ?0.3 | ??0.22 | ??0.08 | Manganese acetate | ??22.4159 | ????0.3569 | ????0.0282 | ??0.0000142 | |
Cobalt | ?0.03 | ??0.03 | Cobaltous diacetate | ??23.6604 | ????0.1268 | ????0.0100 | ??0.000005 | ||
Molybdenum | ?0.015 | ??0.015 | Sodium orthomolybdate | ??46.5919 | ????0.0322 | ????0.0025 | ??0.000001 | ||
Zinc | ?1.5 | ??0.07 | ??1.43 | Zinc acetate | ??29.7863 | ????4.8009 | ????0.3799 | ??0.000192 | |
Iron | ?2 | ??0.05 | ??1.95 | Iron protochloride | ??28.0878 | ????6.9425 | ????0.5493 | ??0.000277 | |
Impurity in the acetic acid calcium powder | ????74.5991 | ????5.9022 | ??0.002982 | ||||||
Add up to | ????1263.9227 | ????100 | |||||||
Selenium | ?0.02 | ??0.02 | Sodium Selenite | ??45.6395 | ????0.0438 | ??0.000002 | ??0.000002 | ||
Potassium | ?200 | ??5.38 | ??194.62 | Repone K | ??52.4446 | ????371.0964 | ??0.014833 | ??0.014833 | |
Magnesium | ?35 | ??5.40 | ??29.6 | Magnesium chloride | ??11.9553 | ????247.5889 | ??0.009896 | ??0.009896 | |
Water | ?2500000 | ??2500000 | ????2500000 | ??99.92474 | ??99.92474 | ||||
Amount to | ????2501882.7 | ??99.999998 | ??99.999998 | ||||||
Strontium | ?0.546 | Calcium acetate is contained |
(calcium acetate contains strontium 0.042%)
Annotate: need intake (mg) everyone every day of being grown up: calcium 800, manganese 3, cobalt 0.3, molybdenum 0.15, zinc 15, iron 20, selenium 0.2, potassium 2000, magnesium 350, strontium 2.Because China is calcium deficiency 300mg per capita, so calcium is 300mg in design 2.5 premium on currency, quite calcium acetate 1.3g contains strontium 0.546mg.Other elements 10% by providing in the water, i.e. the 2nd hurdle indication in the table.Make each constituent content of water (mg/l): calcium 120, manganese 0.12, cobalt 0.012, molybdenum 0.006, zinc 0.6 (reaching the mineral water index), iron 0.8, selenium 0.008 (near mineral water index 0.01mg/l), potassium 80, magnesium 14, strontium 0.22 (reaching the mineral water index).
B, calculate to add compound weight and give and weighing up, used agitator can stir 500 kilograms in former water at every turn, and all cpds weight that then need add is: can be made into drinking water containing several mineral nutrients weight (kilogram)=
500 kilograms of ÷ of former water weight
Former water individual event prescription value 99.92474%=500.3766 kilogram;
Calcium acetate 250.3479 grams, manganese acetate 0.0717 gram, Cobaltous diacetate 0.0251 gram, Sodium orthomolybdate 0.0051 gram, zinc acetate 0.9704 gram, iron protochloride 1.4000 grams, Sodium Selenite 0.0103 gram, Repone K 74.9705 grams, magnesium chloride 50.0174 grams.
C, dissolving and sterilization: Jiang Yuanshui places the agitator of the molten 500 kilograms of former water of energy, and the precedence of pressing sodium selenate, Sodium orthomolybdate, muriate, acetate slowly adds the compound that has weighed up, and fully stir, make it be dissolved into colourless transparent solution, leave standstill about 1 hour, precipitation and sterilization.
D, pressure filter press filtration: filtrate is drinking water containing several mineral nutrients.
E, be fed in the container, and seal, product.
F, check: product project check according to the pertinent regulations of state must reach qualified.
The Standard for Natural Mineral Waters of formulating according to country, in this water strontium, zinc, selenium and metasilicic acid totally 4 projects reach the mineral water standard, so this water can be described as " manually mineralized water ".
