CN117758135A - A kind of wear-resistant steel ball and its production process - Google Patents
A kind of wear-resistant steel ball and its production process Download PDFInfo
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 94
- 239000010959 steel Substances 0.000 title claims abstract description 94
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 28
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 60
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 54
- 239000000126 substance Substances 0.000 claims abstract description 31
- 229910052742 iron Inorganic materials 0.000 claims abstract description 30
- 239000000463 material Substances 0.000 claims abstract description 21
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 20
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 16
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 16
- 239000012535 impurity Substances 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 7
- 238000001816 cooling Methods 0.000 claims description 55
- 238000005266 casting Methods 0.000 claims description 14
- 238000004321 preservation Methods 0.000 claims description 14
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000000465 moulding Methods 0.000 claims description 10
- 229910052802 copper Inorganic materials 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- 229910052786 argon Inorganic materials 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 238000003723 Smelting Methods 0.000 claims description 5
- 229910045601 alloy Inorganic materials 0.000 abstract description 4
- 239000000956 alloy Substances 0.000 abstract description 4
- 239000011651 chromium Substances 0.000 description 54
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 36
- 239000000203 mixture Substances 0.000 description 25
- 229910001018 Cast iron Inorganic materials 0.000 description 24
- 238000000227 grinding Methods 0.000 description 19
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 17
- 150000001247 metal acetylides Chemical class 0.000 description 16
- 229910001566 austenite Inorganic materials 0.000 description 15
- 239000011572 manganese Substances 0.000 description 12
- 239000011159 matrix material Substances 0.000 description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 9
- 230000005496 eutectics Effects 0.000 description 9
- 239000010703 silicon Substances 0.000 description 9
- 239000004615 ingredient Substances 0.000 description 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000006104 solid solution Substances 0.000 description 5
- 229910052729 chemical element Inorganic materials 0.000 description 4
- 239000011733 molybdenum Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910000734 martensite Inorganic materials 0.000 description 3
- 229910001562 pearlite Inorganic materials 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
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- 229910001567 cementite Inorganic materials 0.000 description 2
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- 238000005516 engineering process Methods 0.000 description 2
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- SKIIKRJAQOSWFT-UHFFFAOYSA-N 2-[3-[1-(2,2-difluoroethyl)piperidin-4-yl]oxy-4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]pyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound FC(CN1CCC(CC1)OC1=NN(C=C1C=1C=NC(=NC=1)NC1CC2=CC=CC=C2C1)CC(=O)N1CC2=C(CC1)NN=N2)F SKIIKRJAQOSWFT-UHFFFAOYSA-N 0.000 description 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- 229910001037 White iron Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
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- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910001349 ledeburite Inorganic materials 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
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- 230000000717 retained effect Effects 0.000 description 1
- 238000004901 spalling Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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Abstract
Description
技术领域Technical field
本申请涉及耐磨材料技术领域,更具体地说,它涉及一种耐磨钢球及其生产工艺。The present application relates to the technical field of wear-resistant materials, and more specifically, it relates to a wear-resistant steel ball and its production process.
背景技术Background technique
耐磨钢球广泛用于冶金、选矿、煤碳、水泥、化工等行业,磨球的全球年消耗量约500~600万吨,而且需求量将会逐步增加。Wear-resistant steel balls are widely used in metallurgy, mineral processing, coal, cement, chemical and other industries. The global annual consumption of grinding balls is about 5 to 6 million tons, and the demand will gradually increase.
以铸造工艺生产成形的铸造磨球主要通过控制铸造材料中合金元素的含量、种类和成型模具等条件,制备出具有不同性能、尺寸的耐磨钢球,铬系铸铁是最常见的磨球材料,根据含铬量的多少,铬系铸铁可分为低铬,中铬和高铬铸铁,低铬铸铁含铬量0.5-2.5%之间,中铬铸铁的含铬量3.0-7.0%之间,高铬铸铁的含铬量≥10.0%,低、中铬铸铁磨球耐磨性是低碳钢球的数倍,但是破碎率较高。高铬铸铁含有大量高硬度的初生和共晶碳化物,破碎率低,有良好的耐蚀性,但韧性的不足,限制了其在工业领域的应用范围。The cast grinding balls formed by the casting process are mainly produced by controlling the content and type of alloy elements in the casting material and the forming mold and other conditions to prepare wear-resistant steel balls with different properties and sizes. Chromium cast iron is the most common grinding ball material. According to the chromium content, chromium cast iron can be divided into low chromium, medium chromium and high chromium cast iron. The chromium content of low chromium cast iron is between 0.5-2.5%, and the chromium content of medium chromium cast iron is between 3.0-7.0%. , the chromium content of high chromium cast iron is ≥10.0%. The wear resistance of low and medium chromium cast iron grinding balls is several times that of low carbon steel balls, but the breakage rate is higher. High-chromium cast iron contains a large amount of high-hardness primary and eutectic carbides, has a low breakage rate, and has good corrosion resistance. However, its lack of toughness limits its application scope in the industrial field.
相关技术中,通过在钢球成分中掺入钇等贵金属元素,但其会增加成本,难以满足现实需求。In the related technology, precious metal elements such as yttrium are mixed into the steel ball composition, but this will increase the cost and make it difficult to meet actual needs.
发明内容Contents of the invention
为了克服上述缺陷,提高的耐磨钢球的冲击韧性,本申请提供了一种耐磨钢球及其生产工艺。In order to overcome the above defects and improve the impact toughness of the wear-resistant steel ball, this application provides a wear-resistant steel ball and its production process.
第一方面,本申请提供一种耐磨钢球,其采用如下技术方案:In the first aspect, this application provides a wear-resistant steel ball, which adopts the following technical solution:
一种耐磨钢球,钢球的化学成分重量百分比为:C 3.0-3.2%,Cr 11-26%,Si0.3-1.2%,Mn 1.2-2.6%,Ni 0-1.5%,P≤0.1%,S≤0.1%,Cu 0-2.0%,其余为铁以及不可避免的杂质。A kind of wear-resistant steel ball, the chemical composition weight percentage of the steel ball is: C 3.0-3.2%, Cr 11-26%, Si0.3-1.2%, Mn 1.2-2.6%, Ni 0-1.5%, P≤0.1 %, S≤0.1%, Cu 0-2.0%, the rest is iron and inevitable impurities.
本申请耐磨钢球的化学成分重量百分比为:C 3.0-3.2%,Cr 11-26%,Si 0.3-1.2%,Mn 1.2-2.6%,Ni 0-1.5%,P≤0.1%,S≤0.1%,Cu 0-2.0%,其余为铁以及不可避免的杂质,可选用各自范围内的任一值,且能提高的耐磨钢球的冲击韧性。The chemical composition weight percentage of the wear-resistant steel ball in this application is: C 3.0-3.2%, Cr 11-26%, Si 0.3-1.2%, Mn 1.2-2.6%, Ni 0-1.5%, P≤0.1%, S≤ 0.1%, Cu 0-2.0%, the rest is iron and inevitable impurities, any value within the respective ranges can be selected, and the impact toughness of the wear-resistant steel ball can be improved.
本申请耐磨钢球中各化学元素起到如下作用:Each chemical element in the wear-resistant steel ball of this application plays the following roles:
碳元素(C):碳是高铬铸铁磨球中最核心、最基本的化学元素。碳元素与铁元素等结合成为渗碳体,在基体中以先析出渗碳体或莱氏体组成部分存在,成为基体中的耐磨组分。碳元素以间隙固溶体的方式固溶在基体中,提高基体本身的硬度和耐冲击韧性。Carbon element (C): Carbon is the core and most basic chemical element in high chromium cast iron grinding balls. Carbon elements combine with iron elements to form cementite, which exists in the matrix as a component of cementite or ledeburite that precipitates first and becomes a wear-resistant component in the matrix. The carbon element is solidly dissolved in the matrix in the form of interstitial solid solution, improving the hardness and impact resistance toughness of the matrix itself.
铬元素(Cr):铬是高铬铸铁磨球中最核心、最基本的化学元素。铬有助于提高铸铁的硬度、韧性和淬透性。在共晶凝固时,合金中铬大部分消耗于碳化物中,从而使碳化物中的铬浓度高于奥氏体中。在白口铸铁中,随着铬含量的增加,共晶温度逐渐提高。此外,铬含量也会影响共晶碳化物的大小和形状。提高铬的含量,阻止了石墨的形成,也有助于提高碳化物的数量。工艺上常用调整碳含量来改变碳化物量,在实际生产中,铬一般要和碳合理地搭配使用,以达到提高磨球硬度、韧性的目的。Chromium (Cr): Chromium is the core and most basic chemical element in high-chromium cast iron grinding balls. Chromium helps increase the hardness, toughness and hardenability of cast iron. During eutectic solidification, most of the chromium in the alloy is consumed in carbides, resulting in a higher chromium concentration in carbides than in austenite. In white cast iron, as the chromium content increases, the eutectic temperature gradually increases. In addition, the chromium content also affects the size and shape of the eutectic carbides. Increasing the chromium content prevents the formation of graphite and also helps to increase the number of carbides. In technology, it is common to adjust the carbon content to change the amount of carbides. In actual production, chromium is generally used in a reasonable combination with carbon to achieve the purpose of improving the hardness and toughness of the grinding ball.
碳及铬元素,碳是高铬铸铁磨球中最核心、最基本的化学元素,可以通过改变C含量来调整碳化物数量,较高的C含量会形成较多的碳化物,甚至初生碳化物,这将使耐磨性能提高而韧性降低。为了在最大范围内提升硬度,耐磨性和冲击韧性,必须加入一定量的铬进行配合。高铬铸铁磨球中的碳化物类型与Cr/C在合适的比例内,会使M3C碳化物(840-1100HV)向M7C碳化物(1300-1800HV)的转变,此时高铬铸铁磨球的硬度和韧性就越高。但是,M3C的增大要遵守一定的原则,即碳含量要保持在一定的范围之内,如果碳含量过低就会造成碳化物减少,耐磨性能也会变差,增加碳含量会提高高铬铸铁磨球的硬度和耐磨性,但碳含量高于一定值时会降低材料的抗热裂性和抗剥落性,进而降低其耐磨性。通过改变M3C相对含量,可以获得所需的碳化物类型和基体组织。Carbon and chromium elements. Carbon is the core and most basic chemical element in high-chromium cast iron grinding balls. The number of carbides can be adjusted by changing the C content. A higher C content will form more carbides and even primary carbides. , which will increase the wear resistance and reduce the toughness. In order to improve the hardness, wear resistance and impact toughness to the greatest extent, a certain amount of chromium must be added for coordination. The carbide type and Cr/C in the high chromium cast iron grinding ball are within the appropriate ratio, which will cause the transformation of M 3 C carbide (840-1100HV) to M 7 C carbide (1300-1800HV). At this time, the high chromium The higher the hardness and toughness of cast iron grinding balls. However, the increase of M 3 C must abide by certain principles, that is, the carbon content must be kept within a certain range. If the carbon content is too low, carbides will decrease and the wear resistance will also become worse. Increasing the carbon content will Improve the hardness and wear resistance of high chromium cast iron grinding balls, but when the carbon content is higher than a certain value, the material's resistance to hot cracking and spalling will be reduced, thereby reducing its wear resistance. By changing the relative content of M 3 C, the required carbide type and matrix structure can be obtained.
硅元素(Si):硅是非碳化物形成元素,主要溶于基体中。硅能影响碳化物形态,使碳化物孤立、等轴、细化。铸铁中硅含量过高时易出现珠光体,使初性下降,且磨损过程中极易产生剥落。此外,硅的加入对冶炼时脱氧及增加铁水流动性有利。硅元素从多个方面影响高铬铸铁磨球的组织。在凝固时的共晶反应过程中,硅含量的上升会促进铬元素更多地扩散进入碳化物中,增加共晶碳化物的析出量,并使奥氏体中的含碳量下降。此外,硅能减小固液两相区的大小,从而细化共晶碳化物,并使其更为弥散地分布在奥氏体中再者,硅在奥氏体中的固溶能起到固溶强化作用,提高基体的性能。Silicon element (Si): Silicon is a non-carbide-forming element and is mainly soluble in the matrix. Silicon can affect the morphology of carbides, making them isolated, equiaxed, and refined. When the silicon content in cast iron is too high, pearlite is likely to appear, which reduces the initial properties and is prone to peeling during wear. In addition, the addition of silicon is beneficial to deoxidation and increasing the fluidity of molten iron during smelting. Silicon element affects the structure of high chromium cast iron grinding balls in many aspects. During the eutectic reaction during solidification, the increase in silicon content will promote more diffusion of chromium elements into carbides, increase the precipitation of eutectic carbides, and decrease the carbon content in austenite. In addition, silicon can reduce the size of the solid-liquid two-phase zone, thereby refining the eutectic carbide and making it more dispersedly distributed in austenite. Furthermore, the solid solution of silicon in austenite can play a role in Solid solution strengthening effect improves the performance of the matrix.
锰元素(Mn):锰元素是较为廉价的固溶元素,通常以代位固溶的方式存在,同时Mn具有稳定奥氏体的作用。在高铬铸铁磨球中,锰是常有的元素之一,它并不能单独对高铬铸铁磨球中的组织和碳化物造成影响,但锰是强奥氏体形成元素,能够细化初生和共晶奥氏体相的尺寸,增加碳和铬元素在奥氏体中的溶解度,从而抑制珠光体形成,并能够增加奥氏体的稳定性,提高基体的淬透性。Manganese element (Mn): Manganese element is a relatively cheap solid solution element, which usually exists in the form of substitutional solid solution. At the same time, Mn has the function of stabilizing austenite. In high chromium cast iron grinding balls, manganese is one of the common elements. It cannot alone affect the structure and carbides in high chromium cast iron grinding balls. However, manganese is a strong austenite forming element and can refine the primary and the size of the eutectic austenite phase, increasing the solubility of carbon and chromium elements in austenite, thereby inhibiting the formation of pearlite, increasing the stability of austenite, and improving the hardenability of the matrix.
镍元素(Ni):镍能够扩大奥氏体相区,是稳定奥氏体的合金元素。镍的加入能够降低MSA,使基体由奥氏体组成而不易形成马氏体或其他奥氏体分解产物。但是当镍含量过高时,组织中难以避免会存在过冷奥氏体,同时,镍的加入还可以明显提高高铬铸铁磨球的抗氧化性。Nickel element (Ni): Nickel can expand the austenite phase area and is an alloy element that stabilizes austenite. The addition of nickel can reduce MSA , making the matrix composed of austenite and making it less likely to form martensite or other austenite decomposition products. However, when the nickel content is too high, it is inevitable that supercooled austenite will exist in the structure. At the same time, the addition of nickel can also significantly improve the oxidation resistance of high-chromium cast iron grinding balls.
作为优选:所述钢球的化学成分重量百分比为:C 3.0-3.2%,Cr 16-22%,Si0.3-1.2%,Mn 1.2-2.6%,Ni 0-1.5%,P≤0.1%,S≤0.1%,Cu 0-2.0%,其余为铁以及不可避免的杂质。其余为铁以及不可避免的杂质。Preferably: the chemical composition weight percentage of the steel ball is: C 3.0-3.2%, Cr 16-22%, Si0.3-1.2%, Mn 1.2-2.6%, Ni 0-1.5%, P≤0.1%, S≤0.1%, Cu 0-2.0%, the rest is iron and inevitable impurities. The remainder is iron and unavoidable impurities.
本申请钢球的化学成分重量百分比为C 3.0-3.2%,Cr 16-22%,Si 0.3-1.2%,Mn1.2-2.6%,Ni 0-1.5%,P≤0.1%,S≤0.1%,Cu 0-2.0%,其余为铁以及不可避免的杂质。其余为铁以及不可避免的杂质,可选用各自范围内的任一值,均能提高的耐磨钢球冲击韧性。The chemical composition weight percentage of the steel ball in this application is C 3.0-3.2%, Cr 16-22%, Si 0.3-1.2%, Mn 1.2-2.6%, Ni 0-1.5%, P≤0.1%, S≤0.1% , Cu 0-2.0%, the rest is iron and inevitable impurities. The rest is iron and inevitable impurities. Any value within the respective range can be selected to improve the impact toughness of the wear-resistant steel ball.
作为优选:所述钢球的化学成分重量百分比为:C 3.0-3.2%,Cr 16-22%,Si0.3-1.2%,Mn 1.2-2.6%,Ni 0-1.5%,P≤0.1%,S≤0.1%,Cu 0-2.0%,Mo 1.5-3.0%,其余为铁以及不可避免的杂质。Preferably: the chemical composition weight percentage of the steel ball is: C 3.0-3.2%, Cr 16-22%, Si0.3-1.2%, Mn 1.2-2.6%, Ni 0-1.5%, P≤0.1%, S≤0.1%, Cu 0-2.0%, Mo 1.5-3.0%, the rest is iron and inevitable impurities.
通过采用上述技术方案,钼元素(Mo)加入到高铬铸铁磨球中,可以改善材料的性能。钼能有效地推迟珠光体转变,但很少影响马氏体转变温度,从而获得更多的残余奥氏体,提高了高铬铸铁磨球的冲击韧性。此外,当钼含量达到一定程度后,空冷即可使基体充分硬化。由于钼元素为强碳化物形成元素,极易与碳形成Mo2C碳化物,其硬度可以达到1800-2200HV,较M7C3更硬,但是它们尺寸更小,且广泛分布于共晶组织中,能够显著提高高铬铸铁磨球的耐磨性能。By adopting the above technical solution, molybdenum element (Mo) is added to the high chromium cast iron grinding ball, which can improve the performance of the material. Molybdenum can effectively delay pearlite transformation, but rarely affects martensite transformation temperature, thereby obtaining more retained austenite and improving the impact toughness of high-chromium cast iron grinding balls. In addition, when the molybdenum content reaches a certain level, air cooling can fully harden the matrix. Since molybdenum is a strong carbide-forming element, it can easily form Mo 2 C carbide with carbon. Its hardness can reach 1800-2200HV, which is harder than M 7 C 3 , but they are smaller in size and widely distributed in the eutectic structure. , which can significantly improve the wear resistance of high chromium cast iron grinding balls.
第二方面,本申请提供一种上述所述的耐磨钢球的生产工艺。In a second aspect, this application provides a production process for the above-mentioned wear-resistant steel ball.
一种耐磨钢球的生产工艺,包括如下步骤:A production process for wear-resistant steel balls includes the following steps:
S1配料:将各原料按照上述成分进行配料;S1 batching: batch each raw material according to the above ingredients;
S2电炉熔炼:在真空、氩气条件下,将S1配好的料,升温到1500-1800℃使各物质熔化后成铁水后,停止加热;S2 electric furnace melting: Under vacuum and argon conditions, heat the materials prepared in S1 to 1500-1800°C to melt each substance into molten iron, then stop heating;
S3浇筑成型:将S2得到的铁水降温到1100-1500℃,然后浇铸进模具内得到铸造球;S3 pouring molding: Cool the molten iron obtained in S2 to 1100-1500°C, and then pour it into the mold to obtain a casting ball;
S4冷却:将S3得到的铸造球水冷到20-25℃即可。S4 cooling: water-cool the cast ball obtained in S3 to 20-25°C.
通过采用上述技术方案,S1中将各原料按照上述成分进行配料在真空、氩气条件下,可减少气体和杂质的含量,将配好的料,升温到1500-1800℃使各物质熔化后成铁水后,停止加热;然后将铁水降温到1100-1500℃时,使钢水在浇筑成型时具有较好的流动性,有利于填充模具,并且在凝固过程中能够获得良好的结晶组织和物理性能,然后将铸造球水冷,水冷降温可以快速降低钢球的温度,防止过热造成钢球的变形或者内部组织结构的不均匀,降温到20-25℃即可得到耐磨钢球。By adopting the above technical solution, in S1, the raw materials are batched according to the above ingredients under vacuum and argon conditions, which can reduce the content of gases and impurities. The prepared materials are heated to 1500-1800°C to melt each substance and become After the molten iron is poured, stop heating; then cool the molten iron to 1100-1500°C, so that the molten steel has better fluidity during pouring and molding, which is conducive to filling the mold, and good crystallographic structure and physical properties can be obtained during the solidification process. The cast ball is then water-cooled. Water-cooling cooling can quickly reduce the temperature of the steel ball and prevent overheating from causing deformation of the steel ball or uneven internal structure. Wear-resistant steel balls can be obtained by cooling the ball to 20-25°C.
作为优选:所述S3浇筑成型中降温到1100-1500℃步骤后,还包括保温步骤;所述保温的时间为60-120s。Preferably: after the step of cooling down to 1100-1500°C during the S3 pouring and molding, a heat preservation step is also included; the heat preservation time is 60-120s.
通过采用上述技术方案,调节铁水温度在1100-1500℃后进行保温60-120s是为了确保钢水的温度均匀和稳定,使高铬耐磨钢材料达到较好的流动性,使熔融的高铬耐磨钢材料可以充分混合并达到均匀的温度分布,有助于提高浇铸成型的质量和一致性,还有助于去除钢水中的气体和杂质,提高耐磨钢球的韧性和强度。By adopting the above technical solution, adjusting the temperature of the molten iron to 1100-1500°C and then holding it for 60-120 seconds is to ensure that the temperature of the molten steel is uniform and stable, so that the high-chromium wear-resistant steel material can achieve better fluidity, and the molten high-chromium wear-resistant steel material can be kept warm for 60-120 seconds. Grinding steel materials can be fully mixed and achieve uniform temperature distribution, which helps to improve the quality and consistency of casting molding. It also helps to remove gas and impurities in molten steel and improve the toughness and strength of wear-resistant steel balls.
作为优选:所述S4冷却步骤中还包括保温步骤;所述保温步骤为:当铸造球从1100-1500℃水冷降温到800-920℃时,保温50-70min。Preferably: the S4 cooling step also includes a heat preservation step; the heat preservation step is: when the cast ball is water-cooled from 1100-1500°C to 800-920°C, the temperature is maintained for 50-70 minutes.
通过采用上述技术方案,水冷降温到800-920℃,使铸造球组织内马氏体增多,组织结构得到细化,保温50-70min可以让钢球内部的组织结构得到充分的调整和稳定,从而提高耐磨钢球的韧性和强度。By adopting the above technical solution, water cooling to 800-920°C will increase the martensite in the cast ball structure and refine the organizational structure. The heat preservation for 50-70 minutes can fully adjust and stabilize the internal organizational structure of the steel ball. Improve the toughness and strength of wear-resistant steel balls.
作为优选:所述热处理步骤的水冷步骤后还包括空冷步骤。Preferably: the heat treatment step further includes an air cooling step after the water cooling step.
通过采用上述技术方案,将铸造球水冷再进行空冷,可以促使近球状的碳化物形成,使碳原子重新分布,从而减少碳化物的尺寸和数量,小尺寸颗粒析出,可以使铸造球的组织变得更加均匀,而且还可以缓解材料内部由于淬火过程中的快速冷却导致的残余应力,从而提高材料的韧性。By adopting the above technical solution, the casting ball is water-cooled and then air-cooled, which can promote the formation of nearly spherical carbides and redistribute carbon atoms, thereby reducing the size and quantity of carbides, and precipitating small-sized particles, which can change the structure of the cast ball. It is more uniform, and it can also alleviate the residual stress inside the material caused by the rapid cooling during quenching, thereby improving the toughness of the material.
作为优选:所述空冷步骤为:将铸造球在20-25℃的流动空气中冷却到400-600℃时,保温50-70min后,再自然冷却到20-25℃。Preferably: the air cooling step is: cooling the cast ball to 400-600°C in flowing air at 20-25°C, holding it for 50-70 minutes, and then cooling it naturally to 20-25°C.
通过采用上述技术方案,调节空冷到400-600℃,保温50-70min,可以进一步使铸造球的组织变得均匀,进一步减少材料内部的残余应力,提高材料的韧性。By adopting the above technical solution, adjusting the air cooling to 400-600°C and holding the temperature for 50-70 minutes, the structure of the cast ball can be further made uniform, the residual stress inside the material can be further reduced, and the toughness of the material can be improved.
综上所述,本申请包括以下至少一种有益技术效果:To sum up, this application includes at least one of the following beneficial technical effects:
(1)本申请通过调节耐磨钢球的化学成分种类和化学成分,得到耐磨钢球的钢球表面硬度、钢球心部硬度和冲击韧性分别为61.2-61.7HRC、59.5-60.0HRC和3.4-3.9J/cm2,提高了钢球的硬度和耐冲击韧性。(1) In this application, by adjusting the chemical composition type and chemical composition of the wear-resistant steel ball, the surface hardness, core hardness and impact toughness of the wear-resistant steel ball are respectively 61.2-61.7HRC, 59.5-60.0HRC and 3.4-3.9J/cm 2 , which improves the hardness and impact resistance toughness of the steel ball.
(2)本申请通过调节耐磨钢球生产工艺中浇铸和冷却步骤,使得到耐磨钢球的钢球表面硬度、钢球心部硬度和冲击韧性分别为62.0-62.7HRC、60.2-60.8HRC和4.2-4.8J/cm2,进一步提高了钢球的硬度和耐冲击韧性。(2) In this application, by adjusting the casting and cooling steps in the wear-resistant steel ball production process, the surface hardness, core hardness and impact toughness of the wear-resistant steel ball are 62.0-62.7HRC and 60.2-60.8HRC respectively. and 4.2-4.8J/cm 2 , further improving the hardness and impact resistance toughness of the steel ball.
因此,本申请通过在抗磨钢球原料中调节各个元素含量,使Cr/C在合适的比例内,并加入钼元素,同时调控生产工艺,使得到的钢球表面硬度、钢球心部硬度和冲击韧性最高分别为62.7HRC、60.8HRC和4.8J/cm2,且其耐疲劳寿命均大于18000次数,硬度和韧性均不同程度提高。Therefore, this application adjusts the content of each element in the raw material of the anti-wear steel ball to make Cr/C within the appropriate ratio, and adds molybdenum element, while regulating the production process, so that the obtained steel ball surface hardness and steel ball core hardness The highest impact toughness and impact toughness are 62.7HRC, 60.8HRC and 4.8J/cm 2 respectively, and its fatigue life is greater than 18,000 times, and the hardness and toughness are improved to varying degrees.
附图说明Description of the drawings
图1是本申请提供的生产工艺的流程图。Figure 1 is a flow chart of the production process provided by this application.
具体实施方式Detailed ways
以下结合具体实施例对本申请作进一步详细说明。The present application will be further described in detail below with reference to specific embodiments.
本申请中的如下各原料均为市售产品,均为使本申请的各原料得以公开充分,不应当理解为对原料的来源产生限制作用。The following raw materials in this application are all commercially available products. They are all used to fully disclose the raw materials in this application and should not be understood as limiting the source of the raw materials.
本申请钢球的各元素原材料包括碳块、单晶硅块、锰片、铬块、钼条,其余为纯度为99.9%的铁块;The raw materials of each element of the steel ball in this application include carbon blocks, single crystal silicon blocks, manganese flakes, chromium blocks, molybdenum strips, and the rest are iron blocks with a purity of 99.9%;
实施例Example
以下以制备规格为直径10mm的钢球为例The following is an example of preparing a steel ball with a diameter of 10mm.
实施例1Example 1
实施例1的钢球,通过如下生产工艺制得:The steel ball of Example 1 is produced through the following production process:
S1配料:按照表1的化学成分,将各原料按照上述成分进行配料;S1 ingredients: According to the chemical composition in Table 1, mix each raw material according to the above ingredients;
S2电炉熔炼:抽真空使真空度达到10-2Pa,并冲入氩气,将S1配好的料,升温到1650℃使各物质熔化后成铁水后,停止加热;S2 electric furnace smelting: evacuate to make the vacuum degree reach 10 -2 Pa, and rush in argon gas. Heat the materials prepared in S1 to 1650°C to melt each substance and turn it into molten iron, then stop heating;
S3浇筑成型:将S2得到的铁水降温到1100℃,然后浇铸进模具内得到铸造球;S3 pouring molding: Cool the molten iron obtained in S2 to 1100°C, and then pour it into the mold to obtain a casting ball;
S4冷却:将S3得到的铸造球用水冷到25℃即得耐磨钢球。S4 cooling: Cool the cast ball obtained in S3 with water to 25°C to obtain a wear-resistant steel ball.
实施例2Example 2
实施例2的钢球,通过如下生产工艺制得:The steel ball of Example 2 is produced through the following production process:
S1配料:按照表1的化学成分,将各原料按照上述成分进行配料;S1 ingredients: According to the chemical composition in Table 1, mix each raw material according to the above ingredients;
S2电炉熔炼:抽真空使真空度达到10-2Pa,并冲入氩气,将S1配好的料,升温到1650℃使各物质熔化后成铁水后,停止加热;S2 electric furnace smelting: evacuate to make the vacuum degree reach 10 -2 Pa, and rush in argon gas. Heat the materials prepared in S1 to 1650°C to melt each substance and turn it into molten iron, then stop heating;
S3浇筑成型:将S2得到的铁水降温到1300℃,然后浇铸进模具内得到铸造球;S3 pouring molding: Cool the molten iron obtained in S2 to 1300°C, and then pour it into the mold to obtain a casting ball;
S4冷却:将S3得到的铸造球用水冷到25℃即得耐磨钢球。S4 Cooling: Cool the cast ball obtained in S3 with water to 25°C to obtain a wear-resistant steel ball.
实施例3Example 3
实施例3的钢球,通过如下生产工艺制得:The steel ball of Example 3 is produced through the following production process:
S1配料:按照表1的化学成分,将各原料按照上述成分进行配料;S1 ingredients: According to the chemical composition in Table 1, mix each raw material according to the above ingredients;
S2电炉熔炼:抽真空使真空度达到10-2Pa,并冲入氩气,将S1配好的料,升温到1650℃使各物质熔化后成铁水后,停止加热;S2 electric furnace smelting: evacuate to make the vacuum degree reach 10 -2 Pa, and rush in argon gas. Heat the materials prepared in S1 to 1650°C to melt each substance and turn it into molten iron, then stop heating;
S3浇筑成型:将S2得到的铁水降温到1500℃,然后浇铸进模具内得到铸造球;S3 pouring molding: Cool the molten iron obtained in S2 to 1500°C, and then pour it into the mold to obtain a casting ball;
S4冷却:将S3得到的铸造球用水冷到20℃即得耐磨钢球。S4 cooling: Cool the cast ball obtained in S3 with water to 20°C to obtain a wear-resistant steel ball.
实施例4-7Example 4-7
实施例4-7的钢球的生产工艺与实施例2相同,区别在于原料化学成分不同,具体详见表1所示。The production process of the steel balls of Examples 4-7 is the same as that of Example 2, except that the chemical composition of the raw materials is different. The details are shown in Table 1.
表1实施例1-7钢球得化学成分重量百分比(%)Table 1 Chemical composition weight percentage (%) of steel balls in Examples 1-7
实施例8-9Example 8-9
实施例8的钢球的化学成分和生产工艺与实施例6相同,区别在于生产工艺中S3浇筑成型中降温到1300℃步骤后,还包括保温步骤;保温的时间分别为60s、120s。The chemical composition and production process of the steel ball in Example 8 are the same as those in Example 6. The difference is that the production process also includes a heat preservation step after the step of cooling to 1300°C during S3 pouring and molding; the heat preservation times are 60s and 120s respectively.
实施例10Example 10
实施例10的钢球的化学成分和生产工艺与实施例8相同,区别在于生产工艺中S4冷却中水冷降温到800℃时,保温70min,即S4冷却步骤具体为:将S3得到的铸造球水冷降温到800℃后,保温70min,然后再水冷到25℃。The chemical composition and production process of the steel ball in Example 10 are the same as those in Example 8. The difference is that in the production process, the water cooling in S4 cooling is followed by 70 minutes of heat preservation when the temperature reaches 800°C. That is, the S4 cooling step is specifically: water-cooling the cast ball obtained in S3. After cooling to 800°C, keep it warm for 70 minutes, and then water-cool to 25°C.
实施例11Example 11
实施例11的钢球的化学成分和生产工艺与实施例8相同,区别在于生产工艺中S4冷却中水冷降温到920℃时,保温50min,即S4冷却步骤具体为:将S3得到的铸造球水冷降温到920℃后,保温50min,然后再水冷到25℃。The chemical composition and production process of the steel ball in Example 11 are the same as those in Example 8. The difference is that in the production process, the water cooling in S4 cooling is followed by 50 minutes of heat preservation when the temperature reaches 920°C. That is, the S4 cooling step is specifically: water-cooling the cast ball obtained in S3. After cooling to 920°C, keep warm for 50 minutes, and then water-cool to 25°C.
实施例12Example 12
实施例12的钢球的化学成分和生产工艺与实施例11相同,区别在于生产工艺中S4冷却并保温后,进行空冷,即S4冷却步骤具体为:将S3得到的铸造球水冷降温到920℃时,保温50min后,将铸造球在25℃的流动空气中冷却到400℃时,保温70min后,再自然冷却到25℃。The chemical composition and production process of the steel ball in Example 12 are the same as those in Example 11. The difference is that in the production process, after S4 is cooled and kept warm, air cooling is performed, that is, the S4 cooling step is specifically: water cooling the cast ball obtained in S3 to 920°C. When the temperature is maintained for 50 minutes, the cast ball is cooled to 400°C in flowing air at 25°C. After being kept for 70 minutes, the cast ball is naturally cooled to 25°C.
实施例13Example 13
实施例13的钢球的化学成分和生产工艺与实施例11相同,区别在于生产工艺中S4冷却并保温后,进行空冷,即S4冷却步骤具体为:将S3得到的铸造球水冷降温到920℃时,保温50min后,将铸造球在25℃的流动空气中冷却到600℃时,保温50min后,再自然冷却到25℃。The chemical composition and production process of the steel ball in Example 13 are the same as those in Example 11. The difference is that in the production process, after S4 is cooled and kept warm, air cooling is performed, that is, the S4 cooling step is specifically: water-cooling the cast ball obtained in S3 to 920°C. When the temperature is maintained for 50 minutes, the cast ball is cooled to 600°C in flowing air at 25°C. After being kept for 50 minutes, the cast ball is naturally cooled to 25°C.
对比例Comparative ratio
对比例1-2Comparative Example 1-2
对比例1-2的钢球的生产工艺与实施例1相同,区别在于原料化学成分不同,具体详见表2所示。The production process of the steel balls of Comparative Example 1-2 is the same as that of Example 1, except that the chemical composition of the raw materials is different. The details are shown in Table 2.
表2对比例1-2钢球得化学成分重量百分比(%)Table 2 Comparative Example 1-2 Steel Ball Chemical Composition Weight Percentage (%)
性能检测Performance testing
采用GB/T 17445.1-2010《耐磨铸造铁球.第1部分:性能》分别对不同的实施例1-13和对比例1-2得到的耐磨钢球进行性能检测,检测结果详见表3所示。GB/T 17445.1-2010 "Wear-resistant Cast Iron Balls. Part 1: Performance" was used to conduct performance testing on the wear-resistant steel balls obtained in different Examples 1-13 and Comparative Examples 1-2. The test results are detailed in the table 3 shown.
表3不同耐磨钢球性能检测结果Table 3 Performance test results of different wear-resistant steel balls
由表3的检测结果表明,本申请得到的耐磨钢球的钢球表面硬度、钢球心部硬度和冲击韧性最高分别为62.7HRC、60.8HRC和4.8J/cm2,且其耐疲劳寿命均大于18000次数,具有较高的硬度和耐冲击韧性和耐疲劳寿命。The test results in Table 3 show that the wear-resistant steel ball obtained in this application has the highest steel ball surface hardness, steel ball core hardness and impact toughness of 62.7HRC, 60.8HRC and 4.8J/cm 2 respectively, and its fatigue life is are more than 18,000 times, with high hardness, impact resistance, toughness and fatigue life.
实施例1-5所得到耐磨钢球的耐疲劳寿命均大于18000次数,实施例4-5的钢球表面硬度、钢球心部硬度和冲击韧性分别为61.4-61.5HRC、59.8HRC和3.5J/cm2,均高于实施例1-3,表明当钢球的化学成分重量百分比为:C 3.0-3.2%,Cr 16-22%,Si 0.3-1.2%,Mn1.2-2.6%,Ni 0-1.5%,P≤0.1%,S≤0.1%,Cu 0-2.0%,其余为铁以及不可避免的杂质时较为合适,提高了钢球的硬度和耐冲击韧性。The fatigue life of the wear-resistant steel balls obtained in Examples 1-5 is greater than 18,000 times. The surface hardness, core hardness and impact toughness of the steel balls in Examples 4-5 are 61.4-61.5HRC, 59.8HRC and 3.5 respectively. J/cm 2 , are higher than those in Examples 1-3, indicating that when the chemical composition weight percentage of the steel ball is: C 3.0-3.2%, Cr 16-22%, Si 0.3-1.2%, Mn 1.2-2.6%, Ni 0-1.5%, P≤0.1%, S≤0.1%, Cu 0-2.0%, the rest is iron and unavoidable impurities. It is more suitable to improve the hardness and impact resistance toughness of the steel ball.
实施例2、6-7所得到耐磨钢球的耐疲劳寿命均大于18000次数,实施例6-7的钢球表面硬度、钢球心部硬度和冲击韧性分别为61.6-61.7HRC、59.9-60.0HRC和3.8-3.9J/cm2,均高于实施例3,表明当钢球的化学成分重量百分比为:C 3.0-3.2%,Cr 16-22%,Si0.3-1.2%,Mn 1.2-2.6%,Ni 0-1.5%,P≤0.1%,S≤0.1%,Cu 0-2.0%,Mo0-3.0%,其余为铁以及不可避免的杂质时较为合适,提高了钢球的硬度和耐冲击韧性。The fatigue life of the wear-resistant steel balls obtained in Examples 2 and 6-7 are both greater than 18,000 times. The surface hardness, core hardness and impact toughness of the steel balls in Examples 6-7 are 61.6-61.7HRC and 59.9- 60.0HRC and 3.8-3.9J/cm 2 , both higher than Example 3, indicating that when the chemical composition weight percentage of the steel ball is: C 3.0-3.2%, Cr 16-22%, Si0.3-1.2%, Mn 1.2 -2.6%, Ni 0-1.5%, P≤0.1%, S≤0.1%, Cu 0-2.0%, Mo0-3.0%, the rest is iron and unavoidable impurities. It is more suitable to improve the hardness and Impact toughness.
实施例6和8-9所得到耐磨钢球的耐疲劳寿命均大于18000次数,实施例8-9的钢球表面硬度、钢球心部硬度和冲击韧性分别为62.0-62.1HRC、60.1-60.2HRC和4.2-4.3J/cm2,高于实施例6,表明当S3浇筑成型中降温到1100-1500℃后保温60-120s时较为合适,提高了钢球的硬度和耐冲击韧性,这可能与调节铁水温度在1100-1500℃后进行保温60-120s,可确保钢水的温度均匀和稳定有关。The fatigue life of the wear-resistant steel balls obtained in Examples 6 and 8-9 are both greater than 18,000 times. The surface hardness, core hardness and impact toughness of the steel balls in Example 8-9 are 62.0-62.1HRC and 60.1-HRC respectively. 60.2HRC and 4.2-4.3J/cm 2 , higher than Example 6, indicating that it is more appropriate to cool down to 1100-1500°C and then hold for 60-120s during S3 casting molding, which improves the hardness and impact resistance toughness of the steel ball. This It may be related to the fact that the temperature of the molten iron is adjusted to 1100-1500°C and then kept warm for 60-120 seconds to ensure that the temperature of the molten steel is uniform and stable.
实施例8和10-11所得到耐磨钢球的耐疲劳寿命均大于18000次数,实施例10-11的钢球表面硬度、钢球心部硬度和冲击韧性分别为62.2-62.3HRC、60.4-60.6HRC和4.4J/cm2,高于实施例8,表明当S4冷却中当铸造球从1100-1500℃水冷降温到800-920℃时,保温50-70min时较为合适,提高了钢球的硬度和耐冲击韧性,这可能与调节铸造球从1100-1500℃水冷降温到800-920℃时,保温50-70min,可使铸造球组织结构细化并稳定有关。The fatigue life of the wear-resistant steel balls obtained in Examples 8 and 10-11 are both greater than 18,000 times. The surface hardness, core hardness and impact toughness of the steel ball in Example 10-11 are 62.2-62.3HRC and 60.4-HRC respectively. 60.6HRC and 4.4J/cm 2 , which are higher than those in Example 8, indicating that when the cast ball is water-cooled from 1100-1500℃ to 800-920℃ during S4 cooling, it is more appropriate to hold it for 50-70min, which improves the performance of the steel ball. Hardness and impact resistance toughness, this may be related to adjusting the water cooling of the cast ball from 1100-1500°C to 800-920°C and keeping it warm for 50-70 minutes, which can refine and stabilize the structure of the cast ball.
实施例11和12-13所得到耐磨钢球的耐疲劳寿命均大于18000次数,实施例12-13的钢球表面硬度、钢球心部硬度和冲击韧性分别为62.5-62.7HRC、60.7-60.8HRC和4.6-4.8J/cm2,高于实施例11,表明当S4冷却中水冷降温保温步骤后进行空冷步骤,并调节空冷步骤为,将铸造球在20-25℃的流动空气中冷却到400-600℃时,保温50-70min后,再自然冷却到20-25℃时较为合适,提高了钢球的硬度和耐冲击韧性,这可能与调节铸造球热处理步骤的水冷步骤后还包括空冷步骤;即将铸造球在20-25℃的流动空气中冷却到400-600℃时,保温50-70min后,再自然冷却到20-25℃,可减少材料内部的残余应力有关。The fatigue life of the wear-resistant steel balls obtained in Examples 11 and 12-13 are both greater than 18,000 times. The surface hardness, core hardness and impact toughness of the steel balls in Examples 12-13 are 62.5-62.7HRC and 60.7- 60.8HRC and 4.6-4.8J/cm 2 , higher than Example 11, indicating that when the water cooling step in S4 cooling is followed by an air cooling step, and the air cooling step is adjusted to cool the cast ball in flowing air at 20-25°C When the temperature reaches 400-600°C, it is more appropriate to keep the temperature for 50-70 minutes and then naturally cool to 20-25°C to improve the hardness and impact resistance toughness of the steel ball. This may be related to the adjustment of the water cooling step after the heat treatment step of the cast ball. Air cooling step: cooling the cast ball to 400-600°C in flowing air at 20-25°C, holding it for 50-70 minutes, and then cooling it naturally to 20-25°C, which can reduce the residual stress within the material.
另外,结合对比例1-2和实施例1的耐磨钢球的各项指标数据发现,本申请在原料中调节各个元素含量,使Cr/C在合适的比例内,并加入钼元素,同时调控生产工艺,使得到的耐磨钢球的硬度和韧性均不同程度提高。In addition, combined with the various index data of the wear-resistant steel balls of Comparative Examples 1-2 and Example 1, it was found that the application adjusted the content of each element in the raw materials to make Cr/C within the appropriate ratio, and added molybdenum element, while The production process is controlled to increase the hardness and toughness of the wear-resistant steel balls to varying degrees.
本具体实施例仅仅是对本申请的解释,其并不是对本申请的限制,本领域技术人员在阅读完本说明书后可以根据需要对本实施例做出没有创造性贡献的修改,但只要在本申请的权利要求范围内都受到专利法的保护。This specific embodiment is only an explanation of the present application, and it is not a limitation of the present application. After reading this specification, those skilled in the art can make modifications to this embodiment without creative contribution as needed, but as long as the rights of this application are All requirements are protected by patent law.
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