CN1199503A - Fluorescent lamp - Google Patents

Fluorescent lamp Download PDF

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Publication number
CN1199503A
CN1199503A CN96197582A CN96197582A CN1199503A CN 1199503 A CN1199503 A CN 1199503A CN 96197582 A CN96197582 A CN 96197582A CN 96197582 A CN96197582 A CN 96197582A CN 1199503 A CN1199503 A CN 1199503A
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CN
China
Prior art keywords
fiber
lamp
vacuum plant
cold cathode
phosphorus
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN96197582A
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Chinese (zh)
Inventor
A·K·思扎尔斯
R·W·斯普林格尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of California
EIDP Inc
Original Assignee
University of California
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University of California, EI Du Pont de Nemours and Co filed Critical University of California
Publication of CN1199503A publication Critical patent/CN1199503A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J63/00Cathode-ray or electron-stream lamps
    • H01J63/06Lamps with luminescent screen excited by the ray or stream

Abstract

A lighting apparatus including a fibrous cold cathode field emitter wherein fibers of said cold cathode have a diameter of less than about 100 microns, an anode for attraction of electrons emitted by the fibrous cold cathode field emitter, a phosphor capable upon contact with emitted electrons from the cold cathode field emitter of generating a persistent light, and an evacuated enclosure of less than about 10<-5> Torr containing within the enclosure the cold cathode field emitter, the anode and the phosphor is provided.