Embodiment 2
With hole, big west, Guangdong Jiangmen city spring system drinking water containing several mineral nutrients.Hole, big west spring is positioned at western big Xi Keng forest farm, Jiangmen city ring town, and there is big Xi Kengshuiku in the spring downstream.These regional landforms belong to the knob, and the distribution rock is the Cambrian system metasandstone, because each orogeny influence of later stage, lithology is broken, and cranny development constitutes good waterbearing stratum, and the water source is abundanter under the old place.Local area is the liver cancer district occurred frequently, according to Zhongshan Medical Univ. and the investigation of Guangdong Province geology and minerals bureau, thinks that the liver cancer district occurred frequently is relevant with local water source manganese deficiency.Therefore, when utilizing herein spring system drinking water containing several mineral nutrients, manganese addition is more.Now adopt the mode of directly adding to prepare drinking water containing several mineral nutrients with various relevant element compounds.Its technology, step are as follows:
A, formulating of recipe see Table 4:
Table 4
It is required to prepare drinking water containing several mineral nutrients with hole, the big west of Jiangmen city mineral water
Element compound weight and prescription value design table
Element | Need to add this element compound | ||||||||
Title | Be grown up and from water, need intake (milligram) everyone every day | 2.5 rise content in the former water (milligram) | 2.5 rise and need addition (milligram) in the former water | Title | Constituent content % | Weight (milligram) | Make the prescription value % of polynary calcium | Single prescription value % | Grouping prescription value % |
Calcium | ??300 | ?1.957 | 298.04 | Calcium acetate | ??23.9749 | ????1243.1334 | ??92.1971 | ??0.04967 | Polynary calcium 0.0538735 |
Manganese | ??0.6 | ?0.198 | 0.402 | Manganese acetate | ??22.4159 | ????1.7934 | ??0.13301 | ??0.000072 | |
Cobalt | ??0.06 | 0.06 | Cobaltous diacetate | ??23.6604 | ????0.2536 | ??0.01881 | ??0.000010 | ||
Molybdenum | ??0.03 | 0.03 | Sodium orthomolybdate | ??46.5919 | ????0.0644 | ??0.00478 | ??0.0000025 | ||
Zinc | ??3 | 3 | Zinc acetate | ??29.7863 | ????1.0717 | ??0.74697 | ??0.000402 | ||
Iron | ??4 | ?0.00 | 4 | Iron protochloride | ??28.0878 | ????14.2411 | ??1.05619 | ??0.000569 | |
Impurity in the acetic acid calcium powder | ????78.7864 | ??5.84319 | ??0.003148 | ||||||
Add up to | ????1348.344 | ??100 | |||||||
Selenium | ??0.04 | 0.04 | Sodium Selenite | ??45.6395 | ????0.0876 | ??0.0000035 | ??0.0000035 | ||
Potassium | ??400 | ??4.55 | 395.45 | Repone K | ??52.4446 | ????754.0338 | ??0.030129 | ??0.030129 | |
Magnesium | ??70 | ??1.18 | 68.82 | Magnesium chloride | ??11.9553 | ????575.6443 | ??0.023001 | ??0.023001 | |
Water | ??2500000 | 2500000 | ????2500000 | ??99.89299 | ??99.89299 | ||||
Amount to | ????2502678.1 | ??100 | ??100 | ||||||
Strontium | ??0.546 | Calcium acetate is contained |
(calcium acetate contains strontium 0.042%)
Annotate: need intake (mg) everyone every day of being grown up: calcium 800, manganese 3, cobalt 0.3, molybdenum 0.15, zinc 15, iron 20, selenium 0.2, potassium 2000, magnesium 350, strontium 2.Because China is calcium deficiency 300mg per capita, so calcium is 300mg in design 2.5 premium on currency, quite calcium acetate 1.3g contains strontium 0.546mg.Other elements 20% by providing in the water, i.e. the 2nd hurdle indication in the table.Make each constituent content of water (mg/l): calcium 120, manganese 0.24, cobalt 0.024, molybdenum 0.012, zinc 1.2 (reaching mineral water index 0.2-5mg/l), iron 1.6, selenium 0.016 (near mineral water index 0.01-0.05mg/l), potassium 160, magnesium 28, strontium 0.22 (reaching mineral water index 0.2-5mg/l).
