JP2003082387A - Liquid detergent composition - Google Patents
Liquid detergent compositionInfo
- Publication number
- JP2003082387A JP2003082387A JP2001275340A JP2001275340A JP2003082387A JP 2003082387 A JP2003082387 A JP 2003082387A JP 2001275340 A JP2001275340 A JP 2001275340A JP 2001275340 A JP2001275340 A JP 2001275340A JP 2003082387 A JP2003082387 A JP 2003082387A
- Authority
- JP
- Japan
- Prior art keywords
- carbon atoms
- group
- formula
- chemical
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 33
- 239000003599 detergent Substances 0.000 title claims abstract description 17
- 239000007788 liquid Substances 0.000 title claims abstract description 10
- 230000008719 thickening Effects 0.000 claims abstract description 22
- 239000012190 activator Substances 0.000 claims abstract description 20
- 125000000129 anionic group Chemical group 0.000 claims abstract description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 30
- 125000000217 alkyl group Chemical group 0.000 claims description 25
- 239000000126 substance Substances 0.000 claims description 20
- 229910052783 alkali metal Inorganic materials 0.000 claims description 14
- 150000001340 alkali metals Chemical class 0.000 claims description 14
- 125000003342 alkenyl group Chemical group 0.000 claims description 13
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
- 238000004140 cleaning Methods 0.000 claims description 5
- 239000004480 active ingredient Substances 0.000 claims description 3
- 239000002280 amphoteric surfactant Substances 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims 7
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 4
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 6
- 206010040880 Skin irritation Diseases 0.000 abstract description 5
- 230000036556 skin irritation Effects 0.000 abstract description 5
- 231100000475 skin irritation Toxicity 0.000 abstract description 5
- 239000004094 surface-active agent Substances 0.000 abstract description 4
- 230000002411 adverse Effects 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 18
- 229930195729 fatty acid Natural products 0.000 description 18
- 239000000194 fatty acid Substances 0.000 description 18
- -1 for example Chemical group 0.000 description 16
- 239000003240 coconut oil Substances 0.000 description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 14
- 150000004665 fatty acids Chemical class 0.000 description 13
- 125000006353 oxyethylene group Chemical group 0.000 description 11
- 235000019864 coconut oil Nutrition 0.000 description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 8
- 239000003945 anionic surfactant Substances 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 7
- 159000000000 sodium salts Chemical class 0.000 description 7
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 6
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 230000000638 stimulation Effects 0.000 description 3
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 3
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- DUXYWXYOBMKGIN-UHFFFAOYSA-N trimyristin Chemical compound CCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCC DUXYWXYOBMKGIN-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- VCRXMSMANOGRCM-UHFFFAOYSA-N 2-(dodecanoylamino)butanedioic acid Chemical class CCCCCCCCCCCC(=O)NC(C(O)=O)CC(O)=O VCRXMSMANOGRCM-UHFFFAOYSA-N 0.000 description 1
- AVBJHQDHVYGQLS-UHFFFAOYSA-N 2-(dodecanoylamino)pentanedioic acid Chemical class CCCCCCCCCCCC(=O)NC(C(O)=O)CCC(O)=O AVBJHQDHVYGQLS-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- UNWFFCPRJXMCNV-UHFFFAOYSA-N 3-[dodecanoyl(methyl)amino]propanoic acid Chemical class CCCCCCCCCCCC(=O)N(C)CCC(O)=O UNWFFCPRJXMCNV-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 1
- 101100321669 Fagopyrum esculentum FA02 gene Proteins 0.000 description 1
- 101100321670 Fagopyrum esculentum FA18 gene Proteins 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 1
- BACYUWVYYTXETD-UHFFFAOYSA-N N-Lauroylsarcosine Chemical class CCCCCCCCCCCC(=O)N(C)CC(O)=O BACYUWVYYTXETD-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000005643 Pelargonic acid Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940009098 aspartate Drugs 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- IUNMPGNGSSIWFP-UHFFFAOYSA-N dimethylaminopropylamine Chemical compound CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000000755 henicosyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 229940071180 lauryl sulfosuccinate Drugs 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229940105132 myristate Drugs 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- UDGSVBYJWHOHNN-UHFFFAOYSA-N n',n'-diethylethane-1,2-diamine Chemical compound CCN(CC)CCN UDGSVBYJWHOHNN-UHFFFAOYSA-N 0.000 description 1
- DILRJUIACXKSQE-UHFFFAOYSA-N n',n'-dimethylethane-1,2-diamine Chemical compound CN(C)CCN DILRJUIACXKSQE-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 125000001196 nonadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Natural products NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、液体洗浄剤組成物に関
する。本洗浄剤組成物は、良好な起泡性を有し、毛髪及
び皮膚に対する刺激が少なく、毛髪用、身体用、繊維用
及び各種家庭用洗浄剤等として有用である。FIELD OF THE INVENTION The present invention relates to liquid detergent compositions. The detergent composition has a good foaming property, is less irritating to hair and skin, and is useful as a detergent for hair, body, textiles and various households.
【０００２】[0002]
【従来技術】単独では必要とする増粘効果が得られない
アニオン界面活性剤（難増粘性アニオン活性剤）を主基
材とする液体洗浄剤組成物は、一般に低刺激性で低温安
定性良好であるものの、その使用において必要とされる
適度な粘度の付与が困難であった。2. Description of the Related Art A liquid detergent composition containing an anionic surfactant (difficulty thickening anionic surfactant) as a main base material, which cannot obtain the required thickening effect by itself, is generally mild and has good low temperature stability. However, it was difficult to impart the appropriate viscosity required for its use.