Description

Fluorescent lamp
Invention field
The present invention relates to lamp, more specifically, is a kind of lighting device that adopts suitable phosphorus to combine with the cold-cathode field emitter.This invention is the product (patent No. W-7405-ENG-36) that combines with Ministry of Energy.
Background of invention
Fluorescent lamp is the lighting system of standard in the commercial building always for many years, but less in the family application.Generally when needing economic illumination, large space just adopts it.Though tungsten lamp is compared with fluorescent lamp, efficient is low and expensive, because it is easy to use and reliable, be still the main mode of domestic lighting.
Though fluorescent lamp is a kind of lighting system with greater efficiency, it truly have many weak points, these weak points are related to ecological aspect.Fluorescent tube is classified as harmful substance by EPA (EPA) at present, because it contains restricted material mercury huge poison, strict.This problem has caused the generation of No. 5229686 and No. 5229687 patents of the U.S., and they have described in the fluorescent lamp mercury can filtrable problem and add chemical reagent in fluorescent tube, when fluorescent tube is broken, these reagent just with mercury generation chemical reaction.But, in most of the cases need the ballast resistor, otherwise fluorescent lamp series containing polychlorinated biphenyl base oil (PCB), this oil also is the height carcinogen of EPA restriction.
Usually fluorescent tube needs many operations.At first the liquid mercury in the pipe is carried out electric heating, part mercury is evaporated, thereby make electric current excite mercury to enter plasmoid then by mercury vapour, the mercury plasma that is excited sends ultraviolet, phosphorus in the last ultraviolet irradiation fluorescent tube, phosphorus becomes visible light with the ultraviolet light power conversion and launches.The method of this generation light has weak point.Compare with common incandescent tungsten lamp, because mercury must be heated to form mercury vapour, fluorescent lamp starting is slow.And because well-known converter noise needs to start ballast and deposit electronics, and holding current passes through mercury vapour.When fluorescent lamp is colder, and open for the first time, the situation of optical flare can occur, therefore can attract people's attentiveness.Though and fluorescent lamp is incompatible with low light level technology commonly used, this low light level technology need be used the low light level fluorescent lamp of the costliness of higher external power usually for the output intensity of regulating light.
I.Brodie is disclosed a kind of lamp in U.S.4818914, comprises a negative electrode that is made of the prong array-as tissue, an accelerating electrode that is made of array of orifices, the cover layer of a phosphorus and an anode of protruding on a surface.Voltage is added between negative electrode and the intensifying ring, also is added between negative electrode and the anode simultaneously, causes collecting electronics at the cathode emission electronics at anode.Electron collision phosphorus cover layer sends light.Dworsky etc. disclose uniform source of light in U.S.5180951, be a high crystal diamond wafers electronic emitter basically.The light source of people such as Y-Taniguichi disclosed a kind of fluorescent tube in WO 94/28571 comprises that the noncrystal diamond wafers of one deck is placed on the conduction filament, one swathe on filament anode and by emitting electrons collision and luminous thin slice.Noncrystal diamond wafers has constituted many distributed fixedly electron emission regions, and each subregion is divided into the zonule by different characteristic electrons.
The purpose of this invention is to provide a non-mercury florescent lamp that adopts fibrous field emission unit.
Another object of the present invention provides a fluorescent lamp of moment unlatching basically.
Another object of the present invention provides the back of the body formula lamp of a low voltage and low power.
Summary of the invention
In order to achieve the above object, in conjunction with purpose of the present invention, here embodiments of the invention are described widely.The invention provides a kind of lighting device, comprise a kind of fiber cold cathode electronic generator, here said cold cathode fiber has the diameter less than 100 microns, a kind of and the interactional anode of fiber cold-cathode emitters electrons emitted, a kind of can the interaction and the phosphorus of generation lasting light with the cold-cathode emitters electrons emitted, a kind of less than 10 -5The vacuum plant of torr is included in cold-cathode emitters is housed, and within the container of anode and phosphorus, preferred lamp has the illumination of 20lm/W at least.
The accompanying drawing summary
The extension pipe device that shown in Figure 1 is according to lighting device of the present invention;
Shown in Figure 2 is according to the figure that blows of the plate shaped device of lighting device of the present invention;
The spherical device that shown in Figure 3 is according to lighting device of the present invention;
The beam generated device that shown in Figure 4 is according to lighting device of the present invention;
The testing apparatus figure that shown in Figure 5 is according to lighting device of the present invention;
The drive circuit figure that shown in Figure 6 is according to lighting device of the present invention;
The spherical device that shown in Figure 7 is according to the standard lamp socket of lighting device of the present invention.
Describe in detail
Field emission illumination device and fiber field emission illumination device (FFEL) have been the present invention relates to.
What lighting device of the present invention used is the field emission that produces light from phosphorus, i.e. cathodoluminescence material.