B, calculate to add compound weight and give and weighing up, used agitator can stir 500 kilograms in former water at every turn, and all cpds weight that then need add is: can be made into drinking water containing several mineral nutrients weight (kilogram)=
500 kilograms of ÷ of former water weight
Former water individual event prescription value 99.89299%=500.5356 kilogram;
Calcium acetate 264.3726 grams, manganese acetate 0.364 gram, Cobaltous diacetate 0.0503 gram, Sodium orthomolybdate 0.0126 gram, zinc acetate 2.0324 grams, iron protochloride 2.8768 grams, Sodium Selenite 0.018 gram, Repone K 152.3296 grams, magnesium chloride 116.2911 grams.
C, dissolving and sterilization: with embodiment 1.
D, pressure filter press filtration: with embodiment 1.
E, be fed in the container, and seal, product.
F, check: product project check according to the pertinent regulations of state must reach qualified.
According to the Standard for Natural Mineral Waters that country formulates, strontium, zinc, selenium content reach the mineral water standard in this water, so this water can be described as " artificial mineralized water ".Owing to this kind water is to cause the situation of liver cancer, the esophageal carcinoma and custom-designed at Delta of the Pearl River area drinkable water manganese deficiency, molybdenum, so water should play prevention preferably and assisting therapy (dietotherapy) effect to these two kinds of diseases and rich man disease, this water also can dilute.
Claims (12)
1, a kind of drinking water containing several mineral nutrients, comprise various drinkable waters as carrier, it is characterized in that: also comprise acetate, muriate and Sodium Selenite (or sodium selenate), calglucon, calcium lactate, l threonic acid, VC calcium, the amino acid calcium of the magnanimity of significant quantity, particularly trace element etc., wherein water-content is 98~99.99 (WT) %.
2, drinking water containing several mineral nutrients as claimed in claim 1 is characterized in that: the element that adds in the described water can be calcium, potassium, magnesium, selenium, manganese, zinc, cobalt, molybdenum, strontium, iron, silicon etc., can add one or more separately.
3, as claim 1,2 described drinking water containing several mineral nutrients, it is characterized in that containing in this drinking water containing several mineral nutrients calcium, manganese, zinc, iron, selenium, magnesium ion, wherein, the content of above-mentioned ion in water is: (unit: mg/litre)
Calcium ion (Ca
2+): 78~400; Magnesium ion (Mg
2+): 4.5~60;
Mn ion (Mn
2+): 0.04~1.5; Zine ion (Zn
2+): 0.2~7.5;
Iron ion (Fe
2+): 0.26~10; Plasma selenium (Se
2-): 0.003~0.1.
4, as claim 1,2 described drinking water containing several mineral nutrients, it is characterized in that containing in this drinking water containing several mineral nutrients calcium, manganese, zinc, iron, selenium, magnesium ion, wherein, the content of above-mentioned ion in water is: (unit: mg/litre)
Calcium ion (Ca
2+): 78~162; Magnesium ion (Mg
2+): 4.6~9.5;
Mn ion (Mn
2+): 0.04~0.1; Zine ion (Zn
2+): 0.2~0.4;
Iron ion (Fe
2+): 0.3~0.5; Plasma selenium (Se
2-): 0.003~0.005.
5, as claim 1,2 described drinking water containing several mineral nutrients, it is characterized in that containing in this drinking water containing several mineral nutrients calcium, manganese, zinc, iron, selenium, magnesium ion, wherein, the content of above-mentioned ion in water is: (unit: mg/litre)
Calcium ion (Ca
2+): 78~162; Magnesium ion (Mg
2+): 9~19;
Mn ion (Mn
2+): 0.08~0.2; Zine ion (Zn
2+): 0.4~1.0;
Iron ion (Fe
2+): 0.5~1.1; Plasma selenium (Se
2-): 0.005~0.011.
