CN1235179A - Ink for forming receiving layer and product using the same - Google Patents
Ink for forming receiving layer and product using the same Download PDFInfo
- Publication number
- CN1235179A CN1235179A CN99103433A CN99103433A CN1235179A CN 1235179 A CN1235179 A CN 1235179A CN 99103433 A CN99103433 A CN 99103433A CN 99103433 A CN99103433 A CN 99103433A CN 1235179 A CN1235179 A CN 1235179A
- Authority
- CN
- China
- Prior art keywords
- ink
- receiving layer
- printing ink
- product
- printing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5227—Macromolecular coatings characterised by organic non-macromolecular additives, e.g. UV-absorbers, plasticisers, surfactants
Abstract
To provide an ink for forming a receiving layer, said ink containing an agent to enhance an ink-jet ink-receiving property and to confer a phosphorescent property, and products which use said ink. The ink for forming a receiving layer according to the present invention has a receiving property to ink-jet inks and a phosphorescent property and enable to print or coat on substrates and to print with ink-jet inks on said ink, phosphorescent pigments used in said ink for forming a receiving layer being commercial pigments such as an N noctilucent phosphorescent pigment and an S noctilucent phosphorescent pigment, average particle size of said phosphorescent pigments being 0.5-50 mu m, most preferably 8-25 mu m. Water-absorptive or water-absorbing organic fillers or inorganic fillers can be mixed to said ink.
Description
The product that the present invention relates to be used to form the printing ink of receiving layer and used this printing ink.
Receiving layer is imprinted on or covers in the substrate always so that printing ink absorbed securely, and reduce when with ink jet method to substrate, the infiltration when printing as paper, film and plate.The printing ink that is used to form receiving layer is to be dissolved in the water-bearing media by the pigment with water soluble, and then absorb fillers, makes as silicon-dioxide, aluminium sesquioxide and aluminium hydroxide.
Also recommend by adding the printing ink that absorbs water filler and described ink solidification is made to the soluble monomer of liquid water always.
The object of the present invention is to provide the printing ink that is used to form receiving layer, it contains and is useful on the novel agent that strengthens receptivity.Another purpose of the present invention is that the product that is provided for forming the printing ink of receiving layer and used this printing ink, this printing ink contain the novel agent that also has other function except that strengthening receptivity, and the described receptivity that is enhanced is by traditional material, as SiO
2, Al
2O
3And Al (OH)
3Provide with the organic materials of suction.That is to say that the invention provides the printing ink that is used to form receiving layer and used the product of this printing ink, described printing ink contains the receptivity that strengthens jetted ink, also makes it to have phosphorescent reagent.
The invention provides the printing ink that is used to form the jetted ink receiving layer, it contains the phosphorescent pigment that strengthens receptivity.The present invention also provides the product that receives jetted ink, described product is printed in substrate or scribbles and is used to form receiving layer, the printing ink that contains the phosphorescent pigment that strengthens receptivity, the present invention also provides the product of making on the product that receives described printing ink by jetted ink is imprinted on.
The phosphorescent pigment that adds for the enhancing receptivity comprises commercially available phosphorescent pigment, phosphorescent pigment luminous in the dark as N (noctilucent phosphorescent pigment) and the luminous in the dark phosphorescent pigment of S.
General employing particle size is 0.5-50 μ m, is more preferably 5-35 μ m, preferably the phosphorescent pigment of 8-25 μ m.Adopt too small particle size, tend to reduce the effect that strengthens receptivity and phosphorescence performance.On the other hand, adopt excessive particle size to tend to make the picture of ink jet printing coarse and reduce the quality of printed image.
Be used to form and receive receiving layer, the phosphorescent pigment in the printing ink of the present invention be generally ink carrier weight 5-120%, be more preferably 15-90%.
The reagent that is used to strengthen receptivity can and be used to strengthen the known agent of receptivity with phosphorescent pigment, as organic materials, the SiO of suction
2, Al
2O
3And Al (OH)
3Use together.The organic materials of phosphorescent pigment and suction, as the combination results of the polymer powder of protein powder, cellulose powder and suction excellent result.
