CN1212408C - Carburant for steel-making and producing process and method of using thereof - Google Patents

Carburant for steel-making and producing process and method of using thereof Download PDF

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Publication number
CN1212408C
CN1212408C CN 03124798 CN03124798A CN1212408C CN 1212408 C CN1212408 C CN 1212408C CN 03124798 CN03124798 CN 03124798 CN 03124798 A CN03124798 A CN 03124798A CN 1212408 C CN1212408 C CN 1212408C
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steel
carbon
carburant
reductor
weight
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CN1523122A (en
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吴光亮
王哲
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Changsha Dongxin Environmental Protection Material Co Ltd
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Abstract

The present invention discloses a carburant for steel making, a production process thereof, and a using method thereof. The carburant is composed of carbon-containing materials, deoxidizing agents, specific weight regulating agents and bonding agents in the certain weight percentage; the carbon-containing materials, the deoxidizing agents and the specific weight regulating agents are respectively crushed through a crushing machine and are respectively ground into powder materials through a grinding machine to be uniformly mixed in a stirrer, the bonding agents are added in the powder materials to be uniformly mixed, the powder materials are then made into solid particles in a certain shape by a forming machine, and the solid particles are dried and baked at a certain temperature in the prescribed time and then are cooled and packed. Molten steel is added in the process of tapping and refining the molten steel, and then enters an argon flushing station, and the argon flushing treatment is carried out. The carburant for steel making is used for electric furnaces of 30 tons or rotary furnaces of 100 tons, the recovery rate of carbon is stabilized by more than 90% to 95%, steel has no carbon aliquation phenomena, and the carburant for steel making has the advantages of operating condition improvement, production cost reduction, popularization value and no environmental pollution of operation.

