CN1230235A - Process for generating structure effect in textile fabrics - Google Patents

Process for generating structure effect in textile fabrics Download PDF

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Publication number
CN1230235A
CN1230235A CN97197749A CN97197749A CN1230235A CN 1230235 A CN1230235 A CN 1230235A CN 97197749 A CN97197749 A CN 97197749A CN 97197749 A CN97197749 A CN 97197749A CN 1230235 A CN1230235 A CN 1230235A
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China
Prior art keywords
fabric
levigate
silicon compound
weight
cellulase
Prior art date
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Pending
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CN97197749A
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Chinese (zh)
Inventor
特里萨·科普特·维达尔
拉斐尔·皮苏比拉纳
安德鲁·科洛梅拉
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Henkel AG and Co KGaA
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Henkel AG and Co KGaA
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Filing date
Publication date
Priority claimed from DE1996136531 external-priority patent/DE19636531C1/en
Priority claimed from DE1996143036 external-priority patent/DE19643036A1/en
Priority claimed from DE1996145188 external-priority patent/DE19645188A1/en
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of CN1230235A publication Critical patent/CN1230235A/en
Pending legal-status Critical Current

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P7/00—Dyeing or printing processes combined with mechanical treatment
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/15—Locally discharging the dyes
    • D06P5/158—Locally discharging the dyes with other compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67383—Inorganic compounds containing silicon

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Detergent Compositions (AREA)
  • Treatment Of Fiber Materials (AREA)

Abstract

A process is disclosed for generating a structure effect on textile fabrics. An aqueous bath which contains dyed or undyed fibres, yarns, fabrics or textiles is treated with (a) ground silicium compounds and optionally (b) cellulases. The process is particularly suitable for producing stonewashed jeans.

Description

Constitute the method that produces fabric quality effect on the fabric at the weaving plain cloth
Invention field
The present invention relates to a kind of at the levigate silicon compound of use, especially levigate silicate, under the situation of cellulase in case of necessity, constitute the method that produces fabric quality effect on the fabric and use levigate silicon compound at the weaving plain cloth, on dyeing or undyed COTTON FABRIC, to produce the effect of granite-wash as additive.
Prior art
In the world, the annual production of twill coarse cloth reaches millions of.Major part in these cottons all will be carried out artificial aging technique processing, and wherein people handle with float stone twill coarse cloth in washing lotion, meanwhile, although can wear and tear on the one hand, but, also improve its soft feeling simultaneously, and therefore improve its snugness of fit.In addition, users often wish to wash (granite-wash effect) with the static state of the color that combines of wearing and tearing.Certainly, carry out the burden that this process has increased washing machine with stone, they are had higher requirement to raw material.In addition float stone is natural and expensive raw material source, and stone has worn away when once using consumingly, so that no longer have recycle value.Part float stone finally also can enter in the slit of twill coarse cloth, need difficultly they be removed with hand.Also there is such situation, each washing process, only can so handle limited amount twill coarse cloth, and in this program, in them quite a few is subjected to so serious damage, so that can not consider to sell, this has just occurred replacing the process of only being undertaken by mechanical system to small part with chemical treatment again.
Known by prior art, cellulase has the characteristic of the blue indigoid dye of decolouring denim fiber.To this, N.K.Lange is at C.R.2.TRICEL academic exchange proceedings, Espoo, and Finland has set forth overview for 1993, the 363 pages.Further developing in the process of this understanding, European patent specification EP-B10452393 (Cayla) has introduced a kind of inhomogeneous pre-washing method of COTTON FABRIC, and this method is under the situation of using some cellulase, carries out under the pH value below the pH=6.European patent application EP-A20307564 (Ecolab) discloses a kind of by handling with a kind of aqueous fluid, and the generation cellulose fabric has the method for coloured differently scope, except cellulase, also can contain the non-ionic surface active agent that every mole of aliphatic alcohol has the aliphatic alcohol ethoxylate type that reaches 20 ethoxylation unit at the most in the water liquid.
Up to the present, the main points of system of selection are at first to use the float stone pretreating fabrics, then add cellulase in water liquid.But consider above-mentioned shortcoming, on market, require to use a kind of raw material replace expensive only can nonrecoverable float stone, this raw material produces the effect of identical fabric tissue to COTTON FABRIC, ecological and to operate be nontoxic, have economic advantage, and thereby particularly it is recycling.In this respect, for example, " chemical abstracts " 121,282.299 introduced with Ceramic Balls or hard rubber ball and replaced float stone.US5213581 discloses a kind of preparation method of twill coarse cloth of granite-wash, comprise with cellulase with inorganic salts for example silicate use.WO95/09225 (lvax) has introduced a kind of similar methods, wherein reaches the granite-wash effect by means of cellulase, and adds the not levigate silicate of bentonite type in water liquid, precipitates to prevent pigment again.But bentonite does not play a part to handle fiber, and promptly they do not have erosion property.At last, WO95/35363 (Novo) has introduced with expanded perlite and has replaced float stone.Perlite is a kind of volcanic rock, and they produce a kind of extremely light rock foam 1200 ℃ of following dehydrations when expanding.This foam just becomes little rock ballast through fragmentation slightly, then, as float stone, need not further to grind.But owing to cause using this material can produce relevant same problem with the fairly similar of float stone, especially, usability and form dust again.
Therefore, the purpose of this invention is to provide a kind of constitute at the weaving plain cloth produce fabric quality effect on the fabric, preferably on the denim fabric of dyeing, produce the granite-wash effect, and do not have the method for above-mentioned shortcoming.
Description of the invention
Theme of the present invention relates to a kind of method that constitutes generation fabric quality effect on the thing at the weaving plain cloth, wherein use (a) levigate silicon compound, preferred levigate silicate or levigate glass and a kind of water liquid that contains dyeing or un-dyed fibers, yarn, raw material or fabric of (b) cellulose treatment in case of necessity.
Be surprisingly found out that levigate silicon compound, the substitute that preferred levigate silicate or levigate glass are suitable for use as zeolite in a preferred manner.Constitute fabric at the textiles plain cloth, on the preferred cotton, not only produced same at least good fabric tissue or granite-wash effect, and silicon compound is nontoxic on ecology, in batching no problem, little to the damage of washing machine, reduced treated additive, the defect rate of twill coarse cloth particularly, and can repeatedly use again after from water liquid, separating.Another advantage is that this process also carries out serially.The weaving plain cloth constitutes fabric
Term " the weaving plain cloth constitutes fabric " is meant all spendable in the methods of the invention additives.To this, corresponding therewith, not only spinning fiber and yarn can be considered, and the raw material for preparing thus and woven product and the final products of making again by these products can be considered, also comprise textiles.Additive both can be made up of plant, also can be made up of synthetic fiber.Though COTTON FABRIC and specific here denim are preferred,, for example also consider the mixture of molten born of the same parents (Lyocell-) fiber and cellulose fibre and fiber and polyester fiber or polyamide fiber.Silicon compound
As levigate silicon compound, preferably use silica, wherein, under the simplest situation, use sand.But, preferably use levigate silicate or levigate glass, their source is not crucial.Corresponding therewith, common recirculation glass is equally applicable to for example preparation of expensive glass foam of abrasive basically.Can consider to use for example diatomite of natural source material.The initiation material of silicate does not preferably contain the crystallization water, so that it does not at high temperature expand; Therefore, can not consider to use the perlite that is transformed into float stone class material under 1200 ℃ as initiation material, this is a problem same when they can exist with the use float stone again because of use.Can obtain the result of good especially application technology with levigate silicate or levigate glass, the granular size that they had is 0.01-200 μ m, and has a specific composition, wherein the average diameter of the 40-70% (weight) of whole particles is less than 50 μ m, 40-70% (weight) is 50-100 μ m, 20-40% (weight) is greater than 100 μ m, and condition is that summation is 100% (weight).Usually the abrasive consumption that constitutes on the fabric at the weaving plain cloth is 0.5-2.5, preferred 1.0-2.0kg/kg.The preparation of levigate silicon compound can be by the method for prior art, in suitable pulverizer, disintegrating machine for example, carry out in grinding mill, grater or the impact grinder, for example referring to Winnacker-Kuechler, " chemical technology ", the 1st volume, the 4th edition, describe in the 87-93 page or leaf (1984).Cellulase
Cellulase (1,4-callose-4-glucan hydrolase; EC3.2.1.4) show it is to participate in the enzyme complex that native cellulose decomposes.Wherein, with regard to meaning of the present invention, when optional component (b) when preferably using acidic cellulase, their are preferably a kind of by the culture preparation of inulinase element or trichodermin type and the enzyme that has active optimum value under the acid ph value of 4-6.Particularly preferably be that the trade mark of being promoted by NovoNordish is Celluzyme And the acidic cellulase of the submergence fermenting process of preparing by the Humicolainsolens bacterium.E.Hoshino is in " chemistry chemistry " magazine, 114,230; 236 (1994), the same 115,837 (1994) and " enzyme bioengineering " magazine disclose cellulase and the interactional overview of cellulose in 77,496 (1994).Usually, the consumption of cellulase is counted 0.1-15% (weight) by weaving plain cloth formation fabric.Zeolite
Term " zeolite " is meant the hydrous alkali metal of formula (I)-or alkaline earth metal aluminosilicate, M in case of necessity 2zO*Al 2O 3* xSiO 2* yH 2O wherein M represents that alkali metal or the alkaline-earth metal of valence z, x represent the number of 1.8-12 and the number [Chem, i.u.Zt., 20,117 (1986)] of expression 0-8.The representative instance of zeolite is naturally occurring mineral clinoptilolite, erionite or chabasie.But, He Cheng zeolite preferably, for example
Zeolite NaANa 12[(AlO 2) 12(SiO 2) 12] *27H 2O
Zeolite NaXNa 86[(AlO 2) 86(SiO 2) 106] *264H 2O
Zeolite Y Na 56[(AlO 2) 56(SiO 2) 136] *325H 2O
Zeolite L K 9[(AlO 2) 9(SiO 2) 27] *22H 2O
Modenite Na 8.7[(AlO 2) 8.7(SiO 2) 39.3] *24H 2O.
With regard to the meaning of the inventive method, preferably use the mixture of zeolite NaA and zeolite NaA and NaX, wherein the content of the zeolite NaX in this mixture is suitably less than 30%, preferably less than 20%.The granular size that the zeolite that is suitable for has is no more than 30mm, and the granular size of at least 80% particle is less than 10mm.The mean particle size that they have (volume distributed median, method of testing: the Ku Erte particle collector) be 1-10mm.Preferably, the mean particle size that has of zeolite is 2-4mm.The calcium-binding capacity of measuring according to German patent application DE-AS2412837 explanation is 100-200mgCaO/g.The consumption of zeolite constitutes fabric by the weaving plain cloth and is generally 1-15% (weight), and preferred 1-10% (weight) considers from their preparation, also can contain excessive alkali.Non-ionic surface active agent
With regard to the meaning of the inventive method, prove in order to carry out the stable and dirt that disappears of enzyme, with cellulose with suitable preferred anhydrous non-ionic surface active agent for example the fatty alcohol polyglycol ether of formula (II) to use be favourable.
R 1O (CH 2CH 2O) nIn H (II) formula: R 1Expression has the straight or branched alkyl of 12-22 carbon atom, and n represents 2-50, the number of preferred 5-30.Typical example is to be added with average 2-50 thereon, and the technical grade fatty alcohol with 12-18 carbon atom of preferred 5-10 moles of ethylene oxide is the addition compound product of dodecanol, Permethyl 99A alcohol, coconut fatty alcohol, isooctadecane alcohol, hexadecanol and/or tallow fatty alcohol for example.The conventional amount used of non-ionic surface active agent constitutes fabric by the weaving plain cloth and counts 1-15% (weight), preferred 1-10% (weight).Buffer salt
Recommendation is used buffer salt with surfactant, the example of buffer salt can comprise the sulfate of alkali metal and/or alkaline-earth metal, carbonate, phosphate and citrate.Typical example is sodium sulphate, potassium sulfate, calcium carbonate, sodium phosphate and natrium citricum.Obviously, although can not use salt,, also can consider to use citric acid.In addition, as dust-laying agent, also can use polyethylene glycol ether or the glycol polypropylene ether of mean molecule quantity as 500-5000.The conventional amount used of buffer salt constitutes the fabric product by the weaving plain cloth and counts 1-10% (weight), preferred 1-3% (weight).Composition
In the preferred embodiment of the present invention, can use composition to implement this method with following composition:, (a) 95-99%, (weight), preferred 75-95%, the silicon compound that (weight) is levigate, (b) 0.1-4%, (weight), preferred 1-2%, (weight) cellulase, (c) 0.1-10%, (weight), preferred 1-5%, (weight) zeolite, (d) 0.1-10%, (weight), preferred 1-5%, (weight) non-ionic surface active agent and, (e) 0.5-3%, (weight), preferred 1-1.5%, (weight) buffer salt
Wherein condition is that consumption adds to 100% (weight).Under the common use of polymer, composition can be mixed with aqueous gel shape preparation in case of necessity, use with convenient.The enforcement of method
For example COTTON FABRIC and water liquid weight ratio are 1: 5-1: 20.The water liquid that preferred water liquid is made up of about 3-5kg twill coarse cloth and 30-50kg water, at first in water liquid, add the levigate silicon compound of 3-5kg, preferred levigate glass, add 50-100g in case of necessity, preferred 5-10g cellulase and add zeolite in case of necessity, anhydrous non-ionic surface active agent and/or buffer salt.Be recommended under the pH value of 4.5-8.5,, implement this method under preferred 55-60 ℃ the temperature at 50-65 ℃.If necessary, can use with the softening purificant of for example ester quat (Esterquat) type washing of routine.As mentioned above, also can under the situation of using correspondent composition, implement method of the present invention.
If necessary, implement this method serially, example is as shown in FIG. 1: a kind of aqueous suspension of levigate silicon compound joined in the depositing reservoir (1) of being furnished with agitator, measure (eindosieren) and be added in the washing machine (3) by entering valve (2).After wash cycle and dehydration in case of necessity, top washing soda liquid is discharged by drain valve (4) with abrasive, and turns back in the depositing reservoir (1) by means of pump (5).Fresh water is pumped in the washing machine by entering valve (6), after discharging washing machine by valve (4) and pump (5), is used for diluting the aqueous suspension in the depositing reservoir (1).In depositing reservoir, isolate the abrasive of top aqueous phase; Dirty washings are discharged from depositing reservoir by drain valve (7).Then by entering valve (8), infeed fresh water in depositing reservoir, described water plays the levigate silicon compound aqueous suspension of preparation again.Job applications
Levigate silicon compound not only makes dyeing or undyed weaving plain cloth constitute fabric, preferred cotton, especially blue denim has typical fabric quality or granite-wash effect, and has improved pleasant soft feeling, thereby has also improved sense comfortable and easy to wear.Therefore, another theme of the present invention relates to levigate silicon compound, and the purposes of especially levigate silicate or levigate glass is used for producing the granite-wash effect on dyeing or undyed COTTON FABRIC.
EXAMPLE Example 1
Several the blue twill coarse cloth that newly dispatch from the factory are put into the washing machine of Siemens Siewamat 3573 types, and the capacity of washing machine is 5.5kg washings and about 60L water.With the potent washing agent of the starch-containing enzyme of routine once at 40 ℃ of following prewashing twill coarse cloth.Then, in washing lotion, add the levigate glass (Pulcra/ES of Miltopan  GB type, particle size distribution: 75%＜50 μ m, 20% is 50-100 μ m, 5%＞100 μ m), fabric and weight of glass are than=1: 1 and 100g preparation 35% (weight) cellulase 15% (weight) tallow fatty alcohol+5EO and 50% (weight) natrium citricum/citric acid (1: 1) be made up of following material.
Washing lotion was handled 60 minutes down at 50 ℃, then cleaned 2 times.Twill coarse cloth has pleasant soft feeling and uniform granite-wash effect.Embodiment 2
Repeat embodiment 1 with product, particle size distribution is 75%＜50 μ m, and 20% be 50-100 μ m, and 5%＞100 μ m wherein uses by the glass of handling recovery for the first time mechanical treatment fabric once more.After washing finished, twill coarse cloth had soft feeling and the granite-wash effect as the sample of embodiment 1.Embodiment 3
Repeat embodiment 2, handle fabric with levigate glass machinery, this glass reclaims for 5 times altogether.In addition, except levigate glass, use product: 15% (weight) cellulase, 10% (weight) tallow fatty alcohol+5EO and 15% (weight) zeolite A60% (weight) natrium citricum/citric acid (1: 1) with following composition.
After this process finished, this twill coarse cloth had soft feeling and the granite-wash effect as the sample of embodiment 1.Embodiment 4
Be similar to embodiment 1, several the blue twill coarse cloth that newly dispatch from the factory are put into the washing machine of Siemens Siewamat3573 type, the capacity of washing machine is 5.5kg washings and about 60L water.With the potent washing agent of the starch-containing enzyme of routine once at 40 ℃ of following prewashing twill coarse cloth.Then, in washing lotion, add the compound that 5kg has following composition: 96% (weight) Miltopan GB1% (weight) cellulase, 1% (weight) Permethyl 99A alcohol+6EO and 1% (weight) zeolite A and 1% (weight) natrium citricum/citric acid (1: 1)
The weight ratio of fabric and compound=1: 1 is washed fabric 35 minutes down at 60 ℃, then cleans 2 times.Twill coarse cloth has pleasant soft feeling and uniform granite-wash effect.

Claims (10)

1. constitute the method that produces fabric quality effect on the fabric at the weaving plain cloth, wherein use (a) levigate silicon compound and in case of necessity (b) cellulose treatment contain the water liquid of dyeing or un-dyed fibers, yarn, raw material or textiles.
2. according to the method for claim 1, it is characterized in that, use the weaving plain cloth of forming by cotton and/or cellulose to constitute fabric.
3. according to the method for claim 1 and 2, it is characterized in that, use levigate silicate, sand, glass and/or diatomite as component (a).
4. according to the method for claim 1-3, it is characterized in that, use the silicon compound of diameter as 0.01-200 μ m.
5. according to the method for claim 1-4, it is characterized in that the consumption of levigate silicon compound is the 1.0-2.5kg/kg COTTON FABRIC.
6. according to the method for claim 1-5, it is characterized in that, use under the pH of 4.5-5.5 value, to have the acidic cellulase of active optimum value as component (b).
7. according to the method for claim 1-6, it is characterized in that the consumption of cellulase constitutes fabric by the weaving plain cloth and counts 0.1-15% (weight).
8. according to the method for claim 1-7, it is characterized in that, use the zeolite of formula (I) in addition,
M 2zO *Al 2O 3 * xSiO 2 * yH 2O wherein M represents alkali metal or the alkaline-earth metal of valence z, and x represents the number of 1.8-12 and the number that y represents 0-8.
9. according to the method for claim 1-8, it is characterized in that, use the fatty alcohol polyglycol ether of formula (II) in addition
R 1O (CH 2CH 2O) nH (II) is wherein: R 1Expression has the straight or branched alkyl of 12-22 carbon atom, and n represents the number of 2-50.
10. the purposes of levigate silicon compound is as the additive that produces the granite-wash effect on dyeing or undyed COTTON FABRIC.
CN97197749A 1996-09-09 1997-09-01 Process for generating structure effect in textile fabrics Pending CN1230235A (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
DE19636531.7 1996-09-09
DE1996136531 DE19636531C1 (en) 1996-09-09 1996-09-09 Stone-wash effect production on cotton fabric using ground glass instead of pumice
DE19643036.4 1996-10-18
DE1996143036 DE19643036A1 (en) 1996-10-18 1996-10-18 Structure, especially stonewashed effect production on textile without using pumice
DE1996145188 DE19645188A1 (en) 1996-11-02 1996-11-02 Structure, especially stonewashed effect production on textile without using pumice
DE19645188.4 1996-11-02

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Publication Number Publication Date
CN1230235A true CN1230235A (en) 1999-09-29

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CN97197749A Pending CN1230235A (en) 1996-09-09 1997-09-01 Process for generating structure effect in textile fabrics

Country Status (6)

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EP (1) EP0927276B1 (en)
CN (1) CN1230235A (en)
BR (1) BR9711719A (en)
DE (1) DE59706063D1 (en)
TR (1) TR199900498T2 (en)
WO (1) WO1998010136A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112368442A (en) * 2018-06-12 2021-02-12 塞罗斯有限公司 Method for conditioning textiles and conditioned textiles produced therefrom

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19738625C1 (en) * 1997-09-04 1999-02-04 Henkel Kgaa Texturising and softening knitwear, especially cotton knitwear to give used look
US6565613B1 (en) * 1999-04-29 2003-05-20 Genencor International, Inc. Cellulase detergent matrix
WO2022106072A1 (en) 2020-11-18 2022-05-27 Aplicacion Y Suministros Textiles, S.A.U. Textile stone washing process

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2641555B1 (en) * 1989-01-09 1992-03-27 Cayla PROCESS FOR HETEROGENEOUS WASHING OF DYED COTTON-BASED ARTICLES USING CELLULASES IN AN AQUEOUS MEDIUM
ATE114748T1 (en) * 1992-06-12 1994-12-15 Dennert Poraver Gmbh METHOD OF RAFFLING TEXTILE FABRIC.
US5565006A (en) * 1993-01-20 1996-10-15 Novo Nordisk A/S Method for the treatment of dyed fabric
DE19502514A1 (en) * 1994-02-03 1995-08-10 Sandoz Ag New finishing agent for textile fibres
IL113714A0 (en) * 1994-06-22 1995-08-31 Ivax Ind Inc Method of treating dyed cellulosic fabric

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112368442A (en) * 2018-06-12 2021-02-12 塞罗斯有限公司 Method for conditioning textiles and conditioned textiles produced therefrom
CN112368442B (en) * 2018-06-12 2023-06-06 塞罗斯有限公司 Method for conditioning textile and conditioned textile produced thereby

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WO1998010136A1 (en) 1998-03-12
DE59706063D1 (en) 2002-02-21
BR9711719A (en) 1999-08-24
EP0927276B1 (en) 2001-11-21
EP0927276A1 (en) 1999-07-07

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