【０００３】かかる欠点を解消するために無機塩を用い
る方法があるが、このものを添加した場合には低温安定
性が低下する。また、脂肪酸ジエタノールアミドは、増
粘作用には極めて優れているが、主剤となるアニオン活
性剤の種類により増粘効果を示さなかったり、分離する
といった欠点を有している。更に、目的の粘度を得るた
めに難増粘性のアニオン活性剤とサルフェート型アニオ
ン界面活性剤とを併用する方法も試みたが、この場合に
は、刺激性が増大し、何れの方法も満足し得るものでは
なかった。There is a method of using an inorganic salt in order to solve such a drawback, but when this is added, the low temperature stability is lowered. Further, the fatty acid diethanolamide is extremely excellent in thickening action, but has a defect that it does not show a thickening effect or separates depending on the type of anionic activator as a main ingredient. Furthermore, in order to obtain the target viscosity, a method of using an anionic surfactant having a difficulty in thickening and a sulfate type anionic surfactant in combination has been tried, but in this case, irritation is increased, and any method is satisfied. I didn't get it.
【０００４】[0004]
【発明が解決しようとしている課題】本発明は、難増粘
性アニオン界面活性剤を必須成分とし、適度な粘度を有
し、低温安定性が良好で、且つ低刺激性の洗浄剤組成物
を提供することを目的とする。DISCLOSURE OF THE INVENTION The present invention provides a detergent composition which contains a hardly-viscosifying anionic surfactant as an essential component, has an appropriate viscosity, has good low-temperature stability, and is mild. The purpose is to do.
【０００５】[0005]
【課題を解決するための手段】本発明者らは、難増粘性
のアニオン界面活性剤に特定の両性界面活性剤及びアミ
ドアミン型活性剤を混合することにより、低温安定性及
び低刺激性を損なうことなく所定の効果が得られること
を見いだし、かかる知見に基づいて本発明を完成するに
至った。The present inventors impair low temperature stability and low irritation by mixing a specific amphoteric surfactant and an amidoamine type surfactant with an anionic surfactant having a low viscosity increase. It has been found that a predetermined effect can be obtained without them, and the present invention has been completed based on such findings.
【０００６】そこで本発明は、下記の（Ａ），（Ｂ）及
び（Ｃ）の３成分を含有し、（Ａ）／（Ｂ）の重量比が
１０／９０〜８０／２０であり、（（Ａ）＋（Ｂ））／
（Ｃ）の重量比が１００／１〜１００／４０である混合
物を活性成分とする液体洗浄剤組成物であって、（Ａ）
成分は、下記、一般式（１）で表わされる１種又は２種
以上のアルキルジメチルアミンオキシド型界面活性剤か
ら選ばれ、Therefore, the present invention contains the following three components (A), (B) and (C), and the weight ratio of (A) / (B) is 10/90 to 80/20. (A) + (B)) /
A liquid detergent composition comprising, as an active ingredient, a mixture in which the weight ratio of (C) is 100/1 to 100/40, wherein (A)
The component is selected from one or more alkyldimethylamine oxide type surfactants represented by the following general formula (1),
【０００７】[0007]
【化１０】 [Chemical 10]
【０００８】〔式中、Ｒ1 は炭素数８〜２２のアルキル
基、アルケニル基を示す。〕[In the formula, R 1 represents an alkyl group or an alkenyl group having 8 to 22 carbon atoms. ]
【０００９】（Ｂ）成分は、下記、一般式（２）〜
（８）で表される１種又は２種以上の難増粘性アニオン
活性剤から選ばれ、The component (B) is represented by the following general formula (2) to
Selected from one or two or more types of hardly-viscosifying anionic activators represented by (8),
【００１０】[0010]
【化１１】 [Chemical 11]
【００１１】〔式中、Ｒ2 は炭素数７〜２１のアルキル
基又はアルケニル基を表し、Ｍ1 はアルカリ金属、アル
カノールアミンを表す。〕[In the formula, R 2 represents an alkyl group or an alkenyl group having 7 to 21 carbon atoms, and M 1 represents an alkali metal or an alkanolamine. ]
【００１２】[0012]
【化１２】 [Chemical 12]
【００１３】〔式中、Ｒ3 は炭素数７〜２１のアルキル
基又はアルケニル基を表し、Ｍ2 はアルカリ金属、アル
カノールアミンを表し、ａは１又は２の整数を示す。〕[In the formula, R 3 represents an alkyl group or an alkenyl group having 7 to 21 carbon atoms, M 2 represents an alkali metal or an alkanolamine, and a represents an integer of 1 or 2. ]
【００１４】[0014]
【化１３】 [Chemical 13]
【００１５】〔式中、Ｒ4 は炭素数７〜２１のアルキル
基又はアルケニル基を表し、Ｍ3 、Ｍ 4 は同一又は異な
って、水素原子、アルカリ金属、アルカノールアミンを
表す。但し、Ｍ3 、Ｍ4 が共に水素原子であることはな
い。ｂは１又は２の整数で示す。〕[Wherein RFourIs an alkyl having 7 to 21 carbon atoms
Group or alkenyl group, M3, M FourAre the same or different
So hydrogen atom, alkali metal, alkanolamine
Represent However, M3, MFourAre not both hydrogen atoms
Yes. b is an integer of 1 or 2. ]
【００１６】[0016]
【化１４】 [Chemical 14]
【００１７】〔式中、Ｒ5 は炭素数８〜２２の直鎖又は
分岐鎖のアルキル基又はアルケニル基を表し、Ｍ5 はア
ルカリ金属、アルカノールアミンを表す。ｃは１〜１０
