CN1235480C - Chlorpyrifos and phoxim compound insecticidal granules - Google Patents
Chlorpyrifos and phoxim compound insecticidal granules Download PDFInfo
- Publication number
- CN1235480C CN1235480C CN 200310106176 CN200310106176A CN1235480C CN 1235480 C CN1235480 C CN 1235480C CN 200310106176 CN200310106176 CN 200310106176 CN 200310106176 A CN200310106176 A CN 200310106176A CN 1235480 C CN1235480 C CN 1235480C
- Authority
- CN
- China
- Prior art keywords
- phoxim
- chlopyrifos
- carrier
- agent
- granular insecticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229950001664 phoxim Drugs 0.000 title claims abstract description 27
- 239000008187 granular material Substances 0.000 title claims abstract description 13
- 230000000749 insecticidal effect Effects 0.000 title claims description 10
- -1 phoxim compound Chemical class 0.000 title claims description 8
- 239000005944 Chlorpyrifos Substances 0.000 title abstract 3
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 title abstract 3
- ATROHALUCMTWTB-OWBHPGMISA-N phoxim Chemical compound CCOP(=S)(OCC)O\N=C(\C#N)C1=CC=CC=C1 ATROHALUCMTWTB-OWBHPGMISA-N 0.000 claims abstract description 19
- 239000011230 binding agent Substances 0.000 claims abstract description 11
- 239000003381 stabilizer Substances 0.000 claims abstract description 11
- 239000003463 adsorbent Substances 0.000 claims abstract description 10
- 150000001875 compounds Chemical class 0.000 claims abstract description 8
- 239000002917 insecticide Substances 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 238000004040 coloring Methods 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 239000003814 drug Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical compound CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 claims description 2
- 244000215068 Acacia senegal Species 0.000 claims description 2
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 claims description 2
- 244000025254 Cannabis sativa Species 0.000 claims description 2
- 229920001353 Dextrin Polymers 0.000 claims description 2
- 239000004375 Dextrin Substances 0.000 claims description 2
- 229920000084 Gum arabic Polymers 0.000 claims description 2
- 241000233855 Orchidaceae Species 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- ZMJPCIAEJKVKMQ-UHFFFAOYSA-M [4-[[4-[benzyl(methyl)amino]phenyl]-[4-(dimethylamino)phenyl]methylidene]cyclohexa-2,5-dien-1-ylidene]-dimethylazanium;chloride Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC(=CC=1)N(C)CC=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 ZMJPCIAEJKVKMQ-UHFFFAOYSA-M 0.000 claims description 2
- 239000000205 acacia gum Substances 0.000 claims description 2
- 235000010489 acacia gum Nutrition 0.000 claims description 2
- 239000012752 auxiliary agent Substances 0.000 claims description 2
- JBTHDAVBDKKSRW-UHFFFAOYSA-N chembl1552233 Chemical compound CC1=CC(C)=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 JBTHDAVBDKKSRW-UHFFFAOYSA-N 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- ZXJXZNDDNMQXFV-UHFFFAOYSA-M crystal violet Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1[C+](C=1C=CC(=CC=1)N(C)C)C1=CC=C(N(C)C)C=C1 ZXJXZNDDNMQXFV-UHFFFAOYSA-M 0.000 claims description 2
- 235000019425 dextrin Nutrition 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 238000012856 packing Methods 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 229960005235 piperonyl butoxide Drugs 0.000 claims description 2
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 2
- 239000011118 polyvinyl acetate Substances 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 239000004576 sand Substances 0.000 claims description 2
- 238000007873 sieving Methods 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 2
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 2
- 240000000111 Saccharum officinarum Species 0.000 abstract description 16
- 235000007201 Saccharum officinarum Nutrition 0.000 abstract description 16
- 238000002360 preparation method Methods 0.000 abstract description 12
- 239000000575 pesticide Substances 0.000 abstract description 10
- 241000607479 Yersinia pestis Species 0.000 abstract description 5
- 241000270708 Testudinidae Species 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000004480 active ingredient Substances 0.000 abstract 1
- 239000003086 colorant Substances 0.000 abstract 1
- 244000144972 livestock Species 0.000 abstract 1
- 241000238631 Hexapoda Species 0.000 description 11
- 239000002689 soil Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 231100000419 toxicity Toxicity 0.000 description 5
- 230000001988 toxicity Effects 0.000 description 5
