CN117124672A - 非织造布层叠体以及伸缩性非织造布层叠体、纤维制品、吸收性物品和卫生口罩 - Google Patents

非织造布层叠体以及伸缩性非织造布层叠体、纤维制品、吸收性物品和卫生口罩 Download PDF

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Publication number
CN117124672A
CN117124672A CN202311093032.6A CN202311093032A CN117124672A CN 117124672 A CN117124672 A CN 117124672A CN 202311093032 A CN202311093032 A CN 202311093032A CN 117124672 A CN117124672 A CN 117124672A
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CN
China
Prior art keywords
nonwoven fabric
fabric laminate
laminate
elastic
mfr
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Pending
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CN202311093032.6A
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English (en)
Inventor
高久翔一
岛田幸一
本村茂之
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemical Asahi Living Materials Co ltd
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Mitsui Chemicals Inc
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Application filed by Mitsui Chemicals Inc filed Critical Mitsui Chemicals Inc
Publication of CN117124672A publication Critical patent/CN117124672A/zh
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Abstract

本发明涉及非织造布层叠体以及伸缩性非织造布层叠体、纤维制品、吸收性物品和卫生口罩。所述非织造布层叠体,其具有:弹性非织造布,其包含40℃时的储能弹性模量E40与23℃时的储能弹性模量E23之比,即E40/E23为37%以上的α‑烯烃共聚物;以及伸长性纺粘非织造布,其配置于所述弹性非织造布的至少一面侧,所述α‑烯烃共聚物相对于所述弹性非织造布的总量的比例为90质量%~100质量%,所述弹性非织造布中的所述α‑烯烃共聚物的熔体流动速率为15g/10分钟~50g/10分钟。

Description

非织造布层叠体以及伸缩性非织造布层叠体、纤维制品、吸收 性物品和卫生口罩
本申请是申请日为2019年10月25日,申请号为201980065990.8,发明名称为《非织造布层叠体以及伸缩性非织造布层叠体、纤维制品、吸收性物品和卫生口罩》的中国专利申请的分案申请。
技术领域
本发明涉及非织造布层叠体以及伸缩性非织造布层叠体、纤维制品、吸收性物品和卫生口罩。
背景技术
近年来,非织造布由于透气性和柔软性优异,因此广泛用于各种用途中。因此,对于非织造布,要求与其用途相应的各种特性的同时,要求其特性的提高。
