CN1237347A - Composite for expelling mosquito and paster made of said composite - Google Patents

Composite for expelling mosquito and paster made of said composite Download PDF

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Publication number
CN1237347A
CN1237347A CN98101888A CN98101888A CN1237347A CN 1237347 A CN1237347 A CN 1237347A CN 98101888 A CN98101888 A CN 98101888A CN 98101888 A CN98101888 A CN 98101888A CN 1237347 A CN1237347 A CN 1237347A
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China
Prior art keywords
weight
composition
effective ingredient
paster
polymer colloid
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Granted
Application number
CN98101888A
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Chinese (zh)
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CN1089556C (en
Inventor
赖荣芳
李清源
郑建新
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HUAJIAN MEDICAL SCIENCE AND TECHNOLOGY Co Ltd
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HUAJIAN MEDICAL SCIENCE AND TECHNOLOGY Co Ltd
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Priority to CN98101888A priority Critical patent/CN1089556C/en
Publication of CN1237347A publication Critical patent/CN1237347A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to a medicinal composite for expelling mosquito and the paster made of said medicinal composite. Its preparation method includes the following steps: using natural plant components of citronella oil, citronella, garlic oil, citronellal, camphor oil and camphor as effective components, mixing them with polymer colloid with stereo net structure and excipient to make the polymer colloid form into microcapsule and cover the effective components, applying said mixture on the non-woven fabric substrate, and covering the above-mentioned material with strippable covering film so as to obtain the invented paster for expelling mosquito. Its effective components can be controlled and released out progressively.