It is of the present invention that to be used to form preferred adhesive used in the printing ink of receiving layer be a kind of hydrophilic polymkeric substance.As described hydrophilic polymer, preferably adopt water-insoluble polymkeric substance with the hydrophilic radical that reduces water repelling property, and the polymkeric substance of water soluble.Be preferably in curable printing ink, as adopting the monomer of the water soluble that wherein is dissolved with various oligopolymer or polymkeric substance and the monomer of water soluble in the UV-curable ink.
Can add the various additives that adopt in the normal printing ink.
The product that receives jetted ink can be by printing and apply generation in various substrates.Described printing and coating comprise that silk screen printing, photograph resemble intaglio plate printing, flexography, letterpress, spraying and roller coat.In order to solvent for the printing carried out of printing ink of base with the solvent seasoning step, the printing of carrying out with the UV-curable ink is with steps such as UV-exposures.
The thickness of the receiving layer of printing is generally 1-100 μ m, is more preferably 5-50 μ m.Therefore, the most handy method such as silk screen printing is printed receiving layer.
Preferably adopt the synthetic polymkeric substance to do to receive the substrate of product.Described synthetic polymer comprises: polycarbonate, polyvinyl chloride, polyester, polyolefine, ABS resin, hardening resin (setting resin) and acrylic resin (acryl resin).Though the performance of the reception jetted ink of these resins is low in general, can produces with the printing ink printing that is used to form receiving layer of the present invention and to have the excellent reception jetted ink performance and the product that is used to receive of phosphorescence performance.
If this synthetic resins substrate medium that are a kind of recorded information, then can produce and have utmost point high value-added product.That is to say, as the medium that meet recorded information of the present invention, as CD, they have performance and the phosphorescence performance that receives jetted ink, these medium have so good advantage, and consequently the various models of this dish and usage and performance all can stamp, even and also can see darkling.
The present invention makes printing ink have performance and the phosphorescence performance that receives jetted ink, and people are read darkling, and the performance that receives jetted ink is strengthened.
Product and reference product with receptivity according to the invention carried out some property comparison.According to the invention, be used to form the printing ink I (embodiment 1) of receiving layer: the phosphorescent pigment (average particle size particle size 15 μ m) that N is luminous in the dark
Organic filler 15.0% (weight) photolytic activity acrylic acid oligomer (Photo-active acryl oligomer) 20.0% (weight) photoactive monomer 43.0% (weight) light trigger 5.0% (weight) additive 2.0% (weight) of 15.0% (weight) suction is according to the invention, is used to form in the dark luminous phosphorescent pigment (average particle size particle size 15 μ m) of the printing ink II (embodiment 2) of receiving layer: N
30.0% (weight) photolytic activity acrylic acid oligomer 20.0% (weight) photoactive monomer 43.0% (weight) light trigger 5.0% (weight) additive, 2.0% (weight) is used for the printing ink III of contrast: photolytic activity acrylic acid oligomer 45.0% (weight) photoactive monomer 48.0% (weight) light trigger 5.0% (weight) additive 2.0% (weight)
With embodiment 1 and 2 and the printing ink of control group 300 purpose silk screen printings are carried out in the CD-R substrate, make ink solidification by being exposed in the UV light then, thereby obtain the product that thickness is 15 μ m.Ink-jet printer 4 (Canon Co.Ltd.) and ink-jet printer B are used in the substrate of gained, and (Epson Co. Ltd.) prints.Observe the printing performance of these substrates in bright place and dark place.The knot of observing be summarized in the table 1 (symbol: ◎, fabulous; Zero, fine; *, bad)
Table 1
| The printing ink I | The printing ink II | The printing ink III | |
| The printing performance of ink-jet printer A | ???????◎ | ??????○ | ??????× |
| The printing performance of ink-jet printer B | ???????◎ | ??????○ | ??????× |
| Observe in the dark | Coil as seen, printed character is readable | Coil as seen, printed character is clear readable | Coil invisiblely, printed character is not readable |
When adopting the printing ink I, printing performance is splendid: can see dish darkling and can read printed character.When adopting the printing ink II, printing performance is fine: can see dish darkling, printed character is clear readable.But when adopting the printing ink III, printing performance is bad: cannot see dish darkling, printed character is not readable.
Claims (8)
1, be used to form the printing ink of jetted ink receiving layer, wherein said printing ink contains the phosphorescent pigment that is useful on the improvement receptivity.
2, the printing ink that is used to form receiving layer of claim 1, the mean diameter of wherein said pigment are 5-35 μ m.