を示す。〕[In the formula, R 5 represents a linear or branched alkyl group or alkenyl group having 8 to 22 carbon atoms, and M 5 represents an alkali metal or an alkanolamine. c is 1-10
Indicates. ]
【００１８】[0018]
【化１５】 [Chemical 15]
【００１９】〔式中、Ｒ6 は炭素数７〜２１のアルキル
基又はアルケニル基を表し、Ｒ7 は水素原子又は炭素数
１〜３のアルキル基を表し、Ｍ6 はアルカリ金属、アル
カノールアミンを表す。ｄは１〜１０を示す。〕[In the formula, R 6 represents an alkyl group or an alkenyl group having 7 to 21 carbon atoms, R 7 represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and M 6 represents an alkali metal or an alkanolamine. Represent d shows 1-10. ]
【００２０】[0020]
【化１６】 [Chemical 16]
【００２１】〔式中、Ｒ8 は炭素数８〜２２の直鎖又は
分岐鎖のアルキル又はアルケニル基を表し、Ｍ7 、Ｍ8
は同一又は異なっても良く、アルカリ金属、アルカノー
ルアミンを表す。ｅは０〜１０を示す。〕[In the formula, R 8 represents a linear or branched alkyl or alkenyl group having 8 to 22 carbon atoms, and M 7 and M 8
May be the same or different and represent an alkali metal or an alkanolamine. e shows 0-10. ]
【００２２】[0022]
【化１７】 [Chemical 17]
【００２３】〔式中、Ｒ9 は炭素数７〜２１のアルキル
基又はアルケニル基を表し、Ｒ10は水素原子又は炭素数
１〜３のアルキル基を表し、Ｍ9 、Ｍ10は同一又は異な
っても良く、アルカリ金属、アルカノールアミンを表
す。ｆは０〜１０を示す。〕[In the formula, R 9 represents an alkyl group or an alkenyl group having 7 to 21 carbon atoms, R 10 represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and M 9 and M 10 are the same or different. May represent an alkali metal or alkanolamine. f shows 0-10. ]
【００２４】（Ｃ）成分は、下記、一般式（９）で表さ
れる１種又は２種以上のアミドアミン型活性剤The component (C) is one or more amidoamine type activators represented by the following general formula (9).
【００２５】[0025]
【化１８】 [Chemical 18]
【００２６】〔式中、Ｒ11は炭素数７〜２１のアルキル
又はアルケニル基を表し、Ｒ12は炭素数１〜２のアルキ
ル基を表す。ｇは２〜３の整数を示す。〕から選ばれる
液体洗浄剤組成物を提供する。[In the formula, R 11 represents an alkyl or alkenyl group having 7 to 21 carbon atoms, and R 12 represents an alkyl group having 1 to 2 carbon atoms. g shows the integer of 2-3. ] The liquid detergent composition selected from these is provided.
【００２７】[0027]
【発明の実施の形態】本発明の（Ａ）成分は、下記一般
式（１）で表されるアルキルジメチルアミンオキサイド
型両性活性剤である。BEST MODE FOR CARRYING OUT THE INVENTION The component (A) of the present invention is an alkyldimethylamine oxide type amphoteric activator represented by the following general formula (1).
【００２８】[0028]
【化１９】 [Chemical 19]
【００２９】一般式（１）において、Ｒ1 は炭素数８〜
２２のアルキル基又はアルケニル基であり、例えば、オ
クチル基、ノニル基、デシル基、ウンデシル基、ドデシ
ル基、トリデシル基、テトラデシル基、ペンタデシル
基、ヘキサデシル基、ヘプタデシル基、オクタデシル
基、ノナデシル基、イコシル基、ヘンイコシル基、ドコ
シル基等を挙げることが出来る。一般式（１）で表され
るアミンオキサイド型両性活性剤を製造する方法には特
に制限はなく、任意の公知の方法により製造することが
出来る。例えば、Ｎ−アルキルジメチルアミンを、過酸
化水素やペルオキシ酸等により酸化する事によって得る
ことが出来る。In the general formula (1), R 1 has 8 to 8 carbon atoms.
22 alkyl groups or alkenyl groups, for example, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, tridecyl group, tetradecyl group, pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group, nonadecyl group, icosyl group. , Henicosyl group, docosyl group and the like. The method for producing the amine oxide type amphoteric activator represented by the general formula (1) is not particularly limited, and it can be produced by any known method. For example, it can be obtained by oxidizing N-alkyldimethylamine with hydrogen peroxide, peroxy acid or the like.
【００３０】本発明の（Ｂ）である難増粘性アニオン活
性剤としては、以下の活性剤を挙げることができる。Examples of the hardly thickening anionic activator which is the component (B) of the present invention include the following activators.
【００３１】一般式（２）で表される難増粘性アニオン
活性剤としては、ラウリン酸塩、ミリスチン酸塩、パル
ミチン酸塩、ステアリン酸塩、オレイン酸塩、ヤシ油脂
肪酸塩、パーム核油脂脂肪酸塩、パーム油脂肪酸塩、等
が挙げられそれらの混合物も用いられ、その塩としては
ナトリウム塩、カリウム塩、トリエタノールアミン塩等
が挙げられる。Examples of the hardly thickening anionic activator represented by the general formula (2) include laurate, myristate, palmitate, stearate, oleate, coconut oil fatty acid salt, palm kernel fat and oil fatty acid. Salts, palm oil fatty acid salts, and the like can be used, and a mixture thereof can also be used. Examples of the salts include sodium salts, potassium salts, triethanolamine salts, and the like.
