CN117398299A - Hair cleansing composition - Google Patents
Hair cleansing composition Download PDFInfo
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- CN117398299A CN117398299A CN202310823692.9A CN202310823692A CN117398299A CN 117398299 A CN117398299 A CN 117398299A CN 202310823692 A CN202310823692 A CN 202310823692A CN 117398299 A CN117398299 A CN 117398299A
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- component
- mass
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- acid
- alkyl group
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- 239000000203 mixture Substances 0.000 title claims abstract description 72
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 36
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 18
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 13
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 12
- 229920000642 polymer Polymers 0.000 claims abstract description 11
- 239000004094 surface-active agent Substances 0.000 claims abstract description 11
- 239000000126 substance Substances 0.000 claims abstract description 9
- 125000002252 acyl group Chemical group 0.000 claims abstract description 8
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 7
- 150000001342 alkaline earth metals Chemical class 0.000 claims abstract description 7
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 6
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims description 11
- 150000003839 salts Chemical class 0.000 claims description 7
- 239000012459 cleaning agent Substances 0.000 abstract description 21
- UCMIRNVEIXFBKS-UHFFFAOYSA-N beta-alanine Chemical compound NCCC(O)=O UCMIRNVEIXFBKS-UHFFFAOYSA-N 0.000 abstract description 8
- 229940000635 beta-alanine Drugs 0.000 abstract description 5
- 239000006260 foam Substances 0.000 abstract description 4
- 238000004140 cleaning Methods 0.000 abstract description 2
- -1 triethanolamine alkyl sulfate Chemical class 0.000 description 34
- 230000015572 biosynthetic process Effects 0.000 description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- 235000014113 dietary fatty acids Nutrition 0.000 description 18
- 239000000194 fatty acid Substances 0.000 description 18
- 229930195729 fatty acid Natural products 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 17
- 150000004665 fatty acids Chemical class 0.000 description 17
- 238000011156 evaluation Methods 0.000 description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 11
- 229910052708 sodium Inorganic materials 0.000 description 11
- 239000011734 sodium Substances 0.000 description 11
- 229920001577 copolymer Polymers 0.000 description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 239000003599 detergent Substances 0.000 description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
- 239000003945 anionic surfactant Substances 0.000 description 6
- 235000019864 coconut oil Nutrition 0.000 description 6
- 239000003240 coconut oil Substances 0.000 description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 6
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
- 235000019865 palm kernel oil Nutrition 0.000 description 6
- 239000003346 palm kernel oil Substances 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- 239000001913 cellulose Substances 0.000 description 5
- 229920002678 cellulose Polymers 0.000 description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- VDIPNVCWMXZNFY-UHFFFAOYSA-N N-methyl-beta-alanine Chemical compound CNCCC(O)=O VDIPNVCWMXZNFY-UHFFFAOYSA-N 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 3
- NBDYSLCMCUDINP-UHFFFAOYSA-N 3-[dodecanoyl(methyl)amino]propanoic acid;sodium Chemical compound [Na].CCCCCCCCCCCC(=O)N(C)CCC(O)=O NBDYSLCMCUDINP-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 3
- 239000005639 Lauric acid Substances 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001413 amino acids Chemical class 0.000 description 3
- 235000015165 citric acid Nutrition 0.000 description 3
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 3
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- 239000004310 lactic acid Substances 0.000 description 3
- 235000014655 lactic acid Nutrition 0.000 description 3
- 229940049920 malate Drugs 0.000 description 3
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- 239000002453 shampoo Substances 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- 239000000213 tara gum Substances 0.000 description 3
- 235000010491 tara gum Nutrition 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- DDGPBVIAYDDWDH-UHFFFAOYSA-N 3-[dodecyl(dimethyl)azaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC(O)CS([O-])(=O)=O DDGPBVIAYDDWDH-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229920002907 Guar gum Polymers 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 229920006317 cationic polymer Polymers 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 239000000665 guar gum Substances 0.000 description 2
- 235000010417 guar gum Nutrition 0.000 description 2
- 229960002154 guar gum Drugs 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 239000002563 ionic surfactant Substances 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 239000001630 malic acid Substances 0.000 description 2
- 235000011090 malic acid Nutrition 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 235000014593 oils and fats Nutrition 0.000 description 2
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 2
- 150000004671 saturated fatty acids Chemical class 0.000 description 2
- FMUCLMJVJBCHGB-UHFFFAOYSA-M sodium 3-(tridecylamino)propanoate Chemical compound CCCCCCCCCCCCCNCCC(=O)[O-].[Na+] FMUCLMJVJBCHGB-UHFFFAOYSA-M 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 2
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- FKKAGFLIPSSCHT-UHFFFAOYSA-N 1-dodecoxydodecane;sulfuric acid Chemical compound OS(O)(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC FKKAGFLIPSSCHT-UHFFFAOYSA-N 0.000 description 1
