CN1210829A - Naturally solidifying building material with high cinder content and its preparing method - Google Patents
Naturally solidifying building material with high cinder content and its preparing method Download PDFInfo
- Publication number
- CN1210829A CN1210829A CN98113670A CN98113670A CN1210829A CN 1210829 A CN1210829 A CN 1210829A CN 98113670 A CN98113670 A CN 98113670A CN 98113670 A CN98113670 A CN 98113670A CN 1210829 A CN1210829 A CN 1210829A
- Authority
- CN
- China
- Prior art keywords
- flyash
- cinder
- magnesia
- building material
- magnesium chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Abstract
The building material of the present invention contains flyash, sand, slag, industrial sludge, magnesia, water solution of MgCl2 and modifier, and it has low cost and high cinder content. The preparation is a baking-free and steaming-free naturally solidifying process almost without power consumption. Furthermore, the addition of modifier can activate flyash and other filler into entirely new synthetic material and improve greatly the product performance. The present invention may be used to produce brick, block, light colored partition board, zebra crossing tile, floor tile and other building material.
Description
The present invention relates to a kind of naturally solidifying building material with high cinder content and method for making thereof.
Energy-conservation and environmental protection is the two big problems that the world today faces, and the innovation of materials for wall is carried out round this two big problem just.Industrial residue, rivers silt, deserted mountain roach and powdered coal cinder are converted into useful material of construction, can turn waste into wealth, can reduce environmental pollution again, and the clay solid brick of energy alternate country limit production, thereby protection land resources and physical environment.At present, be the technology that raw material is made material of construction although have with flyash, this class technology, mostly with cement, lime is raw material, its product cost is higher, and cinder content is lower.
It is lower to the purpose of this invention is to provide a kind of cost, material of construction that cinder content is higher and manufacture method thereof.
Technical scheme of the present invention is a kind of naturally solidifying building material with high cinder content, it contains (weight percentage): 50～80% flyash and/or rivers silt and/or cinder and/or industrial residue, 10～30% magnesia, 9～20% magnesium chloride solution, 0.01～1% ammonium chloride and/or urea-formaldehyde resin and/or methylene dinaphthalene sulfonate and/or hydrochloric acid and/or phosphoric acid and/or stearic acid, wherein, the proportion of magnesium chloride brine is 1.15～1.30.
The present invention also provides a kind of method for preparing above-mentioned material of construction, may further comprise the steps, the flyash chosen and/or rivers silt and/or cinder and/or industrial residue are mixed with magnesia, add magnesium chloride brine and ammonium chloride and/or urea-formaldehyde resin and/or methylene dinaphthalene sulfonate and/or hydrochloric acid and/or phosphoric acid and/or stearic acid then and stir, compression moulding again, natural curing curing promptly gets product.
In the aforesaid method, can be earlier with ammonium chloride and/or urea-formaldehyde resin and/or methylene dinaphthalene sulfonate and/or hydrochloric acid and/or phosphoric acid and/or stearic acid be added to again in the mixture of flyash and/or rivers silt and/or cinder and/or industrial residue and magnesia after magnesium chloride brine mixes.
It is packing material that technique scheme of the present invention adopts flyash, cinder, silt class raw material, with the magnesia is auxiliary material, being to coagulate admittedly agent with magnesium chloride, is properties-correcting agent with ammonium chloride and/or urea-formaldehyde resin and/or methylene dinaphthalene sulfonate and/or hydrochloric acid and/or phosphoric acid and/or stearic acid etc.Raw materials used cheapness, making method is simple, thereby makes product cost of the present invention lower and cinder content is higher.In manufacture method of the present invention, adopted the technology of free of calcining and steam curing spontaneous curing, make that the present invention almost need not consumes energy.In addition, the present invention can make weighting material activation such as flyash and become brand-new synthetic materials after adding properties-correcting agent, make the performance of products made thereby improve greatly and improve.
The present invention can be processed into sand lime brick, flyash brick, clinker brick, common brick, light-weight aggregate small-sized hollow building block, light color partition plate, pavement bricks, flooring, decorative board for wall, the material of construction such as ashes and interior wall coating of building a wall.
Below in conjunction with example the present invention is further described.
The present invention can select a kind of in flyash, rivers silt, cinder, laterite, the industrial residue as the case may be or severally arbitrarily be filler, mixes with magnesia, adds magnesium chloride solution and properties-correcting agent again and stirs compression moulding afterwards.For brick, plate series products, available existing shaper compression moulding; As the ashes of building a wall, interior wall coating etc., can directly on body of wall, construct, natural curing is solidified.