例如,纸尿布、生理用卫生巾等卫生材料、湿敷布材的基布等所使用的非织造布要求具有耐水性,且透湿性优异。此外,根据使用的场所还要求具有伸缩性和膨松性。
作为对于非织造布赋予伸缩性的方法之一,提出了作为纺粘非织造布的原料使用热塑性弹性体的方法(例如,参照专利文献1),使用低结晶性聚丙烯的方法(例如,参照专利文献2和专利文献3)等。
专利文献2或专利文献3中,为了改良纺粘非织造布的发粘等,提出了在低结晶性聚丙烯中添加高结晶性聚丙烯或脱模剂的方案。专利文献4中公开了,包含低结晶性聚丙烯的非织造布、与热塑性弹性体长纤维和热塑性树脂的长纤维的混纤纺粘非织造布的层叠体。
专利文献1:日本特表平7-503502号公报
专利文献2:日本特开2009-62667号公报
专利文献3:日本特开2009-79341号公报
专利文献4:国际公开第2007/138733号
发明内容
发明所要解决的课题
专利文献2或专利文献3所记载的方法中,在制造非织造布时,为了防止附着于装置内的各旋转设备和其它与非织造布接触的部位,需要在低结晶性聚丙烯中增加高结晶性聚丙烯或脱模剂的添加量,其结果是存在所得的纺粘非织造布的残留应变变大,伸缩性差的倾向。专利文献4所记载的方法中,通过将包含低结晶性聚丙烯的非织造布与混纤纺粘非织造布进行层叠,从而保持伸缩性,但是强烈要求伸缩性进一步的提高。
此外,在纸尿布、生理用卫生巾等卫生材料、湿敷布材的基布等用途中,要求伸长时应力小以便用弱的力就能够穿戴,且要求恢复时应力大以使穿着时不移动。即,在上述用途中,要求增大伸缩特性(恢复时应力/伸长时应力之比)的值。
进一步,在纸尿布、生理用卫生巾等卫生材料、湿敷布材的基布等用途中,要求在常温室温(23℃)~体温的范围(例如,23℃~40℃的范围)内恢复时应力不会降低,即,应力维持优异。由此,纸尿布、生理用卫生巾等卫生材料在穿戴时即使上升至体温,也难以移动。
本发明的一个方式鉴于上述课题,其目的在于提供伸缩特性优异,并且应力维持优异的非织造布层叠体、以及伸缩性非织造布层叠体、纤维制品、吸收性物品及卫生口罩。
用于解决课题的方法
用于解决上述课题的具体的方法包括下述方式。
[1]一种非织造布层叠体,其具有:
弹性非织造布,其包含40℃时的储能弹性模量E40与23℃时的储能弹性模量E23之比(E40/E23)为37%以上的α-烯烃共聚物;以及
伸长性纺粘非织造布,其配置于上述弹性非织造布的至少一面侧。
[2]根据上述[1]所述的非织造布层叠体,上述α-烯烃共聚物的上述23℃时的储能弹性模量E23为30MPa以下。
[3]根据上述[1]或[2]所述的非织造布层叠体,上述α-烯烃共聚物包含乙烯和丙烯的共聚物。
[4]根据上述[1]~[3]中任一项所述的非织造布层叠体,上述α-烯烃共聚物的抗拉弹性模量为30MPa以下。
[5]根据上述[1]~[4]中任一项所述的非织造布层叠体,在上述弹性非织造布的两面侧配置有上述伸长性纺粘非织造布。
[6]根据上述[1]~[5]中任一项所述的非织造布层叠体,上述伸长性纺粘非织造布的至少一个方向的最大载荷伸长率为45%以上。
[7]根据上述[1]~[6]中任一项所述的非织造布层叠体,上述弹性非织造布为弹性纺粘非织造布。
[8]根据上述[1]~[7]中任一项所述的非织造布层叠体,上述伸长性纺粘非织造布为包含同芯的芯鞘型复合纤维的伸长性纺粘非织造布,所述同芯的芯鞘型复合纤维中,将芯部设为MFR处于1g/10分钟~1000g/10分钟的范围的低MFR的烯烃系聚合物,将鞘部设为MFR处于1g/10分钟~1000g/10分钟的范围的高MFR的烯烃系聚合物,且上述低MFR的烯烃系聚合物与上述高MFR的烯烃系聚合物的MFR之差为1g/10分钟以上。
[9]根据上述[1]~[8]中任一项所述的非织造布层叠体,上述伸长性纺粘非织造布含有烯烃系聚合物组合物,所述烯烃系聚合物组合物包含80质量%~99质量%的结晶性丙烯系聚合物和1质量%~20质量%的高密度聚乙烯。