- 125000004066 1-hydroxyethyl group Chemical group [H]OC([H])([*])C([H])([H])[H] 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- ZKWJQNCOTNUNMF-QXMHVHEDSA-N 2-[dimethyl-[3-[[(z)-octadec-9-enoyl]amino]propyl]azaniumyl]acetate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O ZKWJQNCOTNUNMF-QXMHVHEDSA-N 0.000 description 1
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 1
- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 description 1
- NCZPCONIKBICGS-UHFFFAOYSA-N 3-(2-ethylhexoxy)propane-1,2-diol Chemical compound CCCCC(CC)COCC(O)CO NCZPCONIKBICGS-UHFFFAOYSA-N 0.000 description 1
- SUOYMAAKYJKLCS-UHFFFAOYSA-N 3-(dodecanoylamino)propanoic acid;sodium Chemical compound [Na].CCCCCCCCCCCC(=O)NCCC(O)=O SUOYMAAKYJKLCS-UHFFFAOYSA-N 0.000 description 1
- YZPJYHCJKCSXBS-UHFFFAOYSA-N 3-(ethylamino)propanoic acid Chemical compound CCNCCC(O)=O YZPJYHCJKCSXBS-UHFFFAOYSA-N 0.000 description 1
- GDMFYPNVLLFABQ-UHFFFAOYSA-N 3-(tert-butylamino)propanoic acid Chemical compound CC(C)(C)NCCC(O)=O GDMFYPNVLLFABQ-UHFFFAOYSA-N 0.000 description 1
- MXRGSJAOLKBZLU-UHFFFAOYSA-N 3-ethenylazepan-2-one Chemical compound C=CC1CCCCNC1=O MXRGSJAOLKBZLU-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- NDKYEUQMPZIGFN-UHFFFAOYSA-N Butyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCC NDKYEUQMPZIGFN-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- 238000007696 Kjeldahl method Methods 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 235000021319 Palmitoleic acid Nutrition 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 244000250129 Trigonella foenum graecum Species 0.000 description 1
- 235000001484 Trigonella foenum graecum Nutrition 0.000 description 1
- UYCAGRPOUWSBIQ-WOYAITHZSA-N [(1s)-1-carboxy-4-(diaminomethylideneamino)butyl]azanium;(2s)-5-oxopyrrolidine-2-carboxylate Chemical compound OC(=O)[C@@H]1CCC(=O)N1.OC(=O)[C@@H](N)CCCN=C(N)N UYCAGRPOUWSBIQ-WOYAITHZSA-N 0.000 description 1
- XXDFVBSTWYZRCH-UHFFFAOYSA-N [Cl-].[Cl-].[Cl-].C(=C)[NH+]1C=NCC1.C(=C)[NH+]1C=NCC1.C(=C)[NH+]1C=NCC1 Chemical compound [Cl-].[Cl-].[Cl-].C(=C)[NH+]1C=NCC1.C(=C)[NH+]1C=NCC1.C(=C)[NH+]1C=NCC1 XXDFVBSTWYZRCH-UHFFFAOYSA-N 0.000 description 1
- FFUVBZPOXOBYGY-UHFFFAOYSA-N [Na].C(CCCCCCCCCCC)(=O)N(CCC(=O)O)CC Chemical compound [Na].C(CCCCCCCCCCC)(=O)N(CCC(=O)O)CC FFUVBZPOXOBYGY-UHFFFAOYSA-N 0.000 description 1
- CESLXGKTCRGIKU-UHFFFAOYSA-N [Na].C(CCCCCCCCCCC)(=O)N(CCC(=O)O)CCO Chemical compound [Na].C(CCCCCCCCCCC)(=O)N(CCC(=O)O)CCO CESLXGKTCRGIKU-UHFFFAOYSA-N 0.000 description 1
- XHAWOPZOWFHFFP-UHFFFAOYSA-N [Na].CCCCCCCCCCCCCNCCC(O)=O Chemical compound [Na].CCCCCCCCCCCCCNCCC(O)=O XHAWOPZOWFHFFP-UHFFFAOYSA-N 0.000 description 1
- AGFMBKWNLFBGMI-UHFFFAOYSA-N [Na].[Na].[Na].OCCN(CCO)CCO Chemical compound [Na].[Na].[Na].OCCN(CCO)CCO AGFMBKWNLFBGMI-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229920006322 acrylamide copolymer Polymers 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003910 behenoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- UCMIRNVEIXFBKS-UHFFFAOYSA-M beta-alaninate Chemical compound NCCC([O-])=O UCMIRNVEIXFBKS-UHFFFAOYSA-M 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-O carboxymethyl-[3-(dodecanoylamino)propyl]-dimethylazanium Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)=O MRUAUOIMASANKQ-UHFFFAOYSA-O 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229920006319 cationized starch Polymers 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
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- 229940071124 cocoyl glutamate Drugs 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical compound C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 description 1
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 229940100524 ethylhexylglycerin Drugs 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 229920006007 hydrogenated polyisobutylene Polymers 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 229940075468 lauramidopropyl betaine Drugs 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 229940094506 lauryl betaine Drugs 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 125000002801 octanoyl group Chemical group C(CCCCCCC)(=O)* 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 125000001312 palmitoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- FJWSMXKFXFFEPV-UHFFFAOYSA-N prop-2-enamide;hydrochloride Chemical compound Cl.NC(=O)C=C FJWSMXKFXFFEPV-UHFFFAOYSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
- 235000001019 trigonella foenum-graecum Nutrition 0.000 description 1
- UZNHKBFIBYXPDV-UHFFFAOYSA-N trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)NCCC[N+](C)(C)C UZNHKBFIBYXPDV-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/447—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof containing sulfur
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
The invention provides a hair cleaning agent composition which has excellent coacervate forming capability, is easy to be sprayed out from a pump, has proper viscosity which is easy to foam during cleaning, and has low-temperature stability which can maintain transparent appearance even at low temperature. A hair cleansing composition comprising 1 to 20% by mass of component (A): a surfactant represented by the following formula (1), and 1 to 20 mass% of a component (B): an amphoteric surfactant, and 0.03 to 3 mass% of component (C): a cationized polymer, and 0.001 to 1.5 mass% of component (D): beta-alanine and/or its derivative, the mass ratio ((A)/(B)) is0.2 to 4, and the mass ratio ((A)/(D)) is 15 to 300.[ chemical formula 1]]R 1 CO represents an aliphatic acyl group having 8 to 22 carbon atoms, R 2 Represents a hydrogen atom or a straight-chain alkyl group or branched alkyl group having 1 to 4 carbon atoms optionally having one hydroxyl group, and M represents an alkali metal, 1/2 alkaline earth metal or organic ammonium.