This field emission illumination device comprises a fiber cold-cathode field reflector.The field emission electron emissive material can be provided by any fiber-based material.Preferably field emission electron emission fiber material is diamond, diamond-like-carbon or vitreous carbon, and diamond is preferred especially person.Most preferably, the fiber negative electrode is by one or more diamond, diamond-like-carbon or vitreous carbon synthetic fibers.Diamond, diamond-like-carbon or vitreous carbon basic comprising the core fiber of non-diamond.The non-diamond core can be made up of conductor or semi-conducting material.A kind of selection, core can be made by non-conductive material, is swathed by conductor or semiconductor material thin film cover again.That is, the core material in the diamond fiber can be conductor carbon, as graphite or metal, as tungsten, promptly also can be silicon, copper, molybdenum, titanium or silicon carbide.Another embodiment is to be made up of uncomplicated structure, as the non-conductive material that swathes with conductor or semiconductor material thin film cover, and diamond, diamond-like-carbon or glassy carbon layer are enclosed on the cover.For example, the non-conductor core can be to resemble nylon, KEVLAR (KEVLAR Registered in E.I.dupontde Nomours and Company, Wilmington.DE market) so artificial manufacturing fiber, or polyamides, inorganic material, as pottery or glass.Another embodiment is, the early production of diamond, diamond-like-carbon or vitreous carbon can be enclosed within on the non-diamond core, perhaps, core can be diamond, diamond-like-carbon or vitreous carbon early production, and diamond, diamond-like-carbon or vitreous carbon also can be formed by the suitable processing method of early production.
Especially, the field emission illumination device comprises a fiber cold-cathode field reflector, this reflector U.S. Valone on February 14th, 1994 applied for 08/196, describe to some extent in No. 343 patents, patent name is " diamond-graphite field emission device ", or describes to some extent in 08/387, No. 539 patent that U.S. Blanchet-Fincher applies on February nineteen ninety-five 13, patent name is " a diamond fiber field emission device ", and description like this is hereby incorporated by.In addition, the cold-cathode field reflector also can be any other suitable emission fiber material, for example, come the suitable graphite fibre after the exposure-processed or apply for a patent 60/002 with strong ion by what the Friedman of the U.S. proposed, describe in 277 handle with laser explosure after suitable graphite fibre, 60/002, No. 277 patent was applied in August 14 nineteen ninety-five, title is " production method of the transmitting site in control field ", perhaps diamond cover, diamond like carbon neck cover LEVLAR Fiber, this fiber is described in 08/387, No. 539 patent of U.S.'s application in 13 days February nineteen ninety-five to some extent; Or contain the fiber of vitreous carbon, one is presented on about 1380~1598cm -1Amorphous materials of Raman peak value or the like.Here " diamond-like-carbon " title that is adopted is meant diamond like carbon material with carbon element, vitreous carbon, contains the carbon of atomic little vitreous carbon composition.All above materials its performance as field emmision material the time is all similar to diamond-like-carbon.
In addition, the fiber cold cathode can be an electric conducting material with activated surface usually, promptly under a relatively low voltage, can launch electron surface, it has suitable dimensions, be that diameter is usually approximately less than 100 microns, preferably, preferred approximately less than 10 microns approximately less than 15 microns.In suitable material, can comprise magnetic oxide fine fibre or the like.It is based on the activated surface of fiber treatment, and for example Fast Heating is handled.
Usually, the fibre diameter of each fiber negative electrode is approximately less than 100 microns, and is preferably approximately less than 15 microns, preferred approximately less than 10 microns.Fiber than minor diameter will reduce the necessary voltage that produces the field emission, and preferred diameter exceeds 1 micron.Usually, the fiber diameter size of cold cathode is less than the metallic filament in the present common spendable lighting device.When an independent fiber can be used as the fiber negative electrode, the single fiber of the fiber negative electrode of the electronics emission that its usage more is better than providing too much.
Be used in the phosphorus in the lighting device of the present invention and produce visible light owing to be launched electron collision, this phosphorus can have a lot of suitable kinds.For example, phosphorus can be by zinc oxide: zinc, zinc sulphide, cadmium sulfide, zinc cadmium sulphur compound, zinc selenium compound, zinc cadmium selenium compound, yttrium alum salts compound: caesium, the zinc phosphorus compound: magnet or other known material substitution, can send light by suitable activation.The compound of phosphorus also can be used.
Phosphorus application in the present invention can also produce lasting light, can not slacken after promptly being activated from the light of special phosphorus point.In addition, the product that activates phosphorus can also produce the illumination of 20lm/W not at least.
Lighting device of the present invention comprises fiber cold-cathode field reflector, phosphorus and is provided with a negative electrode for emitting electrons gravitation in the cold-cathode field reflector that all these are usually included in the vacuum plant.As mercury vapor fluorescent lamps not, lighting device of the present invention need not heat mercury and form plasma and just can open.Need not keep a plasma, light can be produced light at an easy rate by lighting device of the present invention, and can use the shading value that the fiber regulation voltage is easily regulated light.When using stronger voltage, more electronics is launched and collides phosphate material, and the result just produces too much light, i.e. Ming Liang light.When using less voltage, less electronics is launched and collides phosphate material, and resultant light just reduces, promptly dim light.The start-up circuit that lighting device of the present invention there is no need only has a commutating voltage start-up circuit and a simple current-limiting circuit.Such current-limiting circuit for example is made up of a resistance/inductance of connecting with the fiber cold cathode.
Typical vacuum plant will keep one about 10 at least -5The minimum pressure of torr.For example, such scavenge unit can be a big glass marble, or a polygon glass plate that accompanies the suitable space material.
Lighting device of the present invention produces emitting electrons by having certain orientation and shape using electric field, and this is different with using the plasma that produces non-directional light.The shape and structure that this invention allows this lighting device reality to traditional lengthening fluorescent tube without limits.No matter lighting device is any shape, and the emitting electrons that generates from the fiber negative electrode all is to launch along the length that is used fiber, rather than emits from the top and the end of fiber.