6, as claim 1,2 described drinking water containing several mineral nutrients, it is characterized in that also can containing cobalt, molybdenum, potassium and strontium ion in this drinking water containing several mineral nutrients, wherein, the content of above-mentioned ion in water is: (unit: mg/litre)
Cobalt ion (Co
2+): 0.004~0.2; Molybdenum ion (Mo
2+): 0.002~0.1;
Potassium ion (K
+): 26~1000; Strontium ion (Sr
2+): 0.1~1.0.
7, as claim 1,2 described drinking water containing several mineral nutrients, it is characterized in that also can containing cobalt, molybdenum, potassium and strontium ion in this drinking water containing several mineral nutrients, wherein, the content of above-mentioned ion in water is: (unit: mg/litre)
Cobalt ion (Co
2+): 0.008~0.02; Molybdenum ion (Mo
2+): 0.004~0.008;
Potassium ion (K
+): 50~108; Strontium ion (Sr
2+): 0.14~0.3.
8,, it is characterized in that described many mineral ions can select from calcium acetate, calglucon, calcium lactate, l threonic acid, VC calcium, amino acid calcium, manganese acetate, Cobaltous diacetate, Sodium orthomolybdate, zinc acetate, iron protochloride, Sodium Selenite, Repone K, magnesium chloride etc. as the described drinking water containing several mineral nutrients of claim 1~7.
9, as the described drinking water containing several mineral nutrients of claim 1~7, it is characterized in that described water is a kind of of various drinkable waters, can be pure water, distilled water, deionized water, also can be rivers water, well water, spring, mineral water, tap water.
10,, it is characterized in that comprising the steps: as the preparation method of the described drinking water containing several mineral nutrients of claim 1~9
A, take by weighing element compound: (unit: gram/ton) in following ratio
Calcium acetate or other calcium agent 325~1668; Manganese acetate 0.2~7; Cobaltous diacetate 0.02~0.8;
Sodium orthomolybdate 0.004~0.2; Zinc acetate 0.7~25; Iron protochloride 0.9~36;
Sodium Selenite 0.007~0.2; Repone K 50~1907; Magnesium chloride 38~502.
B, in the agitator of excess water is arranged, press the precedence of sodium selenate, Sodium orthomolybdate, muriate, acetate and other calcium salts, the compound that has weighed up is slowly added, and fully stirs, make it be dissolved into colourless transparent solution, leave standstill about 1 hour;
C, be drinking water containing several mineral nutrients with pressure filter press filtration, filtrate;
D, be fed in the container, and seal, product;
The project check according to the pertinent regulations of state of E, product.
11, the preparation method of drinking water containing several mineral nutrients as claimed in claim 10 is characterized in that comprising the steps:
A, take by weighing element compound: (unit: gram/ton) in following ratio
Calcium acetate or other calcium agent 325~676; Manganese acetate 0.4~0.9; Cobaltous diacetate 0.03~0.08;
Sodium orthomolybdate 0.01~0.02; Zinc acetate 1.3~3.4; Iron protochloride 1.8~3.9;
Sodium Selenite 0.011~0.024; Repone K 95~206; Magnesium chloride 75~159.
B, in the agitator of excess water is arranged, press the precedence of sodium selenate, Sodium orthomolybdate, muriate, acetate and other calcium salts, the compound that has weighed up is slowly added, and fully stirs, make it be dissolved into colourless transparent solution, leave standstill about 1 hour;
C, be drinking water containing several mineral nutrients with pressure filter press filtration, filtrate;
D, sterilization, sterilization;
E, be fed in the container, and seal, product;
The project check according to the pertinent regulations of state of F, product.
12,, it is characterized in that it can make daily drinkable water or be processed as beverage such as carbonated drink, for the eater provides required moisture content and can efficiently replenish the nutrition of needed by human body several mineral materials as the described drinking water containing several mineral nutrients of claim 1~9.
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