Description

A kind of steel-smelting carburant and production technique and using method
Technical field
The present invention relates to a kind of steel-smelting carburant and production technique and using method that is applied to ferrous metallurgy or machinery or casting industry, belong to the C21C5/00 class.
Background technology
At present the method for in the STEELMAKING PRODUCTION process molten steel being carried out carburetting is mainly to utilize carbonaceous material (as graphite, class graphite, electrode powder, refinery coke or Jiao Li etc.) and contain carbon-iron alloy and joins in the molten steel at tapping process and refining process and handle molten steel is carried out carburetting.Though this kind carbonaceous material is used extensively and technical maturity, they are generally meal (small quantities of particles is arranged), and proportion is little, therefore very easily produce airborne dust in use, float again at the top of the slag, cause environmental pollution, the rate of recovery of carbon is controlled by slag of different nature, carburetting rate instability, powder is exposed in the air easily, causes the scaling loss height of carbon, thereby the rate of recovery of carbon lower (generally about 85%), cause carbon Local enrichment in molten steel easily, and cause carbon on the low side.To with containing carbon-iron alloy, the carburetting rate of recovery stable and carbon is higher, but following defective is also arranged: 1. price height causes the smelting cost height; 2. carbon increasing amount is contained the restriction of other alloying element in the carbon-iron alloy, and operation easier is also bigger, is not a kind of ideal carburetting material.
Summary of the invention
The object of the present invention is to provide the compound iron carbon carburelant of the solid granular that a kind of proportion is big, the carbon rate of recovery is stable, the present invention proposes the production technique and the using method of this compound iron carbon carburelant simultaneously.
For achieving the above object, the technical solution used in the present invention: technical scheme is divided into composition or proportioning and the production technique and the using method of compound iron carbon carburelant.
Steel-smelting carburant is by carbonaceous material, reductor, proportion conditioning agent and binding agent are formed, earlier carbonaceous material, the proportion conditioning agent, reductor becomes the particle of 0~45mm respectively with crusher in crushing, screening respectively then, the small-particle of 0~6mm is stayed, macrobead is ground to form 0~250 purpose powder with ball mill or Raymond mill etc., the small-particle of 0~6mm and 0~250 purpose powder be mixed be starting material, by weight percentage various starting material being put into stirrer mixed 2~55 minutes, add the binding agent remix 2~65 minutes account for weight 2-15%, with shaper the mixing material is made solid particulate, with solid particulate seasoning at room temperature or at the oven dry in 2~60 hours of 25~750 ℃ of roasting temperatures, naturally cooling test package warehouse-in.
Adopt the steel-smelting carburant that as above technical scheme provides and the production technique and the using method of this carburelant, compared with prior art its advantage is:
1. because the proportion of carburelant is a bit larger tham the proportion of slag, and be solid granular, when carrying out adding molten steel in the refining process in tapping or to molten steel, carburelant will sink to below the interface of molten steel and slag, under the high-temperature molten steel condition, carburelant constantly melts, and carbon is fused in the molten steel admittedly, and molten steel is played recarburization; 2. because of carburelant is a particulate state, in use can not produce airborne dust, free from environmental pollution; 3. because of carburelant melts at molten steel and below the slag interface, can not cause carbon to expose in air, reduce the influence of slag character to the carbon rate of recovery, the carbon rate of recovery can reach more than 90%; 4. carburelant is granular composite C-Fe, and carbon diffuses in the molten steel, is necessarily blowing under the hydrogen effect of (Ar) time, and carbon can more evenly enter in the molten steel, can not cause carbon segregation, and cost is lower; 5. certain desoxydatoin is arranged, can save the consumption of reductor.
Embodiment
Below in conjunction with embodiment the specific embodiment of the present invention is described in further detail.
A kind of steel-smelting carburant of the present invention is made up of carbonaceous material, reductor, proportion conditioning agent and binding agent, reductor accounts for 1~15% of weight, the proportion conditioning agent accounts for 2~25% of weight, and carbonaceous material accounts for 60~94% of weight, and binding agent accounts for 2~15% of weight.Wherein
Carbonaceous material is coke, coal, graphite, pitch, refinery coke or electrode powder, and its carbon content is 70~100%, it as surplus;
Reductor is selected from aluminium, silicon, calcium, silicon carbide, ferrosilicon or silicocalcium;
The proportion conditioning agent is selected from abrasive grit, iron scale or iron filings, and its iron-holder is 70~90%;
Binding agent is selected from water glass, resin, pitch, paper pulp, tar, sugared slag or water.
With carbonaceous material, the proportion conditioning agent, reductor becomes the particle of 0~45mm respectively with crusher in crushing, screening respectively, the small-particle of 0~6mm is stayed, macrobead is ground to form 0~250 purpose powder with ball mill or Raymond mill etc., small-particle and 0~250 purpose powder of 0~6mm are mixed as starting material, by weight percentage starting material being put into stirrer mixed 2~55 minutes, add the binding agent remix 2~65 minutes account for weight 2-15%, with shaper the mixing material is made solid particulate, dried in 2~60 hours with solid particulate seasoning at room temperature or at 25~750 ℃ of roasting temperatures, naturally cooling packing warehouse-in is stand-by.
The using method of the steel-smelting carburant that provides with as above composition or proportioning and production technique is: in tapping or liquid steel refining process carburelant is joined in the molten steel, gone out to enter after steel or refining process finish the Argon station and again molten steel has been carried out the Argon processing and cast in 0~8 minute.
The steel-smelting carburant that as above composition or proportioning and production technique are made is applied to respectively in 30 tons of electric furnaces and the 100 tons of converters.Show at 30 tons of electric furnace application results: 1. the rate of recovery of carbon is stabilized in more than 90~95%; 2. adition process does not have airborne dust; 3. there is not carbon segregation in the steel; Compare 2.0~5.0 yuan of/ton steel that reduce production costs with using the carbonaceous carburelant when 4. smelting carbon content and be 0.45% carbon steel, compare 3.0~7.0 yuan of/ton steel that reduce production costs with using iron alloy.Application result shows in 100 tons of converters: 1. the carbon rate of recovery is stabilized in more than 90~95%; 2. adition process does not have airborne dust; 3. there is not carbon segregation in the steel; Compare 2.5~5.5 yuan of/ton steel that to reduce production costs with using carbonaceous carburetting when 4. smelting carbon content and be 0.45% carbon steel, compare 3.5~8.0 yuan of/ton steel that to reduce production costs with using high-carbbon iron alloy; 5. easy to operate, need not change existing charging technology.
All the other embodiment:
Embodiment 1
With reductor 5%, proportion conditioning agent 10%, carbonaceous material 75%, binding agent 2.5%, with reductor, proportion conditioning agent, carbonaceous material fragmentation, grind, stir, add binding agent, be mixed and made into solid particulate, 25~750 ℃ of roasting temperatures 2~60 hours, naturally cooling was stand-by.In tapping or liquid steel refining process carburelant is joined in the molten steel, tapping or refining finish back Argon (Ar) processing and cast in 0~8 minute.
Embodiment 2
With reductor 10%, proportion conditioning agent 15%, carbonaceous material 65%, binding agent 3.0%, with reductor, proportion conditioning agent, carbonaceous material fragmentation, grind, stir, add binding agent, be mixed and made into solid particulate, 25~750 ℃ of roasting temperatures 2~60 hours, naturally cooling was stand-by.In tapping or liquid steel refining process carburelant is joined in the molten steel, tapping or refining finish back Argon (Ar) processing and cast in 0~8 minute.
Embodiment 3
With reductor 13%, proportion conditioning agent 20%, carbonaceous material 85%, binding agent 4.5%, with reductor, proportion conditioning agent, carbonaceous material fragmentation, grind, stir, add binding agent, be mixed and made into solid particulate, 25~750 ℃ of roasting temperatures 2~60 hours, naturally cooling was stand-by.In tapping or liquid steel refining process carburelant is joined in the molten steel, tapping or refining finish back Argon (Ar) processing and cast in 0~8 minute.

