CN1205379C - 附着钛超微粒子的纤维制品 - Google Patents
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Abstract
本发明公开了一种附着钛超微粒子的纤维制品，于高压水中燃烧氧氢混合气体，以该燃烧气体溶解钛金属，将所得钛超微粒子水溶液用作纤维质基材含浸处理，使其附着钛超微粒子，以得具健康效果的纤维制品。
Description
技术领域
本发明有关利用经钛水溶液含浸处理的纤维质基材，所得含有、附着钛超微粒子的纤维制品。
另，本发明有关含有、附着钛超微粒子的裤袜、袜子、手套、内衣、衬衫、健康运动服、围巾、护膝、护腕等健康纤维制品。
背景技术
近来反应社会健康取向，众多健康商品纷纷问世。其中，关于日常生活穿着衣物的改良，集中于健康布料的应用上倍受瞩目。但关于健康纤维制品，只见实开平1-93054号公报、实开平5-69104号公报所载远红外线与磁力产生素材，实开昭63-199110号公报所载炭化纤维等为人所知，但上述发明皆以治疗疾病为目的，反以促进健康功能而处理纤维质基材的技术则寥寥可数。
再者，另有提升内衣类衣物的除臭、抗菌、质感性的发想，例如于内衣部分附着碳酸钠、碳酸氢钠等臭气吸收化合物钛，使其赋有除臭功能(特开昭52-21951号公报)、经金属酞菁类处理以提升袜子抗菌、除臭功能(特开昭63-112701号公报、实开平7-9906号公报)、通过二价三价铁盐等使内衣部分具抗菌功能(实开平2-3402号公报)。
另，将装有香料的微型胶囊作为壁材，以丙烯酸粘合剂接合纤维所制成的芳香长筒袜(特开平4-100901号公报)，添加聚氧基伸烷基二醇及磺酸金属盐混合物以改良其触感的长筒袜(特开平4-241101号公报)；经聚乙酰氨基葡糖壳聚糖处理提高抗菌防霉性的不织物(特开平4-272273号公报)；将添加不含氧化钛的聚酰氨纤维，组成具透明性、平坦性、光泽性、舒适性的长筒袜(特开平7-157902号公报)；经壳聚糖液处理，含有排汗性的纤维制品(特开平9-228249号公报)；经聚磺酸与第4级铵盐组合处理的具抗静电性衬衫(特开平9-268476号公报)；添加棓酸表棓儿茶酯(epigallocatechin gallate)的袜子、长筒袜(特开平10-195701号公报)；添加陶瓷粒子的保温衣料(特开平11-269761号公报)；经抗坏血酸类处理具清凉感与镇痛效果的纤维构造物(日本专利第2562233号)；附带电石(tourmaline)，具除臭及恢复疲劳效果的袜子(日本实用新型注册3040113号)；以及经无机盐处理者(日本实用新型注册第3028232号)；上述皆广为人知，但于应合社会健康取向要求仍有相当距离。
另，金属钛与铁、铜、铝相比，属较新颖的金属材料，利用其质轻即耐高温特性，可用于工业领域如喷射引擎等航天产业、核能发电或火力发电的热交换器管或管板等能源相关领域，再者亦多用于眼镜架、高尔夫球杆头等日用品领域，其利用范围正日益扩大。
钛多用于日用品、健康医疗品或化妆品，例如表面具有钛薄膜的剪发剪(特开昭62-268584号公报)，钛熔融物利用于远红外线方面(特开昭61-59147号公报，特开平1-155803号公报、特开平3-112849号公报)，床具(特开平8-322695号公报)，烹饪用具(特开平9-140593号公报)，眼罩(特开平10-71168号公报)，健康器材(特开平11-285541号公报、特开平11-285543号公报)，健康带(新型注册第3045835号)，健康拖鞋(新型注册第3061466号)等。然而于纤维材料、特别在衣物、内衣方面，关于钛的利用则未尝见。
上述将钛制成功能水的活用技术仍未为人所知，仅有将钛作为阴极，以行电气渗透作用的饮水制造装置(特开昭50-40779号公报)，至于将钛用于生理活性材料、食品材料或医疗品等领域，其发展被受期待，惟其实际状态仍未明朗。
本发明人积极研究钛于健康用途方面的利用，结果开发出于装有高压水的耐压容器内燃烧氧氢混合气体，通过该燃烧气体所生高温燃烧钛金属，得含钛熔融物的含钛高机能水，该制造方法及装置业已提出申请(特愿2000-136932号)，但是本发明将此制造方法与装置所得含钛水，应用于纤维质基材处理上。
发明内容
为促进健康，市面上存有数多健康饮料、健康食品、健康器具，其中以将具促进健康效果的材料，用于日常生活最为贴近的衣物者，被视为最具效果，惜关于该种纤维制品所知技术甚少。
本发明人，鉴于上述状况，遂针对健康取向，积极研究能有效促进健康、价格低廉且多用途的健康纤维制品。
本发明通过经上述钛超微粒子机能水浸渍处理的纤维质基材，通过钛所具有活化人体细胞的优良效果，以提供能有效防止臭脚、消除疲劳等促进健康的纤维制品为目的。
本发明为解决上述公知问题，于纤维质基材上附着钛的一种健康纤维制品。
本发明为开发新颖健康纤维制品，于多数高功能性材料的取舍上，选择钛为机能赋予材料，而基材则为纤维质，通过添加或附着钛超微粒子于纤维质基材内，可提供优越纤维制品。
本发明将纤维质基材于钛水溶液中行浸渍处理、后经干燥所成含钛超微粒子的纤维制品；其中纤维质基材指不织物或织物。
本发明的纤维质基材，指由天然纤维、木棉、缧萦、醋酸酯等天然、半合成纤维、聚丙烯酸酯系纤维、聚乙烯醇系纤维、聚酯系纤维或聚醯胺系纤维等合成纤维制成的不织物或织物。
又，本发明含有钛超微粒子的纤维制品，以裤袜、袜子、手套、内衣类、衬衫类、健康运动服、围巾、护腕或护膝等形式作为范例。
本发明的钛水溶液浸渍处理，将纤维质基材浸渍于一般处理液中，或通过喷雾处理将处理液附于纤维质基材，使钛超微粒子浸渍或附着于纤维质基材上。
本发明所用的钛，自来即被称为″不可思议的生命力″，具有除臭作用、杀菌作用、防霉作用、耐燃作用等多数有用功能，只通过人体直接接触，以发挥增进健康的此类特殊功能，本发明属首创，此种与人体直接接触以促进健康的功能，原理虽尚未明朗，通过本发明所得纤维质基材使钛直接接触肌肤，可透过人体主要部位的″穴道″，促进发汗、肌肉新陈代谢、以及血液循环的净化作用。
附图说明
图1：经钛水溶液喷雾处理的纤维质基材表面状态，可看出钛超微粒子的附着程度(被测体1)。
图2：经钛水溶液浸渍处理的纤维质基材表面状态，同样可看出钛超微粒子的附着程度(被测体2)。
图3：未处理者，表面无任何变化(被测体3)。
图4：图1纤维质基材经清洗后状态。可看出经喷雾处理者，5次清洗后，其表面仍附有钛超微粒子(被测体4)。
图5：图2纤维质基材经清洗后状态。可看出经浸渍处理者，5次清洗后，其表面仍附有钛超微粒子(被测体5)。
具体实施方式
本发明所用钛熔融水，如上述日本特愿2000-136932号所载，于装有高压水的耐压容器内燃烧氧氢混合气体，通过该燃烧气体所生高温燃烧钛金属，得含钛熔融物的含钛高机能水。
本发明中，将上述纤维质基材行含钛水溶液浸渍处理，待处理液充分干燥后，即可得表面附有钛超微粒子的健康纤维制品。
本发明中，钛超微粒子机能水的处理，可于纤维质基材阶级进行，亦可在上述裤袜、袜子、手套、内衣、衬衫、健康运动服、围巾、护腕、护膝等制品成形后，再加行浸渍处理。
本发明中，以含钛超微粒子纤维质基材制成的健康纤维制品，可有效活用金属钛的促进健康功能。
另，本发明中，以裤袜形式最可充分发挥原有效果，但其余制品亦可有效发挥功能。
本发明以浸渍处理为主要处理方式，各方式处理的纤维表面钛附着程度，经电子显微镜放大后如图1～5。
图1(被测体1)经钛水溶液喷雾处理的纤维质基材表面状态，可明显看出钛超微粒子附着程度。
图2(被测体2)经钛水溶液浸渍处理的纤维质基材表面状态，同样可明显看出钛超微粒子附着程度。
图3(被测体3)为未处理者，当然纤维质基材的表面上并无任何变化。
图4(被测体4)为图1纤维质基材经清洗后状态。可看出经喷雾处理者，5次清洗后，其表面仍附有钛超微粒子。
图5(被测体5)为图2纤维质基材经清洗后状态。可看出经喷雾处理者，5次清洗后，其表面仍附有钛超微粒子。
照片中钛超微粒子以箭号(←)表示。
以下说明本发明健康纤维制品的效能实验结果。
使用本发明纤维制品(A)、(B)及对照用纤维制品(C)、(D)，实施感官试验(感官受验者5位)。
测试对象纤维制品
(A)经含钛水处理，表面附有钛的尼龙裤袜(本发明)。
(B)经含钛水处理，附有钛的聚酯棉混纺布内衣(本发明)。
(C)未经处理的尼龙裤袜(对照用)。
(D)未处理的聚酯棉混纺布内衣(对照用)。
评估基准
由排汗作用、消除疲劳、恢复体力等观点，由受验者5人以○～×评分主观判断。
甲 a：排汗作用 b：消除疲劳 c：恢复体力
乙 ◎：良好 ○：略佳 ◇：可 ×：无效
所得的测试结果示于第1表。
第1表
| 健康用品 | 全新 | 清洗1次 | 清洗5次 | 清洗10次 |
| A-a | ◎ | ◎ | ◎ | ○ |
| -b | ◎ | ◎ | ○ | ○ |
| -c | ◎ | ◎ | ○ | ○ |
| B-a | ◎ | ◎ | ◎ | ◎ |
| -b | ◎ | ◎ | ◎ | ○ |
| -c | ◎ | ◎ | ○ | ○ |
| C-a | ○ | ◇ | × | × |
| -b | × | × | × | × |
| -c | × | × | × | × |
| D-a | ○ | ◇ | ◇ | × |
| -b | ○ | × | × | × |
| -c | × | × | × | × |
测试结果的评估
由以上的测试结果，可看出本发明纤维制品，因附有钛超微粒子，而具有排汗作用，消除疲劳、恢复体力等优越效果，且因钛超微粒子以牢附于纤维内，因此即使重复清洗亦不致大幅影响其功能。
如上述说明，附有钛超微粒子的纤维制品，可发挥优异的排汗功能、消除疲劳促进新陈代谢等作用，作为高功能纤维制品极实用；又，此本发明所得附有钛超微粒子的纤维制品，具有优异耐洗性。
Claims (3)
1、一种含有或附着钛超微粒子的纤维制品，特征为，凭借含钛水溶液浸渍处理纤维质基材所得。
2、如权利要求1所述的纤维制品，其特征在于：其纤维质基材为不织物或织物。
3、如权利要求1或2所述的纤维制品，其特征在于：为裤袜、袜子、手套、内衣、衬衫、健康运动服、围巾、护腕、护膝等制品。
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| Application Number | Priority Date | Filing Date | Title |
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| JP201971/2000 | 2000-07-04 | ||
| JP2000201971A JP3735240B2 (ja) | 2000-07-04 | 2000-07-04 | 健康繊維製品 |
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| US20090000007A1 (en) * | 1998-12-07 | 2009-01-01 | Meridian Research And Development, Inc. | Nonwoven radiopaque material for medical garments and method for making same |
| US7476889B2 (en) * | 1998-12-07 | 2009-01-13 | Meridian Research And Development | Radiation detectable and protective articles |
| JP3735240B2 (ja) | 2000-07-04 | 2006-01-18 | ファイルド株式会社 | 健康繊維製品 |
| CA2442727A1 (en) * | 2001-03-29 | 2002-10-10 | Phild Co., Ltd. | Hair-restoring liquid comprising aqueous dispersion of ultrafine titanium particles and process and apparatus for producing the same |
| TWI301164B (zh) | 2001-10-12 | 2008-09-21 | Phild Co Ltd | |
| CA2465788A1 (en) * | 2001-11-06 | 2003-05-15 | Phild Co., Ltd. | Skin lotion comprising aqueous dispersion of ultra-fine titanium particles |
| JP2006346067A (ja) * | 2005-06-15 | 2006-12-28 | Amity Co Ltd | 血液浄化体 |
| US8262856B2 (en) * | 2007-06-18 | 2012-09-11 | Andritz Inc. | Processes and systems for the bleaching of lignocellulosic pulps following cooking with soda and anthraquinone |
| JP2009108001A (ja) | 2007-10-31 | 2009-05-21 | Fuairudo Kk | 疼痛緩和用組成物とその利用 |
| CN101910257B (zh) | 2007-12-14 | 2013-04-03 | 罗狄亚聚酰胺特殊品有限公司 | 聚合物组合物、该聚合物组合物的制备方法、基于该聚合物组合物的制品以及这些制品的用途 |
| CN101785783A (zh) * | 2009-01-22 | 2010-07-28 | 朱晓颂 | 金属Ti微粒子在促进或增大皮肤外用抗菌或杀菌药物功效上的用途 |
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| JPH01155868A (ja) * | 1987-12-14 | 1989-06-19 | Kuratoshi Ueda | 遠赤外線放射シヤツ |
| JP2525839Y2 (ja) | 1989-07-07 | 1997-02-12 | 株式会社 孝安産業 | 高速流熱、断熱圧縮熱による事故防止用ガス減圧調整器 |
| JPH03190990A (ja) * | 1989-12-20 | 1991-08-20 | Toshio Komuro | 赤外線微弱エネルギー放射用の粉末及びそれを混入した合成繊維 |
| JP3146262B2 (ja) | 1991-06-12 | 2001-03-12 | 敷島紡績株式会社 | 無機金属化合物を把持した天然セルロース繊維及びその製造法 |
| JP2916068B2 (ja) | 1992-10-07 | 1999-07-05 | 旭光学工業株式会社 | 機能性不織布の製造方法 |
| JP3280433B2 (ja) | 1992-10-09 | 2002-05-13 | 株式会社日清製粉グループ本社 | 超微粒子を表面に均一に分散付着した繊維または織布およびその製造方法およびそれを用いた繊維強化複合材 |
| JPH09241970A (ja) | 1995-12-29 | 1997-09-16 | Japan Exlan Co Ltd | 金属微粒子含有繊維とその製造方法 |
| US5897673A (en) * | 1995-12-29 | 1999-04-27 | Japan Exlan Company Limited | Fine metallic particles-containing fibers and method for producing the same |
| US6077794A (en) * | 1996-06-11 | 2000-06-20 | Toray Industries, Inc. | Deodorant fibrous material and method of producing the same |
| JPH10323400A (ja) | 1997-05-23 | 1998-12-08 | Tokuriki Honten Co Ltd | 生体機能回復用付着体 |
| JPH10323399A (ja) | 1997-05-23 | 1998-12-08 | Tokuriki Honten Co Ltd | 生体機能回復用付着体 |
| JP3050952U (ja) * | 1998-01-27 | 1998-08-07 | 有限会社 ライト | 機能性生地素材 |
| JPH11228141A (ja) * | 1998-02-18 | 1999-08-24 | C I Kasei Co Ltd | 二酸化チタン微粒子水分散体およびその製造方法 |
| US6841791B2 (en) * | 1998-12-07 | 2005-01-11 | Meridian Research And Development | Multiple hazard protection articles and methods for making them |
| US6264967B1 (en) * | 1999-07-14 | 2001-07-24 | Shinei Fermentec Corporation | Method for eliminating Staphylococcus aureus, novel microorganism of genus Brachybacterium, and care garment, care sheet or care bedclothes, each being immobilized with microorganism of genus Brachybacterium |
| JP3686819B2 (ja) * | 2000-05-10 | 2005-08-24 | ファイルド株式会社 | チタン含有高機能水及びその製造方法と装置 |
| JP3735240B2 (ja) | 2000-07-04 | 2006-01-18 | ファイルド株式会社 | 健康繊維製品 |
| TW558471B (en) | 2001-03-28 | 2003-10-21 | Phild Co Ltd | Method and device for manufacturing metallic particulates and manufactured metallic particulates |
| TW570851B (en) | 2001-03-28 | 2004-01-11 | Phild Co Ltd | Method and device for producing metal powder |
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| Publication number | Publication date |
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| DE60029257T8 (de) | 2007-12-27 |
| NZ523432A (en) | 2003-09-26 |
| CN1454271A (zh) | 2003-11-05 |
| ATE332403T1 (de) | 2006-07-15 |
| JP2002020969A (ja) | 2002-01-23 |
| AU1648101A (en) | 2002-01-14 |
| ES2266004T3 (es) | 2007-03-01 |
| DE60029257D1 (de) | 2006-08-17 |
| EP1316637A4 (en) | 2005-03-16 |
| KR100627830B1 (ko) | 2006-09-25 |
| AU2001216481B2 (en) | 2005-08-04 |
| US7201945B2 (en) | 2007-04-10 |
| EP1316637B1 (en) | 2006-07-05 |
| NO20030013D0 (no) | 2003-01-02 |
| MXPA02012706A (es) | 2003-04-25 |
| EP1316637A1 (en) | 2003-06-04 |
| HUP0301106A2 (en) | 2007-11-28 |
| DK1316637T3 (da) | 2006-10-23 |
| NO20030013L (no) | 2003-03-03 |
| WO2002002860A1 (fr) | 2002-01-10 |
| US20040213995A1 (en) | 2004-10-28 |
| HK1055769A1 (en) | 2004-01-21 |
| BR0017274A (pt) | 2003-07-29 |
| KR20030011903A (ko) | 2003-02-11 |
| JP3735240B2 (ja) | 2006-01-18 |
| TW495347B (en) | 2002-07-21 |
| PL358915A1 (en) | 2004-08-23 |
| DE60029257T2 (de) | 2007-05-31 |
| CA2414902A1 (en) | 2002-01-10 |
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