CN1257852C - Method of eliminating nitrite and ammonia nitrogen in aquatic culture - Google Patents
Method of eliminating nitrite and ammonia nitrogen in aquatic culture Download PDFInfo
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- CN1257852C CN1257852C CN 03140190 CN03140190A CN1257852C CN 1257852 C CN1257852 C CN 1257852C CN 03140190 CN03140190 CN 03140190 CN 03140190 A CN03140190 A CN 03140190A CN 1257852 C CN1257852 C CN 1257852C
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- ammonia nitrogen
- nitrite
- hydrogen peroxide
- oxygen
- pond
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Abstract
The present invention discloses a method for removing nitrite and ammonia nitrogen in the aquatic product culture. The method comprises the following steps that hydrogen peroxide is filled in an opening container, and an osmotic layer is covered at an opening of the container; subsequently, the container filled with the hydrogen peroxide is immersed in a culture pond and is fixed on an oxygen enriching machine in the culture pond; the oxygen enriching machine is started to make the hydrogen peroxide slowly diffused by the water flow, and the hydrogen peroxide is decomposed into water and oxygen in the process of diffusing so that the decomposed oxygen simultaneously makes the nitrite and the ammonia nitrogen oxidized into nitrate; and finally, cultured photosynthetic bacteria are sprinkled in the culture pond, and consequently, the nitrate is absorbed and used by the photosynthetic bacteria, etc. The nitrite and the ammonia nitrogen in the aquatic product culture can be rapidly removed by the method, and additionally, the method has long effect sustaining time and no recurrence. Furthermore, the residual substance does not exist after use so that the method does not have the adverse effect on the animal in the aquatic product culture and the growth of the floating algae.
Description
Technical field
The present invention relates to a kind of method of removing nitrite and ammonia nitrogen in the water, particularly a kind of method of removing nitrite and ammonia nitrogen in the aquaculture.
Background technology
At present, the water quality regulation of pond aquaculture mainly relies on the self-cleaning of water body, and change water and mechanical enhancement, but because the pond eutrophication aggravation that highdensity breed bait throwing in fertilising causes, thereby cause nitrite, ammonia-nitrogen content to exceed standard, when nitrite, will cause the aquatic animal mass mortality when ammonia-nitrogen content exceeds standard, directly influence the economic benefit and the human beings'health of culture fishery, culture the major issue that the owner has a headache most thereby become, and pond water quality only relies on self to regulate and is difficult to the aquaculture ecotope that keeps good.Development along with water technology, nitrite, the utilization in ammonia nitrogen of water technology in removing aquaculture obtains promoting gradually, at present the utilization water technology remove nitrite, ammonia nitrogen in the aquaculture method mainly contain physisorphtion, chemical method and biological process, these methods have certain effect for the removal of nitrite in the aquaculture and ammonia nitrogen, yet these methods exist certain defective again in the utilization process.The treatment capacity of physisorphtion is limited, and easily bounce-back; Some chemical substance strong toxicity when the utilization chemical process is handled aquatic animal and planktonic algae are had very strong lethal effect, and residual quantity is big; Biological treatment is slow excessively for the removal speed of the nitrite of high density.
Summary of the invention
In order to overcome the deficiencies in the prior art, the invention provides a kind of method of removing nitrite and ammonia nitrogen in the aquaculture, it can remove nitrite and ammonia nitrogen in the aquaculture fast, efficiency time is long, be difficult for bounce-back, and do not have residually after using, the growth of aquatic animal and planktonic algae is had no adverse effects.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of method of removing nitrite and ammonia nitrogen in the aquaculture, this method comprises the steps: in order
(1). hydrogen peroxide is packed in the open containers, and vessel port place covers a pervious course, the container that hydrogen peroxide is housed is immersed in cultures in the pond and be fixed on the oxygenating machine of culturing in the pond;
(2). start oxygenating machine, hydrogen peroxide is spread by sluggish flow, decomposing hydrogen dioxide solution is water and oxygen in diffusion process, and the oxygen of decomposition is oxidized to nitrate with nitrite and ammonia nitrogen simultaneously:
(3). the photosynthetic bacterium of splashing and cultivating in culturing the pond makes nitrate absorb by photosynthetic bacterium.
For hydrogen peroxide slowly and is constantly spread, the open containers of splendid attire hydrogen peroxide can adopt the wide-mouth bucket, and at opening part covering one deck pervious course of wide-mouth bucket, pervious course can adopt sponge or the bigger material of other void ratio.
