CN117801575A - Anti-fouling aerosol paint and preparation method thereof - Google Patents

Anti-fouling aerosol paint and preparation method thereof Download PDF

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Publication number
CN117801575A
CN117801575A CN202311571790.4A CN202311571790A CN117801575A CN 117801575 A CN117801575 A CN 117801575A CN 202311571790 A CN202311571790 A CN 202311571790A CN 117801575 A CN117801575 A CN 117801575A
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CN
China
Prior art keywords
resin
aerosol paint
antifouling
solvent
paint
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202311571790.4A
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Chinese (zh)
Inventor
梁伟明
叶伟男
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Guangdong Laiya New Chemical Technology Co ltd
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Guangdong Laiya New Chemical Technology Co ltd
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Priority to CN202311571790.4A priority Critical patent/CN117801575A/en
Publication of CN117801575A publication Critical patent/CN117801575A/en
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Abstract

The invention provides an anti-fouling aerosol paint and a preparation method of the anti-fouling aerosol paint, which belong to the technical field of aerosol paint, and the anti-fouling aerosol paint comprises the following components in percentage by weight: 10-15 parts of ceramic precursor; 4-6 parts of resin; 35-40 parts of solvent; 0.01 to 0.1 part of leveling agent; 40-50 parts of propellant. The aerosol paint has the advantages of water repellency, oil repellency, high hardness, wear resistance, good adhesive force and the like, and can overcome the defect that the existing wall paint cannot prevent water stains, greasy dirt and ink stains.