- 230000002195 synergetic effect Effects 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 244000144977 poultry Species 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 241000661398 Bathytricha truncata Species 0.000 description 1
- 235000016936 Dendrocalamus strictus Nutrition 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- DUEPRVBVGDRKAG-UHFFFAOYSA-N carbofuran Chemical compound CNC(=O)OC1=CC=CC2=C1OC(C)(C)C2 DUEPRVBVGDRKAG-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 231100000571 death by poisoning Toxicity 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- KRTSDMXIXPKRQR-AATRIKPKSA-N monocrotophos Chemical compound CNC(=O)\C=C(/C)OP(=O)(OC)OC KRTSDMXIXPKRQR-AATRIKPKSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- BULVZWIRKLYCBC-UHFFFAOYSA-N phorate Chemical compound CCOP(=S)(OCC)SCSCC BULVZWIRKLYCBC-UHFFFAOYSA-N 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 229960004793 sucrose Drugs 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to a high-efficiency pesticide for preventing and controlling underground pests, and particularly relates to a compound granule taking chlorpyrifos and phoxim as main active ingredients. The preparation is mainly used for preventing and controlling underground pests such as cane tortoise, cane borer and the like on sugarcane crops. The preparation consists of chlorpyrifos, phoxim, an adsorbent, a binder, a colorant, a synergist, a stabilizer and a carrier. The product has the characteristics of convenient application, high efficiency, durability, safety to crops, human and livestock, environmental friendliness and the like.
Description
Technical field
The present invention relates to a kind of efficient pesticides that is used to prevent and treat soil insect, a kind of compound insecticidal granule that contains chlopyrifos and phoxim of more specifically saying so.
Background technology
Sugarcane moth borer, sugarcane tortoise are the main soil insect in the sugarcane production, deal with improperly and will cause sugarcane to drop in production over a large area and the quality reduction.Sugarcane is the primary raw material source that China produces sucrose, and its industry size is big, and the pesticide dosage that is used for the sugarcane controlling underground pest has considerable scale.In recent years, because the using repeatedly in a large number of some high-toxic pesticides, unitary agent, cause the part insect to produce resistance or resistance strengthens, some conventional pesticide preventive effects constantly descend, and must increase dosage and frequency of utilization improves preventive effect, the production cost increasing; Simultaneously, directly have influence on the foreign exchange earning of people's consumption health and even China's sugar industry because the use of a large amount of high-toxic pesticides will cause exceeding standard of persticide residue in the sugarcane.On the other hand; because the China environmental protection dynamics is strengthened day by day; restriction, the use of forbidding high-toxic pesticide have become inevitable, and this also will cause, and the control of insect preparation variety reduces in the sugarcane field, develop for this reason new efficient, low-residual sugarcane controlling underground pest preparation is very necessary and urgent.
Though China's sugarcane controlling underground pest preparation has kind more than ten at present, but many weak points have been remained, the for example use of some high poison, persistent pesticide nuvacron, carbofuran, thimet and complex preparation thereof etc. is because of it progressively is limited person poultry toxicity's height, residual quantity senior general or bans use of; Insecticide remains shortcomings such as having immediate effect property is poor, insecticide efficiency is low under a lot of sugarcane fields that use at present; Some conventional agricultural chemicals list agent will cause the sugarcane insect to produce resistance because of its prolonged and repeated use or resistance strengthens; Some missible oil class pesticidal preparations because of its production will consume a large amount of organic solvents, cause its cost to raise, and unfavorable transportation, in use will cause bigger environmental pollution again, need careful for using.
Summary of the invention
The objective of the invention is to by science, advanced compounded preparation of pesticide technology, for the control of sugarcane soil insect provide a kind of efficient, quick-acting, low-residual, formulation advanced person, safe in utilization, what be difficult for producing resistance is that Main Ingredients and Appearance is by the composite granular insecticide that forms of certain technology path by chlopyrifos and phoxim.