Ultimate principle of the present invention is such: the present invention adopts chemistry to combine with biological method, utilizing strong oxidizer---hydrogen peroxide discharges slowly and spreads under the current that oxygenating machine stirred and comes, in diffusion process, be decomposed into water and oxygen, the oxygen that decomposes is oxidized to nitrate with nitrite and ammonia nitrogen, after three days to culturing the pond photosynthetic bacterium of splashing, nitrate is absorbed by photosynthetic bacterium as nutritive substance, thereby reaches the purpose of removing nitrite and ammonia nitrogen.
Photosynthetic bacterium of the present invention can obtain with following method:
One, the photosynthetic bacteria culture medium prescription is (unit be weight percentage %): ammonia chloride 0.08-0.15, Sodium n-caproate 0.20-0.35, DL-oxysuccinic acid 0.05-0.10, sodium hydroxide 0.20-0.30, dipotassium hydrogen phosphate 0.08-0.15, magnesium chloride 0.01-0.02, calcium chloride 0.01-0.02, yeast extract paste 0.05-0.1, distilled water 99.32-98.81;
Two, cultural method: the pH value of substratum is transferred to 7.2-7.5, so 120 ℃ following high-temperature sterilization 20-30 minute, cooling back adds 10% bacterial classification (volume ratio), 25-30 ℃ of following anaerobism illumination cultivation 6-8 days, obtains wine-colored liquid photosynthetic bacteria liquid.
Compare with the water quality that contrasts the pond using test of the present invention to culture the pond, control methods is as follows: test tank (1) area is eight mu, 1.2 meters of the depth of waters; 5 mu of test tank (2) areas, 1.3 meters of the depth of waters; Six mu of test tank (3) areas, 1.1 meters of the depth of waters; Test tank discharges hydrogen peroxide by 3 kilograms/mu consumption, throws in photosynthetic bacterium after three days, and consumption is 1.5 kilograms/mu, six mu of contrast pool areas, 1.1 meters of the depth of waters.Continuous five days synchronous Analysis Results of Water Quality as table 1,2,3,4, shown in.
Table 1 test tank (1) Analysis Results of Water Quality
Water quality factor | First day | Second day | The 3rd day | The 4th day | The 5th day |
Dissolved oxygen (mg/l) | 6.00 | 6.50 | 7.00 | 6.74 | 6.86 |
NH 3-NH 4 -(mg/l) | 0.80 | 0.35 | 0.20 | <0.20 | <0.20 |
NO 2 --N(mg/l) | 0.60 | 0.32 | 0.10 | <0.05 | <0.05 |
PH | 8.20 | 8.15 | 8.10 | 8.10 | 8.12 |
CODcr(mg/l) | 22.5 | 15.6 | 10.4 | 6.00 | 4.80 |
Table 2 test tank (2) Analysis Results of Water Quality
Water quality factor | First day | Second day | The 3rd day | The 4th day | The 5th day |
Dissolved oxygen (mg/l) | 5.80 | 6.35 | 6.80 | 6.20 | 6.00 |
NH 3-NH 4 -(mg/l) | 0.70 | 0.32 | 0.1 | <0.20 | 0.25 |
NO 2 --N(mg/l) | 0.64 | 0.35 | 0.12 | <0.05 | 0.16 |
PH | 8.30 | 8.25 | 8.20 | 8.15 | 8.20 |
CODcr(mg/l) | 18.6 | 13.6 | 10.2 | 8.00 | 9.20 |
Table 3 test tank (3) Analysis Results of Water Quality
Water quality factor | First day | Second day | The 3rd day | The 4th day | The 5th day |
Dissolved oxygen (mg/l) | 6.00 | 6.30 | 7.00 | 6.80 | 6.80 |
NH 3-NH 4 -(mg/l) | 0.60 | 0.56 | 0.44 | 0.36 | 0.28 |
N0 2 --N(mg/l) | 0.50 | 0.40 | 0.36 | 0.30 | 0.25 |
PH | 8.15 | 8.12 | 8.14 | 8.16 | 8.20 |
CODcr(mg/l) | 18.00 | 15.80 | 12.60 | 8.36 | 6.20 |
Table 4 contrast pond Analysis Results of Water Quality
Water quality factor | First day | Second day | The 3rd day | The 4th day | The 5th day |
Dissolved oxygen (mg/l) | 5.00 | 4.84 | 5.28 | 4.60 | 5.00 |
NH 3-NH 4 -(mg/l) | 0.30 | 0.35 | 0.40 | 0.48 | 0.60 |
NO 2 --N(mg/l) | 0.15 | 0.20 | 0.22 | 0.30 | 0.39 |
PH | 8.00 | 8.15 | 8.30 | 8.35 | 8.42 |
CODcr(mg/l) | 22.4 | 19.8 | 23.8 | 22.6 | 22.0 |
From above tabulation as seen, the water quality of test tank obviously is better than contrasting the pond, the present invention can make nitrite clearance in the water more than 60%, ammonia-N removal rate is more than 60%, simultaneously the chemical oxygen demand in the water has descended more than 65%, and culturing pool deeply below 2 meters the time effect especially obvious.