【００３２】一般式（３）で表される難増粘性アニオン
活性剤としては、Ｎ−ラウロイルサルコシン塩、Ｎ−ヤ
シ油脂肪酸サルコシン塩、Ｎ−ラウロイル−Ｎ−メチル
−β−アラニン塩、Ｎ−ヤシ油脂肪酸−Ｎ−メチル−β
−アラニン塩、等が挙げられ、その塩としてはナトリウ
ム塩、カリウム塩、トリエタノールアミン塩等が挙げら
れる。Examples of the hardly thickening anion activator represented by the general formula (3) include N-lauroyl sarcosine salt, N-coconut oil fatty acid sarcosine salt, N-lauroyl-N-methyl-β-alanine salt, N- Coconut oil fatty acid-N-methyl-β
-Alanine salt and the like, and examples of the salt include sodium salt, potassium salt, triethanolamine salt and the like.
【００３３】一般式（４）で表される難増粘性アニオン
活性剤としては、Ｎ−ラウロイル−Ｌ−グルタミン酸
塩、Ｎ−ヤシ油脂肪酸−Ｌ−グルタミン酸塩、Ｎ−ラウ
ロイルアスパラギン酸塩、Ｎ−ヤシ油脂肪酸アスパラギ
ン酸塩、等が挙げられ、その塩としてはナトリウム塩、
カリウム塩、トリエタノールアミン塩等が挙げられる。Examples of the hardly thickening anionic activator represented by the general formula (4) include N-lauroyl-L-glutamic acid salt, N-coconut oil fatty acid-L-glutamic acid salt, N-lauroyl aspartic acid salt and N- Coconut oil fatty acid aspartate, and the like, as its salt, a sodium salt,
Examples thereof include potassium salt and triethanolamine salt.
【００３４】一般式（５）で表される難増粘性アニオン
活性剤としては、ポリ（１〜１０）オキシエチレンラウ
リルエーテル酢酸塩、ポリ（１〜１０）オキシエチレン
ヤシ油アルキルエーテル酢酸塩、ポリ（１〜１０）オキ
シエチレントリデシルエーテル酢酸塩、等が挙げられ、
その塩としては、ナトリウム塩、カリウム塩、トリエタ
ノールアミン塩等が挙げられる。Examples of the hardly thickening anionic activator represented by the general formula (5) include poly (1-10) oxyethylene lauryl ether acetate, poly (1-10) oxyethylene coconut oil alkyl ether acetate, and poly (1-10) oxyethylene coconut oil alkyl ether acetate. (1-10) oxyethylene tridecyl ether acetate, and the like,
Examples of the salt include sodium salt, potassium salt, triethanolamine salt and the like.
【００３５】一般式（６）で表される難増粘性アニオン
活性剤としては、ポリ（１〜１０）オキシエチレンラウ
ロイルエタノールアミドエーテル酢酸塩、ポリ（１〜１
０）オキシエチレンヤシ油脂肪酸エタノールアミドエー
テル酢酸塩、ポリ（１〜１０）Ｎ−メチル−ラウロイル
エタノールアミドエーテル酢酸塩、ポリ（１〜１０）Ｎ
−エチル−ラウロイルエタノールアミドエーテル酢酸
塩、ポリ（１〜１０）オキシエチレンＮ−メチル−ヤシ
油脂肪酸エタノールアミドエーテル酢酸塩、ポリ（１〜
１０）オキシエチレンＮ−エチル−ヤシ油脂肪酸エタノ
ールアミドエーテル酢酸塩、等が挙げられ、その塩とし
てはナトリウム塩、カリウム塩、トリエタノールアミン
塩等が挙げられる。Examples of the hardly thickening anion activator represented by the general formula (6) include poly (1-10) oxyethylene lauroyl ethanolamide ether acetate and poly (1-1).
0) Oxyethylene coconut oil fatty acid ethanolamide ether acetate, poly (1-10) N-methyl-lauroylethanolamide ether acetate, poly (1-10) N
-Ethyl-lauroyl ethanolamide ether acetate, poly (1-10) oxyethylene N-methyl-coconut oil fatty acid ethanolamide ether acetate, poly (1-10)
10) Oxyethylene N-ethyl-coconut oil fatty acid ethanolamide ether acetate, and the like, and examples of the salt include sodium salt, potassium salt, triethanolamine salt, and the like.
【００３６】一般式（７−１）又は（７−２）で表され
る難増粘性アニオン活性剤としては、ポリ（０〜１０）
オキシエチレンラウリルスルホコハク酸塩、ポリ（０〜
１０）オキシエチレンヤシ油脂肪酸スルホコハク酸塩、
等が挙げられ、その塩としてはナトリウム塩、カリウム
塩、トリエタノールアミン塩等が挙げられる。As the hardly thickening anionic activator represented by the general formula (7-1) or (7-2), poly (0-10)
Oxyethylene lauryl sulfosuccinate, poly (0
10) Oxyethylene coconut oil fatty acid sulfosuccinate,
And the like, and examples of the salt include sodium salt, potassium salt, triethanolamine salt and the like.
【００３７】一般式（８−１）又は（８−２）で表され
る難増粘性アニオン活性剤としては、ポリ（０〜１０）
オキシエチレンラウロイルエタノールアミドスルホコハ
ク酸塩、ポリ（０〜１０）オキシエチレンヤシ油脂肪酸
エタノールアミドスルホコハク酸塩、ポリ（０〜１０）
オキシエチレンＮ−メチル−ラウロイルエタノールアミ
ドスルホコハク酸塩、ポリ（０〜１０）オキシエチレン
Ｎ−メチル−ヤシ油脂肪酸エタノールアミドスルホコハ
ク酸塩、ポリ（０〜１０）オキシエチレンＮ−エチル−
ラウロイルエタノールアミドスルホコハク酸塩、ポリ
（０〜１０）オキシエチレンＮ−エチル−ヤシ油脂肪酸
エタノールアミドスルホコハク酸塩、等が挙げられ、そ
の塩としてはナトリウム塩、カリウム塩、トリエタノー
ルアミン塩等が挙げられる。The sparingly viscous anionic surfactant represented by the general formula (8-1) or (8-2) is poly (0-10).