Description

The composition of expelling mosquito and the paster of making by said composition
The invention relates to a kind of composition of expelling mosquito and the paster of being made by said composition, particularly the composition that disengages by amount relevant for a kind of effective ingredient of controlled expelling mosquito reaches the paster of being made by said composition.
Though traditional expelling mosquito product such as spray, mosquito-repellent incense, electric mosquito repellent etc. are expelling mosquito effectively, shortcomings such as the inconvenience of use, contaminated air, harm environment and consumes energy are arranged.In addition, new on the market mosquito-proof product, for example (off) aerosol type or emulsion-type are protected in Europe, are be sprayed directly on on the skin, may cause the user that allergy and the long-time injury of using skin are arranged.
For overcoming the shortcoming of above known expelling mosquito product, the object of the present invention is to provide a kind of carrying, use everywhere, contaminated air does not endanger environment, not consumes energy, do not injure skin, the paster of rendeing a service lasting expelling mosquito composition and making by said composition.
In order to reach above-mentioned purpose of the present invention, the effective ingredient of expelling mosquito used in the present invention is to use the natral plant ingredients that does not harm human body and ecotope, citronella oil (CitronellaOil) for example, the volatility oils material of lemongrass (Citronella), garlic oil (Garlic Oil), citronellal (Citronellal), camphorated oil (Camphor Oil), camphor (Camphor) and other tool mosquito-repelling effects or with the l of two compositions of taking up an official post: 1 equal amount of mixture.
In addition, use can be compatible with above-mentioned effective ingredient and have the carrier of the polymer colloid of space network as effective ingredient in the present invention.The selected polymer colloid of the present invention is controlled the function of effective ingredient release rate in addition not only as the carrier of effective ingredient.The function of this kind control effective ingredient release rate is to form particulate capsule (microcapsule) when polymer colloid mixes with active ingredient, effective ingredient is coated wherein realize.
Be applicable to that polymer colloid of the present invention is as: carboxymethyl cellulose, methylcellulose, hydroxyethylcellulose, polyvinyl alcohol, polyvinylpyrrolidone, acryl resin series glue (as Carbopol  series glue), acryl glue, water soluble polymer pressure sensitive adhesive, oil-soluble polymeric pressure sensitive adhesive and composition thereof.
The method for making of the composition of expelling mosquito of the present invention is earlier the macromolecule sizing material to be added in the water, heating for dissolving leaves standstill to room temperature after forming solution, again effective ingredient and suitable vehicle are added in the alcohols and stir, form a suspension, and then solution and suspension mixed get final product.
According to the present invention, can use any suitable excipient, as titanium dioxide (TiO 2), starch etc.
In addition, according to the present invention, the usage amount of effective ingredient is 1~30 weight portion, the usage amount of polymer colloid is 10~20 weight portions, the usage amount of excipient is 0.5~1 weight portion, and the usage amount of water is 30~50 weight portions, and the usage amount of alcohols is 30~50 weight portions.
The present invention also comprises the paster that uses above-mentioned expelling mosquito composition to make, and the method for making of paster of the present invention is that composition is mixed, and after coating a matrix (for example on the matrix of nonwoven) and go up with gluing machine again, does with the wind that is no more than 60 ℃ in baking oven.At the port of export of gluing machine, before rolling, cover on the coated face then with the double faced adhesive tape of peelling off the one side release liners.Left standstill after the rolling about two days, treat that polymer colloid is shaped fully after, cut into slices and package processing gets final product.
Product of the present invention can be made optimal prescription according to the timely machine in different fields of employment, in the time of for example will making the paster that the sleep type uses, can use effective ingredient 2 weight portions, polymer colloid 10 weight portions, excipient 1 weight portion, water 43.5 weight portions, the prescription of alcohols 43.5 weight portions.If will make the paster of indoor type, then should use effective ingredient 10 weight portions, polymer colloid 10 weight portions, excipient 1 weight portion, water 39.5 weight portions, the prescription of alcohols 39.5 weight portions.As making the outdoor version paster, then can use effective ingredient 25 weight portions, polymer colloid 10 weight portions, excipient 1 weight portion, the prescription of water 32 weight portions and alcohols 32 weight portions.
Effective ingredient used in the present invention is the material of natural output, these material safety, avirulence and have the function of expelling mosquito, and boiling point is low, and promptly volatilizable in room temperature.And the selected polymer colloid of the present invention can form microcapsules effective ingredient is coated wherein when mixing with effective ingredient, allows the effective ingredient of expelling mosquito slowly disengage, and reaches the effect of long-time expelling mosquito.
In addition, paster of the present invention needn't directly be attached on the skin and can be attached to the place that any hope is pasted, and as clothes, furniture, with oneself on the object, thereby can not cause user's allergy and the long-time injury of using skin.
Below describe the present invention in detail by embodiment, but scope of the present invention is not limited to following examples.
Embodiment 1
Two kilograms of poly-ethanol (PVA) and 6.4 kilograms of deionized waters are put into mixing channel, stir 1 hour (temperature is set at 60 ℃), leave standstill and make it to be cooled to room temperature with the stir speed (S.S.) of 100rpm.
With 5.4 kilograms of citronella oils, 0.2 kilogram of titanium dioxide and 6 kilogram of 95% alcohol add in another mixing channel, stir with the speed of 50rpm.
After above-mentioned two mixtures are mixed, be coated on gluing machine on the matrix of nonwoven, coating speed is 1 meter of a per minute, and thickness is after the 0.75mm, does with the wind that is no more than 60 ℃ in baking box.
At the port of export of gluing machine, cover on the coated face with the double faced adhesive tape of peelling off the one side release liners earlier before the rolling, the nonwoven fabric roll of keeping well is placed in air-locked plastic bag, and sealing prevents that smell scatters and disappears.
At room temperature left standstill about two days, treat that polymer colloid is shaped fully after, cut into slices and package processing.
As above-mentioned method make for being fit to the paster of outdoor type.The paster of being made takes out in packaging bag, still has enough smells to send after 24 hours, can continue 48 hours at most.And truly have mosquito-proof effect through the actual use of 40 people checking.
Embodiment 2
1 kilogram of Carbopol  and 10 kilograms of deionized waters are put into mixing channel, with 1 hour (temperature is set at room temperature) of stir speed (S.S.) stirring of 100rpm.
With 2 kilograms of citronella oils, 0.05 kilogram of starch and 6.95 kilogram of 95% alcohol add in another mixing channel, stir with the speed of 50rpm.
After above-mentioned two mixtures are mixed, be coated on gluing machine on the matrix of nonwoven, coating speed is 1 meter of a per minute, and thickness is after the 0.75mm, in baking box to be no more than 60 ℃ the wind universe.
At the port of export of gluing machine, cover on the coated face with the double faced adhesive tape of peelling off the one side release liners earlier before the rolling, the nonwoven fabric roll of keeping well is placed in air-locked plastic bag, and sealing prevents that smell scatters and disappears.
At room temperature left standstill about two days, treat that polymer colloid is shaped fully after, cut into slices and package processing.
As the paster for suitable indoor type that above-mentioned method is made, the paster of being made takes out in packaging bag and still had enough smells to send after 24 hours, can continue 48 hours at most.And truly have mosquito-proof effect through the actual use of 40 people checking.
Embodiment 3
2 kilograms of poly-ethanol and 6.4 kilograms of deionized waters are put into mixing channel, stir 1 hour (temperature is set at 60 ℃), leave standstill and make it to be cooled to room temperature with the stir speed (S.S.) of 100rpm.
With 0.2 kilogram of citronella oil, 0.2 kilogram of camphorated oil, 0.2 kilogram of titanium dioxide and 11 kilogram of 95% alcohol add in another mixing channel, stir with the speed of 50rpm.
After above-mentioned two mixtures are mixed, be coated on the nonwoven matrix with gluing machine, coating speed is 1 meter of a per minute, and thickness is after the 0.75mm, does with the wind that is no more than 60 ℃ in baking box.
At the port of export of gluing machine, cover on the coated face with the double faced adhesive tape of peelling off the one side release liners earlier before the rolling, the nonwoven fabric roll of keeping well is placed in air-locked plastic bag, and sealing prevents that smell scatters and disappears.
At room temperature left standstill about two days, treat that polymer colloid is shaped fully after, cut into slices and package processing.
As above-mentioned method make for being fit to sleep type paster, institute's paster of making takes out in packing machine and still had enough smells to send after 24 hours, can continue 48 hours at most, and verifies through the actual use of 40 people and to truly have mosquito-proof effect.

