CN1181001C - Preparation method of inner shell frosting liquor of environment protection bulb - Google Patents
Preparation method of inner shell frosting liquor of environment protection bulb Download PDFInfo
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- CN1181001C CN1181001C CNB011263830A CN01126383A CN1181001C CN 1181001 C CN1181001 C CN 1181001C CN B011263830 A CNB011263830 A CN B011263830A CN 01126383 A CN01126383 A CN 01126383A CN 1181001 C CN1181001 C CN 1181001C
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- frosting
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- environment protection
- inner shell
- liquor
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Abstract
The present invention relates to a method for preparing a frosting material, particularly to a method for preparing inner casing frosting liquor of an environment protection type bulb. The method solves the problem in the prior art that hydrofluoric acid used as a main body frosting material of the frosting liquor pollutes the environment. The preparing method comprises the following steps: a. preparing frosting powder which has the following proportion by weight: 30 to 60 portions of ammonium hydrogen fluoride, 5 to 30 portions of fluoride, 5 to 30 portions of fluorosilicate, 5 to 30 portions of borofluoride, 1 to 10 portions of guar gum, 1 to 10 portions of organic acids, 1 to 10 portions of barium salts and 2 to 15 portions of macromolecular polysaccharide compounds; b. placing the mixture in a rotary stirring vessel, and sealing and stirring the mixture for 10 to 40 minutes; c. mixing the mixed frosting powder and industrial hydrochloric acids according to the ratio in the range of 1: 0.1 to 1: 2 to obtain the frosting liquor. The method can be used for the mass production of glass frosting bulb casings in mechanical injection.
Description
One, technical field
The present invention relates to a kind of glass frosting preparation methods, particularly a kind of preparation method of inner shell frosting liquor of environment protection bulb.
Two, background technology
Skin grinder machinery frosted and chemical liquid frosting are generally adopted in the production of glass frosting bulb, Chinese patent ZL88215320 has introduced a kind of " skin grinder in the glass bulb ", this patent is to utilize skin grinder that pressurized air and miniature frosted are carried out the frosted processing to the glass bulb internal surface, because of adopting the method frosted of machinery, so exist glass bulb easily by the defective of impact failure, frosting method for chemical liquid, in decades, it is that main body frosting material is produced the glass frosting bulb that various countries all adopt with hydrofluoric acid, Chinese patent ZL96122275 has introduced a kind of " prescription of glasswork frosted liquid and frosting method ", this patent also is as main body frosting material with this hydrofluoric acid, the shortcoming of the frosted liquid that production technique is used is that volatility is big, unstable, human body there is severe toxicity, environment is had pollution.
Three, summary of the invention
The technical issues that need to address of the present invention are, seek a kind of raw material of instead of hydrogen fluoric acid, solve problem of environmental pollution, obtain a kind of inner shell frosting liquor of environment protection bulb.Technical scheme of the present invention is: a kind of preparation method of inner shell frosting liquor of environment protection bulb, comprise preparation frosting powder and obtain frosted liquid with acid-respons, it is characterized in that may further comprise the steps: a. preparation frosting powder, its weight proportion following (in 100 parts): ammonium bifluoride 30-60 part, fluorochemical 5-30 part, silicofluoride 5-30 part, fluoroborate 5-30 part, guar gum 1-10 part, organic acid 1-10 part, barium salt 1-10 part, macromolecule polysaccharide compound 2-15 part; Wherein fluorochemical is by two or more at least composition the in Neutral ammonium fluoride, Calcium Fluoride (Fluorspan), the Potassium monofluoride, silicofluoride is by aluminum fluosilicate, magnesium silicofluoride, ammonium silicofluoride, potassium silicofluoride, at least a above composition the in the Sodium Silicofluoride, fluoroborate is by at least a above composition the in Sodium tetrafluoroborate, potassium fluoborate, the fluoroboric acid magnesium, organic acid is by at least a above composition the in oxalic acid, the thionamic acid, barium salt is by at least a above composition the in barium sulfate, the barium carbonate, and the macromolecule polysaccharide compound is by at least a above composition the in starch, white sugar, the sucrose.B. said mixture is placed to seal in the rotation stirring tank and stirred 10-40 minute; C. with the frosting powder that stirs and technical hydrochloric acid by 1: 0.1-1: 2 carry out hybrid reaction obtains frosted liquid.The invention has the beneficial effects as follows: owing to will severe toxicity be arranged to human body in the prescription of the present invention, there is the hydrofluoric acid of pollution to substitute to environment, it is little to have obtained a kind of volatility, environmentally safe bulb inner shell frosting liquor, and can satisfy mechanical injection and produce glass frosting bulb shell in enormous quantities.
