CN117326683A - Method for reinforcing low-temperature sewage co-metabolism treatment by recycling high-concentration organic wastewater - Google Patents

Method for reinforcing low-temperature sewage co-metabolism treatment by recycling high-concentration organic wastewater Download PDF

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Publication number
CN117326683A
CN117326683A CN202311557739.8A CN202311557739A CN117326683A CN 117326683 A CN117326683 A CN 117326683A CN 202311557739 A CN202311557739 A CN 202311557739A CN 117326683 A CN117326683 A CN 117326683A
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wastewater
low
concentration
sewage
temperature
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张崇军
周丹丹
李少冉
王骞
尤志昂
孙浩然
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Northeast Normal University
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Northeast Normal University
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1236Particular type of activated sludge installations
    • C02F3/1263Sequencing batch reactors [SBR]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Life Sciences & Earth Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Microbiology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Activated Sludge Processes (AREA)

Abstract

The invention relates to a method for reinforcing low-temperature sewage co-metabolism treatment by recycling high-concentration organic wastewater, and relates to the technical field of sewage treatment. Solves the technical problem of low treatment effect of the sewage treatment plant in the low temperature state in the prior art. The method for reinforcing the co-metabolism treatment of low-temperature sewage by recycling high-concentration organic wastewater adopts the high-concentration organic wastewater as an easily degradable organic matter, and is mixed with domestic sewage for treatment, thereby promoting the reduction of refractory organic matters in the low-temperature environmental sewage and simultaneously realizing the recycling of pharmaceutical wastewater. The experimental results show that: under the condition of low temperature (10 ℃), compared with the control group, the degradation rate of the soluble organic matters is improved by 18 percent and the degradation rate of ammonia nitrogen is improved by 28 percent by adding ethanol to extract the pharmaceutical wastewater. In addition, compared with the control group, the microbial oxygen consumption rate is improved by 49%, and the microbial activity is obviously improved.

