CN1234296A - Method for recovering cation-exchange resin - Google Patents
Method for recovering cation-exchange resin Download PDFInfo
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- CN1234296A CN1234296A CN99114719A CN99114719A CN1234296A CN 1234296 A CN1234296 A CN 1234296A CN 99114719 A CN99114719 A CN 99114719A CN 99114719 A CN99114719 A CN 99114719A CN 1234296 A CN1234296 A CN 1234296A
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- resin
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- cation
- exchange resin
- flushing
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- Treatment Of Water By Ion Exchange (AREA)
Abstract
The restoration method of cation exchange resin is characterized by that said method includes the following steps: flushing the resin to be restored, stirring and vibrating, soaking with antitoxic, secondary flushing, injecting regeneration agent into ion exchange unit, soaking, front-flushing and back-flushing. The flushing before restoration can enlarge back-flushing space to increase back-flushing intensity so as to can wash suspension pollutant off resin, and the stirring and vibration by using compressed air can make resin produce mutual friction in its interior so as to wash organic matter off the resin, and the use of antitoxic can remove high-valence inorganic ion and oxide and general organic matter, so that these can make the resin restore to possess normal exchange capacity.
Description
The invention belongs to the process field of water, particularly a kind of method for resuscitation that is used for the cationic ion-exchange resin of water treatment.
Cationic ion-exchange resin is usually used in water correction or desalination is handled.In use, resin is subjected to high price inorganic ions and oxide in the water body, or the organic matter that is had in the exchanged water, or suspension in the water, or the pollution of coal tar wet goods material makes cationic ion-exchange resin be poisoned or destroy, cause the intensity of resin to reduce, lose exchange capacity.Be subjected to high price inorganic ions and oxide in the water body for resin, or the organic matter that is had in the exchanged water, or the pollution of suspension in the water, usually adopt the processing of recovering of hydrochloric acid or compressed air or supersonic wave cleaning machine, but to being subjected to the cationic ion-exchange resin that above-mentioned pollution and coal tar wet goods material pollute simultaneously, can not be with the processing of recovering of these method.
The purpose of this invention is to provide a kind of method for recovering cation-exchange resin, it can make the resin cation that is polluted by suspension, organic matter (comprising coal tar) in high price inorganic ions, the water simultaneously recover normal function of exchange, and uses characteristic of simple in addition.
The objective of the invention is to realize by the following method:
With the resin preceding flushing of recovering, resin volume during flushing: backwash spatial volume=1: 1~1.5 make general pollutant separate discharge with resin particle.With compressed air resin is stirred, shakes, make the mutual friction of interlaminar resin phase, its intergranular separated from contaminants is discharged.
Soak with antidote, make the greasy dirt demulsification, be not attached to resin surface, and remove the high price inorganic ions.Soaking temperature better is 30~90 ℃, preferably 45~75 ℃, is more preferably 50~70 ℃; Soak time better is 20~60 hours, preferably 30~50 hours, is more preferably 35~48 hours.In the immersion process, every 30 minutes, stir, shake once, the time of stirring, shaking is 5~10 minutes.
Antidote can be ion exchange resin antidote for hard-water softener, resin cation antidote, hydrochloric acid.Its concentration is preferably 5~30%, is preferably 8~25%, and more preferably 15%.
It is limpid and for neutral that the flushing of resin after the detoxifcation, its flushing should reach water outlet, soaks positive and negative again washing with injecting regenerative agent.The injection rate of regenerative agent is 2 times of positive usual amounts, soaks 20 hours.
Regenerative agent can be salt or hydrochloric acid or sulfuric acid according to the cation type difference.
The present invention increases backwash intensity because the preceding flushing of recovering increases the backwash space, can wash the suspended contaminant in the resin off; Stir, shake with compressed air, make the mutual friction of interlaminar resin phase, can wash the organic matter in the resin off; Can remove high price inorganic ions and oxide and organic matter in the resin with antidote.Therefore, the present invention can make and be subjected to the resin recovery that suspension, coal tar wet goods material pollute in high price inorganic ions, organic matter, the water simultaneously, and the resin cation after the recovery can recover normal exchange capacity.
The present invention is described further below by embodiment.
Embodiment 1:
With the resin preceding flushing of recovering, resin volume during flushing: backwash spatial volume=1: 1.5 makes general pollutant separate discharge with resin particle.With compressed air resin is stirred, shakes, make the mutual friction of interlaminar resin phase, its intergranular separated from contaminants is discharged.With concentration is that 5% resin cation antidote soaks, and makes the pollutant generation displacement reaction in antidote and the resin, to remove high price inorganic ions and oxide and general organic matter.Soaking temperature is 90 ℃, makes the greasy dirt demulsification, is not attached to resin surface; Soak time is 20 hours, every 30 minutes, stirs, shakes once, and the time of stirring, shaking is 5 minutes.
It is limpid that the flushing of resin after the detoxifcation, its flushing should reach the water outlet of ion-exchanger, and water outlet be a neutrality.Resin after the detoxifcation soaks positive and negative again washing with injecting regenerative agent before use.The injection rate of regenerative agent is 2 times of positive usual amounts, soaks 20 hours.
Regenerative agent can be salt or hydrochloric acid or sulfuric acid according to the cation type difference.
Recover to polluting resin by above-mentioned condition, the operating capacity of cationic ion-exchange resin is by 263 gram equivalents/meter before recovering
3, rise to 974~1082 gram equivalents/meter
3, the exchange capacity that improves resin is more than 80%.
Embodiment 2:
With the resin preceding flushing of recovering, resin volume during flushing: backwash spatial volume=1: 1.5 makes general pollutant separate discharge with resin particle.With compressed air resin is stirred, shakes, make the mutual friction of interlaminar resin phase, its intergranular separated from contaminants is discharged.With concentration is that 15% ion exchange resin antidote for hard-water softener soaks, and makes the pollutant generation displacement reaction in antidote and the resin, to remove high price inorganic ions and oxide and general organic matter.Soaking temperature is 60 ℃, makes the greasy dirt demulsification, is not attached to resin surface; Soak time is 45 hours, every 30 minutes, stirs, shakes once, and the time of stirring, shaking is 8 minutes.
It is limpid that the flushing of resin after the detoxifcation, its flushing should reach the water outlet of ion-exchanger, and water outlet be a neutrality.Resin after the detoxifcation soaks positive and negative again washing with injecting regenerative agent before use.The injection rate of regenerative agent is 2 times of positive usual amounts, soaks 20 hours.
Regenerative agent can be salt or hydrochloric acid or sulfuric acid according to the cation type difference.
Recover to polluting resin by above-mentioned condition, the operating capacity of cationic ion-exchange resin is by 263 gram equivalents/meter before recovering
3, rise to 974~1082 gram equivalents/meter
3, the exchange capacity that improves resin is more than 80%.
Embodiment 3:
With the resin preceding flushing of recovering, resin volume during flushing: backwash spatial volume=1: 1~1.5 make general pollutant separate discharge with resin particle.With compressed air resin is stirred, shakes, make the mutual friction of interlaminar resin phase, its intergranular separated from contaminants is discharged.With concentration is 30% antidote salt acid soak, makes the pollutant generation displacement reaction in antidote and the resin, to remove high price inorganic ions and oxide and general organic matter.Soaking temperature is 30 ℃, makes the greasy dirt demulsification, is not attached to resin surface; Soak time is 20 hours, every 30 minutes, stirs, shakes once, and the time of stirring, shaking is 10 minutes.
It is limpid that the flushing of resin after the detoxifcation, its flushing should reach the water outlet of ion-exchanger, and water outlet be a neutrality.Resin after the detoxifcation soaks positive and negative again washing with injecting regenerative agent before use.The injection rate of regenerative agent is 2 times of positive usual amounts, soaks 20 hours.
Regenerative agent can be salt or hydrochloric acid or sulfuric acid according to the cation type difference.
Recover to polluting resin by above-mentioned condition, the operating capacity of cationic ion-exchange resin is by 263 gram equivalents/meter before recovering
3, rise to 974~1082 gram equivalents/meter
3, the exchange capacity that improves resin is more than 80%.
Claims (10)
1. method for recovering cation-exchange resin is characterized in that the resin preceding flushing of recovering, and through stirring, after the vibrations, soaking with antidote, through the detoxifcation afterflush, regenerative agent is injected ion-exchanger, soaks, and just washes backwash again.
2. method for recovering cation-exchange resin according to claim 1, when it is characterized in that the recovery flushing, resin volume: backwash spatial volume=1: 1~1.5.
3. method for recovering cation-exchange resin according to claim 1 is characterized in that with compressed air resin being stirred, shaking.
4. method for recovering cation-exchange resin according to claim 1 is characterized in that antidote can be ion exchange resin antidote for hard-water softener, resin cation antidote, hydrochloric acid.
5. method for recovering cation-exchange resin according to claim 1, the concentration that it is characterized in that antidote is 5~30%.
6. method for recovering cation-exchange resin according to claim 1, the soaking temperature that it is characterized in that antidote is 30~90 ℃, the time is 20~60 hours, stirs, shakes once in per 30 minutes.
7. method for recovering cation-exchange resin according to claim 1 is characterized in that the time of stirring, shaking is 5~10 minutes.
8. it is limpid and for neutral that method for recovering cation-exchange resin according to claim 1, the afterflush that it is characterized in that detoxifying should reach water outlet.
9. method for recovering cation-exchange resin according to claim 1 is characterized in that the consumption of regenerative agent is normal 2 times of using, and soak time is 20 hours.
