CN102060490A - Unburned and non-autoclaved caustic calcined dolomite brick and building block - Google Patents

Unburned and non-autoclaved caustic calcined dolomite brick and building block Download PDF

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Publication number
CN102060490A
CN102060490A CN 201010551929 CN201010551929A CN102060490A CN 102060490 A CN102060490 A CN 102060490A CN 201010551929 CN201010551929 CN 201010551929 CN 201010551929 A CN201010551929 A CN 201010551929A CN 102060490 A CN102060490 A CN 102060490A
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building block
parts
fired
light dolomite
steamed bricks
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余红发
武金永
王梅娟
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Inner Mongolia Xiangxiang New Building Material Development Co ltd
Nanjing University of Aeronautics and Astronautics
Qinghai Institute of Salt Lakes Research of CAS
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Inner Mongolia Xiangxiang New Building Material Development Co ltd
Nanjing University of Aeronautics and Astronautics
Qinghai Institute of Salt Lakes Research of CAS
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Abstract

The invention relates to an unburned and non-autoclaved caustic calcined dolomite brick and building block, which comprises the following components in part by weight: 5 to 40 parts of caustic calcined dolomite powder, 4 to 35 parts of conditioner solution, 5 to 85 parts of aggregate, 0.01 to 8 parts of water-resistant admixture, 1 to 50 parts of industrial residues, 1 to 30 parts of reinforcing and thickening agent and 0.01 to 0.5 part of water reducing agent. The unburned and non-autoclaved caustic calcined dolomite brick and building block has the advantages of greatly utilizing the industrial residues and agricultural wastes, saving resources and energy and not producing emissions of waste gas, wastewater and the industrial residues, along with freeness of burning, vapor-free or autoclaving-free maintenance, high normal temperature reaction and curing speed, strong strength, high water resistance, no absorption of moisture and separation of halide, no scumming, resistance to frost, acoustic insulation, thermal insulation, heat preservation, fire retardance and the like.

