CN1233461C - 用于浆态床反应器的铁基费托合成催化剂的工业还原方法 - Google Patents
用于浆态床反应器的铁基费托合成催化剂的工业还原方法 Download PDFInfo
- Publication number
- CN1233461C CN1233461C CN 03151105 CN03151105A CN1233461C CN 1233461 C CN1233461 C CN 1233461C CN 03151105 CN03151105 CN 03151105 CN 03151105 A CN03151105 A CN 03151105A CN 1233461 C CN1233461 C CN 1233461C
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- Prior art keywords
- reduction
- catalyst
- reactor
- tropsch synthesis
- iron
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- 239000003054 catalyst Substances 0.000 title claims abstract description 136
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 53
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 53
- 238000000034 method Methods 0.000 title claims abstract description 43
- 239000002002 slurry Substances 0.000 title claims abstract description 35
- 238000010438 heat treatment Methods 0.000 claims abstract description 11
- 239000007788 liquid Substances 0.000 claims abstract description 11
- 238000011946 reduction process Methods 0.000 claims abstract description 11
- 238000001816 cooling Methods 0.000 claims abstract description 7
- 238000006722 reduction reaction Methods 0.000 claims description 133
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 58
- 239000007789 gas Substances 0.000 claims description 31
- 229910052757 nitrogen Inorganic materials 0.000 claims description 29
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 23
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 230000001105 regulatory effect Effects 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 230000005587 bubbling Effects 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 239000012188 paraffin wax Substances 0.000 claims description 7
- 238000011084 recovery Methods 0.000 claims description 5
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 4
- 230000001143 conditioned effect Effects 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 3
- 238000013461 design Methods 0.000 claims description 2
- 238000005553 drilling Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 description 10
- 239000012071 phase Substances 0.000 description 10
- 229910052742 iron Inorganic materials 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000004062 sedimentation Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 229910001567 cementite Inorganic materials 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000013467 fragmentation Methods 0.000 description 2
- 238000006062 fragmentation reaction Methods 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000007701 flash-distillation Methods 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 239000013462 industrial intermediate Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Landscapes
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Description
Claims (11)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 03151105 CN1233461C (zh) | 2003-09-22 | 2003-09-22 | 用于浆态床反应器的铁基费托合成催化剂的工业还原方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 03151105 CN1233461C (zh) | 2003-09-22 | 2003-09-22 | 用于浆态床反应器的铁基费托合成催化剂的工业还原方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1600419A CN1600419A (zh) | 2005-03-30 |
CN1233461C true CN1233461C (zh) | 2005-12-28 |
Family
ID=34659846
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 03151105 Expired - Lifetime CN1233461C (zh) | 2003-09-22 | 2003-09-22 | 用于浆态床反应器的铁基费托合成催化剂的工业还原方法 |
Country Status (1)
Country | Link |
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CN (1) | CN1233461C (zh) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100404137C (zh) * | 2005-06-21 | 2008-07-23 | 上海兖矿能源科技研发有限公司 | 颗粒状铁基费托合成催化剂的工业还原方法 |
US8906314B2 (en) | 2008-09-30 | 2014-12-09 | Japan Oil, Gas And Metals National Corporation | Bubble column reactor and method of controlling bubble column reactor |
CN101703937B (zh) * | 2009-09-29 | 2012-05-23 | 武汉凯迪工程技术研究总院有限公司 | 一种浆态床钴基费-托合成催化剂的再生方法 |
CN103170284B (zh) * | 2013-04-03 | 2016-02-17 | 神华集团有限责任公司 | 高温、高压浆态床反应器费托合成系统及其工艺 |
CN103769241A (zh) * | 2014-02-18 | 2014-05-07 | 神华集团有限责任公司 | 一种固定床费托催化剂还原活化系统及其工艺 |
CN106311361B (zh) * | 2015-06-24 | 2019-09-24 | 神华集团有限责任公司 | 催化剂活化与在线更新系统及方法 |
CN106552571A (zh) * | 2015-09-30 | 2017-04-05 | 江苏创新石化有限公司 | 一种强适应性电脱盐剂的生产系统 |
CN107638848A (zh) * | 2017-10-20 | 2018-01-30 | 中科合成油工程股份有限公司 | 一种浆态床反应器催化剂在线加料方法及其专用设备系统 |
CN114345340A (zh) * | 2022-01-08 | 2022-04-15 | 安庆市长虹化工有限公司 | 一种载体铜纳米管脱氢催化剂的制备工艺及工作系统 |
-
2003
- 2003-09-22 CN CN 03151105 patent/CN1233461C/zh not_active Expired - Lifetime
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Publication number | Publication date |
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CN1600419A (zh) | 2005-03-30 |
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Application publication date: 20050330 Assignee: SHAANXI FUTURE ENERGY CHEMICAL CO.,LTD. Assignor: Shanghai Yankuang Energy Sources Technology Research & Development Co.,Ltd. Contract record no.: 2012310000147 Denomination of invention: Industrial reduction method for catalyst of Fischer-Tropsch synthesis in use for reactor in slurry state bed Granted publication date: 20051228 License type: Common License Record date: 20120813 |
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Application publication date: 20050330 Assignee: Sichuan Yilong masukuni Energy Co.,Ltd. Assignor: Shanghai Yankuang Energy Sources Technology Research & Development Co.,Ltd. Contract record no.: 2014310000012 Denomination of invention: Industrial reduction method for catalyst of Fischer-Tropsch synthesis in use for reactor in slurry state bed Granted publication date: 20051228 License type: Common License Record date: 20140121 |
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CB03 | Change of inventor or designer information |
Inventor after: Sun Qiwen Inventor after: Geng Jiahuai Inventor after: Wang Xin Inventor after: Zhu Jicheng Inventor after: Wu Qian Inventor before: Geng Jiahuai Inventor before: Wang Xin Inventor before: Zhu Jicheng Inventor before: Wu Qian |
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COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: GENG JIAHUAI WANG XIN ZHU JICHENG WU QIAN TO: SUN QIWEN GENG JIAHUAI WANG XIN ZHU JICHENG WU QIAN |
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Granted publication date: 20051228 |
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