[10]根据上述[1]~[9]中任一项所述的非织造布层叠体,上述弹性非织造布与上述伸长性纺粘非织造布的目付比(弹性非织造布:伸长性纺粘非织造布)处于10:90~90:10的范围内。
[11]一种伸缩性非织造布层叠体,其为上述[1]~[10]中任一项所述的非织造布层叠体的拉伸加工物。
[12]一种纤维制品,其包含上述[1]~[10]中任一项所述的非织造布层叠体或上述[11]所述的伸缩性非织造布层叠体。
[13]一种吸收性物品,其包含上述[1]~[10]中任一项所述的非织造布层叠体或上述[11]所述的伸缩性非织造布层叠体。
[14]一种卫生口罩,其包含上述[1]~[10]中任一项所述的非织造布层叠体或上述[11]所述的伸缩性非织造布层叠体。
发明的效果
根据本发明的一个方式,可提供伸缩特性优异,并且应力维持优异的非织造布层叠体、以及伸缩性非织造布层叠体、纤维制品、吸收性物品及卫生口罩。
附图说明
图1为齿轮拉伸装置的概略图。
具体实施方式
以下,对于本公开的实施方式进行说明。这些说明和实施例例示实施方式,并不限制实施方式的范围。
本公开中,分层次记载的数值范围内,一个数值范围所记载的上限值或下限值可以置换为其它分层次记载的数值范围的上限值或下限值。此外,在本公开中记载的数值范围内,其数值范围的上限值或下限值可以置换为实施例所示的值。
本公开中,各成分可以包含多种相应的物质。本公开中,提及组合物中的各成分的量的情况下,组合物中与各成分相应的物质存在多种的情况下,只要没有特别的规定,就意味着组合物中存在的该多种物质的合计量。
本公开中“工序”的用语,不仅是独立的工序,即使是不能与其它工序明确地区别的情况,只要能实现该工序的目的,就包含于本用语中。此外,本公开中,使用“~”来表示的数值范围表示包含“~”的前后所记载的数值分别作为最小值和最大值的范围。此外,本公开中,关于组合物中的各成分的含量,在组合物中与各成分相应的物质存在多种的情况下,只要没有特别的规定,就是指组合物中存在的该多种物质的合计量。
-非织造布层叠体-
本公开涉及的非织造布层叠体具有包含40℃时的储能弹性模量E40与23℃时的储能弹性模量E23之比(E40/E23)为37%以上的α-烯烃共聚物的弹性非织造布、以及配置于上述弹性非织造布的至少一面侧的伸长性纺粘非织造布。非织造布层叠体也可以包含其它层来构成。
本公开涉及的非织造布层叠体包含α-烯烃共聚物作为弹性非织造布。因此,与使用不含α-烯烃共聚物的弹性非织造布,例如,由聚丙烯均聚物形成的弹性非织造布的情况相比,认为可获得伸缩特性优异,并且应力维持优异的非织造布层叠体。
此外,上述α-烯烃共聚物的40℃时的储能弹性模量E40与23℃时的储能弹性模量E23之比(E40/E23)为37%以上。即,即使在温度变化环境下(例如,40℃~23℃),也易于抑制弹性非织造布中的弹性的降低。因此,认为可获得应力维持优异的非织造布层叠体。
本公开的非织造布层叠体在弹性非织造布的至少一面侧配置有伸长性纺粘非织造布。由此,认为易于防止非织造布层叠体对于压纹工序等所使用的装置内的各种旋转设备等构件的附着,成型性和生产率优异。此外,伸长性纺粘非织造布具有伸长性,因此弹性非织造布的由优异的弹性带来的伸缩性易于得以维持。
关于非织造布层叠体,从获得伸缩特性优异并且应力维持优异的非织造布层叠体的观点考虑,优选在弹性非织造布的两面侧配置有伸长性纺粘非织造布。
本公开的非织造布层叠体的目付优选为360g/m2以下,更优选为240g/m2以下,进一步优选为150g/m2以下,特别优选为120g/m2~15g/m2,更进一步优选为80g/m2~20g/m2,极其优选为70g/m2~25g/m2
弹性非织造布与伸长性纺粘非织造布的目付比(构成比)可以根据各种用途进行适当设定。例如,弹性非织造布与伸长性纺粘非织造布的目付比(弹性非织造布:伸长性纺粘非织造布)优选为10:90~90:10的范围内,更优选为20:80~80:20的范围内,进一步优选为40:60~60:40的范围内。