The present invention can appoint in above-mentioned component content range and gets a certain assembly ratio, and makes product of the present invention by the method that is provided, and table one provides several embodiments of the present invention (being weight percentage) table one:
| Embodiment content % component | One | Two | Three | Four | Five | Six | Seven |
| ????A | ?50 | ????55 | ????60 | ????65 | ??70 | ???75 | ???80 |
| ????B | ?30 | ???24.5 | ????28 | ????20 | ??18 | ??15.9 | ???10 |
| ????C | ?19 | ????20 | ???11.8 | ???14.95 | ?11.2 | ????9 | ??9.99 |
| ????D | ??1 | ????0.5 | ????0.2 | ????0.05 | ??0.8 | ??0.1 | ??0.01 |
Component A is a packing material in the table one, by in flyash, rivers silt, cinder, the industrial residue any or appoint several raw materials to take over the meaning mixed and form.
Component B is a magnesia.
The component C magnesium chloride brine, its proportion can arbitrarily be chosen in 1.15～1.30 scopes.
Component D is a properties-correcting agent, by in ammonium chloride, urea-formaldehyde resin, methylene dinaphthalene sulfonate, hydrochloric acid, phosphoric acid, the stearic acid any or appoint several raw materials to combine by arbitrary proportion.Table two has provided some and has formed the example of component D by several raw materials, and unit accounts for the weight percentage of component D for this raw material.
Table two
| Example ratio % raw material | One | Two | Three | Four | Five | Six | Seven | Eight |
| Ammonium chloride | 30 | ?20 | ?20 | ?30 | ?/ | ?30 | ?/ | ?20 |
| Urea-formaldehyde resin | 30 | ?/ | ?10 | ?/ | ?20 | ?30 | ?/ | ?20 |
| Methylene dinaphthalene sulfonate | / | ?30 | ?20 | ?25 | ?/ | ??/ | ?40 | ?20 |
| Hydrochloric acid | 40 | ?/ | ?/ | ?45 | ?50 | ??/ | ?60 | ?20 |
| Phosphoric acid | / | ?50 | ?30 | ?/ | ?/ | ?30 | ?/ | ?10 |
| Stearic acid | / | ?/ | ?20 | ?/ | ?30 | ?10 | ?/ | ?10 |
Also available other alkaline earth metal oxide of magnesia among the present invention replaces; Magnesium chloride can replace with other halogen compounds.
Claims (3)
1, a kind of naturally solidifying building material with high cinder content, it is characterized in that containing (weight percentage): 50～80% flyash and/or rivers silt and/or cinder and/or industrial residue, 10～30% magnesia, 9～20% magnesium chloride solution, 0,01～1% ammonium chloride and/or urea-formaldehyde resin and/or methylene dinaphthalene sulfonate and/or hydrochloric acid and/or phosphoric acid and/or stearic acid, wherein, the proportion of magnesium chloride brine is 1.15～1.30.
2, a kind of method for preparing the described material of construction of claim 1, it is characterized in that may further comprise the steps: the flyash chosen and/or rivers silt and/or cinder and/or industrial residue are mixed with magnesia, add magnesium chloride brine and ammonium chloride and/or urea-formaldehyde resin and/or methylene dinaphthalene sulfonate and/or hydrochloric acid and/or stearic acid then and stir, compression moulding again, natural curing curing promptly gets product.
3, method according to claim 2, it is characterized in that earlier with ammonium chloride and/or urea-formaldehyde resin and/or methylene dinaphthalene sulfonate and/or hydrochloric acid and/or phosphoric acid and/or stearic acid be added to again in the mixture of flyash and/or rivers silt and/or cinder and/or industrial residue and magnesia after magnesium chloride brine mixes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98113670A CN1210829A (en) | 1998-08-18 | 1998-08-18 | Naturally solidifying building material with high cinder content and its preparing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98113670A CN1210829A (en) | 1998-08-18 | 1998-08-18 | Naturally solidifying building material with high cinder content and its preparing method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1210829A true CN1210829A (en) | 1999-03-17 |
Family
ID=5223377
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN98113670A Pending CN1210829A (en) | 1998-08-18 | 1998-08-18 | Naturally solidifying building material with high cinder content and its preparing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1210829A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100467621C (en) * | 2007-07-16 | 2009-03-11 | 武汉钢铁(集团)公司 | Molten steel refining agent and preparation method |
| CN101863630A (en) * | 2010-07-02 | 2010-10-20 | 上海交通大学 | Gelled material for preparing baking-free bricks and preparation and application method thereof |
| CN102121302A (en) * | 2011-01-30 | 2011-07-13 | 孙军 | Decorative sheet for building engineering and preparation process thereof |
| CN101633575B (en) * | 2009-07-30 | 2011-11-30 | 江苏江达生态科技有限公司 | Manufacturing method of light high-intensity water permeability pavement bricks |
| CN104557105A (en) * | 2014-11-24 | 2015-04-29 | 湖南科技大学 | Preparation method of gangue porous material |
| CN105198278A (en) * | 2015-10-09 | 2015-12-30 | 蚌埠市天源气体有限责任公司 | Thermal-insulation material for low-temperature pipelines |