Claims (17)

1. the composition of an expelling mosquito comprises:
A) 1~30 weight portion is selected from citronella oil, lemongrass, garlic oil, citronellal, camphor, camphorated oil, the effective ingredient of 1: 1 equal amount of mixture of the volatility oils material of other tool mosquito-repelling effects and wantonly two compositions;
B) 10~20 weight portions and this effective ingredient are compatible and have a polymer colloid of space network; And
C) excipient of 0.5~1 weight portion.
2. composition as claimed in claim 1, wherein, this polymer colloid is to select from carboxymethyl cellulose, methylcellulose, hydroxyethylcellulose, polyvinyl alcohol, polyvinylpyrrolidone, acryl resin series glue, acryl glue, water soluble polymer pressure sensitive adhesive, oil-soluble polymeric pressure sensitive adhesive and composition thereof.
3. composition as claimed in claim 1, wherein, excipient is a titanium dioxide.
4. composition as claimed in claim 1, wherein, excipient is a starch.
5. composition as claimed in claim 1 wherein, more comprises the water of 30~50 weight portions and the alcohols of 30~50 weight portions.
6. composition as claimed in claim 5, wherein, this alcohols is 95% alcohol.
7. composition as claimed in claim 5, wherein, this water is deionized water.
8. the composition of an expelling mosquito as claimed in claim 1 comprises:
This effective ingredient of 2 weight %, this polymer colloid of 10 weight %, the titanium dioxide of 1 weight %, the alcohol of the water of 43.5 weight % and 43.5 weight %.
9. the composition of an expelling mosquito as claimed in claim 1 comprises:
This effective ingredient of 10 weight %, this polymer colloid of 10 weight %, the titanium dioxide of 1 weight %, the alcohol of the deionized water of 39.5 weight % and 39.5 weight %.
10. the composition of an expelling mosquito as claimed in claim 1 comprises:
This effective ingredient of 35 weight %, this polymer colloid of 10 weight %, the titanium dioxide of 1 weight %, the alcohol of the deionized water of 32 weight % and 32 weight %.
11. the paster of an expelling mosquito comprises:
One matrix, and
The coat of composition as claimed in claim 1 is coated on this matrix.
12. paster as claimed in claim 11 comprises that a more peelable emulsion sheet is covered on this coat.
13. paster as claimed in claim 11, wherein, this matrix is made by nonwoven.
14. the method for making of an expelling mosquito paster comprises the following steps:
A) effective ingredient and 0.5~1 weight portion excipient selected from citronella oil, lemongrass, garlic oil, citronellal or mixture with 1~30 weight portion is dissolved in formation one suspension in the alcohols,
B) compatible and have polymer colloid formation one solution soluble in water of space network with 10~20 weight with this effective ingredient,
C) this suspension and this solution are mixed formation one mixture,
D) this mixture is coated on the matrix, and drying, a coat formed;
E) a peelable emulsion sheet is covered on this cover layer.
15. method for making as claimed in claim 14, wherein, this alcohols is 95% alcohol.
16. method for making as claimed in claim 14, wherein, step (a) is that effective ingredient and excipient are added in the deionized water of 30~50 weight portions.
17. method for making as claimed in claim 14, wherein, step (b) is that polymer colloid is added in the alcohols of 30~50 weight portions.
CN98101888A 1998-05-28 1998-05-28 Composite for expelling mosquito and paster made of said composite Expired - Fee Related CN1089556C (en)