Description

Anti-fouling aerosol paint and preparation method thereof
Technical Field
The invention relates to the technical field of aerosol paint, in particular to an anti-fouling aerosol paint and a preparation method of the anti-fouling aerosol paint.
Background
Wall paint or decorative paint is one of the main decorative materials for the wall surfaces in home decoration, and accounts for a considerable proportion in the cost of basic decoration, and the wall paint is mainly divided into two main types, namely inner wall paint and outer wall paint. According to different coating modes, wall paint can be divided into two main types of aerosol paint and painting.
In recent years, there has been an increasing demand for wall coverings. However, in wall paint applications such as household walls, columns, doors, etc. in traditional buildings and public areas, the wall paint in these areas is often contaminated with stains such as water stains, watercolor pens, sign pens, pencils, oil pens, crayons, etc., resulting in poor look and feel. The existing wall paint has poor water and oil repellency and low hardness, and cannot play an effective role in preventing dirt and ink stains.
Therefore, there is a need for improvements to existing wall paints to overcome the drawbacks of the prior art.
Disclosure of Invention
In order to overcome the problems in the related art, one of the purposes of the invention is to provide an anti-fouling aerosol paint which has the advantages of water and oil repellency, high hardness, wear resistance, good adhesive force and the like, and can overcome the defect that the existing wall paint cannot resist the dirt of anti-fouling ink.
An antifouling aerosol paint comprises the following components in percentage by weight:
10-15 parts of ceramic precursor;
4-6 parts of resin;
35-40 parts of solvent;
0.01 to 0.1 part of leveling agent;
40-50 parts of propellant.
In a preferred technical scheme of the invention, the ceramic precursor comprises one or a combination of more of an organic polymer precursor, a metal organic precursor, a silicone rubber precursor, a silazane precursor and an oxide precursor.
In a preferred embodiment of the present invention, the ceramic precursor is a polysilazane ceramic precursor.
In the preferred technical scheme of the invention, the resin is one or a combination of more of acrylic resin, tetrafluoro fluorocarbon resin, aldehyde ketone resin, alkyd resin and phenolic resin.
In the preferred technical scheme of the invention, the resin is a composition of tetrafluoro fluorocarbon resin and aldehyde ketone resin, and the ratio of tetrafluoro fluorocarbon resin to aldehyde ketone resin is 2-5:1.
In a preferred embodiment of the present invention, the resin is a FEVE solvent type tetrafluorofluorocarbon resin.
In a preferred technical scheme of the invention, the solvent is one or more of isohexane, heptane, octane or 120# solvent oil, 120# petroleum ether and 60-90 petroleum ether.
In the preferred technical scheme of the invention, the leveling agent is an organosilicon leveling agent or an organosilicon oil diluent.
In a preferred embodiment of the present invention, the propellant is one or more of liquefied petroleum gas, dimethyl ether, tetrafluoroethane, difluoroethane, carbon dioxide or nitrogen.
The second object of the invention is to provide a preparation method of the anti-fouling aerosol paint, which is used for preparing the anti-fouling aerosol paint, and the preparation method of the anti-fouling aerosol paint comprises the following steps:
adding the solvent into a reaction kettle, stirring, adding the ceramic precursor, the resin and the flatting agent in a stirring state, and primarily stirring for 15-30 min;
standing the primarily stirred feed liquid for 10-20 min, and stirring again for 10-20 min to obtain the final feed liquid;
and (3) filling the final feed liquid, filling a propellant, and testing in a water bath to obtain a final product after no side leakage.
The beneficial effects of the invention are as follows:
the anti-fouling aerosol paint provided by the invention comprises a ceramic precursor, resin, a solvent, a leveling agent and a propellant, wherein the ceramic precursor and the resin can be crosslinked and solidified or cracked into amorphous ceramic under the condition of room temperature or heating to form an organic and inorganic hybrid resin ceramic product with excellent temperature resistance, water resistance and solvent resistance, and the water resistance and solvent resistance of the aerosol paint can be improved, and the adhesive force, hardness and wear resistance of the product can be improved in the formula. The solvent can dissolve the resin in the aerosol paint liquid, and improve the viscosity and the fluidity of the aerosol paint. The resin of this application adopts tetrafluoro fluorocarbon resin, and tetrafluoro fluorocarbon resin can promote the hydrophobic oleophobic performance of paint finish, makes water stain, printing ink, wax be difficult to attach to the paint finish, reduces the smudge and remains. In general, the antifouling aerosol paint disclosed by the application has the advantages of water repellency, oleophobic property, high hardness, abrasion resistance, good adhesive force and the like, and can overcome the defect that the existing wall paint cannot prevent water stains, greasy dirt and ink stains.
The anti-fouling aerosol paint prepared by the method has stable quality, is convenient to use, and has higher capabilities of preventing water stains, oil stains and oil ink stains.
Drawings
FIG. 1 is a flow chart of a method for preparing the anti-fouling aerosol paint provided by the invention.
Detailed Description
Preferred embodiments of the present invention will be described in more detail below with reference to the accompanying drawings. While the preferred embodiments of the present invention are shown in the drawings, it should be understood that the present invention may be embodied in various forms and should not be limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art.
The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used in this specification and the appended claims, the singular forms "a," "an," and "the" are intended to include the plural forms as well, unless the context clearly indicates otherwise. It should also be understood that the term "and/or" as used herein refers to and encompasses any or all possible combinations of one or more of the associated listed items.
