CN117511366A - Coating and preparation method and application thereof - Google Patents

Coating and preparation method and application thereof Download PDF

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Publication number
CN117511366A
CN117511366A CN202311566070.9A CN202311566070A CN117511366A CN 117511366 A CN117511366 A CN 117511366A CN 202311566070 A CN202311566070 A CN 202311566070A CN 117511366 A CN117511366 A CN 117511366A
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CN
China
Prior art keywords
coating
parts
weight
realized
unsaturated polyester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202311566070.9A
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Chinese (zh)
Inventor
陈沛霖
敖欢
林振丰
黄贵淼
孙佳琪
江凯帆
施景瀚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Power Grid Co Ltd
Shanwei Power Supply Bureau of Guangdong Power Grid Co Ltd
Original Assignee
Guangdong Power Grid Co Ltd
Shanwei Power Supply Bureau of Guangdong Power Grid Co Ltd
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Filing date
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Application filed by Guangdong Power Grid Co Ltd, Shanwei Power Supply Bureau of Guangdong Power Grid Co Ltd filed Critical Guangdong Power Grid Co Ltd
Priority to CN202311566070.9A priority Critical patent/CN117511366A/en
Publication of CN117511366A publication Critical patent/CN117511366A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06Unsaturated polyesters having carbon-to-carbon unsaturation
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/22Luminous paints

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention provides a coating, a preparation method and application thereof. The coating comprises 28-32 parts by weight of strontium europium aluminate, 40-45 parts by weight of unsaturated polyester, 18-22 parts by weight of curing agent and 1-5 parts by weight of fluorescent material. The conventional strontium europium aluminate is added with unsaturated polyester and a curing agent to carry out coating modification, under the premise of achieving luminous performance, the sunlight-resistant coating can be realized, the long-time non-change and water-resistant performance under daily sunlight irradiation can be realized, the long-time non-change and alkali resistance of rainwater shower or water immersion can be realized, the phenomena of bubble and powder removal can be realized, the curing speed is high, the volatilization resistance can be realized, the coating is firm after coating, certain electrical insulation performance can be realized, the effect that the surface current is 0 after the conductor is coated and the universal meter is used for measuring after the conductor is electrified can be realized, and fluorescent materials are added, so that the coating has color and can be used for three-phase four wires of electric power, and the identification and operation safety are improved.