Four, description of drawings
Accompanying drawing is technical process of the present invention and implementing procedure figure
Five, embodiment
Embodiment 1: with reference to accompanying drawing, and formulate glass frosting powder at first.In 100 gram total amounts, ammonium bifluoride 50 grams, Neutral ammonium fluoride 8 grams, Calcium Fluoride (Fluorspan) 5 grams, Potassium monofluoride 4 grams, Sodium tetrafluoroborate 5 grams, potassium fluoborate 6 grams, barium sulfate 8 grams, white sugar 6 grams, fluoroboric acid magnesium 3 grams, oxalic acid 5 grams.Above-claimed cpd is placed in the rotation stirring tank, and sealing was stirred 20 minutes, answered temperature control in the whipping process in 5-35 ℃ of scope.By 1: 0.5 mixed, the reaction times kept 24 hours with the frosting powder that stirs and technical hydrochloric acid, and the reaction need of frosting powder and technical hydrochloric acid carry out in the plastic containers of a with closure.Frosted liquid is obtained an even frosted liquid with common silk screen of 30 orders or nylon mesh filtration.Check its frosting power with a clean sheet glass.Place the machinery spray to cover in the device this frosted liquid and spray illiteracy fast, download the back and obtain product comprising machine, frosting cleaning, reinforcement cell-shell, cleaning, cell-shell on the cell-shell.
Embodiment 2: with reference to accompanying drawing: formulate glass frosting powder at first.In 100 gram total amounts, ammonium bifluoride 55 grams, Neutral ammonium fluoride 8 grams, Calcium Fluoride (Fluorspan) 2 grams, Sodium tetrafluoroborate 5 grams, potassium fluoborate 5 grams, Sodium Silicofluoride 5 grams, oxalic acid 5 grams, white sugar 5 grams, barium sulfate 5 grams, thionamic acid 5 grams.Above-claimed cpd is placed in the rotation stirring tank, and sealing was stirred 15 minutes, answered temperature control in the whipping process in 5-35 ℃ of scope.By 1: 0.8 mixed, the reaction times kept 48 hours with the frosting powder that stirs and technical hydrochloric acid, and the reaction need of frosting powder and technical hydrochloric acid carry out in the plastic containers of a with closure.Frosted liquid is obtained an even frosted liquid with common silk screen of 30 orders or nylon mesh filtration.Check its frosting power with a clean sheet glass.Place the machinery spray to cover in the device this frosted liquid and spray illiteracy fast, download the back and obtain product comprising machine, frosting cleaning, reinforcement cell-shell, cleaning, cell-shell on the cell-shell.
Embodiment 3: with reference to accompanying drawing: formulate glass frosting powder at first.In 100 gram total amounts, ammonium bifluoride 45 grams, Neutral ammonium fluoride 10 grams, Potassium monofluoride 5 grams, aluminum fluosilicate 5 grams, magnesium silicofluoride 5 grams, Sodium Silicofluoride 4 grams, barium sulfate 6 grams, starch 6 grams, oxalic acid 4 grams, Sodium tetrafluoroborate 3 grams, guar gum 2 grams, white sugar 2 grams, sucrose 3 grams.Above-claimed cpd is placed in the rotation stirring tank, and sealing was stirred 30 minutes, answered temperature control in the whipping process in 5-35 ℃ of scope.By 1: 1 mixed, the reaction times kept 130 hours with the frosting powder that stirs and technical hydrochloric acid, and the reaction need of frosting powder and technical hydrochloric acid carry out in the plastic containers of a with closure.Frosted liquid is obtained an even frosted liquid with common silk screen of 30 orders or nylon mesh filtration.Check its frosting power with a clean sheet glass.Place the machinery spray to cover in the device this frosted liquid and spray illiteracy fast, download the back and obtain product comprising machine, frosting cleaning, reinforcement cell-shell, cleaning, cell-shell on the cell-shell.
Embodiment 4: with reference to accompanying drawing: formulate glass frosting powder at first.In 100 gram total amounts, ammonium bifluoride 40 grams, Neutral ammonium fluoride 10 grams, Calcium Fluoride (Fluorspan) 8 grams, ammonium silicofluoride 4 grams, potassium silicofluoride 6 grams, Sodium tetrafluoroborate 5 gram starch 6 grams, barium sulfate 6 grams, barium carbonate 4 grams, white sugar 4 grams, sucrose 3 grams, guar gum 4 grams.Above-claimed cpd is placed in the rotation stirring tank, and sealing was stirred 15 minutes, answered temperature control in the whipping process in 5-35 ℃ of scope.By 1: 1.5 mixed, the reaction times kept 300 hours with the frosting powder that stirs and technical hydrochloric acid, and the reaction need of frosting powder and technical hydrochloric acid carry out in the plastic containers of a with closure.Frosted liquid is obtained an even frosted liquid with common silk screen of 30 orders or nylon mesh filtration.Check its frosting power with a clean sheet glass.Place the machinery spray to cover in the device this frosted liquid and spray illiteracy fast, download the back and obtain product comprising machine, frosting cleaning, reinforcement cell-shell, cleaning, cell-shell on the cell-shell.