如果弹性非织造布的目付比为10以上,则存在抑制非织造布层叠体的伸缩性降低的倾向。另一方面,如果弹性非织造布的目付比为90以下,则存在构成弹性非织造布的纤维超过伸长性纺粘非织造布层而露出到表面的比例减少的倾向。因此,易于获得成型性和触感优异的非织造布层叠体。
在弹性非织造布(或伸长性纺粘非织造布)存在2个以上的情况下,弹性非织造布(或伸长性纺粘非织造布)的目付为2个以上的合计。
非织造布层叠体的目付(g/m2)设为如以下那样进行测定而求出的值。另外,弹性非织造布和伸长性纺粘非织造布各自的目付也通过同样的方法来求出。
从非织造布层叠体采集流向(MD)为200mm、横向(CD)为50mm的试验片6张。采集场所为在MD、CD都取任意的3个位置(合计6个位置)。接着,将采集的各试验片的质量(g)使用上皿电子天平(研精工业公司制)分别测定,求出各试验片的质量的算术平均值。由求出的算术平均值,换算成每1m2的质量(g),将小数点后第1位进行四舍五入,将其设为目付〔g/m2〕。
非织造布层叠体的至少一个方向的最大载荷伸长率优选为100%以上,更优选为150%以上,进一步优选为220%以上。
非织造布层叠体的最大载荷伸长率(%)设为如以下那样进行测定而求出的值。
从非织造布层叠体采集流向(MD)为200mm、横向(CD)为50mm的试验片5张。对于该试验片,使用等速伸长型拉伸试验机,以夹盘间100mm,拉伸速度100mm/分钟的条件进行拉伸试验。测定试验片受到的最大的载荷〔N/50mm〕,测定上述最大载荷中的试验片的伸长率〔%〕。求出5张试验片的算术平均值,将其设为最大载荷伸长率。
[弹性非织造布]
本公开涉及的弹性非织造布包含40℃时的储能弹性模量E40与23℃时的储能弹性模量E23之比(E40/E23)为37%以上的α-烯烃共聚物。
弹性非织造布的目付优选为120g/m2以下,更优选为80g/m2以下,进一步优选为50g/m2以下,特别优选为40g/m2~2g/m2,更进一步优选为30g/m2~5g/m2,极其优选为25g/m2~8g/m2
构成弹性非织造布的纤维的纤维直径优选为50μm以下,更优选为40μm以下,进一步优选为30μm以下。构成弹性非织造布的纤维的纤维直径可以为1.0μm以上。
弹性非织造布的制造方法没有特别限定,可以适用各种公知的方法。例如,弹性非织造布可以为通过纺粘法、熔喷法、闪蒸纺丝法等方法来制造的弹性非织造布。上述之中,从使形成非织造布的纤维为长纤维的观点考虑,弹性非织造布优选为通过纺粘法制造的弹性纺粘非织造布。
(α-烯烃共聚物)
弹性非织造布包含α-烯烃共聚物。
α-烯烃共聚物表示使2种以上的具有α-烯烃骨架的共聚成分共聚而成的共聚物。
作为具有α-烯烃骨架的共聚成分,可举出例如,乙烯、丙烯、1-丁烯、1-戊烯、3-甲基-1-丁烯、4-甲基-1-戊烯、1-己烯、1-辛烯、1-癸烯、1-十二碳烯、1-十四碳烯、1-十六碳烯、1-十八碳烯、1-二十碳烯等α-烯烃。
上述之中,关于α-烯烃共聚物,从使非织造布层叠体成为应力更低,且伸缩性更优异的非织造布层叠体的观点考虑,优选包含将乙烯(下述表1和表2中表述为“C2”)和丙烯(下述表1和表2中表述为“C3”)作为共聚成分的乙烯和丙烯的共聚物。
乙烯和丙烯的共聚物中的、乙烯来源的构成单元的含有率(以下,也简称为“乙烯含量”)优选为1质量%~50质量%,更优选为5质量%~25质量%,进一步优选为10质量%~20质量%,特别优选为12质量%~18质量%。
α-烯烃共聚物可以为交替共聚物、接枝共聚物、嵌段共聚物和无规共聚物的任一者。
