CN1261389C - Method for producing light ceramic particles from mud in water supply plant and sewage treating plant - Google Patents

Abstract

The present invention relates to the reclamation processing utilization of sludge waste materials of sewage plants and water plants in cities. A preparation method of the light porcelain granules of the present invention comprises the processes of raw material preparation, homogenization, molding, pretreatment, roasting and refrigeration. The present invention is characterized in that the light porcelain granules are prepared from the raw materials of the following weight ratio: 70 to 100% of water plant sludge and 0 to 30% of sewage plant sludge; the temperature of the pretreatment is from 300 DEG C to 500 DEG C, and the time of the pretreatment is from 10 to 30 minutes; the roasting temperature is from 1130 DEG C to 1170 DEG C, and the roasting time is from 5 to 15 minutes. The porcelain granules are prepared by roasting the water plant sludge as a main raw material and the sewage plant sludge as an additive, wherein the sewage plant sludge is added to the main raw material, and the application value of the porcelain granules is high. A great amount of water plant sludge and sewage plant sludge are simultaneously treated, the comprehensive utilization of the two kinds of sludge is realized, the light porcelain granules with good performance are also obtained, and high strength concrete used for load carrying structures can be prepared.

Description

A kind of method for preparing light ceramic with water supply plant and sewage plant sludge

Technical field

The present invention relates to the changing rejected material to useful resource processing and utilizing of municipal wastewater treatment plant and waterworks sludge.

Background technology

The contained material of water supply plant and sewage plant sludge has the dual nature of polluting with resource, waterworks sludge contains a large amount of inorganic componentss, sewage plant sludge contains large amount of organic, various nutritive element, trace element, more and more be subjected to people's attention as the alternate resources that can turn waste into wealth, meet innoxious, the minimizing and the resource utilization principle of China's solid waste disposal, vast potential for future development will be arranged.Therefore the resource treatment technique of studying two kinds of mud just seems very urgent.

Summary of the invention

The purpose of this invention is to provide a kind of method for preparing light ceramic with waterworks sludge and sewage plant sludge.

The technical scheme that is adopted is for achieving the above object:

The preparation method of light ceramic comprises feed proportioning, homogenizing, moulding, pre-treatment, roasting, cooling, it is characterized in that:

A. raw material weight compares: waterworks sludge 70～100%, sewage plant sludge 0～30%;

B. pre-treatment: 300 ℃～500 ℃ of temperature, pretreatment time 10～30min;

C. roasting: 1130 ℃～1170 ℃ of temperature, time 5～15min.

Prepare the method for concrete segment with sludge ceramsite, sludge ceramsite as raw material, is replaced stone, be mixed and made into cement and sand.

In order to remove the part moisture in the pellet, prevent the roasting process mesomere, necessary first preliminarily dried is once.Waterworks sludge can be concentrated natural air drying, is transported to haydite factory; Sewage plant sludge can directly be taken from the mud cake of dehydration machine room, need not further drying, directly is transported to haydite factory, presses mass ratio and waterworks sludge and mixes, and as the raw material of baking ceramsite, is stored in the feed bin jointly.

Homogenizing is with the pulverizing of milling of the waterworks sludge of seasoning, further is crushed to powdery by Universalpulverizer again.Because the particle of material is thin more favourable more to expanding.Directly the sewage plant sludge with water ratio nearly 80% mixes with the waterworks sludge of pulverizing, and adds suitable water, reaches plastic up to raw material.

Raw material by the stirrer homogenizing good after, on request granularity balling-up on pan-pelletizer.Again pellet is put into baking oven, dry by the fire about 30min down at 105 ℃.Again through pre-treatment, promptly at 300 ℃～500 ℃ pre-burning 10～30min.Pre-treatment is a chemical constitution of further adjusting raw material ball, mainly is the content that carbon in the preceding pellet that expands is burnt in reduction, to reach the best bloated result of burning.Then pellet is put into bitubular rotary kiln and carried out roasting, the temperature that different steps control is different is the important factor that influences baking ceramsite because burn the temperature that expands.It is low excessively to burn the temperature that expands, and the haydite unit weight and the water-intake rate that burn till are all higher, and the haydite goods are inner and surperficial liquid phase is less, can't wrap up gas and sealed porosity, and base substrate can not expand, and causes the increase of unit weight and water-intake rate.The bloated temperature of burning is too high, and the haydite pore that burns till breaks through liquid phase, beginning UNICOM, and the appearance of a small amount of UNICOM pore increases water-intake rate, but the loose volume weight increase is not too obvious.Haydite production must have certain burning temperature range that expands, if it is narrow to burn the temperature range that expands, is difficult to control in process of production.

Burn the length of the time of expanding, very big to the influence of haydite unit weight.Roasting time is long, and haydite unit weight can increase on the contrary, and this is because the glassy phase ratio increases, and has filled the hole that haydite produces in burning the process of expanding, and haydite is shunk, and unit weight raises, and water-intake rate descends.Therefore, burn 1130 ℃～1170 ℃ of bloated temperature, the burning time of expanding is controlled at 5～15min and is advisable.

Burned haydite cools off, and by the sieve apparatus classification, sends into the haydite storehouse at last.As seen, utilize existing leca production line might both reduce the production cost of haydite factory with waterworks sludge and sewage plant sludge simultaneously as the raw material production light ceramic fully, enriched the haydite kind, dispose this two kinds of solid waste again in a large number, realized recycling.

A kind ofly prepare the method for concrete segment, sludge ceramsite as raw material, is replaced stone, be mixed and made into cement and sand with sludge ceramsite.

The invention has the beneficial effects as follows:

(1) with the waterworks sludge be main raw material, add an amount of sewage plant sludge, can burn out the haydite that unit weight is low, intensity is high, this haydite can be prepared the concrete of CL40 label.

(2) with the waterworks sludge be main raw material, adding sewage plant sludge is the haydite that additive is fired, the using value height, a large amount of water supply plants and sewage plant sludge have not only been disposed simultaneously, realize the comprehensive utilization of two kinds of mud, the light ceramic of better performances can also be obtained, and the high-strength concrete that can be used for load larrying member can be made.

(3) sewage plant sludge as swelling agent and waterworks sludge jointly as the raw material of baking ceramsite, objectionable impuritiess such as itself heavy metal, germ have not only been eliminated, can also be for high calorific value be provided in the baking ceramsite process, reduce firing rate, play the effect of certain swelling agent, make the haydite performance that burns out better, realized recycling.

(4) sludge ceramsite compare with leca have sharp useless, energy-conservation, do not damage the soil, the advantage that can preserve the ecological environment is the green building material product, has tangible economic benefit, environmental benefit and social benefit.

Description of drawings

Fig. 1 is the ceramsite production process sketch

The pictorial diagram of Fig. 2 1# haydite

The pictorial diagram of Fig. 3 2# haydite

The internal pore structure figure of Fig. 4 2# haydite

Fig. 5 1# building block pictorial diagram

Fig. 6 2# building block pictorial diagram

Embodiment

The preparation of haydite

Example 1

The waterworks sludge of seasoning is crushed to powdery, and and water ratio be 80% sewage plant sludge by the dry weight ratio be to mix at 7: 3, adds suitable water stirring, reach plastic up to raw material.On request granularity balling-up on pan-pelletizer again, and pellet is put into 105 ℃ baking oven dry by the fire 30min.Then at 400 ℃ of following pre-burning 20min, at last under 1140 ℃, roasting 5min.Can obtain loose volume weight after cooling is 1040kg/m ³, cylindrical compress strength is the high-strength ceramic granule (claiming the 1# haydite) of 7.64Mpa.The pictorial diagram of 1# haydite is seen Fig. 2.