| CN110342847A (en) * | 2019-05-28 | 2019-10-18 | 山东辉石能源工程有限公司 | A kind of double exempt from the building materials such as brick crystallite auxiliary agent and preparation method thereof |
| CN114656279A (en) * | 2022-03-23 | 2022-06-24 | 贾彦 | Formula for preparing hollow brick by using waste polyurethane foam |
| CN115872722A (en) * | 2023-02-07 | 2023-03-31 | 山东绿达建设发展集团有限公司 | Road pavement patching material and preparation method thereof |
-
1998
- 1998-08-18 CN CN98113670A patent/CN1210829A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100467621C (en) * | 2007-07-16 | 2009-03-11 | 武汉钢铁(集团)公司 | Molten steel refining agent and preparation method |
| CN101633575B (en) * | 2009-07-30 | 2011-11-30 | 江苏江达生态科技有限公司 | Manufacturing method of light high-intensity water permeability pavement bricks |
| CN101863630A (en) * | 2010-07-02 | 2010-10-20 | 上海交通大学 | Gelled material for preparing baking-free bricks and preparation and application method thereof |
| CN102121302A (en) * | 2011-01-30 | 2011-07-13 | 孙军 | Decorative sheet for building engineering and preparation process thereof |
| CN102121302B (en) * | 2011-01-30 | 2013-04-24 | 孙军 | Decorative sheet for building engineering and preparation process thereof |
| CN104557105A (en) * | 2014-11-24 | 2015-04-29 | 湖南科技大学 | Preparation method of gangue porous material |
| CN105198278A (en) * | 2015-10-09 | 2015-12-30 | 蚌埠市天源气体有限责任公司 | Thermal-insulation material for low-temperature pipelines |
| CN105198278B (en) * | 2015-10-09 | 2018-02-27 | 蚌埠市天源气体有限责任公司 | The insulation material that a kind of cryogenic piping uses |
| CN110342847A (en) * | 2019-05-28 | 2019-10-18 | 山东辉石能源工程有限公司 | A kind of double exempt from the building materials such as brick crystallite auxiliary agent and preparation method thereof |
| CN114656279A (en) * | 2022-03-23 | 2022-06-24 | 贾彦 | Formula for preparing hollow brick by using waste polyurethane foam |
| CN115872722A (en) * | 2023-02-07 | 2023-03-31 | 山东绿达建设发展集团有限公司 | Road pavement patching material and preparation method thereof |
| CN115872722B (en) * | 2023-02-07 | 2023-06-06 | 山东绿达建设发展集团有限公司 | Road surface repairing material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101112719B1 (en) | The solidification block composition and its manufacturing method that using the sludge and inorganic waste resources | |
| CN100534945C (en) | Chemical industrial gypsum building materials and preparation method thereof | |
| CN100445233C (en) | Concrete slurry containing magnesium and its preparation process and application thereof | |
| CN102206073B (en) | Slit burning-free bricks and production method thereof | |
| CN103319762A (en) | Method for preparing high filling polyvinyl chloride or polyolefin composite material by employing industrial solid wastes | |
| CN102060490A (en) | Unburned and non-autoclaved caustic calcined dolomite brick and building block | |
| CN101186472A (en) | Technique for reclaiming and utilizing building garbage and industrial solid castoff | |
| KR101128424B1 (en) | A process of preparing water permeable block by using unsintered cement and water permeable block thus prepared | |
| CN102060480A (en) | Composite curing agent for dredged silt in watercourse | |
| CN102002366A (en) | Salinized soil curing agent prepared from industrial waste slag | |
| CN110423137A (en) | A kind of novel environment friendly ardealite high-strength light walling product and preparation method thereof | |
| CN104591562A (en) | Method for using solid waste to prepare regenerated building mortar | |
| CN1210829A (en) | Naturally solidifying building material with high cinder content and its preparing method | |
| CN108706944B (en) | Phosphogypsum light board prepared from barium slag and preparation method thereof | |
| CN103723980A (en) | Preparation method of gypsum-based high-strength gel material | |
| CN108585756A (en) | A kind of magnesium oxysulfide concrete regenerated aggregate concrete and preparation method thereof | |
| KR100492621B1 (en) | Manufacture Method of Calcium Chloro-Aluminate Clinker Using Municipal Solid Waste Incineration Ash and Sewage Sludge | |
| CN111116068B (en) | Alkaline residue magnesium oxychloride cement and preparation method and application thereof | |
| CN1502588A (en) | Porous inorganic material and mfg mehtod thereof | |
| CN1110670A (en) | Method of production of porous ceramics material with garbage and its ceramics material and appliance | |
| CN113292303A (en) | Environment-friendly composite material wall brick and manufacturing method thereof | |
| CN1247172A (en) | Building material made up of powdered coal ash, sea sand and seawater | |
| CN102329117A (en) | Lightweight wallboard manufactured by utilizing paper mill sludge and manufacturing method thereof | |
| CN101229548A (en) | Multipurpose use method of town building ruins | |
| CN1322688A (en) | Making color paving tile by utilizing city domestic refuse |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |