CN1202232C - Glass cleaning agent composite for electronic industry - Google Patents
Glass cleaning agent composite for electronic industry Download PDFInfo
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- CN1202232C CN1202232C CN 03138910 CN03138910A CN1202232C CN 1202232 C CN1202232 C CN 1202232C CN 03138910 CN03138910 CN 03138910 CN 03138910 A CN03138910 A CN 03138910A CN 1202232 C CN1202232 C CN 1202232C
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Abstract
The present invention relates to a glass cleaning agent composite for electronic industry, which belongs to the field of cleaning technique in electronic industry. The present invention is composed of sodium metasilicate, sodium hydroxide, sodium carbonate, sodium bicarbonate, pluronic polyalcohol, carboxymethyl cellulose, fluorine surface active agent, a complexing agent, a defoaming agent and deionized water. The glass cleaning agent composite of the present invention is used for cleaning basal plate glass and coated conductive glass. The cleaning method by using the present invention is that 1 to 5% of the glass cleaning agent composite and 99 to 95% of deionized water are compounded into a cleaning liquid, and glass is cleaned by the cleaning liquid thorough spraying or ultrasonic cleaning. The present invention can rapidly and thoroughly clean pollutants on glass, and can be used for replacing the traditional cleaning agent with strong acid, strong alkali or ODS substances. The present invention has no damage to the glass surfaces and has no corrosion to ITO films. The present invention has the advantages of no aberrant smell, no poisonous drug, no corrosion, high safety and reliability, noninflammability, inexplosive performance, no environment pollution, low production cost, convenient transportation and storage, and low cleaning cost.
Description
(1) technical field
The present invention relates to a kind of used in electronic industry glass cleaner composition,, belong to used in electronic industry cleaning technique field in particular for the cleansing composition and the purging method of base plate glass and plated film conductive glass.
(2) background technology
Liquid-crystal display (LCD) is the crystallization of multidisciplinary technical development, has now expanded to every field such as instrument, communication equipment, telecomputer from wrist-watch, calculator application, and transparent conducting glass is the important source material during LCD produces.At first base plate glass can stain pollutents such as glass powder, greasy dirt, dust, fiber, finger mark in cutting and transportation, these pollutents have a strong impact on coating quality, for guaranteeing the homogeneity and the stability of plated film,, cleans base plate glass so will carrying out precision before plating tin indium oxide (ITO) film.Secondly after coated glass is transported to LCD manufacturer, because the pollution that brings in the transportation also will be cleaned before resist coating.
Online spray Cleaning for High Capacity is used in the cleaning of base plate glass and coated glass at present mostly.Traditional clean-out system all adopts strong acid, highly basic or low boiling point solvent such as fluorine Lyons (CFC-113), 1, tetracol phenixin, ethanol, Virahol etc. to clean.As everyone knows, strong acid, highly basic clean-out system have that corrodibility is strong, operation is cumbersome, bigger to environmental hazard, and especially discharge of wastewater is difficult to up to standardly, makes the liquid waste disposal of producer become a difficult problem; All kinds of clean-out systems during low boiling point solvent cleans generally have low, inflammable, the explosive shortcoming of flash-point, some also has toxicity simultaneously, operating environment is had relatively high expectations, and some belongs to ozone-depleting material (ODS), the ozonosphere in these ODS material havoc earth high-altitudes, the harm humans ecotope, be that time limit stops material that to produce and use in the world, according to " whole the eliminating of Chinese cleaning industry ODS planned ", the ODS clean-out system will progressively be cut down and produce and consumption, and final the complete prohibition used in 2010.In recent years, also develop some substitute products both at home and abroad, or alkalescence is too strong, or contains tripoly phosphate sodium STPP, equally environment is polluted.Some replace solvents such as Hydrochlorofluorocarbons (HCFC), perfluoroparaffin (PFC) and other halogenated solvents etc. still damage the ozone layer, and also will be eliminated to the year two thousand twenty, are no more than the year two thousand forty the latest.Some organic solvent also can be used as the surrogate of ODS, but cleaning performance is good not as the CFC cleaning performance, and flash-point is low, inflammable, explosive, and some is also toxic simultaneously, and operating environment is had relatively high expectations.Therefore people's expectation develops that to replace the high performance non-halogen of strong acid, highly basic, ODS material be clean-out system, but does not have such clean-out system with excellent cleaning performance openly to report up to now as yet.
(3) summary of the invention
The present invention is directed to the shortcoming of prior art, a kind of nontoxic non-corrosive glass cleaner composition is provided, and a kind of purging method is provided, can be advantageously used in the cleaning of conducting glass plated film front and back production technique.
Cleansing composition of the present invention comprises following component, all is weight percentage:
Starso 3%-8%
Sodium hydroxide 2%-5%
Yellow soda ash 1%-5%
Sodium bicarbonate 1%-5%
Pluronic (Pluronic) polyvalent alcohol 3%-7%
Carboxymethyl cellulose 0.3%-1.0%
Fluorine surfactant 0.05%-0.1%
Complexing agent 0.1%-0.5%
Defoamer 0.1%-1.0%
The deionized water surplus
Above-mentioned Starso is a metasilicate pentahydrate sodium, and molecular formula is Na
2SiO
35H
2O, molecular weight are 212.14, or non-hydrate sodium metasilicate, and molecular formula is Na
2SiO
39H
2O, molecular weight are 284.20.The two is all white particle or powder.
Described sodium hydroxide, yellow soda ash, sodium bicarbonate are all industrial first grade.
Above-mentioned pluronic (Pluronic) polyvalent alcohol is a kind of surface-active water-soluble polyol that has, and wherein to account for the molecular fraction of total molecule be 34-45% to polyoxyethylene (hydrophilic group part).
Above-mentioned carboxymethyl cellulose, its water content＜10%, purity 〉=55%, degree of etherification 0.5-0.7, pH value 8-11, molecular weight: 240～260.
Above-mentioned complexing agent is ethylenediamine tetraacetic acid (EDTA) (EDTA) and sodium salt thereof, Trisodium Citrate.
Above-mentioned fluorine surfactant is Perfluorocaprylic Acid or its sodium salt, sylvite.
Described defoamer is the polysiloxane organic silicone oil, molecular-weight average 400-800.
In all raw materials of the present invention, Starso, sodium hydroxide, yellow soda ash, sodium bicarbonate are all white plates or particle, purity is industrial one-level, and is soluble in water, is the main component of clean-out system, mainly be in order to keep the suitable alkalinity of clean-out system, to improve surge capability, increasing work-ing life.Complexing agent ethylenediamine tetraacetic acid (EDTA) used in the present invention (EDTA) and sodium salt, Trisodium Citrate etc. are organic chelate and agent, are white particle or Powdered, and main purpose is the heavy metal ion of complex-precipitation glass surface pickup, except can chelating Ca
2+, Mg
2+Outward, can also chelating Fe
3+, Cu
2+Etc. many other metal ions, overcome the overfertilization phenomenon of using the deterioration water quality that the phosphoric acid salt inorganic assistant agent causes, environment do not produced pollution.Pluronic polyvalent alcohol of the present invention is a kind of polyether-type nonionic tensio-active agent, wherein to account for the percentage ratio of total molecule be 34-45% to polyoxyethylene (hydrophilic group part), the cloud point of 10% the aqueous solution is between 60-85 ℃, has the increase cleansing power, improve the function of cleaning efficiency, also belong to the main component of clean-out system.Carboxymethyl cellulose of the present invention has the character of emulsification and protective colloid, plays the sedimentary again effect of anti-soil dirt in washing process.Low bubble fluorine surfactant of the present invention is a kind of Perfluorocaprylic Acid type tensio-active agent, and it mainly acts on is to improve the dissolving power of clean-out system to pollutent, thereby improves its cleansing power, increases the antistatic effect that cleans the back glass surface simultaneously.Described defoamer is a kind of organosilicon macromolecule compound, has good froth breaking and presses down the bubble ability, can effectively be reduced in the foam that produces in the spray Cleaning for High Capacity process, accelerates rinse cycle.
The preparation method of cleansing composition of the present invention, with the accurately weighing in proportion of above-mentioned each component raw material, under 30-50 ℃ of temperature, join in a certain amount of water, make its whole dissolvings, continued under normal pressure high-speed stirring about 1 hour, can obtain the colourless of homogeneous transparent or light yellow liquid slightly, can be mixed with arbitrary proportion with water, and nontoxic, non-corrosiveness, free from environmental pollution, its key technical indexes is:
Outward appearance: colourless homogeneous transparent liquid odour: gentleness
Viscosity (25 ℃): 5～30 centipoise pH values: 11.0～13.0
Proportion (water=1): 1.03 ± 0.02 foams: do not have
Active matter content: greater than 15%.
Used in electronic industry glass cleaner of the present invention is a main raw material with alkaline compound, organic chelate and agent and low-foaming surfactant, raw material is easy to get, manufacture craft is simple, and nontoxic non-corrosiveness can be applicable to the cleaning of conducting glass plated film front-back baseboard glass or plated film conductive glass easily.
Cleansing composition of the present invention can replace strong acid, highly basic and ODS clean-out system, and excellent results is as follows:
1, preceding base plate glass of plated film and the pollutent on the conductive glass behind the plated film can be thoroughly cleaned fast, traditional strong acid and strong base clean-out system and ODS material clean-out system can be replaced.
2,, the ITO film there is not corrosion to the glass surface not damaged.
3, this clean-out system has free from extraneous odour, nontoxic non-corrosiveness, safe and reliable, does not fire not quick-friedly, and human body is not had harm, and is free from environmental pollution, do not destroy the high-altitude ozonosphere, do not cause characteristics such as Greenhouse effect, and cheap, and transportation stores convenient, and it is low to clean cost.
4, low foam, easily rinsing is a kind of efficient cleaner that is applicable to spray Cleaning for High Capacity.
The using method of clean-out system of the present invention is: this clean-out system of weight percent 1-5% and the deionized water of 99-95% are made into scavenging solution, scavenging solution is heated to 30-50 ℃, spray or ultrasonic cleaning use the deionized water spray irrigation clean subsequently then, last warm air drying or vacuum-drying.Can also suitably adjust according to the particular case of producer.
(4) embodiment
The invention will be further described below in conjunction with embodiment.
100 kilograms of embodiment 1. clean-out systems
| Component | Weight | Per-cent (%) |
| Metasilicate pentahydrate sodium (produce in Xi'an, white particle) | 6 kilograms | 6 |
| Sodium hydroxide | 3 kilograms | 3 |
| Yellow soda ash | 3 kilograms | 3 |
| Sodium bicarbonate | 2 kilograms | 2 |
| Pluronic polyvalent alcohol L64 (electrification group company in Hangzhou produces white pulpous state) | 6 kilograms | 6 |
| Carboxymethyl cellulose (produce in Qing Dong chemical plant, Shanghai, white powder) | 0.5 kilogram | 0.5 |
| EDTA | 0.2 kilogram | 0.2 |
| Sodium perfluorooctanoate | 0.06 kilogram | 0.06 |
| Polysiloxane organic silicone oil defoamer | 0.2 kilogram | 0.2 |
| Deionized water | 79.04 kilogram | 79.04 |
With each component of above-mentioned raw materials in proportion weighing good after, under 30-50 ℃ of temperature, add the water heating for dissolving, add above-mentioned each component one by one, make its whole dissolvings, continuation high-speed stirring 1 hour under normal pressure, outward appearance be colourless homogeneous transparent liquid ceanser, proportion is 1.03, viscosity is 25 centipoises, and the pH value is 12.7.
The deionized water of above-mentioned clean-out system 5 weight parts and 95 weight parts is made into scavenging solution, scavenging solution is heated to 30-50 ℃, online then spray Cleaning for High Capacity can effectively be removed pollutents such as grease on the glass surface, dust, uses the deionized water spray irrigation clean subsequently, last warm air drying.
Embodiment 2. is as described in the embodiment 1, and different is that Starso is non-hydrate sodium metasilicate (produces Tianjin, white particle), and complexing agent is a Trisodium Citrate.
When using cleansing composition cleaning base plate glass of the present invention, cleaning performance is compared with the conventional clean mode, result such as following table (glass size is 14 * 14 inches, detects through directional light or powerful microscope):
| Clean-out system | Clean number of packages (sheet) | Clean the front glass surface condition | Clean the back situation | Qualification rate |
| Embodiment 1 | 80 | Pollutions such as dust, finger mark are arranged | 2 have a small amount of fine particle | 97.5％ |
| CFC-113 | 30 | Pollutions such as dust, finger mark are arranged | 2 have a small amount of fine particle | 93.3％ |
| Strong acid and strong base | 28 | Pollutions such as dust, finger mark are arranged | 2 have a small amount of fine particle | 92.9％ |
100 kilograms of embodiment 3. clean-out systems
| Component | Weight | Per-cent (%) |
| Metasilicate pentahydrate sodium (produce in Xi'an, white particle) | 7 kilograms | 7 |
| Sodium hydroxide | 2.5 kilogram | 2.5 |
| Yellow soda ash | 2 kilograms | 2 |
| Sodium bicarbonate | 2 kilograms | 2 |
| Pluronic polyvalent alcohol L64 (electrification group company in Hangzhou produces white pulpous state) | 7 kilograms | 7 |
| Carboxymethyl cellulose (produce in Qing Dong chemical plant, Shanghai, white powder) | 0.4 kilogram | 0.4 |
| EDTA | 0.2 kilogram | 0.2 |
| Potassium perfluorooctanoate | 0.05 kilogram | 0.05 |
| Polysiloxane organic silicone oil defoamer | 0.15 kilogram | 0.15 |
| Deionized water | 78.7 kilogram | 78.7 |
Above-mentioned clean-out system outward appearance is colourless homogeneous transparent liquid, and proportion is 1.02, and viscosity is 24 centipoises, and the pH value is 12.5.By clean-out system using method noted earlier, online spray Cleaning for High Capacity can effectively be removed pollutents such as grease on the glass surface, dust.
Embodiment 4.
As described in embodiment 3, different is that Starso is non-hydrate sodium metasilicate (produces Tianjin, white particle), and complexing agent is a disodium ethylene diamine tetraacetate.
Use the transparent plated film conductive glass of cleaning of cleansing composition of the present invention, and conventional clean mode comparative result such as following table:
| Clean-out system | Clean number of packages (sheet) | Clean the front glass surface condition | Clean the back situation | Qualification rate |
| Embodiment 3 | 70 | Pollutions such as dust, finger mark are arranged | 2 have a small amount of fine particle | 97.5％ |
| CFC-113 | 60 | Pollutions such as dust, finger mark are arranged | 3 have a small amount of fine particle | 95.0％ |
| Strong acid and strong base | 68 | Pollutions such as dust, finger mark are arranged | 4 have a small amount of fine particle | 93.3％ |
100 kilograms of embodiment 5. clean-out systems
| Component | Weight | Per-cent (%) |
| Non-hydrate sodium metasilicate (produce Tianjin, white particle) | 4 kilograms | 4 |
| Sodium hydroxide | 4 kilograms | 4 |
| Yellow soda ash | 2 kilograms | 2 |
| Sodium bicarbonate | 1 kilogram | 1 |
| Pluronic polyvalent alcohol L64 (electrification group company in Hangzhou produces white pulpous state) | 4 kilograms | 4 |
| Carboxymethyl cellulose (produce in Qing Dong chemical plant, Shanghai, white powder) | 0.3 kilogram | 0.3 |
| EDTA | 0.2 kilogram | 0.2 |
| Perfluorocaprylic Acid | 0.07 kilogram | 0.07 |
| Polysiloxane organic silicone oil defoamer | 0.3 kilogram | 0.3 |
| Deionized water | 84.13 kilogram | 84.13 |
Claims (5)
1. the glass cleaner composition is characterized in that, is made up of following component, all is weight percentage:
Starso 3%-8%
Sodium hydroxide 2%-5%
Yellow soda ash 1%-5%
Sodium bicarbonate 1%-5%
Pluronic polyvalent alcohol L64 3%-7%
Carboxymethyl cellulose 0.3%-1.0%
Fluorine surfactant 0.05%-0.1%
Complexing agent 0.1%-0.5%
The polysiloxane organic silicone oil, molecular-weight average 400-800 0.1%-1.0%
The deionized water surplus
Described fluorine surfactant is Sodium perfluorooctanoate, Potassium perfluorooctanoate or Perfluorocaprylic Acid.
2. glass cleaner composition as claimed in claim 1 is characterized in that described Starso is a metasilicate pentahydrate sodium, and molecular formula is Na
2SiO
35H
2O, or non-hydrate sodium metasilicate, molecular formula is Na
2SiO
39H
2O.
3. glass cleaner composition as claimed in claim 1 is characterized in that, to account for the molecular fraction of total molecule be 34-45% to polyoxyethylene among the described pluronic polyvalent alcohol L64.
4. glass cleaner composition as claimed in claim 1 is characterized in that, described carboxymethyl cellulose, its water content＜10%, purity 〉=55%, degree of etherification 0.5-0.7, pH value 8-11, molecular weight: 240-260.
5. glass cleaner composition as claimed in claim 1 is characterized in that, described complexing agent is edta and its sodium salt, Trisodium Citrate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03138910 CN1202232C (en) | 2003-07-24 | 2003-07-24 | Glass cleaning agent composite for electronic industry |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03138910 CN1202232C (en) | 2003-07-24 | 2003-07-24 | Glass cleaning agent composite for electronic industry |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1482223A CN1482223A (en) | 2004-03-17 |
| CN1202232C true CN1202232C (en) | 2005-05-18 |
Family
ID=34154956
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 03138910 Expired - Fee Related CN1202232C (en) | 2003-07-24 | 2003-07-24 | Glass cleaning agent composite for electronic industry |
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|---|---|
| CN (1) | CN1202232C (en) |
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2003
- 2003-07-24 CN CN 03138910 patent/CN1202232C/en not_active Expired - Fee Related
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