Description
Technical Field
The present invention relates to a hair cleansing composition for cleansing hair.
Background
Acyl- β -alanine salts including sodium laurylmethyl- β -alanine are compounds contained in hair cleansing compositions, and the use of such compounds has been increasing in recent years due to the popularity of hair cleansing compositions containing amino acid surfactants.
As one of the characteristics of the hair cleansing composition containing the present compound, good finger comb properties at the time of rinsing are exemplified. For example, patent document 1 discloses a hair cleansing composition containing sodium laurylmethyl- β -alaninate, triethanolamine alkyl sulfate, lauramidopropyl betaine, and a dimethyldiallylammonium chloride-acrylamide copolymer, and describes that the composition contains sodium laurylmethyl- β -alaninate from the viewpoint of finger comb-through during rinsing (see paragraph [0016 ]).
Further, as a method for quantitatively evaluating the finger comb-through property at the time of rinsing, there is a method of measuring turbidity as turbidity observed at the time of diluting the hair cleansing agent. The principle is that a hair cleansing agent containing three components of an anionic surfactant, an amphoteric surfactant, and a cationized polymer is diluted with a large amount of water to form a water-insoluble complex (coacervate), whereby turbidity occurs in the diluted solution. Since the coacervate is insoluble in water, it adheres to hair during rinsing, and reduces friction between hair and fingers, thereby exhibiting an effect of improving finger comb-through.
For example, patent document 2 discloses a shampoo composition comprising an ionic surfactant, a cationized tara gum and a polyoxyethylene fatty acid glyceride, and the evaluation of the coacervate formation ability upon rinsing of a shampoo composition comprising sodium lauroylmethyl β -alaninate as the ionic surfactant has been described previously (see examples 2 and 3, paragraph [0020 ]).
Further, techniques for promoting the formation of the coacervate have been proposed. For example, patent document 3 discloses a shampoo composition which contains a specific alkylene oxide derivative in addition to an anionic surfactant, an amphoteric surfactant, a cationic polymer and an inorganic salt of an alkali metal, and in which the specific alkylene oxide derivative promotes aggregation between the anionic surfactant and the cationic polymer (see paragraph [0024 ]).
In addition, the formation of the coacervate not only reduces friction between the hair and the finger, but also reduces friction between the hair and the finger, thereby suppressing the sticking and exerting an effect of being less likely to be entangled. Thus, the foam generated during washing is not remained in the entangled hair, and the effect of easy rinsing is achieved.
In this way, it has been proposed to form a coacervate by a cleaning agent composition such as the above-mentioned composition, and thereby improve finger comb-through property at the time of rinsing. However, although these compositions have excellent coacervate formation ability, they may have a problem that they are difficult to flow out from a pump or are less likely to foam during cleaning because they increase the viscosity of the hair cleansing agent composition.
In addition, recently, hair cleansing agents have been increasingly designed, and have been required to be transparent as a composition. However, since the above-mentioned composition is intended to promote the formation of a coacervate, there are cases where the coacervate is precipitated and the external transparency is maintained poorly in the hair cleansing composition before dilution. In particular, in winter, there are cases where the transparency is maintained poorly, that is, the transparency at low temperatures (low temperature stability) is poor.
Therefore, a hair cleansing composition is desired which has excellent coacervate formation ability, is easily discharged from a pump, has an appropriate viscosity that is easily foamed during cleansing, and has low-temperature stability that can maintain a transparent appearance even at low temperatures in winter or the like.
Prior art literature
Patent literature
Patent document 1: japanese patent laid-open No. 2021-24828
Patent document 2: japanese patent laid-open No. 2009-120559
Patent document 3: japanese patent laid-open No. 2013-216639
Disclosure of Invention
Technical problem to be solved by the invention
The present invention has been made to solve the above-mentioned problems, and an object of the present invention is to provide a hair cleansing composition which is a cleansing composition for hair, has excellent coacervate formation ability, is easily discharged from a pump, has an appropriate viscosity which is easily foamed during cleansing, and has low-temperature stability which can maintain a transparent appearance even at low temperatures.
Technical means for solving the technical problems
The inventors of the present application have conducted intensive studies to solve the above-mentioned problems, and as a result, have found that the above-mentioned problems can be solved by combining a specific anionic surfactant, an amphoteric surfactant, a cationized polymer and a specific compound and/or a salt thereof in a specific mass ratio, and have completed the present invention.
Namely, the present invention is the following hair cleansing composition.