10. method for recovering cation-exchange resin according to claim 1 is characterized in that regenerative agent can be salt or hydrochloric acid or sulfuric acid.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB991147197A CN1134304C (en) | 1999-03-19 | 1999-03-19 | Method for recovering cation-exchange resin |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB991147197A CN1134304C (en) | 1999-03-19 | 1999-03-19 | Method for recovering cation-exchange resin |
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CN1234296A true CN1234296A (en) | 1999-11-10 |
CN1134304C CN1134304C (en) | 2004-01-14 |
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CNB991147197A Expired - Fee Related CN1134304C (en) | 1999-03-19 | 1999-03-19 | Method for recovering cation-exchange resin |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100408187C (en) * | 2006-12-31 | 2008-08-06 | 徐东 | Composite synergic recovering agent for ion exchange resin |
CN102896003A (en) * | 2012-09-29 | 2013-01-30 | 陕西陕煤黄陵矿业有限公司 | Regeneration water replenishing method of mixed bed |
CN105080624A (en) * | 2015-09-10 | 2015-11-25 | 苏州联科纳米净化科技有限公司 | Ion exchange resin regeneration method |
CN105435865A (en) * | 2015-12-23 | 2016-03-30 | 芜湖美的厨卫电器制造有限公司 | Weak-acid cation-exchange resin regeneration method and application of organic weak acid in regeneration of weak-acid cation-exchange resin |
CN105536888A (en) * | 2014-10-22 | 2016-05-04 | 友特贸易有限公司 | Apparatus and method for reducing regenerant and wastewater using compressed air |
CN106582897A (en) * | 2017-02-13 | 2017-04-26 | 克拉玛依市华隆油田技术服务有限责任公司 | Cleaning device and method for ion exchange resin for oil field softening water treatment |
CN107199055A (en) * | 2017-05-19 | 2017-09-26 | 江苏常熟发电有限公司 | Hydrogen leads resin and dynamically cleans regenerating unit and its operating method |
CN111905842A (en) * | 2020-08-21 | 2020-11-10 | 四川省宜宾惠美线业有限责任公司 | Method for treating poisoned anion resin |
CN112717904A (en) * | 2020-12-28 | 2021-04-30 | 宜宾丝丽雅股份有限公司 | Recovery process method of resin activator by bipolar membrane pretreatment process |
CN116371479A (en) * | 2023-02-24 | 2023-07-04 | 南京霖厚环保科技有限公司 | Multifunctional ion exchange resin regeneration device and regeneration control method thereof |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5734429B2 (en) * | 2010-08-26 | 2015-06-17 | 東レ・ファインケミカル株式会社 | Method for producing dicyclohexyl disulfide |
-
1999
- 1999-03-19 CN CNB991147197A patent/CN1134304C/en not_active Expired - Fee Related
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100408187C (en) * | 2006-12-31 | 2008-08-06 | 徐东 | Composite synergic recovering agent for ion exchange resin |
CN102896003A (en) * | 2012-09-29 | 2013-01-30 | 陕西陕煤黄陵矿业有限公司 | Regeneration water replenishing method of mixed bed |
CN105536888A (en) * | 2014-10-22 | 2016-05-04 | 友特贸易有限公司 | Apparatus and method for reducing regenerant and wastewater using compressed air |
CN105536888B (en) * | 2014-10-22 | 2017-12-08 | 友特贸易有限公司 | Apparatus and method for reducing regenerant and wastewater using compressed air |
CN105080624A (en) * | 2015-09-10 | 2015-11-25 | 苏州联科纳米净化科技有限公司 | Ion exchange resin regeneration method |
CN105080624B (en) * | 2015-09-10 | 2018-04-10 | 舒城联科环境科技有限公司 | A kind of ion exchange resin regeneration method |
CN105435865A (en) * | 2015-12-23 | 2016-03-30 | 芜湖美的厨卫电器制造有限公司 | Weak-acid cation-exchange resin regeneration method and application of organic weak acid in regeneration of weak-acid cation-exchange resin |
CN106582897A (en) * | 2017-02-13 | 2017-04-26 | 克拉玛依市华隆油田技术服务有限责任公司 | Cleaning device and method for ion exchange resin for oil field softening water treatment |
CN107199055A (en) * | 2017-05-19 | 2017-09-26 | 江苏常熟发电有限公司 | Hydrogen leads resin and dynamically cleans regenerating unit and its operating method |
CN111905842A (en) * | 2020-08-21 | 2020-11-10 | 四川省宜宾惠美线业有限责任公司 | Method for treating poisoned anion resin |
CN112717904A (en) * | 2020-12-28 | 2021-04-30 | 宜宾丝丽雅股份有限公司 | Recovery process method of resin activator by bipolar membrane pretreatment process |
CN116371479A (en) * | 2023-02-24 | 2023-07-04 | 南京霖厚环保科技有限公司 | Multifunctional ion exchange resin regeneration device and regeneration control method thereof |
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Publication number | Publication date |
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CN1134304C (en) | 2004-01-14 |
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