3, claim 1 or 2 the printing ink that is used to form receiving layer, wherein said printing ink contains the organic filler of phosphorescent pigment and suction filler or suction.
4, claim 1,2 or 3 the printing ink that is used to form receiving layer, wherein said printing ink contains hydrophilic polymkeric substance.
5, in substrate, be printed on or scribble the product of claim 1,2,3 or 4 the reception jetted ink that is used to form receiving layer.
6, the product of the reception jetted ink of claim 5, wherein said substrate is made with synthetic resins.
7, the product of the reception jetted ink of claim 6, wherein said synthetic resins substrate is the medium of recorded information.
8, by print the printed product that claim 5,6 and 7 reception product produce with jetted ink.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP69523/98 | 1998-03-04 | ||
| JP6952398A JPH11246810A (en) | 1998-03-04 | 1998-03-04 | Ink for forming receiving layer and product using the same |
| JP69523/1998 | 1998-03-04 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1235179A true CN1235179A (en) | 1999-11-17 |
| CN1190468C CN1190468C (en) | 2005-02-23 |
Family
ID=13405180
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB991034333A Expired - Fee Related CN1190468C (en) | 1998-03-04 | 1999-03-04 | Ink for forming receiving layer and product using the same |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0940265B1 (en) |
| JP (1) | JPH11246810A (en) |
| CN (1) | CN1190468C (en) |
| DE (1) | DE69922721T2 (en) |
| HK (1) | HK1023590A1 (en) |
| SG (1) | SG80018A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6749773B2 (en) * | 2001-04-03 | 2004-06-15 | Hewlett-Packard Development Company, L.P. | Phosphorescent ink for use in an ink-jet printer |
| WO2003052025A1 (en) | 2001-12-18 | 2003-06-26 | Nanosolutions Gmbh | Security printing liquid and method using nanoparticles |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4089995A (en) * | 1974-01-25 | 1978-05-16 | Post Office | Phosphorescent materials |
| DE3413371C1 (en) * | 1984-04-09 | 1986-01-02 | Esselte Pendaflex Corp., Garden City, N.Y. | label |
| US4791449A (en) * | 1986-05-30 | 1988-12-13 | Xerox Corporation | System for prevention of unauthorized copying |
| JP2675864B2 (en) * | 1988-07-05 | 1997-11-12 | キヤノン株式会社 | Recording material and inkjet recording method using the same |
| JPH02155795A (en) * | 1988-12-09 | 1990-06-14 | Nitto Denko Corp | Image-receiving body for thermal transfer |
| CA2069464A1 (en) * | 1991-05-28 | 1992-11-29 | Daniel K. Kohn | Phosphorescent identification device |
| US5270100A (en) * | 1992-02-05 | 1993-12-14 | Giglio Anthony J | Phosphorescent coloring method |
| KR100209819B1 (en) * | 1993-10-18 | 1999-07-15 | 사또 아끼오 | Optical recording medium, a method for printing on the surface of the same, and ultraviolet curable ink |
| US5965242A (en) * | 1997-02-19 | 1999-10-12 | Eastman Kodak Company | Glow-in-the-dark medium and method of making |
-
1998
- 1998-03-04 JP JP6952398A patent/JPH11246810A/en active Pending
-
1999
- 1999-02-23 EP EP19990301280 patent/EP0940265B1/en not_active Expired - Lifetime
- 1999-02-23 DE DE1999622721 patent/DE69922721T2/en not_active Expired - Fee Related
- 1999-03-02 SG SG9901048A patent/SG80018A1/en unknown
- 1999-03-04 CN CNB991034333A patent/CN1190468C/en not_active Expired - Fee Related
-
2000
- 2000-05-10 HK HK00102815A patent/HK1023590A1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| SG80018A1 (en) | 2001-04-17 |
| EP0940265B1 (en) | 2004-12-22 |
| EP0940265A3 (en) | 2000-07-12 |
| EP0940265A2 (en) | 1999-09-08 |
| JPH11246810A (en) | 1999-09-14 |
| HK1023590A1 (en) | 2000-09-15 |
| CN1190468C (en) | 2005-02-23 |
| DE69922721T2 (en) | 2005-12-01 |
| DE69922721D1 (en) | 2005-01-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20050223 |