Description

A kind of light dolomite non-fired and non-steamed bricks and building block
Technical field
The present invention relates to a kind of non-fired and non-steamed bricks and building block, particularly relate to a kind of light dolomite non-fired and non-steamed bricks and building block that has a water resisting property.
Background technology
For thousands of years, clay brick is the main building building block of China always.Clay brick must could use through oversintering, and in the process of making sintered clay brick, has both damaged large-area arable land, consumes a large amount of energy again, also gives off a large amount of CO simultaneously 2And SO 2Deng gas, aggravation Greenhouse effect and environmental pollution.For saving resource, protect environment, country bans use of solid clay brick in decision big and medium-sized cities at home for a long time; To the end of the year 2010, all cities and towns, the whole nation will be completely forbidden and use solid clay brick.
For protecting farmland, Chinese invention patent application 00110917.0 discloses a kind of making method of colliery wastes brick, and replacing clay with coal gangue is that raw material is made colliery wastes brick, but still needs sintering; Chinese invention patent application 200410065821.X discloses a kind of making method of blocks from flyash by steaming and pressing, and replacing clay with flyash is raw material, makes flyash brick, but need carry out high-pressure steaming and cultivating.These two kinds of products are meeting consume fuel, discharging waste gas in making processes.
For cutting down the consumption of energy, Chinese invention patent application 200910020879.5 discloses a kind of clay baking-free light insulating brick and preparation method thereof, utilize magnesium oxide and magnesium chloride solution binding agent as various clays, after the insulating brick blanks and moulding and conserving, make clay brick, need not sintering can use, but the main raw material of this product still is a clay.This product still can damage the arable land in making processes.
Replace the material of main part of clay with flyash, building waste and nonmetallic waste slag respectively in Chinese invention patent application 99112868.0 (is unburned, the non-evaporating brick and tile building block series product and the technology of base-material with flyash), 02123184.2 (a kind of baking free hollow wall building block made from construction refuse resource products) and 200810047841.2 (utilizing nonmetallic waste slag to produce baking-free building block and preparation method) as building brick, use magnesium oxide and magnesium chloride solution as consolidating material simultaneously, prepare the sintering free construction brick.These patented products had both been protected the arable land, reduced the energy consumption of product again, and solid waste is got utilization.But in the aforementioned patent product; when utilizing magnesium oxide and magnesium chloride solution as consolidating material; all ignored the shortcoming that the reacted hydrated product of magnesium oxide and magnesium chloride solution does not have a water resisting property; other composition in the above-mentioned patented product does not all possess substantial anti-water conservation effect to this hydrated product; thereby limited the range of application of product; and in the life-time service process; because hydrated product is subjected to the erosion of moist atmosphere and rainwater; corrosion products also can cause the product moisture absorption; return halogen and scum; finally cause the product efflorescence; lost strength; lose use value, influenced the work-ing life of buildings.In addition, magnesium oxide source in the above-mentioned patented product concentrates on Liaoning Province's Haicheng City and Dashiqiao City and Laizhou City, Shandong Province of China, obtain by the magnesite calcining, being subjected to the region on the one hand limits, be difficult to apply in China, on the other hand, again mass consumption the magnesite resource of China's preciousness.
Summary of the invention
The object of the present invention is to provide a kind of lightweight, high-strength, water resisting property good, the light dolomite non-fired and non-steamed bricks and the building block of sound insulation, heat insulation, fire-retardant compliance with environmental protection requirements again.
The present invention is implemented by following technical scheme, and a kind of light dolomite non-fired and non-steamed bricks and building block comprise the component of following weight part:
5 parts~40 parts in light dolomite powder, 4 parts~35 parts of blender solution,
5 parts~85 parts in aggregate, 0.01 part~8 parts of anti-water admixtures.
It also includes the raw material of following parts by weight: 1~50 part of industrial residue.
It also includes the raw material of following parts by weight: strengthen 1~30 part of thickening material.
It also includes the raw material of following parts by weight: 0.01~0.5 part of water reducer.
Described light dolomite powder is that rhombspar is through the powdered material that contains activated magnesia and lime carbonate after the calcining.
Described industrial residue is any one or more than one the mixture in flyash, slag, slag, slag, the desulfurated plaster.
Described blender is the mixture of any one or two kinds in magnesium chloride, the sal epsom.
Described blender solution is that degree Beaume is the magnesium chloride solution of 18~35 ° of B é, the mixture of any one or two kinds in the Adlerika that degree Beaume is 20~35 ° of B é.
Described enhancing thickening material is the mixture of any one or two kinds in magnesium oxide, the Magnesium Silicate q-agent.
Described aggregate is any one or more than one the mixture in natural sandstone, artificial graded sand and stone, mill tailings sandstone, clay pottery sand and haydite, shale pottery sand and haydite, flyash ceramic sand and haydite, coal gangue, building waste, sawdust, the agricultural crop straw.
Described anti-water admixture is that concentration is any one or more than one the mixture in 35%~85% phosphoric acid, sodium phosphate, potassiumphosphate, ammonium phosphate, calcium phosphate, SODIUM PHOSPHATE, MONOBASIC, potassium primary phosphate, primary ammonium phosphate, monocalcium phosphate, sodium-metaphosphate, ferrous sulfate, gypsum or the silicon ash.
Described water reducer is the mixture of any one or two kinds in wooden calcium sulfonate or the naphthalene series high-efficiency water-reducing agent.
Manufacture method of the present invention may further comprise the steps successively:
(1) raw material metering: with light dolomite powder, industrial residue, blender solution, enhancing thickening material, aggregate, anti-water admixture, water reducer, according to the described material fiting ratio of first purpose of the present invention, metering respectively;
(2) mix stirring: the described starting material that will measure mix, and stir and make the light dolomite compound;
(3) compression moulding: on brick pressing machine, the light dolomite compound is injected mould, be pressed into the shape of brick or building block, be placed on after the demoulding on the carriage, be transported to the maintenance place;
(4) natural curing: after light dolomite non-fired and non-steamed bricks or building block curing, pile up, carry out maintenance under field conditions (factors), reach design requirements until performance.
The invention has the advantages that, 1, utilize light dolomite to have ambient cure reaction, fast solidifying, high-strength, heat insulation, sound insulation, fire-retardant, freeze proof advantage for the non-fired and non-steamed bricks of main raw material(s) preparation and building block, three-waste free discharge in the production process, belong to cleaner production, meet the requirement of novel wall material, have the good social economic benefit building function and building energy conservation; 2, add anti-water admixture, improved the water resisting property of product, can be used as the materials for wall under the wet environment, enlarged the range of application of product; Water resisting property improves, and prolongs the work-ing life of product, has overcome the product moisture absorption simultaneously, has returned the shortcoming of halogen and scum; 3, industrial residue and agricultural wastes such as sawdust, agricultural crop straw such as flyash, slag, slag, slag, desulfurated plaster are adopted in light dolomite non-fired and non-steamed bricks and building block in a large number, recycling of solid wastes and comprehensive utilization have been promoted, can reduce pollution to environment, reduce cost, and water repelling property is improved greatly; 4, adopt natural sandstone, artificial graded sand and stone and mill tailings sandstone etc. as aggregate, the light dolomite non-fired and non-steamed bricks and the building block of making are applicable to the construction material as load larrying member; 5, adopt clay pottery sand and haydite, shale pottery sand and haydite, flyash ceramic sand and haydite, coal gangue, building waste, sawdust, agricultural crop straw etc. as aggregate, can alleviate the unit weight of product, reduce the transportation energy consumption, improve thermal resistance, improve thermal and insulating performance, be applicable to construction material as non bearing structure; 6, increase strengthens thickening material, water reducer can improve intensity greatly, improves workability.Light dolomite non-fired and non-steamed bricks of the present invention and building block are nontoxic, tasteless, "dead", harmless, free from environmental pollution, belong to the environment-friendly type new construction material.
Embodiment:
Further set forth light dolomite non-fired and non-steamed bricks of the present invention and building block and preparation method by the following examples, these embodiment are only presented for purposes of illustration, do not limit the scope of the invention.The experimental technique of unreceipted actual conditions in the following example is usually according to normal condition.
Embodiment 1: the manufacture method of a kind of light dolomite non-fired and non-steamed bricks and building block, and it may further comprise the steps successively:
(1) raw material metering: with light dolomite powder, industrial residue, blender solution, strengthen thickening material, aggregate, anti-water admixture, water reducer proportioning, metering respectively according to embodiment 2-9;
(2) mix stirring: the described starting material that will measure mix, and stir and make the light dolomite compound;
(3) compression moulding: on brick pressing machine, the light dolomite compound is injected mould, be pressed into the shape of brick or building block, be placed on after the demoulding on the carriage, be transported to the maintenance place;
(4) natural curing: after light dolomite non-fired and non-steamed bricks or building block curing, pile up, carry out maintenance under field conditions (factors), reach design requirements until performance.
Embodiment 2-9 is as shown in table 1:
Use the preparation method of embodiment 1 among the embodiment 2-9, become building block or brick by table 1 formulation, light dolomite free of calcining and steam curing building block specification is 390mm * 190mm * 190mm; Light dolomite non-fired and non-steamed bricks specification is 240mm * 115mm * 53mm.
Table 1: the embodiment 2-9 tabulation of filling a prescription
Figure BSA00000353147300061
Embodiment 10: the non-fired and non-steamed bricks that makes filling a prescription with embodiment 2-9 and the performance of building block are tested, and the result is as shown in table 2.
Table 2: the non-fired and non-steamed bricks that makes by embodiment 2-9 prescription and the performance test table of building block
Figure BSA00000353147300071
By the data of table 2 as can be seen, the present invention has high-strength light, anti-water, freeze proof technical characterictic.