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Application Number Priority Date Filing Date Title
CN98101888A CN1089556C (en) 1998-05-28 1998-05-28 Composite for expelling mosquito and paster made of said composite

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN98101888A CN1089556C (en) 1998-05-28 1998-05-28 Composite for expelling mosquito and paster made of said composite

Publications (2)

Publication Number Publication Date
CN1237347A true CN1237347A (en) 1999-12-08
CN1089556C CN1089556C (en) 2002-08-28

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Cited By (15)

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CN101649545B (en) * 2008-08-13 2011-06-29 浙江康丝丽家居科技有限公司 Process for producing mosquito repelling silk quilt
CN102165964A (en) * 2010-11-29 2011-08-31 吴克 Mosquito repelling patch and preparation technology thereof
CN101433196B (en) * 2007-11-13 2012-06-13 中山圣磐五金塑料有限公司 Plastic ring with mosquito-repelling function and preparing technique thereof
CN103548893A (en) * 2013-10-30 2014-02-05 成都新柯力化工科技有限公司 Solid mosquito-repelling particles and preparation method thereof
CN103696141A (en) * 2013-12-10 2014-04-02 马鞍山湖滨无纺布科技有限公司 Healthcare non-woven fabric and preparation method thereof
CN103860394A (en) * 2012-12-17 2014-06-18 华中农业大学 Long-acting mosquito and flies repellant spraying agent special for animals and its preparation method
CN104782683A (en) * 2015-03-25 2015-07-22 浙江工业大学之江学院 Environment-friendly polylactic acid mosquito-repellent tablet and preparation method thereof
CN104782679A (en) * 2015-03-25 2015-07-22 浙江工业大学之江学院 Environment-friendly polycaprolactone mosquito-repellent tablet and preparation method thereof
CN104782681A (en) * 2015-03-25 2015-07-22 浙江工业大学之江学院 Environment-friendly poly(3-hydroxybutyrate) mosquito-repellent tablet and preparation method thereof
CN106106448A (en) * 2016-06-25 2016-11-16 广西柳州昊邦日化有限公司 Delicate fragrance mosquito expelling plaster
CN106510107A (en) * 2016-11-29 2017-03-22 成都聚智工业设计有限公司 Wearable bracelet with liquid crystal display screen
CN108301196A (en) * 2018-01-18 2018-07-20 江南大学 A kind of antimosquito finishing agent and preparation method thereof
CN108498572A (en) * 2018-02-27 2018-09-07 浙江小正科技有限公司 A kind of antipruritic and mosquito-expelling and antipruritic patch
CN109691431A (en) * 2017-10-20 2019-04-30 日荣化工株式会社 Patch and its manufacturing method
CN113133449A (en) * 2021-04-22 2021-07-20 成都彩虹电器(集团)中南有限公司 Preparation process of microcapsule slow-release type essential oil mosquito-repellent gel

