CN1176953A - Magnet activated bacleria, full element, and multi-effect fertilizer series, and method for producing same - Google Patents
Magnet activated bacleria, full element, and multi-effect fertilizer series, and method for producing same Download PDFInfo
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Abstract
The complete element fertilizer is composed of micro elements Zn, Fe, Cu, Mn B, Mo, Co and macro elements N, P, K and Ca, Mg, S. it is undergone the organic large molecules compexation and zeolite exchange absorption to activate the microelements, and assisted by fungus and magnet to increase the effect, and further combined with rare earth elements, humic acid, growth regulating agent, pesticide, herbicide, silicon prepn. dried plant powder etc. to form the complete element fertilizer series.
Description
The present invention relates to complete plain multi-effect fertilizer series of a kind of bacterium magnetic activating and method for making thereof, belong to fertilizer and field of fertilizer manufacturing.C05G3/00
Lay particular stress on inorganic elements fertilizer such as using N, P, K, Ca, Mg, S for a long time, regular meeting causes that soil compaction and trace element are weary relatively scarce, and soil fertility descends, ecological damage, and agricultural product quality descends, and total rate of returns can be more and more lower.
The application of trace element fertilizer, remedy it and usually become the problem of limiting factor (" trace element fertilizer " Liu Zheng 1991 Chemical Industry Press P.11), but because liquid fertilizer sprays trouble, and use the influence that is subjected to the edatope situation in the soil, often make Fe, Zn, B, Mn plasma be in non-significant condition, await activation treatment.
Animal dung and other animals and plants organic wastes, single use or directly use, the low and resource-constrained of fertilizer efficiency does not have keying action.
In recent years, the using of rare earth, magnetic iron powder, humic acid, really effectively to plant growth, volume increase, but use loaded down with trivial details, and the compound use of the science that remains.
The rise of bio-feritlizer mushroom fertilizer becomes rising star 1995 press of University of Electronic Science and Technology such as () " bio-feritlizer " Du Binghai, as the emerging fertilizer with great potential, sees at present or better with other fertilizer fit applications.
The present invention releases a kind of many effects fertilizer series that contains the activatory full nutritive element of bacterium magnetic by special prescription and technology.Its principal feature is: 1. adopt organism macromole such as animal dung and other animal and plant waste rich in proteins and hydrolysate amino acid thereof etc., carry out complexation reaction with fertilizer elements such as trace element, rare earth elements.Both made organism macromole hydrolysis " slaking " such as animal dung, and made trace element etc. again by complexing " activation ".Complex state trace element cost height in the past, it is many to be used in foliage-spray, and soil application is restricted.This kind composite reaction uses organism macromole such as the animal dung of crude product state to be used for soil application with trace element reaction complexing, and is not only feasible, but also efficient.In order to quicken this reaction, can add acid, heating.2. adopted zeolite auxiliary simultaneously.Utilize zeolite to have the characteristics of bigger serface and big cation exchange capacity.Fertilizer elements such as free trace element are exchanged, adsorb.This effect of zeolite had both prevented micro-loss or had been fixed, can exchange release in soil again simultaneously in good time, had better solved Fe in the soil, problem that Zn plasma activity is low.Can suppress salinization again simultaneously, improve Soil structure and environment, increase fertilizer efficiency, especially turn into cooperating with above complexing and assist, synergy has fully played the effect of " activation " available fertilizer element.3. add bacterium and magnetic, itself had the usefulness that promotes plant growth, also above activation has been had booster action.4. still can be aided with multiple material becomes multi-functional many effect series fertilizer, adds humic acid as auxilliary, growth regulator, and weedicide, agricultural chemicals etc. become multi-effect fertilizer series.5. all above functional effects also have N, P, K and the Ca, the macroelement such as Mg, S that are fit to soil fertilizer efficiency ratio to add as backing, therefore are called " complete plain ".6. for demands such as the compatibility that cooperates various effective ingredients, dispersion, moulding, add acid supplement, plant materials powder, materials such as binding agents such as flyash and carbon black, silicon sol, starch, water according to different ingredients and process choice.