Claims (9)
1, a kind of preparation method of inner shell frosting liquor of environment protection bulb, comprise preparation frosting powder and obtain frosted liquid with acid-respons, it is characterized in that may further comprise the steps: a. preparation frosting powder, the frosting powder is a kind of mixture that contains multiple mineral compound and organic compound, its weight proportion is as follows in 100 parts: ammonium bifluoride 30-60 part, fluorochemical 5-30 part, silicofluoride 5-30 part, fluoroborate 5-30 part, guar gum 1-10 part, organic acid 1-10 part, barium salt 1-10 part, macromolecule polysaccharide compound 2-15 part; B. said mixture is placed to seal in the rotation stirring tank and stirred 10-40 minute; C. with the frosting powder that stirs and technical hydrochloric acid by 1: 0.1-1: 2 carry out hybrid reaction obtains frosted liquid.
2, the preparation method of a kind of inner shell frosting liquor of environment protection bulb according to claim 1 is characterized in that: fluorochemical is by two or more at least composition the in Neutral ammonium fluoride, Calcium Fluoride (Fluorspan), the Potassium monofluoride.
3, the preparation method of a kind of inner shell frosting liquor of environment protection bulb according to claim 1, it is characterized in that: silicofluoride is by aluminum fluosilicate, magnesium silicofluoride, ammonium silicofluoride, potassium silicofluoride, at least a above composition the in the Sodium Silicofluoride, fluoroborate is by at least a above composition the in Sodium tetrafluoroborate, potassium fluoborate, the fluoroboric acid magnesium.
4, the preparation method of a kind of inner shell frosting liquor of environment protection bulb according to claim 1 is characterized in that: organic acid is by at least a above composition the in oxalic acid, the thionamic acid.
5, the preparation method of a kind of inner shell frosting liquor of environment protection bulb according to claim 1 is characterized in that: barium salt is by at least a above composition the in barium sulfate, the barium carbonate.
6, the preparation method of a kind of inner shell frosting liquor of environment protection bulb according to claim 1 is characterized in that: the macromolecule polysaccharide compound is by at least a above composition the in starch, white sugar, the sucrose.
7, the preparation method of a kind of inner shell frosting liquor of environment protection bulb according to claim 1 is characterized in that: answer temperature control in the whipping process in 5-35 ℃ of scope.
8, the preparation method of a kind of inner shell frosting liquor of environment protection bulb according to claim 1 is characterized in that: the time of frosting powder and technical hydrochloric acid reaction is controlled in 24 hours to 30 days.
9, the preparation method of a kind of inner shell frosting liquor of environment protection bulb according to claim 1 is characterized in that: the reaction of frosting powder and technical hydrochloric acid needs to carry out in the plastic containers of a with closure.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011263830A CN1181001C (en) | 2001-07-31 | 2001-07-31 | Preparation method of inner shell frosting liquor of environment protection bulb |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011263830A CN1181001C (en) | 2001-07-31 | 2001-07-31 | Preparation method of inner shell frosting liquor of environment protection bulb |
Publications (2)
| Publication Number | Publication Date |
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| CN1400184A CN1400184A (en) | 2003-03-05 |
| CN1181001C true CN1181001C (en) | 2004-12-22 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011263830A Expired - Fee Related CN1181001C (en) | 2001-07-31 | 2001-07-31 | Preparation method of inner shell frosting liquor of environment protection bulb |
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Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100457660C (en) * | 2004-12-21 | 2009-02-04 | 陈荷丽 | Etching agent of motor-driven vehicle glass and applying method thereof |
| CN101928109A (en) * | 2009-06-23 | 2010-12-29 | 吴健平 | Glassware surface frosting processing and manufacturing method |
| CN103086609A (en) * | 2011-11-04 | 2013-05-08 | 景志杰 | Glass frosting treatment agent |
| CN103030301A (en) * | 2012-12-20 | 2013-04-10 | 龙岩市和达机械有限公司 | Glass frosting powder for processing anti-dazzle glass and preparation method thereof |
| CN105036561A (en) * | 2015-05-13 | 2015-11-11 | 湖北鸿创科技有限公司 | Frosting liquid used in production line of frosted glass |
| CN111018359A (en) * | 2019-12-26 | 2020-04-17 | 佛山晶美莱科技有限公司 | Mongolian sand powder |
| CN111204984B (en) * | 2020-03-23 | 2022-02-22 | 广州亦盛环保科技有限公司 | High-alumina glass frosting powder and use method thereof |
| CN113666644A (en) * | 2021-08-25 | 2021-11-19 | 翔实光电科技(昆山)有限公司 | Glass frosting liquid, prepared frosted glass and preparation method |
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2001
- 2001-07-31 CN CNB011263830A patent/CN1181001C/en not_active Expired - Fee Related
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| CN1400184A (en) | 2003-03-05 |
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