作为α-烯烃共聚物的40℃时的储能弹性模量E40与23℃时的储能弹性模量E23之比(E40/E23),从获得应力维持优异的非织造布层叠体的观点考虑,为37%以上。上述比(E40/E23)的值越大则越优选,更优选为40%以上,进一步优选为45%以上,特别优选为50%以上。上述比(E40/E23)的上限没有特别限定,可以为100%以下,可以为95%以下,可以为90%以下。
作为使α-烯烃共聚物中的上述储能弹性模量之比E40/E23处于上述特定范围的方法,可举出例如,使α-烯烃共聚物为乙烯和丙烯的共聚物的方法等。
关于α-烯烃共聚物的23℃时的储能弹性模量E23,从使非织造布层叠体成为伸缩性更优异的非织造布层叠体的观点考虑,优选为30MPa以下,更优选为22MPa以下,进一步优选为20MPa以下,特别优选为18MPa以下。
关于α-烯烃共聚物的40℃时的储能弹性模量E40,从使非织造布层叠体成为应力更低,且伸缩性更优异的非织造布层叠体的观点考虑,优选为10MPa以下,更优选为9MPa以下。
α-烯烃共聚物的23℃时的储能弹性模量E23可以为5MPa以上,也可以为10MPa以上。
α-烯烃共聚物的40℃时的储能弹性模量E40可以为3MPa以上,也可以为5MPa以上。
α-烯烃共聚物的各储能弹性模量为利用下述装置和条件测定得到的值。
温度:23℃或40℃
装置:RSA-III(TA Instruments公司制)
变形模式:拉伸模式
温度范围:-20℃~120℃
升温速度:2℃/分钟
变形频率:10Hz
初始应变:0.1%
测定温度间隔:0.3℃
环境:氮气气氛下
α-烯烃共聚物的密度(ASTM D 1505)优选处于0.850g/cm3~0.950g/cm3的范围内,更优选处于0.855g/cm3~0.900g/cm3的范围内,进一步优选处于0.860g/cm3~0.895g/cm3的范围内。
α-烯烃共聚物的密度为按照JIS K7112(1999)的密度梯度法测定而获得的值。
关于α-烯烃共聚物的抗拉弹性模量,从使非织造布层叠体成为伸缩性更优异的非织造布层叠体的观点考虑,优选为30MPa以下,更优选为20MPa以下,进一步优选为15MPa以下。α-烯烃共聚物的抗拉弹性模量的上限没有特别限定,例如可以为5MPa以上。
抗拉弹性模量为利用按照JIS K7161(2011)的方法测定而获得的值。
α-烯烃共聚物的分子量分布(Mw/Mn)优选为1.5~5.0。从获得纺丝性良好,并且纤维强度特别优异的纤维方面考虑,Mw/Mn更优选为1.5~4.5。
α-烯烃共聚物的质均分子量(Mw)和数均分子量(Mn)为通过GPC(凝胶渗透色谱)而求出的值,为采用以下条件测定得到的值。质均分子量(Mw)为聚苯乙烯换算的质均分子量,分子量分布(Mw/Mn)是由以同样操作进行测定而得到的数均分子量(Mn)和质均分子量(Mw)来算出的值。
<GPC测定条件>
柱:TOSO GMHHR-H(S)HT
检测器:液体色谱图用RI检测器WATERS 150C
溶剂:1,2,4-三氯苯
测定温度:145℃
流速:1.0ml/分钟
试样浓度:2.2mg/ml
进样量:160μl
标准曲线:Universal Calibration
解析程序:HT-GPC(Ver.1.0)
α-烯烃共聚物的熔体流动速率(MFR)没有特别限定,例如,优选为1g/10分钟~100g/10分钟,更优选为10g/10分钟~80g/10分钟,进一步优选为15g/10分钟~70g/10分钟,特别优选为15g/10分钟~50g/10分钟。
α-烯烃共聚物的熔体流动速率以ASTM D-1238,230℃,载荷2.16kg的条件进行测定。
α-烯烃共聚物可以为合成品,也可以为市售品。
在α-烯烃共聚物为合成品的情况下,α-烯烃共聚物能够如下调制:在齐格勒-纳塔系催化剂、金属茂系催化剂等以往公知的催化剂的存在下,使单体通过气相法、本体法(bulk method)、浆料法、溶液法等以往公知的聚合法进行聚合或共聚来调制。
作为α-烯烃共聚物的市售品,可举出例如,tafmer(三井化学公司制)、Vistamaxx系列(埃克森美孚化工公司制)等。
