CN1206295C - Environmental protective nano-coating - Google Patents

Environmental protective nano-coating Download PDF

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Publication number
CN1206295C
CN1206295C CN 03119674 CN03119674A CN1206295C CN 1206295 C CN1206295 C CN 1206295C CN 03119674 CN03119674 CN 03119674 CN 03119674 A CN03119674 A CN 03119674A CN 1206295 C CN1206295 C CN 1206295C
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China
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present
coating
parts
calcite
nano
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Expired - Fee Related
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CN 03119674
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Chinese (zh)
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CN1456611A (en
Inventor
黄桂平
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Individual
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Individual
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Priority to CN 03119674 priority Critical patent/CN1206295C/en
Publication of CN1456611A publication Critical patent/CN1456611A/en
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Abstract

The present invention relates to environmental protection type nano coating which is characterized in that the coating comprises nano grade materials, film forming auxiliary agent, dispersant, stiffening agent, defoaming agent and ammonia water, wherein the nano grade materials comprise titanium pigment, calcite, grammite and color paste. The desired product can be obtained by uniformly stirring in high speed. The product of the present invention has the advantages of no poison, no environmental pollution, smooth and shining face layers after construction, soft color, water resistance, flame prevention, high temperature resistance, no deposition, no layer separation, low cost, etc. Thus, the present invention provides environmental protection type coating.

Description

A kind of environment friendly nano coating
Technical field
The present invention relates to technical field of coatings, more particularly, is a kind of environment friendly nano coating composition.
Background technology
In recent years, along with China's rapid development of economy, building decoration and building coating industry also obtain develop rapidly, and some new coatings are also come out one after another.But, from the existing coating of China on the whole, still exist defective in use and decoration functions, though various as the exterior coating color, the ubiquity suspension stability is poor, and thixotropy is poor, and is not ageing-resistant, and smooth finish is not high; Difficulty of construction is after-tacked greatly and easily, easily loss of gloss, yellowing, fades; That have even poisonous, contaminate environment.
Summary of the invention
The objective of the invention is to overcome the shortcoming of prior art, propose the environment friendly nano coating that performances such as a kind of toughness, ageing-resistant, waterproof all have raising.
Main technical schemes of the present invention: adding wraps in titanium dioxide, water-ground limestone, wollastonite in interior nanometer materials in coating composition, thereby changes and improve some character of coating.
The combination of coating of the present invention and parts by weight thereof:
Titanium dioxide 90-95 part, calcite 90-95 part, wollastonite 190-195 part, film coalescence aid 13-15 part, dispersion agent 3-5 part, ammoniacal liquor 2-32.5 part, Natvosol thickening material 2-11 part, defoamer 1-2 part, benzene emulsion 285-290 part, mill base 7-10 part, water 285-295 part.
Titanium dioxide of the present invention is TiO 2, relative molecular weight 79.88, density 3.9-4.2g/cm 3, stable chemical performance, white pigment is nanometer materials.
Calcite of the present invention is a water-ground limestone, and relative molecular weight is 100.9, and the thin sprills of nano level of white are as stopping composition.
Wollastonite of the present invention requires more than No. 96, and fineness is a nano level, as filler.
Film coalescence aid of the present invention, its trade names are alcohol ester-12, and purpose makes the rapid film forming of base-material.
Dispersion agent of the present invention, its trade names are OP-10, and purpose is the bond state of regulating base-material.
Thickening material of the present invention is a Natvosol, and purpose is help emulsion miscible.
Ammoniacal liquor of the present invention, pH value are 7.3-7.8.
Defoamer of the present invention, its trade names are spa-202, are the translucent thick liquid of light color to light brown.
Phenylpropyl alcohol supernatant liquid of the present invention, trade names are HYS-08, are a kind of liquid that helps.
Mill base of the present invention, according to service requirements allotment different colours mill base, requirement is nano level mill base.
The used starting material of coating of the present invention all can buy on market.
Preparation method for coating of the present invention comprises following process:
(1) 285-295 part water, 3-5 part dispersion agent, 1-2 part defoamer are mixed, under 2000 rev/mins rotating speed, stir,
(2) in the mixture of step (1), under 35-45 ℃, add titanium dioxide 90-95 part, calcite 90-95 part, wollastonite 190-195 part is stirred to no granulated,
(3) in the mixture of step (2), add benzene emulsion 285-290 part, mill base 7-10 part again, stir, treat that the qualified after-filtration of every index is detected in its cooling back, encapsulation is desired product.
Advantage of the present invention and effect:
Owing to added the nanometer materials that comprise titanium dioxide, calcite, wollastonite, therefore, have following characteristics in the coating composition of the present invention:
1. product of the present invention does not have organic solvent, so non-environmental-pollution.
2. with the surface layer behind the coating application of the present invention level and smooth light, exquisite in texture, advantage such as color and luster is soft and have waterproof, fire-retardant, and is high temperature resistant.
3. purposes is wide, is not only applicable to the interior exterior wall of buildings, and available water-proof material.
4. easy construction, coating of the present invention does not after-tack, can brush, spraying, roller coating, color can be allocated arbitrarily according to purposes and client's needs.
5. product cost of the present invention is low, storing safety, and do not precipitate, not stratified.
Product performance data of the present invention see Table 1.
Embodiment
Further specify characteristics of the present invention below by specific examples.
Example 1
Fetch water 285 parts, 3.5 parts of dispersion agents, defoamer 1.4 minutes, high-speed stirring (rotating speed is 2000 rev/mins) is even; Temperature is risen to 40 ℃, put into 90 parts of titanium dioxides, 92 parts in calcite, 190 parts of continuation stirrings of wollastonite then, to there not being particulate state; Add 289 parts of benzene emulsions, 8 parts of mill bases again, stir and treat that the every technical indicator of its cooling back detection meets the GB9779-88 standard.
Example 2
Fetch water 285 parts, 5 parts of dispersion agents, defoamer 1 minute, high-speed stirring (rotating speed is 2000 rev/mins) is even; Temperature is risen to 40 ℃, put into 99 parts of titanium dioxides, 95 parts in calcite, 195 parts of continuation stirrings of wollastonite then, until no particulate state; Add 9 parts of 289 parts of benzene emulsions and mill bases again, stir and treat that the every technical indicator of its cooling back detection meets the GB9779-88 standard.
Example 3
Fetch water 289 parts, 4.5 parts of dispersion agents, defoamer 1.87 minutes, high-speed stirring (rotating speed is 2000 rev/mins) is even; Temperature is risen to 40 ℃, put into 93 parts of titanium dioxides, 91 parts in calcite, 192 parts of continuation stirrings of wollastonite then, until no particulate state; Add 8.5 parts of 289 parts of benzene emulsions and mill bases again, stir and treat that the every technical indicator of its cooling back detection meets the GB9779-88 standard.
Table 1
Project National standard Detected value The result
Cohesive strength >0.49 6.3 Qualified
Low-temperature stability Do not lump; Do not have and separate; Nothing is condensed Do not lump; Do not have and separate; Nothing is condensed Qualified
Cold-resistant thermal cycling Do not peel off; Non-foaming; Flawless; No variable color Do not peel off; Non-foaming; Flawless; No variable color Qualified
Contamination resistance Contamination rate<30% 13% Qualified
Weather resisteant Do not peel off; Non-foaming; Flawless Do not peel off; Non-foaming; Flawless Qualified
Alkali resistance Do not peel off; Non-foaming; Flawless; No efflorescence Do not peel off; Non-foaming; Flawless; No efflorescence Qualified
Water-permeable <3.0 0.38 Qualified