Claims (12)

1. light dolomite non-fired and non-steamed bricks and building block is characterized in that, comprise the component of following weight part:
5 parts~40 parts in light dolomite powder, 4 parts~35 parts of blender solution,
5 parts~85 parts in aggregate, 0.01 part~8 parts of anti-water admixtures.
2. a kind of light dolomite non-fired and non-steamed bricks according to claim 1 and building block is characterized in that it also includes the raw material of following parts by weight: 1~50 part of industrial residue.
3. a kind of light dolomite non-fired and non-steamed bricks according to claim 1 and 2 and building block is characterized in that it also includes the raw material of following parts by weight: strengthen 1~30 part of thickening material.
4. according to claim 1-3 described a kind of light dolomite non-fired and non-steamed bricks and building block arbitrarily, it is characterized in that it also includes the raw material of following parts by weight: 0.01~0.5 part of water reducer.
5. a kind of light dolomite non-fired and non-steamed bricks according to claim 1 and building block is characterized in that, described light dolomite powder is that rhombspar is through the powdered material that contains activated magnesia and lime carbonate after the calcining.
6. a kind of light dolomite non-fired and non-steamed bricks according to claim 2 and building block is characterized in that, described industrial residue is any one or more than one the mixture in flyash, slag, slag, slag, the desulfurated plaster.
7. a kind of light dolomite non-fired and non-steamed bricks according to claim 1 and building block is characterized in that, described blender is the mixture of any one or two kinds in magnesium chloride, the sal epsom.
8. a kind of light dolomite non-fired and non-steamed bricks according to claim 7 and building block, it is characterized in that described blender solution is that degree Beaume is the magnesium chloride solution of 18~35 ° of B é, the mixture of any one or two kinds in the Adlerika that degree Beaume is 20~35 ° of B é.
9. a kind of light dolomite non-fired and non-steamed bricks according to claim 3 and building block is characterized in that, described enhancing thickening material is the mixture of any one or two kinds in magnesium oxide, the Magnesium Silicate q-agent.
10. a kind of light dolomite non-fired and non-steamed bricks according to claim 1 and building block, it is characterized in that described aggregate is any one or more than one the mixture in natural sandstone, artificial graded sand and stone, mill tailings sandstone, clay pottery sand and haydite, shale pottery sand and haydite, flyash ceramic sand and haydite, coal gangue, building waste, sawdust, the agricultural crop straw.
11. a kind of light dolomite non-fired and non-steamed bricks according to claim 1 and building block, it is characterized in that described anti-water admixture is that concentration is any one or more than one the mixture in 35%~85% phosphoric acid, sodium phosphate, potassiumphosphate, ammonium phosphate, calcium phosphate, SODIUM PHOSPHATE, MONOBASIC, potassium primary phosphate, primary ammonium phosphate, monocalcium phosphate, sodium-metaphosphate, ferrous sulfate, gypsum or the silicon ash.
12. a kind of light dolomite non-fired and non-steamed bricks according to claim 4 and building block is characterized in that, described water reducer is the mixture of any one or two kinds in wooden calcium sulfonate or the naphthalene series high-efficiency water-reducing agent.
CN 201010551929 2010-11-22 2010-11-22 Unburned and non-autoclaved caustic calcined dolomite brick and building block Pending CN102060490A (en)

