CN1229181C - Application of trichloroisocyanuric acid as novel beneficiation inhibitor - Google Patents
Application of trichloroisocyanuric acid as novel beneficiation inhibitor Download PDFInfo
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- CN1229181C CN1229181C CN 200310110961 CN200310110961A CN1229181C CN 1229181 C CN1229181 C CN 1229181C CN 200310110961 CN200310110961 CN 200310110961 CN 200310110961 A CN200310110961 A CN 200310110961A CN 1229181 C CN1229181 C CN 1229181C
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- closene
- sym
- antimony
- trichloroisocyanuric acid
- inhibitor
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Abstract
The present invention discloses an application of trichloroisocyanuric acid as novel ore dressing inhibitor. The use level of the trichloroisocyanuric acid is from 200 to 400 g/t measured by parts by weight. The trichloroisocyanuric acid is mainly used for sterilizing and bleaching. The application of the trichloroisocyanuric acid as the inhibitor of arsenopyrite and sulfur iron ores in an ore dressing process belongs to the first time. The trichloroisocyanuric acid has obvious effect on the separation of antimonite and the arsenopyrite, and the antimonite and the sulfur iron ores as the novel ore dressing inhibitor. The trichloroisocyanuric acid has strong inhibiting effect on the arsenopyrite and the sulfur iron ores and has no harmful influence on the antimonite. The trichloroisocyanuric acid has good selectivity and is effective inhibitor for the arsenopyrite and the sulfur iron ores.
Description
Technical field
The present invention relates to the new purposes of sym-closene, especially in the mining and metallurgy field sym-closene as a kind of application of novel beneficiation inhibitor.
Background technology
Sym-closene is called for short TCCA, molecular formula C
3N
3O
3CI
3, molecular weight 232.44 claims strong chlorine oil again.Its product is a white powder, or granular, sheet, formulation such as bar-shaped, has hypochlorous pungent odour, when being heated or contacting with low amounts of water, can decompose.Sym-closene is a strong oxidizer, contacts with inflammable organic matter, acid, alkali, ammoniation kickback can take place.
Sym-closene is efficient, the organochlorine disinfectant of wide spectrum, bleaching agent, can kill various bacteriums, algae, fungi and virus.Because its hydrolysis end product is ammonia, water and carbon dioxide, no insoluble matter is considered to desirable sanitizer.Be mainly used in civilian disinfecting, swimming-pool water is disinfected, and herding, culture fishery diseases prevention, cures the disease industry and cooling circulation cooling water of air conditioner sterilization, except that algae, fruit, fresh-keeping of vegetables are handled wastewater treatment, Seed Treatment, fabric bleaching, wool shrinkproof is handled, organic synthesis industry etc.
All in the card crop type gold mine in area, it is gold that the valency that mainly contains reclaims metal in Guizhou three, gold with submicron-sized particulate-2 μ m embedding cloth in mispickel and troilite, and the carrier mineral mispickel of gold and troilite with the fines embedding cloth of-43 μ m in country rock.Less important valuable metal is an antimony, and its content is in 0.5%～1.0% range.Antimony mineral is stibnite and occurs.Require before selecting gold, must select in priority floating the antimony concentrate of qualified grade technically, and reduce antimony concentrate as far as possible and carry the gold loss secretly.Owing to there is the floatability of small part mispickel and troilite close with stibnite, even by 3～4 selected operations of antimony, the golden loss late that antimony concentrate is carried secretly is still up to 2.5～3.5%, and antimony concentrate contains antimony＜46%.Once adopted multiple routines such as potassium permanganate, clorox and bleaching powder to separate medicament, effect is very undesirable, and product contains seriously mutually in foam and the groove.
Summary of the invention
The present invention proposes the application of sym-closene as a kind of novel beneficiation inhibitor, sym-closene is mainly used in disinfection and bleaching, application as mispickel and troilite inhibitor in ore-dressing technique still belongs to the first time, as a kind of novel beneficiation inhibitor, sym-closene is to there being stibnite and separating of mispickel, stibnite and troilite remarkable result, showing as has stronger inhibitory action to mispickel and troilite, and stibnite is had no adverse effects, selectivity is good, is mispickel and troilite effective inhibitors.