Claims (1)

1. environment friendly nano coating is characterized in that system component and parts by weight thereof:
Titanium dioxide 90-95 part, calcite 90-95, wollastonite 190-195, film coalescence aid 13-15, dispersion agent 3-5 part, ammoniacal liquor 2-32.5, Natvosol thickening material 2-11 part, defoamer 1-2 part, benzene emulsion 285-290 part, mill base 7-10 part, water 285-295 part, the fineness of described titanium dioxide, calcite, wollastonite is a nano level.
CN 03119674 2003-03-19 2003-03-19 Environmental protective nano-coating Expired - Fee Related CN1206295C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 03119674 CN1206295C (en) 2003-03-19 2003-03-19 Environmental protective nano-coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 03119674 CN1206295C (en) 2003-03-19 2003-03-19 Environmental protective nano-coating

Publications (2)

Publication Number Publication Date
CN1456611A CN1456611A (en) 2003-11-19
CN1206295C true CN1206295C (en) 2005-06-15

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN 03119674 Expired - Fee Related CN1206295C (en) 2003-03-19 2003-03-19 Environmental protective nano-coating

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CN (1) CN1206295C (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100362064C (en) * 2006-04-04 2008-01-16 中国海洋大学 Environment-friendly latex paint for external wall
CN107603352A (en) * 2017-09-28 2018-01-19 天津市奇才防水材料有限公司 A kind of environment protective nano-paint

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