In a word, the present invention successively exchanges on the basis of activation treatment by complexing, absorption, has made up bacterium magnetic, growth regulator, agricultural chemicals, weedicide etc. and has constituted the multiple-effect energy.And be support with macroelement such as N, P, K, constituted full nutritive element, coordinated the outstanding effect that plays a role, reached main body purpose of the present invention--contain bacterium magnetic activatory full nutritive element multiple-effect can fertilizer series.
The present invention is by organism macromole [A], trace element [B], zeolite [C], mushroom [D], magnetic [E], rare earth [F], humic acid [G], dried plant materials powder [H], macroelement fertilizers [I] such as nitrogen phosphorus potassium and calcium magnesium sulphur, growth regulator [J], flyash and carbon black [K], acid supplement [L], weedicide [M], agricultural chemicals [N], silicon-agent [O], binding agent [P], water [Q] is formed, A+B+C+D+E+F+G+H+I+J+K+L+M+N+O+P+Q=100%, wherein each constituent and content range are: [A] 1-50%, [B] 1-20%, [C] 1-30%, [D] 0.1-5%, [E] 1-10%, [F]≤10%, [G]≤10%, [H]≤15%, [I] 〉=16%, [J]≤1%, [K]≤20%, [L]≤5%, [M]≤5%, [N]≤5%, [O]≤6%, [P]≤10%, [Q]≤30%.Further specify as follows:
[A] organism macromole can derive from animal dung (as chicken manure), animal body waste (as feather etc.), plant proteins (as sesame paste, bean cake powder etc.), single or compound, granularity 〉=40 orders, wet product water content is no more than 50%, total consumption 1-50% in prescription.Can add acid (adding alkali), heating hydrolysis pre-treatment, sour PH≤5 (alkali PH 〉=10 as also must acid adjustment after the alkaline hydrolysis), Heating temperature≤120 ℃ must be carried out in pressure vessel when greater than 100 ℃.[B] micro-composition mainly is composited by zinc, iron, manganese, copper, boron, molybdenum, the optional 2-7 kind of cobalt preparation.Its scope of limiting the quantity of separately (as micro-total amount is decided to be at 100% o'clock) ratio successively is not more than 50%, 60%, 32%, 12%, 25%, 6%, 4% of compound total amount (being micro-total amount).The kind of its preparation and the compound of selecting for use are referring to " trace element fertilizer " Liu Zheng 1991 P14 of chemical industry press tables 3.The ratio here can refer to each element ion weight content, also can refer to select for use successively ZnSO
47H
2O, FeSO
47H
2O, MnSO
44H
2O, CuSO
45H
2O, H
3BO
3, Na
2MoO
42H
2O, CoSO
47H
2The amount of O is calculated.Should note selecting for use as possible acid-salt when selecting the salt of each element.Very little to the activated micro-demand of plant-growth, key is it not by soil fixingization, and the present invention improves its validity, utilization ratio and activity owing to handle with organism complexing and zeolite adsorption exchange greatly.Trace element is total consumption 1-20% in prescription.[C] zeolite is selected cation exchange capacity 〉=180mg equivalent/100g weight for use, generally selects clinoptilolite and mordenite, granularity 〉=80 orders, consumption 1-30%.[D] mushroom, i.e. bio-feritlizer mushroom commonly used is compiled 1995 press of University of Electronic Science and Technology referring to " bio-feritlizer " Du Binghai etc.Adopt chat in this book and the bio-feritlizer mushroom, single or compound, generally can select vinelandii, yield increasing fungus, enzymatic microorganism and Trichoderma etc., arbitrary combination, all viable bacteria content indexs of fertilizer 〉=5 * 10 for use
6/ gram, single or compound contains the 0.1-5% that the bacterium crude product accounts for the fertilizer total amount.[E] magnetic adopts Fe
3O
4The magnetic breeze also can adopt other magnetic powders, granularity 〉=60 orders, magnetic induction density 〉=6.8 * 10 that fertilizer is overall
3Mx./M
2, total consumption 1-10% of magnetic powder, the processing of can magnetizing.[F] rare earth is selected agricultural rare-earth for use, 17 kinds of nitrate of rare earth element classes such as lanthanum, cerium, praseodymium, neodymium particularly, and addition is the 0.03%-0.3% of total amount.[G] humic acid mainly adopts nitro humus acid, and sodium humate can cushion alkaline edatope, improves the urea utilization ratio, improves soil aggregate, increases the replacement amount, holds fertile guarantor's fertilizer and promotes plant growth.Consumption≤10% generally accounts for the 0.5-10% of total amount.[H] dried plant materials powder mainly is the straw powder, is good with the high person of expansion rate of water absorption, content≤15%, and granularity 〉=20 orders as carrier or the nutrition of bacterium, constitutes loose microtexture.Simultaneously after fertiliser granulates is manured into soil, dried plant powder water-swelling disintegratable fertiliser granulates also helps ventilating and protects the effect of rich water.[I] nitrogen phosphorus potassium and calcium magnesium sulphur macroelement mineral manure, the particularly adding of nitrogen phosphorus potassium mineral manure, make the present invention in the complexing of micro-isoreactivity composition organism macromole, zeolite adsorption exchange activation, plant powder carries on all multi-functional and bases that organism is abundant such as bacterium, provide the fertilizer efficiency of macroelement to guarantee, being the basis that other effective ingredients play a role, is " backing ".With regard to nitrogen phosphorus potassium etc. and Yan Kedan with can be compound with arbitrary proportion, general compound use, make its three's content account for total by weight of fertilizer 〉=16%, general desirable 25%.To select the acid and physiological acidic fertilizer kind of chemistry for use, avoid selecting for use alkaline fertilizers such as SODIUMNITRATE, nitrocalcite, sodium phosphate.Calcium, magnesium, sulphur, can select gypsum and sal epsom for use.Calcium, magnesium, sulphur is single or combination, and total amount accounts for total fertile amount≤10%.[J] growth regulator adopts the triacontanol price quote emulsion, and xanthohumic acid etc. stimulate crop growth regulator, and content≤1% is generally below 0.5%.[K] flyash and carbon black (ratio of the two is 1: 1-5: 1), and total content≤20%.[L] acid supplement, sulfuric acid, nitric acid etc.Be used to promote organic hydrolysis, adjust fertilizer subacidity PH5.5-6.5 ,≤PH7 adopts the acid supplement that dilutes 5-10% or denseer＞20%.[M] weedicide can add and can not add, and is safe and effective for guaranteeing usage quantity, add fashionable, the fertilizer specification sheets want clear and definite fertilizer mu amount of application and duration of service method condition etc., the actual amount of weedicide accounts for gross weight≤5%.[N] agricultural chemicals, the adding method, the same weedicide of principle all wants attention dispersion even! [O] silicon-agent, as silicon sol--moisture higher silicon-agents such as silica gel, deodorizing and reinforcement element silicon, and cohesive action is arranged, content≤6%, general≤2%.[P] binding agent, as starch, favourable granulation such as clay and increase granulation intensity, consumption≤10%, general≤4%.[Q] water, usefulness such as reaction medium and mediation granulation, so that operation, total add-on≤30% is handled because dry after the granulation, finally water content≤10%.
More than each composition what, having or not, increase and decrease can be according to concrete different purpose setting, the complete plain multiple-effect fertilizer of formation seriation bacterium magnetic activating.
Method for making of the present invention---the main body blending process is:
1. organism macromole [A] adds silicon-agent [O] and adds acid supplement [L], fully stirs, can heat tracing;
2. trace element [B] water [Q] dissolving adds rare earth [F], humic acid [G] in the stirring;
3.1 and 2 add and stir three times, at interval more than 10 minutes together;
4. zeolite [C] is added 3, stir three times, at interval more than 10 minutes;
5. mushroom [D] adds plant powder [H] stirring, adds growth regulator [J] and stirs, and adds magnetic [E] and stirs, and whole process can be used moisture content [Q] spraying cooperation;
6. flyash and carbon black [K] add weedicide [M], agricultural chemicals [N], stir;
7. add together 4,5,6 and stir;
8. macroelement fertilizer [I] is added 7, stir;
9. binding agent [P] starch is added little water [Q] heating for dissolving, stir;
10. cooperate 9 with 8, stir, granulate, oven dry gets particulate product;
The overall process formula is:
(A+O+L)+(B+Q+F+G)+CC+ (D+H+J+E+Q)+(K+M+N)+I+ (P+Q) → granulation → oven dry → particulate product.Some explanation:
1. organism macromole [A] adds the preliminary deodorizing of silicon-agent [O] and (can add a little MgSO at this
41% amount cooperates deodorizing) acid adjustment again, but 60-100 ℃ of heating, temperature keeping simultaneously made every effort to promote organism macromole hydrolysis becoming nitrogen base acid etc., so that help and trace element [B] complexing action.
2. add zeolite [C], fully stir, so that fully adsorb and exchange.
3. dried plant materials powder [H] wants thorough mixing even as the carrier of mushroom [D] and growth regulator [J] with an amount of moisture content [Q] spraying cooperation, adds magnetic [E] again, stirs.
4. in this main body blending process, flyash and carbon black [K] want thorough mixing even as the dispersion agent of weedicide [M], agricultural chemicals [N], so that easier being uniformly dispersed in the mixing afterwards.
5. in this main body blending process, if removing some composition need not.Then can become the different seriation fertilizer of function, general trace element [B], organism macromole [A], zeolite [C], mushroom [D], magnetic [E], macroelement fertilizer [I] should be as the trunk basis.
Embodiment 1: each component of about one ton prescription is respectively: [A] organism macromole, use chicken manure, and moisture about 40%, 200 kilogram, 12% of the suitable approximately total amount of dry product.[B] trace element amounts to 126 kilograms, and wherein zinc sulfate is 40 kilograms, 40 kilograms in ferrous sulfate, 10 kilograms of manganous sulfates, 5 kilograms in copper sulfate, 30 kilograms of boric acid, 1 kilogram of ammonium molybdate, suitable 12.6%.[D] mushroom, with 2 kilograms of the trichodermins that contains the several 2,000,000,000/grams of bacterium, 2 kilograms of yield increasing funguses are equivalent to 0.4%.[E] magnetic is used Fe
3O
4The magnetic breeze, 〉=60 orders, magnetic induction is greater than 10
6Mx/M
2(10
-2T.), 100 kilograms, suitable 10%.[F] rare earth with 1 kilogram of rare earth nitrate, is equivalent to 0.1%.[G] humic acid with 5 kilograms of nitro humus acids, is equivalent to 0.5%.[H] dried plant materials powder is used sawdust, and 〉=40 orders, are equivalent to 3.5% by 35 kilograms.[I] nitrogen phosphorus potassium and calcium magnesium sulphur macroelement, get N: P: K=12: 8: 5, contained N, P, K in the deduction chicken manure, take 208 kilograms in urea, 150 kilograms of MAPs, 80 kilograms in Repone K, add 6 kilograms in gypsum in addition again, 6 kilograms in sal epsom amounts to the 208+150+80+6+6=450 kilogram, accounts for 45%.[J] growth regulator, 2 kilograms of the triacontanol price quote emulsions of employing 1000ppm are counted pure triacontanol price quote solid 2 grams.[K] flyash and carbon black (ratio of the two 2: 1), granularity 〉=60 orders, accounts for 3% by 30 kilograms.[L] acid supplement, dilute sulphuric acid, 10%, 4 kilogram of concentration.[M] weedicide is according to circumstances determined to add and do not add and adds kind, notices that its chemical property subacidity is better, and 1 kilogram of present embodiment usefulness prometryn 25% wettable powder is equivalent to 0.1%./ N agricultural chemicals can add and can not add, and this example is selected phorate 5% granule for use, 1 kilogram, is equivalent to 0.1% and (notes its toxicity explanation when selling.Or, be equivalent to 0.1%) with 1 kilogram of disosultap 5% granule.[O] silicon-agent, 2 kilograms of the silicon sol with moisture 50% account for 0.1%.[P] binding agent, 1 kilogram of W-Gum, water heating gelatinization is used during granulation, accounts for 0.1%.[Q] water according to the technological operation conditions of demand, adds at any time, should control moisture content≤10% during the granulation oven dry, because of some all moisture, so total amount is disregarded.More than everyly be about 100% altogether.Blending process is with above-mentioned overall process formula.Embodiment 2: remove the weedicide [M] among the embodiment 1.Embodiment 3: remove the agricultural chemicals [N] among the embodiment 1.Embodiment 4: remove weedicide [M} and agricultural chemicals [N] among the embodiment 1.
Claims (5)
1. complete plain multi-effect fertilizer series of bacterium magnetic activating, it is characterized in that with trace elements zn, Fe, Cu, Mn, B, Mo, Co and macroelement N, P, K and Ca, Mg, the fertilizer with full elements material that S constitutes, special successively by the macromolecular complexing of organism, the absorption of zeolite, exchange interaction, make particularly trace element " activation " of fertilizer element, be aided with bacterium, magnetic, rare earth, humic acid, growth regulator, agricultural chemicals, weedicide, silicon-agent, dried plant materials powder etc., whole acid, constituent and content range are: organism macromole [A] 1-50%, trace element [B] 1-20%, zeolite [C] 1-30%, mushroom [D] 0.1-5%, magnetic [E] 1-10%, rare earth [F]≤0.3%, humic acid [G]≤10%, dried plant materials powder [H]≤15%, macroelement fertilizer [I] 〉=16%, growth regulator [J]≤1%, flyash and carbon black [K]≤20%, acid supplement [L]≤5%, weedicide [M]≤5%, silicon-agent [O]≤6%, binding agent [P]≤10%, water [Q]≤30% is formed, A+B+C+D+E+F+G+H+I+J+K+L+M+N+O+P+Q=100%.
2. the complete plain multi-effect fertilizer series of a kind of bacterium magnetic activating as claimed in claim 1, it is characterized in that its each component: [A] organism macromole is animal dung (as chicken manure), animal body waste (as feather etc.), plant proteins (as bean cake powder, sesame paste etc.) and hydrolyzate thereof; [B] trace element mainly is composited by zinc, iron, manganese, steel, boron, molybdenum, the optional 2-7 kind of cobalt preparation, and summation is 100% o'clock, and Qi Geqi limits the quantity of and is followed successively by :≤50% ,≤60% ,≤32% ,≤12% ,≤25% ,≤6% ,≤4%; [C] zeolite, granularity 〉=80 orders, cation exchange capacity 〉=180 milligramequivalents/100 grams: [D] mushroom is probioticss such as vinelandii, yield increasing fungus, enzymatic microorganism, Trichoderma, viable bacteria content 〉=5 * 10
6/ gram; [E] magnetic is magnetic powder, and granularity 〉=60 orders makes total magnetic induction density 〉=6.8 * 10
3Mx/M
2, can add the processing of magnetizing; [F] rare earth, agricultural rare-earth, particularly its Nitrates: [G] humic acid mainly is nitro humus acid and sodium humate etc.; [H] dried plant materials powder, granularity 〉=20 orders, straw powder or cork sawdust are good with the high person of expansion rate of water absorption; [I] macroelement fertilizer mainly is nitrogen phosphorus potassium and calcium magnesium sulphur etc., single or compound composite adding, and nitrogen phosphorus potassium accounts for total amount 〉=16%, is generally 16-28%, and calcium magnesium sulphur accounts for total amount≤10%; [J] growth regulator is generally used the triacontanol price quote emulsion, and xanthohumic acid etc. stimulate the plant growth agent; [K] flyash and carbon black, granularity 〉=80 orders, as far as possible thin for well; [L] acid supplement, sulfuric acid nitric acid etc. are used for hydrolysis of organic matter and transfer total PH≤7; [M] weedicide, acid, the neutral type of choosing, the mu amount of executing that the kind consumption limits with concrete fertilizer and use method and deciding in period; [N] agricultural chemicals, same weedicide; [O] silicon-agent adopts silicon-agents such as silicon sol; [P] binding agent, starch, clay etc.; [Q] water, reaction medium and blending, granulation etc., optionally convenient and decide in the operating process, the finished product water content is not more than 10%.