关于α-烯烃共聚物的组成,能够使用以往公知的方法(例如,IR分析、NMR分析、微量分析等)来进行。
α-烯烃共聚物相对于弹性非织造布的总量的比例优选为90质量%~100质量%,更优选为98质量%~100质量%。
在α-烯烃共聚物包含乙烯和丙烯的共聚物的情况下,关于乙烯和丙烯的共聚物相对于弹性非织造布的总量的比例,从非织造布层叠体中的伸缩特性的观点考虑,优选为80质量%~100质量%,更优选为90质量%~100质量%。
在α-烯烃共聚物为乙烯和丙烯的共聚物的情况下,关于α-烯烃共聚物的结晶度,从非织造布层叠体中的伸缩特性的观点考虑,优选为1%~15%,更优选为1%~13%,进一步优选为2%~10%,特别优选为4%~10%。
α-烯烃共聚物的结晶度由熔化吸热曲线中来源于主成分熔化的熔化热曲线来算出,所述熔化吸热曲线是使用差示扫描型热量计(DSC),在氮气气氛下,在-100℃保持5分钟之后以10℃/分钟使其升温而获得的。具体而言,能够由使用差示扫描型热量计(PerkinElmer公司制,DSC-7),将试样5mg在氮气气氛下,在-100℃保持5分钟之后,以10℃/分钟使其升温而获得的熔化吸热曲线中来源于主成分熔化的熔化热曲线,使用下述式来算出。
结晶度=(ΔH/ΔH0)×100(%)
式中,ΔH为由来源于包含乙烯和丙烯的α-烯烃共聚物的主成分熔化的熔化热曲线求出的熔化热(J/g),ΔH0为主成分的完全结晶的熔化热(J/g)。即,在主成分为乙烯的情况下,ΔH0为293J/g,在主成分为丙烯的情况下,ΔH0为210J/g。
在α-烯烃共聚物为乙烯和丙烯的共聚物的情况下,α-烯烃的熔点可以为130℃以下,可以为115℃以下,可以为100℃以下,可以为40℃~85℃,可以为40℃~60℃。
α-烯烃共聚物的熔点定义为:使用差示扫描型热量计(DSC),在氮气气氛下,在-100℃保持5分钟之后以10℃/分钟使其升温而获得的熔化吸热曲线的最低温侧所观测到的峰的峰顶。具体而言,能够作为使用差示扫描型热量计(Perkin Elmer公司制,DSC-7),将试样5mg在氮气气氛下,在-100℃保持5分钟之后,以10℃/分钟使其升温而获得的熔化吸热曲线的最低温侧所观测到的峰的峰顶来求出。
[伸长性纺粘非织造布]
本公开涉及的伸长性纺粘非织造布的至少一个方向的最大载荷伸长率优选为45%以上,更优选为70%以上,进一步优选为100%以上,特别优选为150%以上。伸长性纺粘非织造布优选为具有几乎没有弹性恢复的性质的非织造布。伸长性纺粘非织造布的最大载荷伸长率〔%〕采用与非织造布层叠体的最大载荷伸长率同样的方法来求出。本公开涉及的伸长性纺粘非织造布的至少一个方向的最大载荷伸长率可以为600%以下,可以为500%以下。
伸长性纺粘非织造布的目付优选为120g/m2以下,更优选为80g/m2以下,进一步优选为50g/m2以下,特别优选为40g/m2~5g/m2,更进一步优选为30g/m2~5g/m2,极其优选为25g/m2~8g/m2
构成伸长性纺粘非织造布的纤维的纤维直径优选为50μm以下,更优选为40μm以下,进一步优选为30μm以下。构成伸长性纺粘非织造布的纤维的纤维直径可以为1.0μm以上。
伸长性纺粘非织造布可以为具有芯部和鞘部的同芯的芯鞘型复合纤维、具有海部和岛部的海岛型复合纤维、并列型复合纤维以及卷曲复合纤维的任一者。伸长性纺粘非织造布优选为同芯的芯鞘型复合纤维或海岛型复合纤维。
包含上述同芯的芯鞘型复合纤维的伸长性纺粘非织造布优选为将芯部设为MFR处于1g/10分钟~1000g/10分钟的范围内的低MFR的烯烃系聚合物,将鞘部设为MFR处于1g/10分钟~1000g/10分钟的范围内的高MFR的烯烃系聚合物,且上述低MFR的烯烃系聚合物与上述高MFR的烯烃系聚合物的MFR之差为1g/10分钟以上。上述MFR之差更优选为15g/10分钟以上,进一步优选为30g/10分钟以上,特别优选为40g/10分钟以上。上述MFR之差可以为100g/10分钟以下,可以为70g/10分钟以下。