A hair cleansing composition comprising
1 to 20 mass% of component (a): a surfactant represented by the following formula (1),
1 to 20 mass% of component (B): an amphoteric surfactant,
0.03 to 3 mass% of component (C): cationized polymers
0.001 to 1.5 mass% of component (D): a compound represented by the following formula (2) and/or a salt thereof,
the mass ratio of the component (A) to the component (B) ((A)/(B)) is 0.2 to 4, and the mass ratio of the component (A) to the component (D) ((A)/(D)) is 15 to 300,
[ chemical formula 1]
In the formula (1), R 1 CO represents an aliphatic acyl group having 8 to 22 carbon atoms, R 2 Represents a hydrogen atom or a straight-chain alkyl or branched alkyl group having 1 to 4 carbon atoms optionally having one hydroxyl group, M represents an alkali metal, 1/2 alkaline earth metal or organic ammonium,
[ chemical formula 2]
In the formula (2), R 3 Represents a hydrogen atom or a straight-chain alkyl group or a branched alkyl group having 1 to 4 carbon atoms.
Effects of the invention
The hair cleansing composition of the present invention (hereinafter also simply referred to as "cleansing composition") has excellent coacervate formation ability, is easily discharged from a pump, has an appropriate viscosity that easily foams at the time of cleansing, and has low-temperature stability that can maintain a transparent appearance even at low temperatures.
Detailed Description
Hereinafter, embodiments of the present invention will be described, but the present invention is not limited to the embodiments described in the present specification, and various modifications may be made without departing from the gist of the present invention.
In the present specification, the symbols "-" are used to include the numerical values at both ends (upper limit and lower limit) of "-". For example, "2 to 4" means 2 or more and 4 or less.
In addition, in the numerical ranges described in the present specification, the upper limit value or the lower limit value of the numerical ranges can be replaced with the values shown in the examples or the values derived from the examples without doubt.
The cleaning agent composition of the present invention contains at least the following components (A), (B), component (C) and component (D). The components will be described below.
The content of each component in the present specification is a content in which the total amount of the cleaning agent composition of the present invention is 100% by mass. When a plurality of substances corresponding to the respective components are present in the composition, the content of the respective components in the composition means the total content of the plurality of substances present in the composition.
[ component (A) ]
The component (a) used in the present invention is a surfactant represented by the following formula (1).
[ chemical formula 1]
R in formula (1) 1 CO represents an aliphatic acyl group having 8 to 22 carbon atoms, preferably 8 to 18 carbon atoms. The aliphatic acyl group includes not only an acyl group derived from a saturated fatty acid or an unsaturated fatty acid having 8 to 22 carbon atoms, but also an acyl group derived from a mixed fatty acid containing two or more of the above fatty acids. Examples of the aliphatic acyl group include cocoyl, palm kernel oleoyl, octanoyl (caproyl), caproyl (caproyl), lauroyl, myristoyl, palmitoyl, stearoyl, oleoyl, and behenoyl groups. Among them, lauroyl, myristoyl, cocoyl, and palm kernel oleoyl are preferable, and lauroyl, cocoyl, and palm kernel oleoyl are more preferable.
R in formula (1) 2 Represents a hydrogen atom or a straight-chain alkyl group or branched alkyl group having 1 to 4 carbon atoms optionally having one hydroxyl group. Examples of the straight-chain alkyl group or branched alkyl group having 1 to 4 carbon atoms include methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, isobutyl group, tert-butyl group and the like. Examples of the straight-chain alkyl group or branched alkyl group having 1 to 4 carbon atoms and having one hydroxyl group include hydroxymethyl group, 1-hydroxyethyl group, 2-hydroxyethyl group, 1-hydroxypropyl group, 2-hydroxypropyl group, 3-hydroxypropyl group, 1-hydroxyisopropyl group, 2-hydroxyisopropyl group, 1-hydroxybutyl group, 2-hydroxybutyl group, 3-hydroxybutyl group, 4-hydroxybutyl group, 1-hydroxyisobutyl group, 2-hydroxyisobutyl group, 3-hydroxyisobutyl group and the like. Among them, preferred are a hydrogen atom, a methyl group, an ethyl group, a 2-hydroxyethyl group and a 3-hydroxypropyl group, and more preferred are a hydrogen atom and a methyl group.
M in the formula (1) represents an alkali metal, 1/2 alkaline earth metal or organic ammonium. Examples of the alkali metal include sodium and potassium, and examples of the alkaline earth metal include magnesium and calcium. Examples of the organic ammonium include monoethanolamine, diethanolamine, and triethanolammonium. M is preferably sodium, potassium or triethanolamine, and more preferably sodium.
In addition, 1/2 of the "1/2 alkaline earth metal" means a coefficient in which the valence (divalent) is monovalent when the alkaline earth metal is a cation.
Specific examples of the surfactant represented by the formula (1) include sodium N-lauroyl- β -alanine, sodium N-cocoyl- β -alanine, sodium N-lauroyl-N-methyl- β -alanine triethanolamine, sodium N-cocoyl-N-methyl- β -alanine, sodium N-lauroyl-N-ethyl- β -alanine, sodium N-lauroyl-N-2-hydroxyethyl- β -alanine triethanolamine, sodium N-lauroyl-N-3-hydroxypropyl- β -alanine triethanolamine, sodium N-cocoyl-N-2-hydroxyethyl- β -alanine, and the like.