Oxyethylene lauroyl ethanolamide sulfosuccinate, poly (0-10) oxyethylene coconut oil fatty acid ethanolamide sulfosuccinate, poly (0-10)
Oxyethylene N-methyl-lauroyl ethanolamide sulfosuccinate, poly (0-10) oxyethylene N-methyl-coconut oil fatty acid ethanolamide sulfosuccinate, poly (0-10) oxyethylene N-ethyl-
Examples thereof include lauroyl ethanolamide sulfosuccinate, poly (0-10) oxyethylene N-ethyl-coconut oil fatty acid ethanolamide sulfosuccinate, and the like, and examples of the salt include sodium salt, potassium salt, triethanolamine salt, and the like. To be
【００３８】（Ｂ）成分として本発明に用いられる難増
粘性アニオン活性剤は、これら（２）〜（８）式で表さ
れるものの中から１種又は２種以上用いる事もできる。As the component (B), the hardly-viscosifying anionic activator used in the present invention may be used alone or in combination of two or more of those represented by the formulas (2) to (8).
【００３９】本発明の（Ｃ）成分であるアミドアミン型
活性剤は、下記、一般式（９）で表される。The amidoamine type activator which is the component (C) of the present invention is represented by the following general formula (9).
【００４０】[0040]
【化２０】 [Chemical 20]
【００４１】一般式（９）において、Ｒ11は炭素数７〜
２１のアルキル基又はアルケニル基であり、Ｒ11ＣＯ−
としては炭素数８〜２２のアシル基を構成し、Ｒ12は炭
素数１〜２のアルキル基であり、ｇは２〜３の整数であ
る。炭素数８〜２２のアシル基を構成する脂肪酸は、直
鎖状又は分岐を有する飽和又は不飽和脂肪酸であり、こ
のような脂肪酸としては、例えばカプリル酸、ペラルゴ
ン酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミ
チル酸、ステアリン酸、イソステアリン酸、アラキン
酸、ベヘン酸、オレイン酸、リノール酸、エルカ酸等の
ほか、ヤシ油脂肪酸、牛脂脂肪酸等を挙げることが出来
る。Ｒ12で示される炭素数１〜２のアルキル基として
は、メチル基、エチル基を挙げることが出来る。一般式
（９）で示されるアミドアミンを製造する方法には特に
制限はなく、任意の公知の方法により製造する事が出来
る。例えば脂肪酸又はその誘導体と、Ｎ，Ｎ−ジメチル
エチレンジアミン、Ｎ，Ｎ−ジエチルエチレンジアミ
ン、Ｎ，Ｎ−ジメチルトリメチレンジアミン、Ｎ，Ｎ−
ジエチルトリメチレンジアミンとを反応して、アミド結
合を生成することより得ることが出来る。In the general formula (9), R 11 has 7 to 7 carbon atoms.
21 alkyl group or alkenyl group, R 11 CO-
Represents an acyl group having 8 to 22 carbon atoms, R 12 is an alkyl group having 1 to 2 carbon atoms, and g is an integer of 2 to 3. The fatty acid constituting the acyl group having 8 to 22 carbon atoms is a linear or branched saturated or unsaturated fatty acid, and examples of such a fatty acid include caprylic acid, pelargonic acid, capric acid, lauric acid, myristin. In addition to acids, palmitic acid, stearic acid, isostearic acid, arachidic acid, behenic acid, oleic acid, linoleic acid, erucic acid and the like, coconut oil fatty acid, tallow fatty acid and the like can be mentioned. Examples of the alkyl group having 1 to 2 carbon atoms represented by R 12 include a methyl group and an ethyl group. The method for producing the amidoamine represented by the general formula (9) is not particularly limited and can be produced by any known method. For example, fatty acid or its derivative, N, N-dimethylethylenediamine, N, N-diethylethylenediamine, N, N-dimethyltrimethylenediamine, N, N-
It can be obtained by reacting with diethyl trimethylene diamine to form an amide bond.
【００４２】本発明において、（Ａ）成分と（Ｂ）成分
との配合比率（重量％）は、（Ａ）／（Ｂ）＝１０／９
０〜８０／２０であり、２０／８０〜７０／３０が増粘
性及び起泡性の面で望ましい。In the present invention, the mixing ratio (% by weight) of the component (A) and the component (B) is (A) / (B) = 10/9.
It is 0 to 80/20, and 20/80 to 70/30 is desirable in terms of thickening and foaming properties.
【００４３】（Ｃ）成分は、（Ａ）成分と（Ｂ）成分の
合計を１００とした場合、１〜４０重量部、好ましくは
２〜３５重量部、より好ましくは５〜２５重量部配合さ
れる。一般式（９）で示されるアミドアミンの含有量が
少ないと、十分な増粘性が得られず、反対に多いと、低
温保存時に白濁沈殿を起こして経時安定性に問題を生じ
るおそれがある。The component (C) is blended in an amount of 1 to 40 parts by weight, preferably 2-35 parts by weight, more preferably 5 to 25 parts by weight, based on the total of the components (A) and (B) being 100. It When the content of amidoamine represented by the general formula (9) is low, sufficient thickening cannot be obtained, and when the content is high, on the other hand, cloudy precipitation may occur during storage at low temperature to cause a problem with stability over time.