It should be understood that although the terms "first," "second," "third," etc. may be used herein to describe various information, these information should not be limited by these terms. These terms are only used to distinguish one type of information from another. For example, first information may also be referred to as second information, and similarly, second information may also be referred to as first information, without departing from the scope of the invention. Thus, a feature defining "a first" or "a second" may explicitly or implicitly include one or more such feature. In the description of the present invention, the meaning of "a plurality" is two or more, unless explicitly defined otherwise.
The existing wall paint or decorative paint is one of the main decorative materials for the wall surface in the home decoration, and accounts for a considerable proportion in the basic decoration cost. Wall paint is mainly divided into two main types, namely inner wall paint and outer wall paint. According to different coating modes, wall paint can be divided into two main types of aerosol paint and painting.
In recent years, there has been an increasing demand for wall coverings. However, in wall paint applications such as household walls, columns, doors, etc. in traditional buildings and public areas, the wall paint in these areas is often contaminated with stains such as water stains, watercolor pens, sign pens, pencils, oil pens, crayons, etc., resulting in poor look and feel. The existing wall paint has poor water and oil repellency and low hardness, and cannot play an effective role in preventing dirt and ink stains. Based on this, the present application provides an anti-fouling aerosol paint.
The anti-fouling aerosol paint comprises the following components in percentage by weight:
10-15 parts of ceramic precursor;
4-6 parts of resin;
35-40 parts of solvent;
0.01 to 0.1 part of leveling agent;
40-50 parts of propellant.
More specifically, the ceramic precursor comprises one or more combinations of an organic polymer precursor, a metal-organic precursor, a silicone rubber precursor, a silazane precursor, and an oxide precursor. In this embodiment, the ceramic precursor is a polysilazane ceramic precursor.
In addition, the resin is one or a combination of more of acrylic resin, tetrafluoro fluorocarbon resin, aldehyde ketone resin, alkyd resin and phenolic resin. In a more preferred embodiment, the composition of the tetrafluoro fluorocarbon resin and the aldehyde ketone resin has a ratio of tetrafluoro fluorocarbon resin to aldehyde ketone resin of 2 to 5:1. The tetrafluoro fluorocarbon resin has good anti-adhesion, chemical corrosion resistance, high temperature resistance, and good smoothness and wear resistance, and can endow the spray coating with excellent anti-adhesion property when used in aerosol paint, so that the coating of the aerosol paint can resist the attack of acid, alkali, solvent and other chemicals, and the coating keeps stability, flat, smooth and wear-resistant under the high-temperature environment. The aldehyde ketone resin can improve the glossiness and hardness of the paint film, and can improve the adhesive force of the paint film, and the tetrafluoro fluorocarbon resin is mixed with the aldehyde ketone resin, so that the aerosol paint coating has better glossiness, strong adhesive capability and high stability.
In another embodiment, the resin is a FEVE solvent-based tetrafluorofluorocarbon resin.
The ceramic precursor and the resin can be crosslinked and solidified or cracked into amorphous ceramic at room temperature or under the heating condition to form an organic-inorganic hybrid resin ceramic product with excellent temperature resistance, water resistance and solvent resistance, the water resistance and solvent resistance of the aerosol paint can be improved, the adhesive force, the hardness and the wear resistance of the product can be improved in the formula, and the solvent-type tetrafluorofluorocarbon resin can improve the hydrophobic and oleophobic performance of the paint surface, so that water stains, ink and wax are difficult to adhere to the paint surface, and the stain residue is reduced.
Still further, the solvent is one or more of isohexane, heptane, octane or 120# solvent oil, 120# petroleum ether, 60-90 petroleum ether.
The solvent disclosed by the application is compatible with the ceramic precursor and the resin, has the advantages of easiness in volatilization, environmental friendliness and good stability, and can be used as a diluent in feed liquid of the aerosol paint.
More specifically, the leveling agent is an organosilicon leveling agent or an organosilicon oil diluent.
The leveling agent is helpful for reducing the surface tension of the spray coating, so that the aerosol paint is easier to naturally level after spraying and forms a smooth and uniform surface. This helps to reduce the occurrence of blemishes, bubbles or lines after spraying, and makes the surface look smoother. In addition, the leveling agent can help molecules in the aerosol paint to be more uniformly arranged after spraying, and can enhance the glossiness of the sprayed paint surface coating, so that the surface of the paint surface looks brighter, and the visual effect is improved.
More specifically, the propellant is one or more of liquefied petroleum gas, dimethyl ether, tetrafluoroethane, difluoroethane, carbon dioxide or nitrogen.
The propellant can be propane and butane, and the propane and butane can be liquefied at room temperature under proper pressure, so that the propellant has higher volatility, high safety and convenient use.
The second object of the invention is to provide a preparation method of the anti-fouling aerosol paint, which is used for preparing the anti-fouling aerosol paint, and the preparation method of the anti-fouling aerosol paint comprises the following steps:
s100, adding a solvent into a reaction kettle, stirring, adding a ceramic precursor, resin and a leveling agent in a stirring state, and primarily stirring for 15-30 min;
s200, standing the primarily stirred feed liquid for 10-20 min, and stirring again for 10-20 min to obtain the final feed liquid;
s300, filling the final feed liquid, filling a propellant, and testing in a water bath to obtain a final product without side leakage. The water bath test process adopts a water bath at 50-55 ℃ to detect leakage, and the filled aerosol paint can is put into water to observe whether the bottle has a leakage point with continuous bubbling.
In the feed liquid preparation process of the aerosol paint, the mode of preliminary stirring and then standing and then stirring again is adopted for production, so that all parts of the feed liquid can be effectively and evenly mixed, the precipitation of the feed liquid can be reduced, and the quality of the aerosol paint is ensured.