Description

Method for reinforcing low-temperature sewage co-metabolism treatment by recycling high-concentration organic wastewater
Technical Field
The invention relates to the technical field of sewage treatment, in particular to a method for reinforcing low-temperature sewage co-metabolism treatment by recycling high-concentration organic wastewater.
Background
At present, the domestic sewage treatment process mainly adopts a physical and chemical technology and takes biological treatment as a main process, and the centralized sewage treatment rate of the domestic sewage treatment process is 81.6 percent of the total national number. However, in cold regions of China, sewage treatment processes face a number of challenges. The cold regions in China are generally distributed in cold temperate regions, middle temperate regions, north regions and high-altitude regions, and the main geographic modules are divided into northeast regions, qinghai-Tibet plateau regions, xinjiang regions and the like, and account for 43.5% of the total land area in China. The average temperature of the coldest month in the cold region of China is-10-0 ℃, the average daily temperature is less than or equal to 5 ℃ for 90-145 days, the lowest air temperature is below-30 ℃, and some towns are in the permafrost region.
Studies have shown that whenever the temperature is reduced by 10 ℃, the microbial activity will be reduced by 50% and the biodegradation efficiency of organics by approximately 60%. When the sewage temperature is as low as 8-15 ℃, the microbial activity, the substrate utilization rate and the cell growth can be seriously inhibited, so that the biological process treatment effect is deteriorated. When the temperature of the sewage is below 5 ℃, the microorganisms are in a dormant state, and the biological behaviors are almost stopped. In the traditional activated sludge treatment process, most of functional microorganism flora optimally grows at the temperature of 30-35 ℃. When the temperature is reduced to 4 ℃ compared with 37 ℃, the activity and hydrolysis rate constant of methanobacteria are reduced by 80% -90%, and the activity and nitrification rate of nitrifying bacteria are reduced by 77%. Thus, the typically low temperature characteristics of cold areas present challenges to biological wastewater treatment.
The strategy of microbial co-metabolism may be an effective way to solve this problem, and the easily degradable substrate in the co-metabolism process is usually an electron donor in the degradation process of the microorganism, and at the same time, serves as a carbon source to provide energy for the microorganism, so as to enhance the activity of the microorganism. At present, most domestic sewage treatment plants increase the treatment efficiency by adding carbon sources such as glucose, sodium acetate and methanol as easily degradable organic matters, but the added carbon sources not only increase the cost of the sewage treatment plants, but also generate a large amount of greenhouse gases. Therefore, an effective method is needed to solve the bottleneck problem of low treatment effect of sewage treatment plants in low temperature.
Disclosure of Invention
The invention aims to solve the technical problem of low treatment effect of a sewage treatment plant in a low-temperature state in the prior art, and provides a method for reinforcing co-metabolism treatment of low-temperature sewage by recycling high-concentration organic wastewater. The method is based on the co-metabolism theory and utilizes the high-concentration traditional Chinese medicine extracting solution to prepare the pharmaceutical wastewater and the low-temperature sewage for mixed strengthening treatment.
In order to solve the technical problems, the technical scheme of the invention is as follows:
a method for reinforcing low-temperature sewage co-metabolism treatment by recycling high-concentration organic wastewater comprises the following steps:
in a low-temperature environment, high-concentration organic wastewater is used as an easily degradable organic matter, and activated sludge is used for treating domestic sewage to degrade pollutants.
In the technical scheme, the Chemical Oxygen Demand (COD) concentration of the high-concentration organic wastewater ranges from 2000 mg/L to 50000mg/L.
In the technical scheme, the high-concentration organic wastewater is Chinese medicine ethanol extract wastewater generated in the extraction process of the effective components of pharmaceutical enterprises, and the COD concentration is 50000mg/L.
In the technical scheme, the Chemical Oxygen Demand (COD) concentration range of the domestic sewage is 200-400 mg/L, and the activated sludge concentration (MLSS) is 3500mg/L.
In the above technical scheme, the temperature of the low-temperature environment is 10 ℃.
In the technical scheme, the weight ratio of the high-concentration organic wastewater to the domestic sewage is 1:200.
A method for reinforcing low-temperature sewage co-metabolism treatment by recycling high-concentration organic wastewater, which is applicable to an SBR wastewater treatment device, comprises the following steps: an organic glass barrel and an aeration pump;
a water inlet is formed in one side of the organic glass barrel, and a water outlet is formed in one side of the organic glass barrel; an aeration disc is arranged at the bottom of the organic glass barrel and is connected with the aeration pump; a heating rod and a stirrer are arranged inside the organic glass barrel;
the method comprises the following steps:
step 1, domestic sewage enters an organic glass barrel filled with activated sludge and high-concentration organic wastewater from the water inlet;
step 2, starting an aeration pump, and keeping the system in a good-raising state after the aeration disc starts aeration;
and 3, maintaining a low-temperature environment required by degradation by using the heating rod, and degrading pollutants by using activated sludge in the organic glass barrel under the condition of stirring by a stirrer.
In the technical scheme, the stirrer is supported and inserted into the interior of the organic glass barrel through the external bracket; the heating rod is attached to the inner wall of the organic glass barrel through a sucker; the aeration disc is arranged at the bottom of the organic glass barrel through threads.
In the technical scheme, the total hydraulic retention time of the SBR wastewater treatment device is 12h, and the SBR wastewater treatment device comprises a water inlet stage of 0.5h, an aeration stage of 9h, a precipitation stage of 1h, a water discharge stage of 0.5h and a standby stage of 1h.
The beneficial effects of the invention are as follows:
the method for reinforcing the co-metabolism treatment of low-temperature sewage by recycling high-concentration organic wastewater adopts the high-concentration organic wastewater as an easily degradable organic matter, and is mixed with domestic sewage for treatment, thereby promoting the reduction of refractory organic matters in the low-temperature environmental sewage and simultaneously realizing the recycling of pharmaceutical wastewater.
The high-concentration organic wastewater represented by ethanol extraction pharmaceutical wastewater is used as a co-metabolism matrix for enhanced biological treatment, has great application potential, is used as a carbon source to be added into a cold region sewage treatment plant for enhanced low-temperature microbial degradation, can change waste into valuables, reduce the running cost, can reduce the emission of greenhouse gases, and can provide guidance for the resource utilization of wastewater and enhanced microbial degradation in a low-temperature state.