A kind of embodiment of the present invention, as shown in Figure 1, a lamp 10 comprises a glass tube 12 as scavenge unit.The inside of glass tube 12 or inner surface are coated with the conductor of layer of transparent as an anode, phosphorus or cathodoluminescence material 13.A fiber cathode electrode unit 14, fiber field emission device, suitable glass tube 12.A terminal small cap 16 comprises an electrode that is connected with fiber negative electrode 14, and the anode that covers of transparent conductor, the fiber cathode electrode unit can by one single fibrous, also can comprise many bodies fiber or bigger single fiber.Usually, single fiber or cry the individual fibers can be fibrous about many bodies of 1~20 micron greatly by diameter is preferably greatly about 5~10 microns.Glass tube can resemble cylindrical shown in the figure, also can be the surperficial shape of a setting.
Another embodiment of the invention, as shown in Figure 2, lamp 20 has a slab design with a flat board 22, and this flat board 20 has a fiber cathode electrode unit to be arranged on 24.Second transparent flat board 26 comprises a transparent conductor cover layer 28, and it is on dull and stereotyped 26 superficial layer, and the cover layer of 24, one phosphorus of faces cathode cell array or cathodoluminescence material 30 are on transparent conductor cover layer 28.Than large-area flat-plate 26 flat board 22 and dull and stereotyped 26 is separated for one, thereby provided a vacuum plant, transparent conductor cover layer 28, phosphorus or cathodoluminescence material 30 for fiber cathode electrode unit array 24.Conductor electrode is connected with fiber cathode electrode unit array 24 with transparent conductor cover layer 28.
Another embodiment of the invention, as shown in Figure 3, a globe lamp 40 comprises a glass marble 42, it has the inner covering layer of a transparent conductor, a phosphorus cover layer, or cathodoluminescence material 46, a fiber cathode electrode unit 48, the fiber field emission device is fixed on the glass marble 46.Conductor is connected with transparent conductor cover layer or anode 44 with fiber cathode electrode unit 48.Fiber cathode electrode unit 48 can by one single fibrous, also can comprise many bodies fiber.Usually, single fiber or be called individual fibers and be made of about many bodies fiber of 1~20 micron greatly diameter is preferably greatly between 5~10 microns.
Another embodiment of the invention, shown in Fig. 4 (a) and Fig. 4 (b), a lamp 50 can produce a branch of light output 52, comprise glass hemisphere supporter 54, this supporter has a cover layer on concave inside surface, transparent conductor material 58, phosphorus or the cathodoluminescence material 60 of reflector material 56.Fiber cathode electrode unit 62, a fiber field emission device are fixed on the glass hemisphere 54, and conductor is connected with transparent conductor cover layer or anode 58 with fiber cathode electrode unit 62.The change of shape of glass support 54 more causes light beam to be assembled more.For example, parabolic supporter can be finished this variation.
Shown in Figure 5 is the variation that a simple testing apparatus is used to test the emission of fiber cathodic field, comprises clean plastics, for example, and Lucite Plastics.Pipe 70 is added by terminal small cap 72 and 74 and covers, so that form a vacuum plant.Terminal small cap 72 comprises a passage 76 that is connected with the vacuum pump pipe.Be suspended in the vacuum plant is a huge copper screen net that has covered phosphorus or cathodoluminescence material 80.A fiber cathode electrode unit 82 is fixed in the huge copper screen net 78.Conductor and fiber cathode electrode unit 82, copper screen net or mutually the utmost point 78 be connected.This testing apparatus proves useful to the emission consistency of determining a large amount of fibers.
Shown in Figure 6 is the current-limiting circuit that is used for lighting device of the present invention.Current-limiting circuit 90 comprises a resistance 92 and an inductance 94 of contacting with emission fiber or fiber cathode electrode unit 96.Power supply 98 is connected by ballast circuit 100 and anode 102 and with current-limiting circuit 90 with cathode electrode unit 96 serial connections.
Another embodiment of the invention, as shown in Figure 7, lamp 120 is spiral pedestal standard lamps.Inside surface coverage layer of transparent conductor oxide 122, phosphorus or the cathodoluminescence material 123 of glass marble 121.A fiber cathodic field reflector comprises the emission fiber 124 of a field emission electron, and it is controlled in the sphere.The fiber reflector is triangular shaped by signal, can not be other shape, for example, and a circle or a polygon.The fiber reflector is being supported by non-conductive carrier 12 4.The electronics emission is by shown in the arrow 126.Spiral pedestal 127 is identical with standard incandescent bulb basically.
During lamp operate as normal of the present invention, the power consumption that produces the negative electrode of effective electron emission is 1.5 watts/inch.Usually, when being 1500V at least as fruit fiber negative electrode two polygonal voltages, the per inch emission current is at least at about about 1 milliampere.
More particularly describe in the present invention's example below, this example only is to illustrate with figure.
Embodiment 1
Shown in Figure 5 is the basic composition of a lighting device, has used a negative electrode fiber that the single strong Ion Beam Treatment of process is exposed.Carbon fiber is prepared as follows.
(commerce can be used to from Hercules to take from the not processed graphite fibre of graphite rod, Inc, the IM7 graphite of Wilmington DE) on a framework, extend, framework is placed on technology (the Rev.Sci Instrum.64 (10) according to Rej etc., the 2753-2760 page or leaf, in October, 1993) among the intense ion beam path of Chan Shenging, the about 300kV of this voltage, this framework is approximately the 6-18 foot to the distance at ion beam center.The energy density of ion beam approximately is estimated as 2~10J/cm 2, the pulse duration of ion beam approximately is 1 millisecond.After the pulse, its framework is rotated (180 °), and the another side of fiber is exposed in the pulse of intense ion beam.Last fiber is tested, and shows that it is outstanding field emission electron reflector.
Shown in Figure 5 is the fiber that is connected with conductor " A ".Zinc oxide: the zinc phosphorus compound is coated on the copper mesh screen.May be approximately the different voltage of 3.5kV and be added on negative electrode and the anode, be i.e. conductor " A " and " B ".Obtain on the fiber of 2~3 milliamperes electric current by one one inch (2.5cm) length, and be attended by lasting light.And obtain about 10W/Inch (2.5cm) and be used for illumination.
Although it is comparatively detailed comparatively speaking that the present invention describes, do not plan this detailed description is considered to the restriction of invention scope, unless the content that some corresponding patent requirement is comprised.