Description

Coating and preparation method and application thereof
Technical Field
The invention belongs to the technical field of coatings, and particularly relates to a coating as well as a preparation method and application thereof.
Background
At present, when a power distribution team in the power industry performs work such as urgent repair and maintenance at night, the 10kV power distribution line and equipment are operated, and then tools with insulating functions (insulating operation rods and electroscope) and corresponding enough light sources are required to be used for operating the primary equipment of the distribution network. In conventional operation, a flashlight or a ground light source is used as main illumination, so that operation by using an insulating operation rod, an electroscope and other tool top contacts which are difficult to correspond to relevant operation parts of distribution network equipment is often caused by low night visibility and poor angles of the light source (flashlight, ground light), the color is not clear, the physical strength is quite lost in the operation process, the operation efficiency and the safety are seriously influenced, the time for urgent repair and overhaul is increased, and the working efficiency is reduced. The long-time power failure can cause the problems of economic loss, reduced power supply reliability and the like.
CN106675247a relates to an environment-friendly luminescent paint. The material comprises the following raw materials in parts by weight: 20-30 parts of emulsion water-based acrylic resin, 20-30 parts of epoxy resin, 10-20 parts of polyurethane resin, 10-20 parts of strontium europium aluminate, 10-20 parts of strontium dysprosium aluminate, 5-10 parts of methyl silicone oil xylene solution, 3-5 parts of glycol, 8-12 parts of hydroxyethyl cellulose and 5-10 parts of zeolite powder, and rare earth aluminate is used as a light storage substance, so that light is continuously stored when light is irradiated, light energy is automatically released when the light is dark, the light-emitting brightness is high, and the time is long. The adopted raw materials are environment-friendly and nontoxic substances, so that the health, environment friendliness and no pollution of the coating are ensured, the brightness and the lighting time of lighting are ensured, and the novel economic and safe light source coating is realized.
The luminous paint widely applied in the market adopts rare earth zinc sulfide, strontium europium aluminate and other novel materials as light storage media, has good luminous performance, but has insufficient light fastness, water resistance and alkali resistance.
The insulating paint for electrical appliances widely applied in the market is generally made of liquid resin materials through various procedures, has the advantages of dielectric property, mechanical strength and environmental resistance, but has the problems of strong volatility resistance and low curing speed.
Therefore, development of a coating material having high light fastness, water resistance, alkali resistance, high curing speed, volatilization resistance and certain electrical insulation property is a problem to be solved in the art.
Disclosure of Invention
Aiming at the defects of the prior art, the invention aims to provide a coating which has the advantages of sunlight resistance, water resistance, alkali resistance, high curing speed, volatilization resistance and certain electrical insulation on the premise of achieving luminous performance. And fluorescent materials are added, so that the coating has color, can be used for three-phase four-wire of electric power, and improves identification and operation safety.
To achieve the purpose, the invention adopts the following technical scheme:
in a first aspect, the present invention provides a coating comprising, in parts by weight: 28-32 parts of strontium europium aluminate, 40-45 parts of unsaturated polyester, 18-22 parts of curing agent and 1-5 parts of fluorescent material.
Preferably, the weight parts of the strontium europium aluminate are 28-32 parts, for example, 28 parts, 29 parts, 30 parts, 31 parts, 32 parts, and specific point values among the above point values, which are limited in space and for the sake of brevity, the present invention is not exhaustive.
Preferably, the unsaturated polyester is 40-45 parts by weight, for example 40 parts, 41 parts, 42 parts, 43 parts, 44 parts, 45 parts, and specific point values between the above point values, are limited in space and for brevity, the invention is not exhaustive of the specific point values included in the range.
Preferably, the weight portion of the curing agent is 18-22, such as 18, 19, 20, 21, 22, and the specific values between the above values, which are not exhaustive in the present invention for reasons of space and brevity.
Preferably, the fluorescent material is 1-5 parts by weight, for example, 1 part, 2 parts, 3 parts, 4 parts, 5 parts, and specific point values between the above point values, and the present invention is not exhaustive of the specific point values included in the range for reasons of space and brevity.
The strontium europium aluminate is a novel luminous coating and plays a role in luminous and brightening. The unsaturated ester adopts polyacrylic resin, so as to protect the coating, increase environmental resistance and play a role in enhancing insulation. The curing agent content is relatively large to increase the curing speed. The red, green and yellow fluorescent material plays a role of color marking.
Preferably, the unsaturated polyester comprises a polyacrylic resin.
Preferably, the molecular weight of the unsaturated polyester is 4000 to 5000, for example 4000, 4200, 4500, 4800, 5000, and specific point values between the above point values, which are not exhaustive in the present invention for reasons of space and for reasons of brevity.
Preferably, the curing agent comprises an isocyanate.
Preferably, the fluorescent material comprises any one or a combination of at least two of red fluorescent pigment, green fluorescent pigment or blue fluorescent pigment.
Preferably, the components of the coating further comprise 1-5 parts by weight of an anti-settling agent.
Preferably, the weight part of the anti-settling agent is 1-5 parts, for example, 1 part, 2 parts, 3 parts, 4 parts, 5 parts, and specific point values among the above point values, which are limited in space and for the sake of brevity, the present invention is not exhaustive.
Preferably, the anti-settling agent comprises an organobentonite.
The visibility can be obviously increased in the state of having a light source or having no light source at night only by coating the top end of the corresponding insulating tool or coating the coating on the operation part of the distribution network equipment, thereby effectively improving the working efficiency, reducing the power failure time and improving the power supply reliability.
The paint has adjustable color, can meet various requirements of painting safety marks and phase marks of different colors on primary equipment of the distribution network, can be widely applied to various equipment of various insulating tools and distribution lines which are required to be used at night, and has simple operation and strong practicality and safety.
The paint has luminous and color resolution, and has the advantages of dielectric, mechanical strength and environmental resistance in terms of electrical performance, and further enhances the insulating performance of electrical equipment.
In a second aspect, the present invention provides a method of preparing a coating as described in the first aspect, the method comprising:
mixing the strontium europium aluminate, the unsaturated polyester, the curing agent and the fluorescent material to obtain the coating.
Preferably, the mixed components further comprise an anti-settling agent.
Preferably, the mixing time is 5-8min, for example, 5min, 6min, 7min, 8min, and specific point values among the above point values, which are not exhaustive in the present invention for the sake of brevity and conciseness.