The experimental results show that: under the condition of low temperature (10 ℃), compared with the control group, the degradation rate of the soluble organic matters is improved by 18 percent and the degradation rate of ammonia nitrogen is improved by 28 percent by adding ethanol to extract the pharmaceutical wastewater. In addition, compared with the control group, the microbial oxygen consumption rate is improved by 49%, and the microbial activity is obviously improved.
Drawings
The invention is described in further detail below with reference to the drawings and the detailed description.
FIG. 1 is a schematic diagram of a SBR wastewater treatment apparatus to which the method of the present invention is applied.
Reference numerals in the drawings denote:
1-stirrer, 2-water inlet, 3-water outlet, 4-heating rod, 5-aeration disc, 6-aeration pump, 7-organic glass barrel.
Detailed Description
Example 1:
control group. An SBR wastewater treatment device suitable for the method of the invention is constructed according to FIG. 1, which comprises a organic glass barrel 7 and an aeration pump 6; the diameter of the organic glass barrel 7 is 15cm and the height is 30cm. The total volume is 5.3L, and the effective volume is 4L; a water inlet 2 is formed in one side of the organic glass barrel 7, and a water outlet 3 is formed in one side of the organic glass barrel; an aeration disc 5 is arranged at the bottom of the organic glass barrel 7, and the aeration disc 5 is connected with the aeration pump 6; the interior of the plexiglass tub 7 is provided with a heating rod 4 and a stirrer 1. The stirrer 1 is supported and inserted into the interior of the organic glass barrel 7 through an external bracket; the heating rod 4 is attached to the inner wall of the organic glass barrel 7 through a sucker; the aeration disc 5 is arranged at the bottom of the organic glass barrel 7 through threads.
Domestic sewage is fed into the organic glass barrel 7 through the water inlet 2, and after the aeration pump 6 is aerated, the system is kept in an aerobic state (DO>2 mg/L), the activated sludge contained in the inside of the SBR reactor, namely the organic glass tank 7, is used for degrading pollutants. The total hydraulic retention time of the SBR reactor is 12h, and mainly comprises a water inlet stage of 0.5h, an aeration stage of 9h, a precipitation stage of 1h, a water discharge stage of 0.5h and a standby stage of 1h. Activated sludge was obtained from municipal wastewater treatment plants at a water intake stage, and the sludge concentration (MLSS) was 3500mg/L. The test water is domestic sewage and has chemical oxygen demandThe amount (COD) is 200-400 mg/L. Degradation was performed using a heating rod 4 under low temperature (10 ℃) conditions and under stirring by a stirrer 1. After 12 hours, the degradation rate of microorganisms to TOC is 45% and the degradation rate to ammonia nitrogen is 66% as measured by the water outlet of the water outlet 3. The specific oxygen consumption rate of the microorganism is 3.5mgO 2 /(g MLSS.h). The microorganism has low biological activity and poor degradation capability to pollutants.
Example 2:
experimental groups. An SBR wastewater treatment device suitable for the method of the invention is constructed according to FIG. 1, which comprises a organic glass barrel 7 and an aeration pump 6; the diameter of the organic glass barrel 7 is 15cm and the height is 30cm. The total volume is 5.3L, and the effective volume is 4L; a water inlet 2 is formed in one side of the organic glass barrel 7, and a water outlet 3 is formed in one side of the organic glass barrel; an aeration disc 5 is arranged at the bottom of the organic glass barrel 7, and the aeration disc 5 is connected with the aeration pump 6; the interior of the plexiglass tub 7 is provided with a heating rod 4 and a stirrer 1. The stirrer 1 is supported and inserted into the interior of the organic glass barrel 7 through an external bracket; the heating rod 4 is attached to the inner wall of the organic glass barrel 7 through a sucker; the aeration disc 5 is arranged at the bottom of the organic glass barrel 7 through threads.
Domestic sewage is fed into the organic glass barrel 7 through the water inlet 2, and after the aeration pump 6 is aerated, the system is kept in an aerobic state (DO>2 mg/L), and ethanol is used for extracting pharmaceutical wastewater (COD concentration is 50000 mg/L) as an easily degradable organic matter, and pollutant degradation is carried out through a reactor, namely activated sludge in the organic glass barrel 7. The ethanol extraction pharmaceutical wastewater is obtained from Tonghua Troma pharmaceutical company, inc., and has COD concentration of 50000mg/L and main components of ethanol, lignin, etc. The total hydraulic retention time of the SBR reactor is 12h, and mainly comprises a water inlet stage of 0.5h, an aeration stage of 9h, a precipitation stage of 1h, a water discharge stage of 0.5h and a standby stage of 1h. Activated sludge was obtained from municipal wastewater treatment plants at a water intake stage, and the sludge concentration (MLSS) was 3500mg/L. The test water is domestic sewage, and the Chemical Oxygen Demand (COD) is 200-400 mg/L. The weight ratio of the ethanol extraction pharmaceutical wastewater to the domestic sewage is 1:200, and degrading at low temperature (10deg.C). After 12 hours, the degradation rate of microorganisms to TOC is 63% and to ammonia nitrogen is measured by the water outlet of the water outlet 3The degradation rate was 94%. The specific oxygen consumption rate of the microorganism is 5.2mgO 2 /(g MLSS·h)。
By comparing the control group with the experimental group, the mixed treatment of the ethanol pharmaceutical wastewater and the sewage can promote the degradation of the microorganism on the soluble organic matters under the low-temperature condition. The experimental results show that: under the condition of low temperature (10 ℃), compared with the control group, the degradation rate of the soluble organic matters is improved by 18 percent and the degradation rate of ammonia nitrogen is improved by 28 percent by adding ethanol to extract the pharmaceutical wastewater. In addition, compared with the control group, the microbial oxygen consumption rate is improved by 49%, and the microbial activity is obviously improved. The high-concentration waste water represented by ethanol extraction pharmaceutical waste water is subjected to enhanced low-temperature sewage treatment, the waste water and sludge used in the embodiment have universality, the selected high-concentration organic waste water is not limited in type, and the COD concentration range of the selected high-concentration organic waste water is 2000-50000 mg/L, and the mixed treatment can be carried out according to a certain proportion so as to improve the treatment efficiency at low temperature. The low-temperature sewage treatment can be further enhanced by means of further optimizing the mixing proportion, adjusting the hydraulic retention time and the like.
The foregoing is merely a preferred embodiment of the present invention, and it should be noted that these examples are only for illustrating the present invention and are not intended to limit the scope of the present invention, and that various changes and modifications may be made by one skilled in the art after reading the contents of the present invention, and the equivalent forms are also within the scope of the present invention as defined in the appended claims.