The invention provides a kind of is the granule complex preparation that mainly contains effective constituent by chlopyrifos and phoxim, and its each component proportioning (percentage by weight) is as follows:
Chlopyrifos 1～20%
Phoxim 1～20%
Adsorbent 1～13%
Binding agent 0.5～11%
Stabilizing agent 0.2～15%
Synergist 0.1～8%
Colouring agent 0.2～1.5%
Carrier 96～40%
In the above-mentioned prescription, described chlopyrifos can be selected the former medicine of chlopyrifos or female powder for use, and phoxim is selected crude oil for use; Described adsorbent can be selected polo-neck soil, bentonite, diatomite, attapulgite, white carbon, potter's clay, atlapulgite, talcum powder, fine particle calcium carbonate for use; Described binding agent is selected a kind of or several mixing in polyvinyl alcohol, polyvinyl acetate, dextrin, starch, the gum Arabic for use; Described stabilizing agent is selected phosphorous acid or triphenyl phosphate for use; Described synergist is Butacide, synergy phosphorus, azone; Described colouring agent selects that brilliant violet, crystalviolet, product purple, the red B of polarity, phthalein green grass or young crops are red for use, the blue or green orchid of phthalein, phthalein viridescent.
Described carrier is selected river sand, ore, gangue for use.
A kind of method for preparing chlopyrifos and phoxim compound granular insecticide, carry out as follows:
1. the former medicine of effective ingredient chlopyrifos or female powder, phoxim crude and adsorbent are mixed, make little wet female powder;
2. get 25～70 order particles with sieving after the carrier drying;
3. the carrier that 2. female powder that 1. step is made and step make is put into to rotate in the dressing machine and is mixed, and adds auxiliary agents such as binding agent, stabilizing agent, synergist, colouring agent more respectively, and fully stirs, and makes female powder be coated on the carrier equably;
4. after the granule drying machine drying that will make, sieve and get the qualified products packing.
Good effect of the present invention is:
1. use chlopyrifos and phoxim binary built, contained two kinds of different insecticidal spectrums, thereby can play the effect that enlarges insecticidal spectrum, improves drug effect, reduces production costs.This complex preparation death by poisoning tick is strong to the insect toxic action, toxicity is medium, act on crop root and have certain conduction, when effectively killing soil insect, can take into account the control of insect on the ground in sugarcane seedling stage: phoxim has to insect that stronger speed is killed effect and toxicity is low toxicity in the preparation; Above-mentioned two kinds of insecticides are mixed by a certain percentage and can play obvious synergistic effect, show in Guangzhou Inst of Cane Sugar plant protection research promotion center " Toxicity Determination report "; Chlopyrifos and phoxim co-toxicity coefficient by 1: 2 and 2: 3 proportionings the time reaches 187.1 and 185.8, and synergistic effect is (co-toxicity coefficient CTC: less than 70, be antagonism very significantly; 70～150, be summation action:, be synergistic effect greater than 150; Be extremely significantly synergistic effect greater than 200).Thereby determine insecticide of the present invention that the sugarcane soil insect is had the better prevention effect.
2. the present invention is granule on preparation, and adopts international advanced pesticide slow-release technology, and therefore can guarantee: this product lasting period is longer: product is easy to transportation: use safer, convenient; Because of its not with an organic solvent, so environmentally friendly.
3. product toxicity of the present invention is lower, and it is fast to degrade in soil and sugarcane, and persticide residue is low, to the person poultry safety.
Below in conjunction with embodiment the present invention is described in further detail.
Embodiment
Embodiment 1 4.5% compound insecticidal granule
Raw material proportioning (weight per volume)
Chlopyrifos 1.5%
Phoxim 3%
Adsorbent 1.3%
Binding agent 0.7%
Stabilizing agent 1.4%
Synergist 6.2%
Colouring agent 0.3%
Carrier 85.6%
Embodiment 2 5% compound insecticidal granules
Raw material proportioning (weight per volume)
Chlopyrifos 2%
Phoxim 3%
Adsorbent 1.3%
Binding agent 0.8%
Stabilizing agent 1.5%
Synergist 5.6%
Colouring agent 0.3%
Carrier 85.5%
Embodiment 3 12% compound insecticidal granules
Raw material proportioning (weight per volume)
Chlopyrifos 4%
Phoxim 8%
Adsorbent 7.5%
Binding agent 6.9%
Stabilizing agent 8.2%
Synergist 3.2%
Colouring agent 0.8%
Carrier 61.4%
Embodiment 4 18% compound insecticidal granules
Raw material proportioning (weight per volume)
Chlopyrifos 6%
Phoxim 12%
Adsorbent 10.1%
Binding agent 8.3%
Stabilizing agent 11.6%
Synergist 1.9%
Colouring agent 1.1%
Carrier 49%
Claims (8)
1, a kind of compound insecticidal granule that contains chlopyrifos and phoxim is characterized in that it is by the composite in proportion granular insecticide of making of following component raw material (percentage by weight):
Chlopyrifos 1～20%
Phoxim 1～20%
Adsorbent 1～13%
Binding agent 0.5～11%
Stabilizing agent 0.2～15%
Synergist 0.1～8%
Colouring agent 0.2～1.5%
Carrier 40～96%.