Preferably, the temperature of the mixture is 40-55deg.C, which may be, for example, 40deg.C, 42deg.C, 44deg.C, 46 deg.C, 48deg.C, 50deg.C and specific point values between the above point values, although the specific point values are not exhaustive and included in the scope of the invention for the sake of brevity.
The preparation method specifically comprises the following steps:
the preparation method comprises the steps of adopting polyacrylic resin as a film forming substance, diluting with a xylene solvent to a proper viscosity (ISO cup 55), adding noctilucent paint (strontium europium aluminate) by stirring at a high speed, heating at 50-60 ℃ for 8-12min, and adding a curing agent, an anti-settling agent and fluorescent materials with corresponding colors for premixing to obtain the paint.
In a third aspect, the present invention provides the use of a coating as described in the first aspect in an electrical apparatus, an insulated tool or a power supply line.
Compared with the prior art, the invention has the following beneficial effects:
according to the coating provided by the invention, the conventional strontium europium aluminate is added with the unsaturated polyester and the curing agent for coating modification, so that the light fastness is achieved on the premise of achieving the luminous performance, the long-time unchanged and water-proof performance under daily sunlight irradiation can be achieved, the long-time unchanged and alkali-proof performance of rainwater showering or water immersion can be achieved, the phenomena of bubble and powder removal can be achieved, the curing speed is high, the volatilization resistance can be achieved, the firm layering after coating can be achieved, certain electrical insulation performance can be achieved, the effect that the surface current is 0 after the conductor is coated and the universal meter is used for measuring after the conductor is electrified can be achieved, the fluorescent material is added, the coating has color and can be used for three-phase four wires of electric power, and the identification performance and the operation safety are improved.
Detailed Description
The technical scheme of the invention is further described by the following specific embodiments. It will be apparent to those skilled in the art that the examples are merely to aid in understanding the invention and are not to be construed as a specific limitation thereof.
The experimental materials used in the examples and comparative examples of the present invention are as follows:
(1) Unsaturated polyester, manufacturer's US Robotic, brand carbomer sf-1;
(2) Curing agent, vanhua, brand HT 100;
(3) Anti-settling agent, manufacturer's sea name, humus, trade name Bengel 908 (854263);
(4) Fluorescent material, hangzhou color multi-family, trade mark 026.
Example 1
The embodiment provides a coating, the components of which include: 30 parts of strontium europium aluminate, 42 parts of polyacrylic resin, 20 parts of isocyanate, 3 parts of organic bentonite and 5 parts of propylene fluorescent material.
The embodiment also provides a preparation method of the coating, which comprises the following steps:
the preparation method comprises the steps of adopting polyacrylic resin as a film forming substance, diluting with a xylene solvent until the viscosity (ISO cup 55) is proper, adding noctilucent paint (strontium europium aluminate) by high-speed stirring, heating at 55 ℃ for 10 minutes, and then adding a curing agent, an anti-settling agent and a fluorescent material for premixing to obtain the paint.
Example 2
The embodiment provides a coating, the components of which include: 30 parts of strontium europium aluminate, 30 parts of polyacrylic resin, 10 parts of isocyanate, 10 parts of organic bentonite, 5 parts of propylene fluorescent material and 15 parts of solvent.
The embodiment also provides a preparation method of the coating, which comprises the following steps:
the preparation method comprises the steps of adopting polyacrylic resin as a film forming substance, diluting with a xylene solvent until the viscosity (ISO cup 55) is proper, adding noctilucent paint (strontium europium aluminate) by high-speed stirring, heating at 80 ℃ for 3 minutes, and adding a curing agent, an anti-settling agent and a fluorescent material for premixing to obtain the paint.
Example 3
The embodiment provides a coating, the components of which include: 30 parts of strontium europium aluminate, 30 parts of polyacrylic resin, 5 parts of isocyanate, 5 parts of organic bentonite, 20 parts of propylene fluorescent material and 10 parts of solvent.
The embodiment also provides a preparation method of the coating, which comprises the following steps:
the preparation method comprises the steps of adopting polyacrylic resin as a film forming substance, diluting with a xylene solvent until the viscosity (ISO cup 55) is proper, adding noctilucent paint (strontium europium aluminate) by high-speed stirring, heating at 80 ℃ for 3 minutes, and adding a curing agent, an anti-settling agent and a fluorescent material for premixing to obtain the paint.
Comparative example 1
This comparative example provides a coating comprising the following components: 30 parts of strontium europium aluminate, 20 parts of isocyanate, 3 parts of organic bentonite and 5 parts of propylene fluorescent material.
The coatings obtained in examples 1-3, comparative example 1 were subjected to performance testing as follows:
(1) Sun resistance: the ultraviolet lamp tube does not fade for 4 hours under irradiation, the higher the grade is, the longer the irradiation time is, and the grade more than 4 is qualified;
(2) Water resistance: immersing the test plate coated with the paint in water, observing the change of the test plate after different times, and obtaining the qualified test plate after the paint layer does not fade after 24 hours;
(3) Alkali resistance: touching an acidic liquid with the sulfuric acid concentration of 5% or an alkaline liquid with the NAOH concentration of 55%, and avoiding the phenomena of air bubbles and powder removal;
(4) Electrical insulation: volume resistivity is more than 1016 omega;
(5) Night vision performance: the night is obviously considered as qualified;
(6) Covering power: uniformly coating the coating on the surface of an object, so that the minimum paint consumption of which the base color is no longer presented is less than 300g/m < 2 > qualified;
(7) Stability at normal temperature: no phenomena of dispersion, agglomeration and demulsification are qualified.
The coatings obtained in example 1, example 2, example 3 and comparative example 1 were tested for each property according to the above-mentioned property test method, and the test results are shown in table 1.
TABLE 1
As is clear from the data in Table 1, when the unsaturated ester was a polyacrylic resin and the components of examples 1, 2 and 3 were adjusted, the performance indexes such as (room temperature stability, light fastness, water resistance, alkali resistance and electrical insulation) were changed.
The curing agent is compared with examples 1, 2 and 3, and the curing performance of example 1 with a relatively large content is the fastest.
The red, green and yellow fluorescent material plays a role in marking and hiding, and the hiding power is obviously influenced by the embodiment 2 and the embodiment 3.
The components in the embodiment 1 can reach the qualification standard, and are the best scheme.
The applicant states that the present invention is illustrated by the above examples as a coating material and a method of preparing and using the same, but the present invention is not limited to the above examples, i.e. it is not meant that the present invention must be practiced in dependence upon the above examples. It should be apparent to those skilled in the art that any modification of the present invention, equivalent substitution of raw materials for the product of the present invention, addition of auxiliary components, selection of specific modes, etc., falls within the scope of the present invention and the scope of disclosure.