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JP4171385B2 (en) * 2003-09-17 2008-10-22 株式会社日本触媒 Manufacturing method of microcapsule carrying sheet
CN103262839B (en) * 2013-05-31 2014-12-03 广州立白企业集团有限公司 Mosquito repelling gel composition with natural plant essential oil
CN111838199A (en) * 2020-06-04 2020-10-30 深圳昌茂粘胶新材料有限公司 Novel incense mosquito-repelling material and preparation method thereof

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US4320112A (en) * 1980-06-06 1982-03-16 Jones Lonnie R Composition for pest repellent receptacle
US4671960A (en) * 1984-03-16 1987-06-09 Peter Thielen Herbal repellent composition
CN1068176C (en) * 1996-05-20 2001-07-11 谢建华 Long effective eating-proof pest repellant and its prepn. method

Cited By (18)

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CN101433196B (en) * 2007-11-13 2012-06-13 中山圣磐五金塑料有限公司 Plastic ring with mosquito-repelling function and preparing technique thereof
CN101649545B (en) * 2008-08-13 2011-06-29 浙江康丝丽家居科技有限公司 Process for producing mosquito repelling silk quilt
CN102165964A (en) * 2010-11-29 2011-08-31 吴克 Mosquito repelling patch and preparation technology thereof
CN103860394A (en) * 2012-12-17 2014-06-18 华中农业大学 Long-acting mosquito and flies repellant spraying agent special for animals and its preparation method
CN103860394B (en) * 2012-12-17 2017-09-05 华中农业大学 A kind of long-acting mosquitos and flies repellent spray liniment of animal specific and preparation method thereof
CN103548893A (en) * 2013-10-30 2014-02-05 成都新柯力化工科技有限公司 Solid mosquito-repelling particles and preparation method thereof
CN103548893B (en) * 2013-10-30 2015-04-08 成都新柯力化工科技有限公司 Solid mosquito-repelling particles and preparation method thereof
CN103696141B (en) * 2013-12-10 2015-12-30 马鞍山湖滨无纺布科技有限公司 A kind of health-care nonwoven fabric and preparation method thereof
CN103696141A (en) * 2013-12-10 2014-04-02 马鞍山湖滨无纺布科技有限公司 Healthcare non-woven fabric and preparation method thereof
CN104782679A (en) * 2015-03-25 2015-07-22 浙江工业大学之江学院 Environment-friendly polycaprolactone mosquito-repellent tablet and preparation method thereof
CN104782681A (en) * 2015-03-25 2015-07-22 浙江工业大学之江学院 Environment-friendly poly(3-hydroxybutyrate) mosquito-repellent tablet and preparation method thereof
CN104782683A (en) * 2015-03-25 2015-07-22 浙江工业大学之江学院 Environment-friendly polylactic acid mosquito-repellent tablet and preparation method thereof
CN106106448A (en) * 2016-06-25 2016-11-16 广西柳州昊邦日化有限公司 Delicate fragrance mosquito expelling plaster
CN106510107A (en) * 2016-11-29 2017-03-22 成都聚智工业设计有限公司 Wearable bracelet with liquid crystal display screen
CN109691431A (en) * 2017-10-20 2019-04-30 日荣化工株式会社 Patch and its manufacturing method
CN108301196A (en) * 2018-01-18 2018-07-20 江南大学 A kind of antimosquito finishing agent and preparation method thereof
CN108498572A (en) * 2018-02-27 2018-09-07 浙江小正科技有限公司 A kind of antipruritic and mosquito-expelling and antipruritic patch
CN113133449A (en) * 2021-04-22 2021-07-20 成都彩虹电器(集团)中南有限公司 Preparation process of microcapsule slow-release type essential oil mosquito-repellent gel

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