Claims (3)

1, a kind of steel-smelting carburant, it is characterized in that: be made up of carbonaceous material, reductor, proportion conditioning agent, binding agent, reductor accounts for 1~15% of weight, and the proportion conditioning agent accounts for 2~25% of weight, binding agent accounts for 2~15% of weight, and surplus is a carbonaceous material;
Carbonaceous material: coke, coal, graphite, pitch, refinery coke or electrode powder, its carbon content is 70~100%;
Reductor is selected from aluminium, silicon, calcium, silicon carbide, ferrosilicon or silicocalcium;
The proportion conditioning agent is selected from abrasive grit, iron scale or iron filings, and its iron-holder is 70~90%;
Binding agent is selected from water glass, resin, pitch, paper pulp, tar, sugared slag or water.
2, a kind of production technique according to the described steel-smelting carburant of claim 1, it is characterized in that: with carbonaceous material, the proportion conditioning agent, reductor becomes the particle of 0~45mm respectively with crusher in crushing, screening respectively, the small-particle of 0~6mm is stayed, macrobead is ground to form 0~250 purpose powder with ball mill or Raymond mill, small-particle and 0~250 purpose powder of 0~6mm are mixed as starting material, by weight percentage starting material being put into stirrer mixed 2~55 minutes, add the binding agent remix 2~65 minutes account for weight 2-15%, with shaper the mixing material is made solid particulate, with solid particulate seasoning at room temperature or in the oven dry in 2~60 hours of 25~750 ℃ of roasting temperatures, naturally cooling packing.
3, a kind of using method according to the described steel-smelting carburant of claim 1, it is characterized in that: in tapping or liquid steel refining process, carburelant is joined in the molten steel, gone out to enter after steel or refining process finish the Argon station and again molten steel has been carried out the Argon processing and cast in 0~8 minute.
CN 03124798 2003-09-04 2003-09-04 Carburant for steel-making and producing process and method of using thereof Expired - Fee Related CN1212408C (en)

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