It is noted that in practical application, the present application needs to calculate the safe filling amount according to the density of the final material liquid and the density of the propellant, and perform the steps of feeding, material liquid filling, valve feeding, sealing, propellant filling, water bath testing, air drying, button mounting and protective cover according to the calculated safe filling amount, so as to obtain the anti-fouling aerosol paint finished product.
Example 1
The embodiment provides an anti-fouling aerosol paint, which comprises the following components in percentage by weight:
10 parts of ceramic precursor;
4 parts of resin;
35 parts of solvent;
0.02 part of leveling agent;
40-50 parts of propellant.
More specifically, the ceramic precursor of the application is polysilazane ceramic precursor, the resin is FEVE solvent type tetrafluorofluorocarbon resin, the solvent is alkane solvent, the leveling agent is organic silicon type leveling agent, and the propellant is propane butane.
The polysilazane ceramic precursor is an organic silicon resin composed of repeated Si-N units, can be crosslinked and solidified or cracked into amorphous ceramic at room temperature or under the condition of heating, and can improve the water resistance and solvent resistance of the product, the adhesive force of the product, the hardness and the wear resistance of the product in the formula of the aerosol paint. The FEVE solvent type tetrafluoro fluorocarbon resin has the characteristics of non-tackiness, non-wettability and low friction coefficient, and can improve the hydrophobic and oleophobic properties of paint surfaces, make water stains, ink and wax difficult to adhere to the paint surfaces and reduce the residual stain after being compounded and cured with other components of the aerosol paint. The alkane solvent is compatible with polysilazane ceramic precursor and FEVE solvent tetrafluoro fluorocarbon resin, is easy to volatilize, has good environmental protection and stability, and is used as a diluent. The leveling agent can reduce the initial paint surface tension of the aerosol paint after being sprayed out of the tank body, keep the paint surface smooth, improve the gloss of the paint surface, and has good phase with the polysilazane ceramic precursor, and the hydrophobic property of the paint surface can be enhanced after the later-stage paint surface is solidified. The compatibility and stability of the propane-butane, polysilazane ceramic precursor and FEVE solvent tetrafluoro fluorocarbon resin are good, the atomization effect can be regulated by regulating the proportion of propane and butane, and different use effects can be presented in different environments.
Example 2
The embodiment provides an anti-fouling aerosol paint, which comprises the following components in percentage by weight:
15 parts of ceramic precursor;
5.8 parts of resin;
40 parts of solvent;
0.1 part of leveling agent;
50 parts of propellant;
5 parts of anti-settling agent.
More specifically, the ceramic precursor of the application is polysilazane ceramic precursor, the resin of the embodiment is PTFE series fluorocarbon resin, the solvent is alkane solvent, the leveling agent is organic silicon leveling agent, and the propellant is propane butane. The anti-settling agent is colloid anti-settling agent.
Because PTFE series fluorocarbon resin is not easily dissolved in solvent, the anti-fouling aerosol paint of the application is also added with an anti-settling agent for reducing the settling of feed liquid, besides the advantages of the aerosol paint described in the embodiment 1, the settling of the aerosol paint in a tank or a nozzle can be prevented, and the uniformity and consistency of the content of the aerosol paint can be improved.
The method for manufacturing the antifouling aerosol paint of the embodiment is as follows:
adding the solvent into a reaction kettle, stirring, adding the ceramic precursor, the resin and the flatting agent in a stirring state, and primarily stirring for 15-30 min;
standing the primarily stirred feed liquid for 10-20 min, adding an anti-settling agent, and stirring for 10-20 min again to obtain a final feed liquid;
and (3) filling the final feed liquid, filling a propellant, and testing in a water bath to obtain a final product without side leakage.
Example 3
The embodiment provides an anti-fouling aerosol paint, which comprises the following components in percentage by weight:
13 parts of ceramic precursor;
5 parts of resin;
38 parts of a solvent;
0.05 part of leveling agent;
47 parts of propellant;
7 parts of anti-settling agent.
More specifically, the ceramic precursor of the application is polysilazane ceramic precursor, the resin is PTFE series fluorocarbon resin, the solvent is alkane solvent, the leveling agent is organic silicon type leveling agent, and the propellant is propane butane. The anti-settling agent is colloid anti-settling agent.
The aerosol paint and the common aerosol paint which are claimed to be protected in the application are used under the same environmental condition, different effects of the aerosol paint and the common aerosol paint are compared, and specific comparison effects are shown in the following table:
table 1 anti-fouling aerosol paint and conventional aerosol paint effect comparison table of the present application
As can be seen from Table 1, the aerosol paint claimed in the present application has excellent performances in terms of glossiness, hardness, abrasion resistance, water resistance, solvent resistance, hydrophobicity, oleophobicity and the like, and has good capabilities of preventing water pens and oil pen marks.
The technical features of the above-described embodiments may be arbitrarily combined, and all possible combinations of the technical features in the above-described embodiments are not described for brevity of description, however, as long as there is no contradiction between the combinations of the technical features, they should be considered as the scope of the description.
The relative arrangement of the components and steps, numerical values set forth in these embodiments do not limit the scope of the present application unless specifically stated otherwise. Meanwhile, techniques, methods and apparatuses known to those of ordinary skill in the related art may not be discussed in detail, but should be regarded as part of the specification of authority where appropriate. In all examples shown and discussed herein, any specific values should be construed as merely illustrative, and not a limitation. Thus, other examples of the exemplary embodiments may have different values. It should be noted that: like reference numerals and letters denote like items in the following figures, and thus once an item is defined in one figure, no further discussion thereof is necessary in subsequent figures.