【００４４】本発明において、（Ａ）、（Ｂ）及び
（Ｃ）成分の合計量は、洗浄剤組成物全体に対して７〜
５０重量％、好ましくは１０〜４０重量％が増粘性、起
泡性及び経済性の面で特に望ましい。In the present invention, the total amount of the components (A), (B) and (C) is 7 to 7 with respect to the entire detergent composition.
50% by weight, preferably 10 to 40% by weight is particularly desirable in terms of thickening property, foaming property and economical efficiency.
【００４５】本発明の洗浄剤組成物には、上記の必須成
分に加えて洗浄剤に常用されている成分や添加剤を配合
することも可能である。即ち、他のアニオン界面活性
剤、他の両性界面活性剤、カチオン活性剤、非イオン界
面活性剤、プロピレングリコール、グリセリン等の保湿
剤、動植物エキス又はその誘導体、有機酸、色剤、防腐
剤、キレート剤、紫外線吸収剤等を本発明の効果を損な
わない範囲で適宜配合される。In addition to the above-mentioned essential components, the detergent composition of the present invention may contain components and additives commonly used in detergents. That is, other anionic surfactants, other amphoteric surfactants, cationic surfactants, nonionic surfactants, propylene glycol, humectants such as glycerin, animal or plant extracts or derivatives thereof, organic acids, colorants, preservatives, A chelating agent, an ultraviolet absorber and the like are appropriately blended within a range not impairing the effects of the present invention.
【００４６】本発明の洗浄剤組成物は、頭髪、身体、食
器用洗浄剤としてのみならず、洗顔剤、住居用洗浄剤の
各種洗浄に好適に使用することができる。The cleaning composition of the present invention can be suitably used not only as a cleaning agent for hair, body and tableware but also for cleaning various facial cleansers and household cleaning agents.
【００４７】以下、本発明を実施例によって具体的に説
明するが、本発明は、これらの実施例によって限定され
るものではない。尚、例中の％は特記しない限り重量基
準である。本発明における評価方法及び試験方法を以下
に示す。Hereinafter, the present invention will be described in detail with reference to Examples, but the present invention is not limited to these Examples. In the examples,% is based on weight unless otherwise specified. The evaluation method and test method in the present invention are shown below.
【００４８】（１）増粘性
表１に示す配合成分組成を持つ洗浄剤組成物を調整し、
２５℃にてＢ型粘度計を用いて粘度の測定を行い、以下
の４段階評価を行った。
◎ １０００ｍＰａ・ｓ以上
〇 ５００〜１０００ｍＰａ・ｓ
△ １００〜５００ｍＰａ・ｓ
× １００ｍＰａ・ｓ未満(1) Thickening agent A cleaning agent composition having the composition shown in Table 1 was prepared,
The viscosity was measured at 25 ° C. using a B-type viscometer, and the following four-stage evaluation was performed. ◎ 1000 mPa · s or more 〇 500 to 1000 mPa · s Δ 100 to 500 mPa · s × less than 100 mPa · s
【００４９】（２）低温安定性
所定の配合組成を持つ洗浄剤組成物を調整し、この溶液
を０℃で２週間保存した後、外観を観察し、以下の３段
階評価を行った。
◎ 透明
〇 ほぼ透明、わずかに濁っている
× やや濁りがあるか、白濁(2) Low-temperature stability A detergent composition having a predetermined composition was prepared, and this solution was stored at 0 ° C. for 2 weeks. Then, the appearance was observed and the following three-stage evaluation was performed. ◎ Transparent 〇 Almost transparent, slightly cloudy × Somewhat cloudy or cloudy
【００５０】（３）皮膚刺激性
所定の配合組成を持つ洗浄剤組成物を調整し、活性成分
０．２％の水溶液を用いて男女各１０名のパネリストの
左右上腕の内側部にて２４時間閉鎖貼付を行い、貼付解
除後、３時間、２４時間を経過したそれぞれの時点で自
己判定を行い、平均値として評価した。
５ 無刺激
３ 弱い刺激
１ 強度の刺激(3) Skin irritation A detergent composition having a predetermined composition was prepared, and an aqueous solution containing 0.2% of active ingredient was used for 24 hours on the inside of the left and right upper arms of 10 male and 10 female panelists. Closing sticking was performed, and after the sticking was released, self-judgment was performed at 3 hours and 24 hours, respectively, and evaluated as an average value. 5 No stimulation 3 Weak stimulation 1 Strong stimulation
【００５１】実施例１〜７を表１に示す。表１に示す
（Ａ）、（Ｂ）及び（Ｃ）の各成分を含有し、残部が水
である洗浄剤組成物を調整し、当該組成物の増粘効果、
低温安定性、皮膚刺激性を評価した。得られた結果を表
１に示す。表中、ポリオキシエチレンは「ＰＯＥ」と略
記し、その付加モル数をそれに続く括弧内に示す。Examples 1 to 7 are shown in Table 1. A cleaning composition containing each of the components (A), (B) and (C) shown in Table 1 with the balance being water was prepared, and the thickening effect of the composition,
The low temperature stability and skin irritation were evaluated. The results obtained are shown in Table 1. In the table, polyoxyethylene is abbreviated as "POE", and the number of added moles thereof is shown in the following parentheses.
【００５２】比較例１〜８を表２に示す。表２に示す
（Ａ）、（Ｂ）及び（Ｃ）の各成分を含有し、残部が水
である洗浄剤組成物を調整し、当該組成物の増粘効果、
低温・安定性、皮膚刺激性を評価した。得られた結果を
表２に示す。表中、ポリオキシエチレンは「ＰＯＥ」と
略記し、その付加モル数をそれに続く括弧内に示す。Table 2 shows Comparative Examples 1 to 8. A cleaning composition containing the components (A), (B) and (C) shown in Table 2 with the balance being water was prepared to increase the viscosity of the composition.