2, the compound insecticidal granule of chlopyrifos according to claim 1 and phoxim is characterized in that: chlopyrifos can be selected the former medicine of chlopyrifos or female powder for use.
3, chlopyrifos according to claim 1 and phoxim compound granular insecticide is characterized in that: described binding agent is selected a kind of in polyvinyl alcohol, polyvinyl acetate, dextrin, starch, the gum Arabic for use.
4, chlopyrifos according to claim 1 and phoxim compound granular insecticide, it is characterized in that: described stabilizing agent is selected phosphorous acid or triphenyl phosphate for use.
5, chlopyrifos according to claim 1 and phoxim compound granular insecticide is characterized in that: described synergist is any in Butacide, synergy phosphorus, the azone.
6, chlopyrifos according to claim 1 and phoxim compound granular insecticide is characterized in that: described colouring agent selects that brilliant violet, crystalviolet, product purple, the red B of polarity, phthalein green grass or young crops are red for use, any in the blue or green orchid of phthalein, phthalein viridescent.
7, chlopyrifos according to claim 1 and phoxim compound granular insecticide is characterized in that: described carrier is selected any in river sand, ore, the gangue for use.
8, a kind of method for preparing the described granular insecticide of claim 1 is characterized in that this method carries out as follows successively:
1. the former medicine of effective ingredient chlopyrifos or female powder, phoxim crude and adsorbent are mixed, make little wet female powder;
2. get 25～70 order particles with sieving after the carrier drying;
3. the carrier that 2. female powder that 1. step is made and step make is put into to rotate in the dressing machine and is mixed, and adds binding agent, stabilizing agent, synergist, colouring agent auxiliary agent more respectively, and fully stirs, and makes female powder be coated on the carrier equably;
4. after the granule drying machine drying that will make, sieve and get the qualified products packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310106176 CN1235480C (en) | 2003-10-29 | 2003-10-29 | Chlorpyrifos and phoxim compound insecticidal granules |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310106176 CN1235480C (en) | 2003-10-29 | 2003-10-29 | Chlorpyrifos and phoxim compound insecticidal granules |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1539284A CN1539284A (en) | 2004-10-27 |
| CN1235480C true CN1235480C (en) | 2006-01-11 |
Family
ID=34334006
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200310106176 Expired - Fee Related CN1235480C (en) | 2003-10-29 | 2003-10-29 | Chlorpyrifos and phoxim compound insecticidal granules |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1235480C (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102047876A (en) * | 2009-11-05 | 2011-05-11 | 甘肃省农业科学院植物保护研究所 | Formula and preparation method of granular pesticide |
| CN103636660B (en) * | 2013-11-26 | 2016-05-25 | 肇庆市真格生物科技有限公司 | A kind of for preventing and treating the Environmental-protection particle agent of Sugarcane Pests |
| CN104304313A (en) * | 2014-09-29 | 2015-01-28 | 青岛康合伟业商贸有限公司 | High-efficiency pesticide containing phoxim, sulfoxaflor, dinotefuran and chlorpyrifos |
| CN107087634A (en) * | 2017-06-29 | 2017-08-25 | 山东大农药业有限公司 | Chlopyrifos and phoxim compound granular insecticide |
-
2003
- 2003-10-29 CN CN 200310106176 patent/CN1235480C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1539284A (en) | 2004-10-27 |
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Granted publication date: 20060111 Termination date: 20121029 |