Example 2

The waterworks sludge of seasoning is crushed to powdery, adds suitable water and stir, reach plastic up to raw material.On request granularity balling-up on pan-pelletizer again, natural air drying is removed the part moisture in the pellet.Then at 400 ℃ of following pre-burning 20min, at last under 1140 ℃, roasting 12min.Can obtain loose volume weight after cooling is 1300kg/m ³, cylindrical compress strength is the high-strength ceramic granule (claiming the 2# haydite) of 8.00Mpa.The pictorial diagram of 2# haydite is seen Fig. 3, and its internal pore structure figure sees Fig. 4.

According to State Standard of the People's Republic of China's " light-weight aggregate and test method thereof " GB/T17431.1-1998,1# haydite and 2# haydite are carried out performance test, the results are shown in Table 1.

Table 1 haydite performance measurement result

Test event	The 1# haydite	The 2# haydite
			Grain composition mm	10～16	10～16
Tap density (kg/m3)	1040	1300
			Cylindrical compress strength (MPa)	7.64	8.00
Strength mark (MPa)	40	40
			Water-intake rate (%)	0.5	1.0
Coefficient of softening	0.95	0.98
			Silt content (%)	0.1	0.1
Grain type coefficient	1.2	1.2
			Frost resistance	Qualified	Qualified
Soundness	Qualified	Qualified

As can be seen from Table 1,1# and 2# haydite tube are pressed enough big, and water-intake rate is also lower, belongs to well behaved haydite.

Figuline building blocks

1, raw material

Haydite: 1# haydite (the sewage plant sludge addition of firing under 1140 ℃ accounts for 30% sludge ceramsite)

2# haydite (the waterworks sludge haydite of firing under 1140 ℃)

Cement: just logical board 425 ordinary Portland cements that Tianjin Zhenxing Cement Co., Ltd. produces

Sand: in thick river sand, fineness pattern 2.8

1# building block batching

Cement: sand: 1# haydite: water=405: 670: 720: 150/g water cement ratio w/c=0.37

2# building block batching

Cement: sand: 2# haydite: water=675: 1140: 1200: the test of 300/g water cement ratio w/c=0.444 concrete mechanics is undertaken by GBJ81-85, and sample dimensions is 70 * 70 * 70mm.

2, operation steps

According to the proportioning that designs, good cement of weighing and sand mix it; in the planetary glue sand agitator of JT-5 type, slowly add entry then, make mud; mix with load weighted haydite then, manually stir, to even; put into ready forming mould; compacting, jolt ramming on ZS-15 type cement mortar plain bumper is then placed a moment slightly; promptly put into the thermostatic curing case, beginning 28d thermostatic curing.Take out the haydite concrete building block behind the 28d, its pictorial diagram is seen Fig. 5 and Fig. 6.And to they tests of testing, test-results sees Table 2.

Table 2 haydite concrete building block 28d compressive strength test result

Density rating according to the light-weight aggregate of stipulating among " light aggregate concrete technical regulation " JGJ51-90, as can be seen from Table 2, the 1# concrete segment belongs to the light aggregate concrete of density rating 1800, and ultimate compression strength reaches 44.5Mpa, can prepare the concrete of CL40 label; It is 2190kg/m that the 2# concrete segment is done apparent density ³, ultimate compression strength reaches 40.5Mpa, can be used as the concrete of preparation CL40 label.

Claims (2)

1. one kind prepares the method for light ceramic with water supply plant and sewage plant sludge, comprises feed proportioning, homogenizing, moulding, pre-treatment, roasting, cooling, it is characterized in that:

A. raw material weight compares: waterworks sludge 70～100%, sewage plant sludge 0～30%;

B. pre-treatment: 300 ℃～500 ℃ of temperature, pretreatment time 10～30min;

C. roasting: 1130 ℃～1170 ℃ of temperature, time 5～15min.

2. one kind prepares the method for concrete segment with sludge ceramsite, and the haydite of the described method preparation of claim 1 as raw material, is replaced stone, is mixed and made into cement and sand.

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