As the component (a), one kind of surfactant selected from the above formula (1) may be used alone or two or more kinds of surfactant selected from the above formula (1) may be used together.
The content of the component (A) is 1 to 20% by mass, preferably 3 to 15% by mass, and more preferably 5 to 10% by mass. When the content of the component (a) is too small, the viscosity may become too low or the coacervate formation ability may be deteriorated, and when the content of the component (a) is too large, the viscosity may become too high or the low-temperature stability may be deteriorated.
[ component (B) ]
The component (B) used in the present invention is an amphoteric surfactant having a structure comprising an N-acyl group or an N-alkyl group, a cationic group and an anionic group. Examples thereof include alkyl betaines, alkyl amidobetaines, alkyl hydroxysulfobetaines, alkyl amidohydroxysulfobetaines, alkyl carboxymethyl hydroxyethyl imidazoline betaines, alkyl amidohydroxyethyl amino acid type amphoteric surfactants, and alkyl iminodiacetic acid salts.
The N-acyl group contained in the amphoteric surfactant is, for example, a linear fatty acid residue or a branched fatty acid residue having 8 to 18 carbon atoms. Examples of fatty acids of fatty acid residues include saturated fatty acids such as caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, and isostearic acid; unsaturated fatty acids such as palmitoleic acid, oleic acid, elaidic acid, linoleic acid, and linolenic acid; and coconut oil fatty acid, palm kernel oil fatty acid, tallow fatty acid, hardened tallow fatty acid, and the like as a mixture thereof. Among these, lauric acid, myristic acid, palmitic acid, oleic acid, coconut oil fatty acid, and palm kernel oil fatty acid are preferable, and lauric acid, coconut oil fatty acid, and palm kernel oil fatty acid are more preferable.
The N-alkyl group contained in the amphoteric surfactant is, for example, a hydrocarbon group having 8 to 18 carbon atoms, and further contains a mixed alkyl group derived from a mixed fatty acid. Examples of the alkyl group include alkyl groups such as octyl (capryl), decyl, lauryl, myristyl, palmityl, stearyl, and oleyl groups; mixed alkyl groups such as coconut oil alkyl group, palm kernel oil alkyl group, and tallow alkyl group. Among them, preferred are lauryl, myristyl, palmityl, coconut oil alkyl and palm kernel oil alkyl groups, and more preferred are lauryl, coconut oil alkyl and palm kernel oil alkyl groups.
Specific examples of the amphoteric surfactant of the component (B) include lauryl betaine, cocamidopropyl betaine, palm kernel oleamidopropyl betaine, lauryl hydroxysulfobetaine, sodium cocoyl amphoacetate, and the like.
As the component (B), one kind selected from the above-mentioned amphoteric surfactants may be used alone or two or more kinds selected from the above-mentioned amphoteric surfactants may be used simultaneously.
The content of the component (B) is 1 to 20% by mass, preferably 3 to 15% by mass, more preferably 4 to 13% by mass, and particularly preferably 5 to 10% by mass. When the content of the component (B) is too small, the viscosity may become too low or the low-temperature stability may be deteriorated, and when the content of the component (B) is too large, the viscosity may become too high or the coacervate formation ability may be deteriorated.
[ component (C) ]
Examples of the component (C) include homopolymers of dialkyldiallylammonium chloride, copolymers of dialkyldiallylammonium chloride and (meth) acrylic acid ester, copolymers of dialkyldiallylammonium chloride and (meth) acrylamide, polychloromethylacryloyloxyethyl trimethyl ammonium chloride, cationized cellulose, cationized starch, cationized guar gum, cationized tara gum, cationized locust bean gum, cationized xanthan gum, cationized fenugreek gum, copolymers of vinylimidazoline trichloride (vinyl imidazolinium trichloride) and vinylpyrrolidone, copolymers of hydroxyethylcellulose and dimethyldiallylammonium chloride, copolymers of vinylpyrrolidone and dimethylaminoethyl methacrylate, copolymers of polyvinylpyrrolidone and alkylaminoacrylic acid ester and vinylcaprolactam, copolymers of vinylpyrrolidone and methacrylamidopropyl trimethyl ammonium chloride, copolymers of alkylacrylamide and acrylic acid ester and alkylaminoalkylacrylamide and polyoxyethylene glycol methacrylate, and copolymers of adipic acid and dimethylaminohydroxypropylvinyl triamine. Among them, preferred are cationized cellulose, cationized guar gum, cationized tara gum, homopolymers of dialkyldiallylammonium chloride, copolymers of dialkyldiallylammonium chloride and (meth) acrylamide.
In addition, "(meth) acrylic acid" means acrylic acid or methacrylic acid, and "(meth) acrylate" means acrylate or methacrylate.
As the component (C), one kind selected from the above-mentioned cationized polymers may be used alone or two or more kinds selected from the above-mentioned cationized polymers may be used simultaneously.
The cationization degree of the cationized polymer is preferably 0.2 to 3meq/g, more preferably 0.5 to 2meq/g, particularly preferably 0.8 to 1.5meq/g, further preferably 1.0 to 1.4meq/g. In the present specification, the cationization degree of the cationized polymer is a value calculated from a measured value of the N content measured by kjeldahl method or the like. In addition, the unit meq/g of the degree of cationization represents the number of milliequivalents of N-cation groups per gram of sample.
The weight average molecular weight of the cationized polymer is preferably in the range of 100,000 ～ 3,000,000, more preferably 400,000 ～ 2,000,000, particularly preferably 600,000 ～ 1,900,000, further preferably 800,000 ～ 1,800,000, particularly preferably 850,000 ～ 1,750,000.
In the present specification, the weight average molecular weight of the cationized polymer is a value obtained by conversion of polyethylene glycol using Gel Permeation Chromatography (GPC).
The content of the component (C) is 0.03 to 3% by mass, preferably 0.1 to 1.5% by mass, more preferably 0.3 to 1% by mass, and particularly preferably 0.4 to 0.8% by mass. When the content of the component (C) is too small, the viscosity may become too low or the coacervate formation ability may be deteriorated, and when the content of the component (C) is too large, the viscosity may become too high or the low-temperature stability may be deteriorated.
[ component (D) ]
The component (D) is beta-alanine or a derivative thereof, which is a compound represented by the following formula (2) or a salt thereof.
[ chemical formula 2]
R in formula (2) 3 Represents a hydrogen atom or a straight-chain alkyl group or a branched alkyl group having 1 to 4 carbon atoms. Examples of the straight-chain alkyl group or branched alkyl group having 1 to 4 carbon atoms include methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, isobutyl group, tert-butyl group and the like. Among them, a hydrogen atom, a methyl group, and an ethyl group are preferable, and a hydrogen atom and a methyl group are more preferable.
Specific examples of the compound represented by the formula (2) include β -alanine, N-methyl- β -alanine, N-ethyl- β -alanine, N-t-butyl- β -alanine, and the like.
Examples of the salt of the compound of formula (2) include, but are not limited to, sodium salt, potassium salt, magnesium salt, calcium salt, monoethanolamine salt, diethanolamine salt, triethanolamine salt, hydrochloride, sulfate, citrate, malate, lactate, and the like. Among them, sodium salt, potassium salt, triethanolamine salt, hydrochloride, citrate, malate and lactate are preferable, and sodium salt, citrate, malate and lactate are more preferable.
As the component (D), one kind selected from the compounds of the above formula (2) and salts thereof or two or more kinds selected from the compounds of the above formula (2) and salts thereof may be used singly or in combination.
The content of the component (D) is 0.001 to 1.5% by mass, preferably 0.01 to 1% by mass, more preferably 0.01 to 0.7% by mass, particularly preferably 0.05 to 0.5% by mass, and even more preferably 0.05 to 0.3% by mass. When the content of the component (D) is too small, the coacervate formation ability or the low-temperature stability may be deteriorated, and when the content of the component (D) is too large, the viscosity may be too low.
[ relation of the amounts of the respective Components ]
The mass ratio ((A)/(B)) of the component (A) to the component (B) in the cleaning agent composition of the present invention is 0.2 to 4, preferably 0.3 to 3, more preferably 0.6 to 2, particularly preferably 0.7 to 1.8, and further preferably 0.7 to 1.6. When the mass ratio ((a)/(B)) is too small, the coacervate formation ability may be deteriorated, and when the mass ratio ((a)/(B)) is too large, the low-temperature stability may be deteriorated.
The mass ratio ((a)/(D)) of the component (a) to the component (D) in the cleaning agent composition of the present invention is 15 to 300, preferably 25 to 150, more preferably 60 to 150, and particularly preferably 80 to 140. When the mass ratio ((a)/(D)) is too small, the viscosity may become too low, and when the mass ratio ((a)/(D)) is too large, the low-temperature stability may be deteriorated.
[ Water ]
The cleaning agent composition of the present invention generally contains water in addition to the above components (a) to (D). Examples of the water include purified water such as distilled water and ion-exchanged water, and tap water. Among them, purified water such as distilled water or ion-exchanged water is preferable.
The water content in the cleaning agent composition of the present invention is preferably 55 to 98% by mass, more preferably 65 to 95% by mass, particularly preferably 75 to 90% by mass, and further preferably 75 to 85% by mass.
The total content of the components (a) to (D) and water is preferably 80% by mass or more, more preferably 85% by mass or more, and particularly preferably 90% by mass or more.
[ other optional Components ]
In addition to the above components (a) to (D) and water, the cleaning agent composition of the present invention may further contain any other components within a range that does not impair the effects of the present invention.
Examples of the other optional components include oils and fats such as vegetable oils and fats and animal oils and fats; hydrocarbon oils such as squalane, liquid paraffin, hydrogenated polyisobutene, and the like; higher alcohols such as cetyl alcohol, stearyl alcohol and cetylstearyl alcohol; silicones such as cyclic silicones, dimethylpolysiloxanes and amino-modified polysiloxanes; ester oils such as 2-ethylhexyl palmitate, caprylic/capric triglyceride, isopropyl myristate, and the like; anionic surfactants such as polyoxyethylene lauryl ether sulfate, α -olefin sulfonate, fatty acid soap, and N-acyl amino acid surfactants other than component (a); cationic surfactants such as stearyl trimethyl ammonium chloride, benzalkonium chloride, and ethyl cocoyl arginine PCA; nonionic surfactants such as polyoxyethylene alkyl ethers, polyglycerin fatty acid esters, polyoxyethylene glycerin fatty acid esters, fatty acid alkanolamides (e.g., diethanolamide laurate, etc.), fatty acid alkylene glycol esters (e.g., monobutyl laurate, etc.); water-soluble polymers other than component (C), such as hydroxyethyl cellulose, polyethylene glycol, polyvinyl alcohol, and carboxyvinyl polymer; solvents such as ethanol, propylene glycol, and glycerin; pH adjusters such as sodium hydroxide, potassium hydroxide, monoethanolamine, triethanolamine, hydrochloric acid, sulfuric acid, citric acid, succinic acid, malic acid, lactic acid, and tartaric acid; antioxidants such as tocopherol; preservative such as sodium benzoate, 1, 3-butanediol; humectant such as ethylhexyl glycerin, polysaccharides, amino acids, peptides, perfume, and colorant.
The content of the other optional components is preferably 20% by mass or less, more preferably 0.1 to 15% by mass, and particularly preferably 1 to 10% by mass.
The pH of the cleaning agent composition of the present invention is not particularly limited, but is preferably 4.5 to 8.0, more preferably 5.0 to 7.5, and particularly preferably 5.5 to 7.0 in a state of a stock solution at 25 ℃ without dilution with water.
In order to adjust the pH of the cleaning agent composition to the above range, the pH adjuster is preferably citric acid, malic acid, or lactic acid, more preferably citric acid or lactic acid. The content of the pH adjustor is 0.05 to 5% by mass, preferably 0.1 to 3% by mass, more preferably 0.5 to 2% by mass.
The pH of the cleaning agent composition in the present specification is a value measured in accordance with JIS Z8802 using a pH meter.
The cleaning agent composition of the present invention can be prepared according to a known method. For example, the above components (a) to (D) are added, and if necessary, other optional components are added, and the total amount of the composition is adjusted with water to 100 mass%. Then, heating and mixing are performed as needed, thereby obtaining the cleaning agent composition of the present invention.
Examples
Hereinafter, the present invention will be specifically described with reference to examples and comparative examples, but the present invention is not limited to these examples.
Examples 1 to 16 and comparative examples 1 to 10
< preparation of detergent composition >
The hair cleansing compositions of examples 1 to 16 and comparative examples 1 to 10 were prepared by sequentially adding the component (a) shown in table 1, the components (B) to (D) shown in tables 2 to 4, and other components to water and mixing them, and uniformly dissolving them.
TABLE 1
TABLE 1
| A-1 | A-2 | A-3 | A-4 | |
| R 1 CO | Lauroyl group | Lauroyl group | Cocoyl radical | Lauroyl group |
| R 2 | Methyl group | Methyl group | Hydrogen atom | 2-hydroxyethyl group |
| M | Sodium salt | Triethanolamine salt | Sodium salt | Sodium salt |
Commercially available products provided as cosmetics were used as each component in tables 1 to 4. The content of each component in tables 2 to 4 is expressed as mass%, and the total amount of the hair cleansing composition is 100 mass%. The cationization degree and the weight average molecular weight of the component (C) are calculated by the method described in the present specification.
The respective cleaning agent compositions of examples 1 to 16 and comparative examples 1 to 10 were evaluated for viscosity, coacervate formation ability, and low-temperature stability as described in the following (1) to (3). The pH of each cleaning agent composition was measured in the state of a stock solution (the cleaning agent composition in a total amount of 100% by mass) which was not diluted with water.
< evaluation of detergent composition >
(1) Viscosity of the mixture
Each of the detergent compositions of the examples and comparative examples was measured at 25℃using a type B viscometer (model "TV-20" manufactured by TOKISANGYO), and at a speed of 12rpm or 30rpm for rotor Nos. 2 to 4. Based on the measured viscosity (mpa·s, 25 ℃), the viscosity of the cleaning agent composition was evaluated on four scales of "," -o "," "Δ", "×" according to the following evaluation criteria. The evaluation was qualified when it was "good" and "good".
< evaluation criteria >
And (3) the following materials: viscosity of 2,000 or more and less than 10,000
O: a viscosity of 1,000 or more and less than 2,000, or 10,000 or more and less than 20,000
Delta: viscosity of less than 1,000
X: viscosity of 20,000 or more
(2) Coacervate formation ability
1g of each of the detergent compositions of examples and comparative examples was diluted with tap water at 40℃to a total of 100mL. The light transmittance of these dilutions was measured at a wavelength of 420nm using a UV-Vis spectrophotometer (U-3010 manufactured by Hitachi High-Tech Corporation). The turbidity was calculated from the values according to the following calculation formula. Based on the calculated turbidity, the coacervate formation ability of the cleaning agent composition was evaluated on four levels of "", "-," "Δ", and "×" according to the following evaluation criteria. The evaluation was qualified when it was "good" and "good".
Turbidity (%) =100-transmittance (%)
< evaluation criteria >
And (3) the following materials: turbidity is above 40%
O: the turbidity is more than 30% and less than 40%
Delta: turbidity is more than 20% and less than 30%
X: turbidity less than 20%
(3) Low temperature stability
The cleaning agent compositions of examples and comparative examples were sealed in a transparent glass container, and stored at 0℃and 5℃for one month, respectively, and the appearance thereof was observed. Based on the observed appearance, the low-temperature stability of the cleaning agent composition was evaluated on three scales of "Σ", "Δλ" and "×" according to the following evaluation criteria. The evaluation was qualified when it was "good".
< evaluation criteria >
O: there was no change in appearance at either 0℃or 5 ℃.
Delta: although there was no change in appearance at 5 ℃, the composition became cloudy at 0 ℃.