The invention has the beneficial effects as follows: by to use test tank of the present invention with do not use contrast of the present invention pond more as can be known, the present invention can handle aquaculture water quality, transform nitrite and ammonia nitrogen in the water fast, make it become the nitrate that can supply photosynthetic bacterium to absorb, thereby help the growth of planktonic algae in the water body, reach maintenance aquaculture water aim of ecological equilibrium, become water and oxygen after the decomposing hydrogen dioxide solution simultaneously, therefore have the effect that increases water body oxygen amount; And noresidue can not have lethal effect to aquatic animal and planktonic algae.
Embodiment
The present invention is further described below in conjunction with embodiment.
Embodiment
By 3 kilograms/mu consumptions hydrogen peroxide is packed in the wide-mouth bucket, the opening part of wide-mouth bucket covers with sponge, then this wide-mouth bucket is tied up on the free leg of oxygenating machine with 1 meter long cord, the wide-mouth bucket is immersed in the water, start oxygenating machine, hydrogen peroxide sees through sponge and passes through sluggish flow ground to diffusion all around, decomposing hydrogen dioxide solution Cheng Shui and oxygen in diffusion process, oxygen is oxidized to nitrate with nitrite and ammonia nitrogen, consumption by 1.5 kilograms/mu after 3 days splashes the photosynthetic bacteria liquid of cultivating equably to culturing in the pond, nitrate is absorbed by photosynthetic bacterium, thereby helps the growth of planktonic algae, and provides nutritive substance for aquatic animal.
Claims (4)
1. a method of removing nitrite and ammonia nitrogen in the aquaculture is characterized in that this method comprises the steps: in order
(1). hydrogen peroxide is packed in the open containers, and vessel port place covers a pervious course, the container that hydrogen peroxide is housed is immersed in cultures in the pond and be fixed on the oxygenating machine of culturing in the pond;
(2). start oxygenating machine, hydrogen peroxide is spread by sluggish flow, decomposing hydrogen dioxide solution is water and oxygen in diffusion process, and the oxygen of decomposition is oxidized to nitrate with nitrite and ammonia nitrogen simultaneously:
(3). the photosynthetic bacterium of splashing and cultivating in culturing the pond makes nitrate absorb by photosynthetic bacterium.
2. a kind of method of removing nitrite and ammonia nitrogen in the aquaculture according to claim 1 is characterized in that described open containers is the wide-mouth bucket.
3. a kind of method of removing nitrite and ammonia nitrogen in the aquaculture according to claim 1 is characterized in that described pervious course is a sponge.
4. a kind of method of removing nitrite and ammonia nitrogen in the aquaculture according to claim 1 is characterized in that described breed tank depth is less than 2 meters.
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CN 03140190 CN1257852C (en) | 2003-08-14 | 2003-08-14 | Method of eliminating nitrite and ammonia nitrogen in aquatic culture |
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CN 03140190 CN1257852C (en) | 2003-08-14 | 2003-08-14 | Method of eliminating nitrite and ammonia nitrogen in aquatic culture |
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CN1513778A CN1513778A (en) | 2004-07-21 |
CN1257852C true CN1257852C (en) | 2006-05-31 |
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Families Citing this family (4)
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CN103030249B (en) * | 2012-11-23 | 2014-08-20 | 广东海兴农集团有限公司 | Method for efficiently reducing ammonia nitrogen and nitrites in aquatic water body |
CN103374539B (en) * | 2013-07-02 | 2014-12-10 | 中国科学院烟台海岸带研究所 | Proteus mirabilis capable of eliminating ammonia nitrogen in water environment and application thereof |
CN104710076A (en) * | 2015-02-28 | 2015-06-17 | 梧州市景泰养鳖专业合作社 | Method for adjusting and controlling water quality in soft-shelled turtle pond for adult Chinese soft-shelled turtles |
CN110746038A (en) * | 2019-10-11 | 2020-02-04 | 浙江先创能源科技股份有限公司 | Method for treating aquaculture water |
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