Claims (9)

1. The method for reinforcing the co-metabolism treatment of the low-temperature sewage by recycling the high-concentration organic wastewater is characterized by comprising the following steps of:
in a low-temperature environment, high-concentration organic wastewater is used as an easily degradable organic matter, and activated sludge is used for treating domestic sewage to degrade pollutants.
2. The method of claim 1, wherein the high concentration organic wastewater has a chemical oxygen demand concentration ranging from 2000 to 50000mg/L.
3. The method according to claim 1, wherein the high-concentration organic wastewater is ethanol extract wastewater of traditional Chinese medicine generated in the extraction process of active ingredients of pharmaceutical enterprises, and the COD concentration is 50000mg/L.
4. The method according to claim 1, wherein the chemical oxygen demand concentration of the domestic sewage is in the range of 200 to 400mg/L and the activated sludge concentration (MLSS) is 3500mg/L.
5. The method of claim 1, wherein the low temperature environment has a temperature of 10 ℃.
6. The method of claim 1, wherein the weight ratio of the high concentration organic wastewater to the domestic wastewater is 1:200.
7. A method for enhancing co-metabolism treatment of low-temperature sewage by recycling high-concentration organic wastewater according to any one of claims 1 to 6, characterized in that an SBR wastewater treatment device suitable for the method comprises: an organic glass barrel (7) and an aeration pump (6);
a water inlet (2) is formed in one side of the organic glass barrel (7), and a water outlet (3) is formed in one side of the organic glass barrel; an aeration disc (5) is arranged at the bottom of the organic glass barrel (7), and the aeration disc (5) is connected with the aeration pump (6); a heating rod (4) and a stirrer (1) are arranged in the organic glass barrel (7);
the method comprises the following steps:
step 1, domestic sewage enters an organic glass barrel (7) filled with activated sludge and high-concentration organic wastewater from the water inlet (2);
step 2, starting an aeration pump (6), and keeping the system in a good-raising state after the aeration disc (5) starts aeration;
and 3, maintaining a low-temperature environment required by degradation by using the heating rod (4), and degrading pollutants by using activated sludge in the organic glass barrel (7) under the condition of stirring by the stirrer (1).
8. The method according to claim 7, characterized in that the stirrer (1) is inserted inside the plexiglas tub (7) supported by an external bracket; the heating rod (4) is attached to the inner wall of the organic glass barrel (7) through a sucker; the aeration disc (5) is arranged at the bottom of the organic glass barrel (7) through threads.
9. The method according to claim 7, wherein the total hydraulic retention time of the SBR wastewater treatment device is 12 hours, and the method comprises a water inlet stage of 0.5 hours, an aeration stage of 9 hours, a precipitation stage of 1 hour, a water discharge stage of 0.5 hours and a standby stage of 1 hour.
CN202311557739.8A 2023-11-21 2023-11-21 Method for reinforcing low-temperature sewage co-metabolism treatment by recycling high-concentration organic wastewater Pending CN117326683A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117623494A (en) * 2023-11-02 2024-03-01 东北师范大学 Method for enhancing low-temperature biological denitrification of activated sludge

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117623494A (en) * 2023-11-02 2024-03-01 东北师范大学 Method for enhancing low-temperature biological denitrification of activated sludge
CN117623494B (en) * 2023-11-02 2024-06-25 东北师范大学 Method for enhancing low-temperature biological denitrification of activated sludge

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