Claims (10)

1. An antifouling aerosol paint is characterized by comprising the following components in percentage by weight:
10-15 parts of ceramic precursor;
4-6 parts of resin;
35-40 parts of solvent;
0.01 to 0.1 part of leveling agent;
40-50 parts of propellant.
2. An antifouling aerosol paint according to claim 1, wherein:
the ceramic precursor comprises one or a combination of a plurality of organic polymer precursors, metal organic precursors, silicone rubber precursors, silazane precursors and oxide precursors.
3. An antifouling aerosol paint according to claim 2, wherein:
the ceramic precursor is polysilazane ceramic precursor.
4. An antifouling aerosol paint according to claim 1, wherein:
the resin is one or a combination of more of acrylic resin, tetrafluoro fluorocarbon resin, aldehyde ketone resin, alkyd resin and phenolic resin.
5. An antifouling aerosol paint according to claim 4, wherein:
the resin is a composition of tetrafluoro fluorocarbon resin and aldehyde ketone resin, and the ratio of tetrafluoro fluorocarbon resin to aldehyde ketone resin is 2-5:1.
6. An antifouling aerosol paint according to claim 4, wherein:
the resin is FEVE solvent type tetrafluorofluorocarbon resin.
7. An antifouling aerosol paint according to claim 1, wherein:
the solvent is one or a combination of more of isohexane, heptane, octane, 120# solvent naphtha, 120# petroleum ether and 60-90 petroleum ether.
8. An antifouling aerosol paint according to claim 1, wherein:
the leveling agent is an organosilicon leveling agent or an organosilicon oil diluent.
9. An antifouling aerosol paint according to claim 1, wherein:
the propellant is one or more of liquefied petroleum gas, dimethyl ether, tetrafluoroethane, difluoroethane, carbon dioxide or nitrogen.
10. A method for preparing an anti-fouling aerosol paint, characterized in that it is used for preparing an anti-fouling aerosol paint according to any one of claims 1 to 9, comprising the steps of:
adding the solvent into a reaction kettle, stirring, adding the ceramic precursor, the resin and the flatting agent in a stirring state, and primarily stirring for 15-30 min;
standing the primarily stirred feed liquid for 10-20 min, and stirring again for 10-20 min to obtain the final feed liquid;
and (3) filling the final feed liquid, filling a propellant, and obtaining a final product after water bath testing without side leakage.
CN202311571790.4A 2023-11-22 2023-11-22 Anti-fouling aerosol paint and preparation method thereof Pending CN117801575A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202311571790.4A CN117801575A (en) 2023-11-22 2023-11-22 Anti-fouling aerosol paint and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202311571790.4A CN117801575A (en) 2023-11-22 2023-11-22 Anti-fouling aerosol paint and preparation method thereof

Publications (1)

Publication Number Publication Date
CN117801575A true CN117801575A (en) 2024-04-02

Family

ID=90432598

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202311571790.4A Pending CN117801575A (en) 2023-11-22 2023-11-22 Anti-fouling aerosol paint and preparation method thereof

Country Status (1)

Country Link
CN (1) CN117801575A (en)

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