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CN102303370A (en) * 2011-09-14 2012-01-04 山西太钢不锈钢股份有限公司 Method for producing slag pot grid by waste magnesia carbon bricks
CN102383501A (en) * 2011-08-26 2012-03-21 天津师范大学 Embedded type aerated concrete composite outer wall heat insulation board
CN102603265A (en) * 2012-03-28 2012-07-25 王佳水 Brick made by solid waste regeneration and method
CN102617109A (en) * 2012-04-10 2012-08-01 张东涛 Energy-saving and environment-friendly straw brick and preparation method thereof
CN103896554A (en) * 2014-02-28 2014-07-02 武汉理工大学 Autoclaved brisk taking dolomite tailings and iron tailings as main raw materials and preparation method thereof
CN103951441A (en) * 2014-04-03 2014-07-30 海城市中兴高档镁质砖有限公司 Method for producing unfired konite brick by using konite waste brick
CN103992093A (en) * 2014-04-21 2014-08-20 本溪傲泰新型建筑材料有限公司 Composition for making lightweight thermal insulation building block
CN104496394A (en) * 2014-11-27 2015-04-08 中国科学院青海盐湖研究所 Exterior wall coating based on magnesium oxychloride cement and preparation method of exterior wall coating
CN104529377A (en) * 2014-12-03 2015-04-22 中国科学院青海盐湖研究所 Water-resistant magnesium oxychloride cement, preparation method and application thereof
CN106747236A (en) * 2015-11-30 2017-05-31 中国科学院青海盐湖研究所 A kind of magnesium oxysulfide concrete concrete material and preparation method thereof
CN106747235A (en) * 2015-11-30 2017-05-31 中国科学院青海盐湖研究所 A kind of water-resistance magnesium oxysulfide concrete concrete material and preparation method thereof
CN106747234A (en) * 2015-11-30 2017-05-31 中国科学院青海盐湖研究所 A kind of magnesium oxysulfide concrete concrete material and preparation method thereof
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CN106747232A (en) * 2015-11-30 2017-05-31 中国科学院青海盐湖研究所 A kind of water-resistance magnesium oxysulfide concrete concrete material and preparation method thereof
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CN106810191A (en) * 2015-11-30 2017-06-09 中国科学院青海盐湖研究所 A kind of water-resistance magnesium oxysulfide concrete concrete material and preparation method thereof
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CN111747722A (en) * 2020-06-12 2020-10-09 中冶武汉冶金建筑研究院有限公司 Cement-based baking-free high-strength plate modified based on sodium silicate and preparation method thereof
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CN108358591A (en) * 2018-02-11 2018-08-03 中科镁基(北京)科技有限公司 Building material compositions and preparation method thereof containing drift-sand
CN108358591B (en) * 2018-02-11 2020-08-18 中科镁基(北京)科技有限公司 Building material composition containing aeolian sand and preparation method thereof
CN108439904A (en) * 2018-04-24 2018-08-24 内蒙古圣清建材科技有限公司 The material for preparing the method for construction material using diabase solid waste and obtaining
CN109251004A (en) * 2018-11-15 2019-01-22 中科镁基(北京)科技有限公司 It is a kind of with carbon chromium slag be main aggregate high-strength concrete and preparation method thereof
CN109455997A (en) * 2018-11-20 2019-03-12 许昌学院 A kind of cement base foamed building block and preparation method thereof
CN110128091A (en) * 2019-06-05 2019-08-16 孙华通 A kind of novel energy-saving environment-friendly mortar and its production method
CN110642588A (en) * 2019-09-29 2020-01-03 中原环资科技有限公司 Process method for producing Lingmei building blocks
CN111747722A (en) * 2020-06-12 2020-10-09 中冶武汉冶金建筑研究院有限公司 Cement-based baking-free high-strength plate modified based on sodium silicate and preparation method thereof
CN114956632A (en) * 2022-08-01 2022-08-30 矿冶科技集团有限公司 Dolomite-based tailing building bean stone and preparation method thereof

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Application publication date: 20110518