After the present invention adopts sym-closene as beneficiation inhibitor, when consumption is 200～400g/t, make antimony concentrate contain antimony＞53%, antimony recovery is 85～90%, antimony concentrate band gold loss late only has 0.8～1.0%, thereby make gold recovery improve 1.5～2.7 percentage points, meanwhile, simplified technological process.
Sym-closene is except that the FLOTATION SEPARATION that is used for stibnite and mispickel, stibnite and troilite, be applicable to that also other need remove the floatation process of sulphur, arsenic, as separating technologies such as copper-sulphur, copper-arsenic, zinc-sulphur, zinc-arsenic, raising antimony, copper, zinc concentrate grade there is remarkable result.
The addition manner of sym-closene in ore-dressing technique is that to be mixed with concentration at normal temperatures be that 2%～10% the aqueous solution adds in the flotation pulp.Because the solubility of sym-closene in the time of 25 ℃ only is 1.2 grams/100 gram water, and is easily molten for making it, adds sodium carbonate or other inorganic base and be prepared into the instant effervescent formulation of energy.Pure sym-closene and corresponding effervescent formulation thereof all have a lot of manufacturer production to sell at home.In embodiments of the present invention, 5% the aqueous solution that had been mixed with after both having added pure sym-closene (accounting for 50～80%) and sodium carbonate (20～50%) mixing mutually, 5% the aqueous solution that has used also that the effervescent formulation that contains sym-closene about 50% is mixed with, its effect unanimity.How many additions all restrains sym-closene with raw ore adding per ton is represented.
Description of drawings
Fig. 1 is when not adding beneficiation inhibitor, the selected naturally separation processes flow chart that carries out of antimony gold bulk concentrate.
Fig. 2 carries out the separation processes flow chart with bleaching powder or sym-closene as beneficiation inhibitor.
The specific embodiment: in conjunction with the embodiments and accompanying drawing the present invention is further described.
Embodiment 1
Do not add any medicament, with the selected naturally separation test that carries out of antimony gold bulk concentrate, its technological process sees Fig. 1 for details.500g is contained golden 4.8g/t, the ore of antimony 0.52% adds in the Laboratary type ore mill, the grinding machine specification is Φ 200 * 240mm, ore milling concentration is 60%, 8 minutes ore grinding time, mog reaches-43 μ m (320 order) and accounts for 90%, it is 1.5 liters Laboratary type flotation device that ore pulp after levigate is adopted specification, and interpolation waterglass 300g/t, plumbi nitras 60+40g/t, diethyldithiocarbamate 60+40g/t, pine tar 60+30g/t, roughly selected and scan totally 8 minutes, acquisition contains antimony 11.25% and contains the antimony gold bulk concentrate of golden 38g/t, in 0.5 liter flotation device, carry out 3 times selected, obtain antimony concentrate 4.5g, antimony grade 41.33%, the rate of recovery are 71.53%, contain golden 14.1g/t, golden loss late is 2.64%.
Embodiment 2
Add bleaching powder 1000g/t and carry out conventional separation test in antimony gold bulk concentrate, its technological process sees Fig. 2 for details.
500g is contained golden 4.8g/t, the ore of antimony 0.52% adds in the Laboratary type ore mill, the grinding machine specification is Φ 200 * 240mm, ore milling concentration is 60%, 8 minutes ore grinding time, mog reaches-43 μ m and accounts for 90%, it is 1.5 liters Laboratary type flotation device that ore pulp after levigate is adopted specification, and interpolation waterglass 300g/t, plumbi nitras 60+40g/t, diethyldithiocarbamate 60+40g/t, pine tar 60+30g/t, roughly selected and scan 8 minutes, acquisition contains antimony 11.25% and contains the antimony gold bulk concentrate of golden 38g/t, add bleaching powder 1000g/t after selected 1 time and carry out 1 separation in 0.5 liter flotation device, the time is 8 minutes, obtains antimony concentrate 3.9g, antimony grade 39.45%, the rate of recovery is 59.18%, contains golden 12.6g/t, and golden loss late is 2.05%.
Embodiment 3
The sym-closene 200g/t that adds the present invention's proposition in antimony gold bulk concentrate carries out separation test as beneficiation inhibitor, and its technological process sees Fig. 2 for details.
500g is contained golden 4.8g/t, the ore of antimony 0.52% adds in the Laboratary type ore mill, the grinding machine specification is Φ 200 * 240mm, ore milling concentration is 60%, 8 minutes ore grinding time, mog reaches-43 μ m and accounts for 90%, it is 1.5 liters Laboratary type flotation device that ore pulp after levigate is adopted specification, and interpolation waterglass 300g/t, plumbi nitras 60+40g/t, diethyldithiocarbamate 60+40g/t, pine tar 60+30g/t, roughly selected and scan 8 minutes, acquisition contains antimony 11.25% and contains the antimony gold bulk concentrate of golden 38g/t, add sym-closene 200g/t after selected 1 time and carry out 1 separation in 0.5 liter flotation device, the time is 8 minutes, obtains antimony concentrate 4.4g, antimony grade 52.10%, the rate of recovery is 88.17%, contains golden 5.4g/t, and golden loss late is 0.99%.
Embodiment 4
Add sym-closene 400g/t and carry out separation test as beneficiation inhibitor in antimony gold bulk concentrate, its technological process sees Fig. 2 for details.
500g is contained golden 4.8g/t, the ore of antimony 0.52% adds in the Laboratary type ore mill, the grinding machine specification is Φ 200 * 240mm, ore milling concentration is 60%, 8 minutes ore grinding time, mog reaches-43 μ m and accounts for 90%, it is 1.5 liters Laboratary type flotation device that ore pulp after levigate is adopted specification, and interpolation waterglass 300g/t, plumbi nitras 60+40g/t, diethyldithiocarbamate 60+40g/t, pine tar 60+30g/t, roughly selected and scan 8 minutes, acquisition contains antimony 11.25% and contains the antimony gold bulk concentrate of golden 38g/t, add sym-closene 400g/t after selected 1 time and carry out 1 separation in 0.5 liter flotation device, the time is 8 minutes, obtains antimony concentrate 4.1g, antimony grade 55.03%, the rate of recovery is 86.78%, contains golden 5.0g/t, and golden loss late is 0.85%.
Claims (5)
1, sym-closene is as a kind of application of novel beneficiation inhibitor.
2, sym-closene is applied in the ore-dressing technique as a kind of novel beneficiation inhibitor according to claim 1, is used for the FLOTATION SEPARATION of stibnite and mispickel, stibnite and troilite, also is applicable in other floatation process that need remove sulphur, arsenic.
3, sym-closene is applied in ore-dressing technique as a kind of novel beneficiation inhibitor according to claim 1, and the consumption that it is characterized in that sym-closene is 200～400g/t by weight.
4, according to the application of the described sym-closene of claim 1 as a kind of novel beneficiation inhibitor, the effervescent formulation that it is characterized in that using pure sym-closene and contain the sym-closene composition.
5, according to the application of the described sym-closene of claim 1 as a kind of novel beneficiation inhibitor, the aqueous solution that is mixed with after it is characterized in that adopting 50～80% pure sym-closene and 20～50% sodium carbonate mixing mutually adds in the flotation pulp.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310110961 CN1229181C (en) | 2003-11-14 | 2003-11-14 | Application of trichloroisocyanuric acid as novel beneficiation inhibitor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310110961 CN1229181C (en) | 2003-11-14 | 2003-11-14 | Application of trichloroisocyanuric acid as novel beneficiation inhibitor |
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| Publication Number | Publication Date |
|---|---|
| CN1544156A CN1544156A (en) | 2004-11-10 |
| CN1229181C true CN1229181C (en) | 2005-11-30 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200310110961 Expired - Fee Related CN1229181C (en) | 2003-11-14 | 2003-11-14 | Application of trichloroisocyanuric acid as novel beneficiation inhibitor |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101596500B (en) * | 2009-06-22 | 2013-03-20 | 广西大学 | Method for preparing inhibitor for arsenic-containing ores and uses |
| CN104718027B (en) * | 2012-04-12 | 2017-07-18 | 淡水河谷公司 | The method for improving selectivity and the rate of recovery in the flotation of the nickel sulfide ores containing magnetic iron ore by using the synergy of various inhibitors |
| CN113600346B (en) * | 2021-08-11 | 2022-12-02 | 厦门紫金矿冶技术有限公司 | Secondary copper sulfide ore inhibitor and preparation and application thereof |
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2003
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