Claims (10)

1. The coating is characterized by comprising 28-32 parts by weight of strontium europium aluminate, 40-45 parts by weight of unsaturated polyester, 18-22 parts by weight of curing agent and 1-5 parts by weight of fluorescent material.
2. The coating of claim 1, wherein the unsaturated polyester comprises a polyacrylic resin.
3. The coating according to claim 1 or 2, wherein the unsaturated polyester has a molecular weight of 4000 to 5000.
4. A coating according to any one of claims 1 to 3, wherein the curing agent comprises an isocyanate.
5. The coating of any one of claims 1-4, wherein the fluorescent material comprises any one or a combination of at least two of a red fluorescent pigment, a green fluorescent pigment, or a blue fluorescent pigment.
6. The coating of any one of claims 1-5, wherein the coating further comprises 1-5 parts by weight of an anti-settling agent.
7. The coating of claim 6, wherein the anti-settling agent comprises an organobentonite clay.
8. A method of preparing the coating of any one of claims 1-7, comprising:
mixing the strontium europium aluminate, the unsaturated polyester, the curing agent and the fluorescent material to obtain the coating.
9. The method of preparing according to claim 8, wherein the mixed components further comprise an anti-settling agent;
preferably, the mixing time is 5-8min;
preferably, the temperature of the mixing is 40-55 ℃.
10. Use of a coating according to any one of claims 1-7 in electrical equipment, insulation tools or power supply lines.
CN202311566070.9A 2023-11-22 2023-11-22 Coating and preparation method and application thereof Pending CN117511366A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202311566070.9A CN117511366A (en) 2023-11-22 2023-11-22 Coating and preparation method and application thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202311566070.9A CN117511366A (en) 2023-11-22 2023-11-22 Coating and preparation method and application thereof

Publications (1)

Publication Number Publication Date
CN117511366A true CN117511366A (en) 2024-02-06

Family

ID=89762299

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202311566070.9A Pending CN117511366A (en) 2023-11-22 2023-11-22 Coating and preparation method and application thereof

Country Status (1)

Country Link
CN (1) CN117511366A (en)

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