Claims (13)

1. lamp comprises:
Contain one or the fiber cold cathode electron emitter of multifilament, one or the multifilament that so-called fiber cold cathode contains has the diameter less than 100 microns;
One anode, it attracts by fiber cold cathode electron emitter electrons emitted;
One can be by producing the phosphorus of lasting light with electron interaction, and electronics is launched by the fiber cold-cathode emitters;
One less than 10 -5The vacuum plant of torr, it is included within the container that cold cathode electron emitter, anode and phosphorus are housed.
2. lamp as claimed in claim 1 is characterized in that, said one or the diameter of multifilament be about 1~15 micron.
3. lamp as claimed in claim 1 is characterized in that, said fiber cold cathode electron emitter comprises more than a kind of fiber.
4. lamp as claimed in claim 3 is characterized in that, the diameter of said fiber is about 1~15 micron.
5. lamp as claimed in claim 1 is characterized in that said vacuum plant is spherical.
6. lamp as claimed in claim 1 is characterized in that said vacuum plant is hemispheric.
7. lamp as claimed in claim 3 is characterized in that said vacuum plant is spherical.
8. lamp as claimed in claim 3 is characterized in that said vacuum plant is hemispheric.
9. lamp as claimed in claim 1 is characterized in that said vacuum plant is plate shaped.
10. lamp as claimed in claim 3 is characterized in that said vacuum plant is plate shaped.
11. lamp as claimed in claim 1 is characterized in that, said vacuum plant is columniform.
12. lamp as claimed in claim 3 is characterized in that, said vacuum plant is columniform.
13. lamp as claimed in claim 1 is characterized in that, said device is characterised in that it is no mercury.
CN96197582A 1995-08-14 1996-08-12 Fluorescent lamp Pending CN1199503A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US226295P 1995-08-14 1995-08-14
US60/002,262 1995-08-14

Publications (1)

Publication Number Publication Date
CN1199503A true CN1199503A (en) 1998-11-18

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CN96197582A Pending CN1199503A (en) 1995-08-14 1996-08-12 Fluorescent lamp

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EP (1) EP0845154B1 (en)
JP (1) JPH11510951A (en)
KR (1) KR100397720B1 (en)
CN (1) CN1199503A (en)
AU (1) AU696412B2 (en)
CA (1) CA2229067A1 (en)
DE (1) DE69605118T2 (en)
WO (1) WO1997007531A1 (en)

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CN1674193B (en) * 2004-03-25 2011-03-23 日本普瑞伦有限责任公司 Lighting device
CN103972030A (en) * 2013-01-29 2014-08-06 海洋王照明科技股份有限公司 Field emission light source

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CN102169807B (en) * 2004-03-25 2013-03-20 日本普瑞伦有限责任公司 Lighting device
CN103972030A (en) * 2013-01-29 2014-08-06 海洋王照明科技股份有限公司 Field emission light source

Also Published As

Publication number Publication date
DE69605118T2 (en) 2000-05-25
KR19990028976A (en) 1999-04-15
WO1997007531A1 (en) 1997-02-27
KR100397720B1 (en) 2006-03-16
CA2229067A1 (en) 1997-02-27
EP0845154B1 (en) 1999-11-10
AU7007596A (en) 1997-03-12
DE69605118D1 (en) 1999-12-16
JPH11510951A (en) 1999-09-21
EP0845154A1 (en) 1998-06-03
AU696412B2 (en) 1998-09-10

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