3. as claim 1, the complete plain multi-effect fertilizer series of 2 described a kind of bacterium magnetic activatings, it is characterized in that adopting dried plant materials powder and flyash to presort powder and carrier as the pettiness composition, dried plant materials powder also be used as fertiliser granulates is used after easy disintegrating more, the effect of rich water is protected in favourable ventilation.
4. method for making of producing the product of claim 1 is characterized in that each moiety divides group reaction respectively, and by the particular sequential group combination also, differential responses purpose differential responses condition merges granulation at last, oven dry; In whole cooperation technological process, make suitably hydrolysis of organism macromole [A] earlier, carry out complexing with dissolved trace element [B] etc. again, adsorb exchange with zeolite [C] again; Mushroom [D] magnetic [E] cooperates with an amount of moisture content [Q] with dried plant materials powder [H] earlier and disperses and load; Flyash and carbon black [K] are earlier with weedicide [M], and agricultural chemicals [N] is uniformly dispersed; Again successively by stirring and stirring reaction mixing at interval.Its overall process formula is: (A+O+L)+(B+Q+E+G)+and C+ (D+H+J+E+Q)+(K+M+N)+I+ (P+Q) → granulation → oven dry → particulate product
5. the method for making of the product of a kind of production claim 1 as claimed in claim 4 can heating, temperature keeping when it is characterized in that organism macromole [A] hydrolysis reaction, promotes hydrolysis reaction to carry out and to the complexing action of trace element [B].
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 96115868 CN1176953A (en) | 1996-06-26 | 1996-06-26 | Magnet activated bacleria, full element, and multi-effect fertilizer series, and method for producing same |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 96115868 CN1176953A (en) | 1996-06-26 | 1996-06-26 | Magnet activated bacleria, full element, and multi-effect fertilizer series, and method for producing same |
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| CN1176953A true CN1176953A (en) | 1998-03-25 |
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|---|---|---|---|
| CN 96115868 Pending CN1176953A (en) | 1996-06-26 | 1996-06-26 | Magnet activated bacleria, full element, and multi-effect fertilizer series, and method for producing same |
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- 1996-06-26 CN CN 96115868 patent/CN1176953A/en active Pending
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| CN101811910A (en) * | 2010-04-16 | 2010-08-25 | 邵映辉 | Humic acid bioorganic liquid manure and special strain preparation |
| CN102503703A (en) * | 2011-11-22 | 2012-06-20 | 刘长福 | Novel compound fertilizer containing active microorganisms |
| CN102503709A (en) * | 2011-12-01 | 2012-06-20 | 郑州丰沃生物科技有限公司 | Multienzyme microbial fertilizer |
| CN102578155A (en) * | 2012-01-11 | 2012-07-18 | 王广富 | Peanut grub prevention and control agent and production method thereof |
| CN102584450B (en) * | 2012-02-21 | 2013-12-11 | 太仓市临江农场专业合作社 | Nutrient compound fertilizer for fuchsia and application method thereof |
| CN102584450A (en) * | 2012-02-21 | 2012-07-18 | 常熟市方塔涂料化工有限公司 | Nutrient compound fertilizer for fuchsia |
| CN103058776A (en) * | 2013-01-10 | 2013-04-24 | 山西昌鑫生物农业科技有限公司 | (5-0-10) composite microorganism liquid fertilizer with total nutrient content of 15 and preparation method thereof |
| CN103304311A (en) * | 2013-06-05 | 2013-09-18 | 山东华粮生物工程集团股份有限公司 | Zeolite controlled-release fertilizer and manufacturing method for same |
| CN103304311B (en) * | 2013-06-05 | 2014-08-06 | 山东华粮生物工程集团股份有限公司 | Zeolite controlled-release fertilizer and manufacturing method for same |
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| CN104961592A (en) * | 2015-07-22 | 2015-10-07 | 长沙秋点兵信息科技有限公司 | Nutrient composition for promoting crop growth |
| CN107382624A (en) * | 2017-08-23 | 2017-11-24 | 无为县群鑫生态农业有限公司 | One kind improves corn resistance fertilizer |
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