The low temperature / stability and skin irritation were evaluated. The obtained results are shown in Table 2. In the table, polyoxyethylene is abbreviated as "POE", and the number of added moles thereof is shown in the following parentheses.
【００５３】[0053]
【表１】 [Table 1]
【００５４】[0054]
【表２】 [Table 2]
【００５５】表１および表２から明らかなように、
（Ａ）、（Ｂ）及び（Ｃ）の３成分のすべてを含む本発
明の組成物は増粘性、低温安定性及び皮膚刺激性のすべ
ての試験項目について満足するが、（Ａ）成分又は
（Ｃ）成分のいずれかを含まない比較例の組成物は少な
くとも増粘性を満足しない。As is clear from Table 1 and Table 2,
The composition of the present invention containing all of the three components (A), (B) and (C) satisfies all the test items of thickening, low temperature stability and skin irritation, but the component (A) or ( The compositions of Comparative Examples not containing any of the components C) do not satisfy at least the thickening property.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ｃ１１Ｄ 1/10 Ｃ１１Ｄ 1/10 1/28 1/28 1/52 1/52 1/75 1/75 17/08 17/08 Ｆターム(参考） 4C083 AC181 AC182 AC241 AC242 AC561 AC562 AC641 AC642 AC661 AC662 AC781 AC782 AC791 AC792 CC23 CC38 DD23 EE01 EE09 4H003 AB03 AB05 AB06 AB09 AB10 AB22 AC15 AE02 BA12 DA01 DA02 ED02 FA02 FA16 FA18 FA30 ─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. 7 Identification code FI theme code (reference) C11D 1/10 C11D 1/10 1/28 1/28 1/52 1/52 1/75 1/75 17 / 08 17/08 F term (reference) 4C083 AC181 AC182 AC241 AC242 AC561 AC562 AC641 AC642 AC661 AC662 AC781 AC782 AC791 AC792 CC23 CC38 DD23 EE01 EE09 4H003 AB03 AB05 AB06 AB09 AB10 AB22 AC15 AE02 BA12 DA01 DA02 ED02 FA02 FA16 FA18 FA30
Claims (2)
を含有し、（Ａ）／（Ｂ）の重量比が１０／９０〜８０
／２０であり、（（Ａ）＋（Ｂ））／（Ｃ）の重量比が
１００／１〜１００／４０である混合物を活性成分とす
る液体洗浄組成物であって、（Ａ）成分は、下記、一般
式（Ｉ）で表される１種又は２種以上のアルキルジメチ
ルアミンオキサイド型両性界面活性剤から選ばれ、 【化１】 〔式中、Ｒ1 は炭素数８〜２２のアルキル基、アルケニ
ル基を示す。〕 （Ｂ）成分は、下記、一般式（２）〜（８）で表される
１種又は２種以上の難増粘性アニオン活性剤から選ば
れ、 【化２】 〔式中、Ｒ2 は炭素数７〜２１のアルキル基又はアルケ
ニル基を表し、Ｍ1 はアルカリ金属、アルカノールアミ
ンを表す。〕 【化３】 〔式中、Ｒ3 は炭素数７〜２１のアルキル基又はアルケ
ニル基を表し、Ｍ2 はアルカリ金属、アルカノールアミ
ンを表し、ａは１又は２の整数を示す。〕 【化４】 〔式中、Ｒ4 は炭素数７〜２１のアルキル基又はアルケ
ニル基を表し、Ｍ3 、Ｍ 4 は同一又は異なって、水素原
子、アルカリ金属、アルカノールアミンを表す。但し、
Ｍ3 、Ｍ4 が共に水素原子であることはない。ｂは１又
は２の整数で示す。〕 【化５】 〔式中、Ｒ5 は炭素数８〜２２の直鎖又は分岐鎖のアル
キル基又はアルケニル基を表し、Ｍ5 はアルカリ金属、
アルカノールアミンを表す。ｃは１〜１０を示す。〕 【化６】 〔式中、Ｒ6 は炭素数７〜２１のアルキル基又はアルケ
ニル基を表し、Ｒ7 は水素原子又は炭素数１〜３のアル
キル基を表し、Ｍ6 はアルカリ金属、アルカノールアミ
ンを表す。ｄは１〜１０を示す。〕 【化７】 〔式中、Ｒ8 は炭素数８〜２２の直鎖又は分岐鎖のアル
キル又はアルケニル基を表し、Ｍ7 、Ｍ8 は同一又は異
なっても良く、アルカリ金属、アルカノールアミンを表
す。ｅは０〜１０を示す。〕 【化８】 〔式中、Ｒ9 は炭素数７〜２１のアルキル基又はアルケ
ニル基を表し、Ｒ10は水素原子又は炭素数１〜３のアル
キル基を表し、Ｍ9 、Ｍ10は同一又は異なっても良く、
アルカリ金属、アルカノールアミンを表す。ｆは０〜１
０を示す。〕 （Ｃ）成分は、下記、一般式（９）で表される１種又は
２種以上のアミドアミン型活性剤、 【化９】 〔式中、Ｒ11は炭素数７〜２１のアルキル又はアルケニ
ル基を表し、Ｒ12は炭素数１〜２のアルキル基を表す。
ｇは２〜３の整数を示す。〕から選ばれる液体洗浄剤組
成物。1. The following three components (A), (B) and (C)
And the weight ratio of (A) / (B) is 10/90 to 80
/ 20, and the weight ratio of ((A) + (B)) / (C) is
The active ingredient is a mixture of 100/1 to 100/40
(A) component is a liquid cleaning composition
One or more alkyl dimethyl groups represented by formula (I)
Selected from ruamine oxide type amphoteric surfactants, [Chemical 1] [In the formula, R1Is an alkyl group having 8 to 22 carbon atoms, alkene
Represents a radical. ] The component (B) is represented by the following general formulas (2) to (8).