X: the composition became cloudy at both 0℃and 5 ℃.
Tables 2 to 4 show the evaluation results of the above (1) to (3) in combination.
The compositions of examples 1 to 16 were excellent in viscosity, coacervate formation ability and low-temperature stability.
On the other hand, in comparative example 1, since sodium polyoxyethylene (3) lauryl ether sulfate (component (a')) was used as an anionic surfactant instead of component (a), the viscosity was high and the coacervate formation ability was poor.
In comparative example 2, since sodium N-cocoyl-N-methyltaurine (component (A')) was used as the N-acyl amino acid surfactant instead of component (A), the viscosity was low, and the coacervate formation ability and low-temperature stability were insufficient.
In comparative example 3, sodium N-cocoyl glutamate (component (A')) as an N-acyl amino acid surfactant was used instead of component (A), and therefore, the viscosity was low and the low-temperature stability was insufficient.
In comparative example 4, the component (a) was not contained, so that the viscosity was low and the coacervate formation ability was poor.
In comparative example 5, since component (B) was not contained, the viscosity was low and the low-temperature stability was also insufficient.
In comparative example 6, since component (C) was not contained, the viscosity was low and the coacervate formation ability was poor.
In comparative example 7, since the component (D) was not contained, the coacervate formation ability was poor and the low temperature stability was also insufficient.
In comparative example 8, the mass ratio ((a)/(B)) of the component (a) to the component (B) was less than 0.2, and therefore the viscosity was low and the coacervate formation ability was poor.
In comparative example 9, the mass ratio ((a)/(B)) of the component (a) to the component (B) was more than 4, and therefore the viscosity was high and the low-temperature stability was poor.
In comparative example 10, the mass ratio ((a)/(D)) of the component (a) to the component (D) was less than 15, and therefore the viscosity was low and the coacervate formation ability was insufficient.
/>
Further, the following specifically shows formulation examples of the hair cleansing agent composition of the present invention. In all the formulation examples, the total amount was adjusted to 100 mass% using purified water.
TABLE 5
Table 5 formulation example 1
*1: cationization degree=1.3 meq/g, weight average molecular weight=1,700,000
In addition, sodium N-lauroyl-N-methyl-beta-alanine corresponds to component (A), cocamidopropyl betaine corresponds to component (B), cationized cellulose corresponds to component (C), and N-methyl-beta-alanine corresponds to component (D). The mass ratio ((A)/(B)) was 1.3, and the mass ratio ((A)/(D)) was 90.
TABLE 6
Table 6 formulation example 2
*1: cationization degree=1.3 meq/g, weight average molecular weight=1,700,000
In addition, sodium N-lauroyl-N-methyl- β -alanine and sodium N-lauroyl-N-2-hydroxyethyl- β -alanine correspond to component (a), lauryl hydroxysulfobetaine corresponds to component (B), and cationized cellulose corresponds to component (C), and N-methyl- β -alanine corresponds to component (D). The mass ratio ((A)/(B)) was 1.1, and the mass ratio ((A)/(D)) was 90.
TABLE 7
Table 7 formulation example 3
*1: cationization degree=1.3 meq/g, weight average molecular weight=1,700,000
In addition, sodium N-lauroyl-N-methyl-beta-alanine corresponds to component (A), cocamidopropyl betaine corresponds to component (B), cationized cellulose corresponds to component (C), and N-methyl-beta-alanine corresponds to component (D). The mass ratio ((A)/(B)) was 0.8, and the mass ratio ((A)/(D)) was 50.
The hair cleansing compositions of these formulation examples were also evaluated in the above-described items (1) to (3), and as a result, the hair cleansing compositions were excellent in coacervate formation ability, had a proper viscosity, and exhibited good low-temperature stability, and therefore, the effects of the present invention were confirmed.
Industrial applicability
The hair cleansing composition of the present invention has excellent coacervate forming ability, is easily discharged from a pump, has a proper viscosity that is easily foamed during cleansing, and has low-temperature stability that can maintain a transparent appearance even at low temperatures such as winter, and therefore not only can obtain good finger comb-through properties during rinsing, but also is convenient to use and excellent in design.
Claims (1)
1. A hair cleansing composition comprising
1 to 20 mass% of component (a): a surfactant represented by the following formula (1),
1 to 20 mass% of component (B): an amphoteric surfactant,
0.03 to 3 mass% of component (C): cationized polymers
0.001 to 1.5 mass% of component (D): a compound represented by the following formula (2) and/or a salt thereof,
the mass ratio of the component (A) to the component (B) ((A)/(B)) is 0.2 to 4, and the mass ratio of the component (A) to the component (D) ((A)/(D)) is 15 to 300,
[ chemical formula 1]
In the formula (1), R 1 CO represents an aliphatic acyl group having 8 to 22 carbon atoms, R 2 Represents a hydrogen atom or a straight-chain alkyl or branched alkyl group having 1 to 4 carbon atoms optionally having one hydroxyl group, M represents an alkali metal, 1/2 alkaline earth metal or organic ammonium,
[ chemical formula 2]
In the formula (2), R 3 Represents a hydrogen atom or a straight-chain alkyl group or a branched alkyl group having 1 to 4 carbon atoms.
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| JP7201411B2 (en) | 2018-11-30 | 2023-01-10 | 川研ファインケミカル株式会社 | Hair cleanser composition |
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