Select from one or two or more difficultly thickening anionic activators
And [Chemical 2] [In the formula, R2Is an alkyl group or alkene having 7 to 21 carbon atoms
Represents a nyl group, M1Is an alkali metal, alkanolamine
Represents the ] [Chemical 3] [In the formula, R3Is an alkyl group or alkene having 7 to 21 carbon atoms
Represents a nyl group, M2Is an alkali metal, alkanolamine
And a is an integer of 1 or 2. ] [Chemical 4] [In the formula, RFourIs an alkyl group or alkene having 7 to 21 carbon atoms
Represents a nyl group, M3, M FourAre the same or different and
Represents a child, an alkali metal, and an alkanolamine. However,
M3, MFourAre not both hydrogen atoms. b is 1
Is an integer of 2. ] [Chemical 5] [In the formula, RFiveIs a linear or branched alkane having 8 to 22 carbon atoms.
Represents a kill group or an alkenyl group, MFiveIs an alkali metal,
Represents an alkanolamine. c shows 1-10. ] [Chemical 6] [In the formula, R6Is an alkyl group or alkene having 7 to 21 carbon atoms
Represents a nyl group, R7Is a hydrogen atom or an alkane having 1 to 3 carbon atoms
Represents a kill group, M6Is an alkali metal, alkanolamine
Represents the d shows 1-10. ] [Chemical 7] [In the formula, R8Is a linear or branched alkane having 8 to 22 carbon atoms.
Represents a kill or alkenyl group, M7, M8Are the same or different
It is possible to display alkali metals and alkanolamines.
You e shows 0-10. ] [Chemical 8] [In the formula, R9Is an alkyl group or alkene having 7 to 21 carbon atoms
Represents a nyl group, RTenIs a hydrogen atom or an alkane having 1 to 3 carbon atoms
Represents a kill group, M9, MTenMay be the same or different,
Represents an alkali metal, alkanolamine. f is 0 to 1
Indicates 0. ] The component (C) is one kind represented by the following general formula (9) or
Two or more amidoamine type activators, [Chemical 9] [In the formula, R11Is an alkyl or alkene having 7 to 21 carbon atoms
Represents a radical, R12Represents an alkyl group having 1 to 2 carbon atoms.
g shows the integer of 2-3. ] Liquid detergent group selected from
A product.
物は、組成物全体の７〜５０重量％を占める請求項１の
液体洗浄剤組成物。2. The liquid detergent composition according to claim 1, wherein the mixture of the components (A), (B) and (C) accounts for 7 to 50% by weight of the total composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001275340A JP2003082387A (en) | 2001-09-11 | 2001-09-11 | Liquid detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001275340A JP2003082387A (en) | 2001-09-11 | 2001-09-11 | Liquid detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2003082387A true JP2003082387A (en) | 2003-03-19 |
Family
ID=19100217
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001275340A Pending JP2003082387A (en) | 2001-09-11 | 2001-09-11 | Liquid detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2003082387A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006007925A1 (en) * | 2004-07-20 | 2006-01-26 | Unilever Plc | Mild, moisturizing sulfosuccinate cleansing compositions |
| JP2008179543A (en) * | 2007-01-23 | 2008-08-07 | Lion Corp | Skin cleanser composition |
| JP2008222577A (en) * | 2007-03-09 | 2008-09-25 | Ajinomoto Co Inc | Thickener |
| JP2011021110A (en) * | 2009-07-16 | 2011-02-03 | Toho Chem Ind Co Ltd | Thickener for detergent |
| WO2020110606A1 (en) * | 2018-11-26 | 2020-06-04 | 株式会社 資生堂 | Detergent composition |
| US20220023177A1 (en) * | 2018-11-26 | 2022-01-27 | Shiseido Company, Ltd. | Cleansing composition |
-
2001
- 2001-09-11 JP JP2001275340A patent/JP2003082387A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006007925A1 (en) * | 2004-07-20 | 2006-01-26 | Unilever Plc | Mild, moisturizing sulfosuccinate cleansing compositions |
| AU2005263384B2 (en) * | 2004-07-20 | 2007-11-01 | Unilever Plc | Mild, moisturizing sulfosuccinate cleansing compositions |
| JP2008179543A (en) * | 2007-01-23 | 2008-08-07 | Lion Corp | Skin cleanser composition |
| JP2008222577A (en) * | 2007-03-09 | 2008-09-25 | Ajinomoto Co Inc | Thickener |
| US8187579B2 (en) | 2007-03-09 | 2012-05-29 | Ajinomoto Co., Inc. | Thickening agent |
| JP2011021110A (en) * | 2009-07-16 | 2011-02-03 | Toho Chem Ind Co Ltd | Thickener for detergent |
| WO2020110606A1 (en) * | 2018-11-26 | 2020-06-04 | 株式会社 資生堂 | Detergent composition |
| CN113164800A (en) * | 2018-11-26 | 2021-07-23 | 株式会社资生堂 | Detergent composition |
| JPWO2020110606A1 (en) * | 2018-11-26 | 2021-10-14 | 株式会社 資生堂 | Detergent composition |
| US20220023177A1 (en) * | 2018-11-26 | 2022-01-27 | Shiseido Company, Ltd. | Cleansing composition |
| US20220023176A1 (en) * | 2018-11-26 | 2022-01-27 | Shiseido Company, Ltd. | Cleansing composition |
| JP7337842B2 (en) | 2018-11-26 | 2023-09-04 | 株式会社 資生堂 | detergent composition |
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