包含上述海岛型复合纤维的伸长性纺粘非织造布可以为将海部设为丙烯系聚合物(优选为丙烯的均聚物),将岛部设为乙烯系聚合物(优选为高密度聚乙烯)的海岛型复合纤维。
作为伸长性纺粘非织造布,可举出例如,使用1种或2种以上后述烯烃系聚合物组合物的非织造布。
(烯烃系聚合物组合物)
伸长性纺粘非织造布优选包含烯烃系聚合物,优选由包含烯烃系聚合物的烯烃系聚合物组合物形成。作为烯烃系聚合物,可以为聚烯烃系弹性体。
烯烃系聚合物组合物在不损害本公开的目的的范围内,作为任意成分,可以包含抗氧化剂、耐热稳定剂、耐候稳定剂、抗静电剂、滑动剂、防雾剂、润滑剂、染料、颜料、天然油、合成油、蜡、亲水剂等各种公知的添加剂。
烯烃系聚合物优选为具有结晶性的聚合物。上述具有结晶性的聚合物中的结晶性成分可举出例如,聚1-丁烯、聚4-甲基-1-戊烯等。烯烃系聚合物可以为单独1种,也可以并用2种以上。
作为烯烃系聚合物,可举出乙烯、丙烯、1-丁烯、1-己烯、4-甲基-1-戊烯、1-辛烯等α-烯烃的均聚物或共聚物。作为α-烯烃的共聚物,可举出乙烯系聚合物、丙烯系聚合物等。
作为乙烯系聚合物,可举出高压法低密度聚乙烯、线型低密度聚乙烯(所谓LLDPE)、高密度聚乙烯(所谓HDPE)等乙烯均聚物、乙烯与α-烯烃的无规共聚物或嵌段共聚物等。
乙烯系聚合物的密度没有特别限制,例如,优选为0.94g/cm3~0.97g/cm3,更优选为0.95g/cm3~0.97g/cm3,进一步优选为0.96g/cm3~0.97g/cm3
乙烯系聚合物的MFR只要具有纺丝性,就没有特别限定,例如,从表现伸长性的观点考虑,优选为0.1g/10分钟~100g/10分钟,更优选为0.5g/10分钟~50g/10分钟,进一步优选为1g/10分钟~30g/10分钟。
丙烯系聚合物一般而言,是指以聚丙烯的名称制造、销售的结晶性树脂。丙烯系聚合物优选为丙烯的均聚物或将丙烯作为主成分的共聚物。
作为将丙烯作为主成分的共聚物,可举出将乙烯、1-丁烯、1-戊烯、1-己烯、1-辛烯、4-甲基-1-戊烯等碳原子数2以上的α-烯烃(优选为碳原子数2~8的α-烯烃)作为共聚成分的共聚物(其中,将碳原子数3的烯烃,即丙烯除外)。另外,将丙烯作为主成分的共聚物可以为无规共聚物、嵌段共聚物等的任一者。
丙烯的均聚物的熔点(Tm)优选为155℃以上,更优选为157℃~165℃。
将丙烯作为主成分的共聚物的熔点(Tm)优选为130℃以上且小于155℃,更优选为130℃~150℃。
丙烯系聚合物的MFR只要能够进行熔融纺丝,就没有特别限定。丙烯系聚合物的MFR例如,优选为1g/10分钟~1000g/10分钟,更优选为5g/10分钟~500g/10分钟,进一步优选为10g/10分钟~100g/10分钟。
伸长性纺粘非织造布可以包含烯烃系聚合物以外的聚合物(以下,也称为“其它聚合物”),也可以不含其它聚合物。作为其它聚合物,可举出例如,热塑性弹性体和烯烃系聚合物以外的热塑性树脂。
作为热塑性弹性体,具体而言,可举出苯乙烯系弹性体、聚酯系弹性体、聚酰胺系弹性体、热塑性聚氨酯系弹性体、氯乙烯系弹性体、氟系弹性体等。
作为烯烃系聚合物以外的热塑性树脂,具体而言,可举出聚酯(聚对苯二甲酸乙二醇酯、聚对苯二甲酸丁二醇酯、聚萘二甲酸乙二醇酯等)、聚酰胺(尼龙-6、尼龙-66、聚己二酰间苯二甲胺等)、聚氯乙烯、聚酰亚胺、乙烯-乙酸乙烯酯共聚物、乙烯-乙酸乙烯酯-乙烯醇共聚物、乙烯-(甲基)丙烯酸共聚物、乙烯-丙烯酸酯-一氧化碳共聚物、聚丙烯腈、聚碳酸酯、聚苯乙烯等。
相对于烯烃系聚合物和其它聚合物(热塑性弹性体和烯烃系聚合物以外的热塑性树脂)的合计,伸长性纺粘非织造布中的烯烃系聚合物的含量优选超过90质量%且为100质量%以下,更优选为95质量%~100质量%。
伸长性纺粘非织造布不含其它聚合物,或者相对于烯烃系聚合物和其它聚合物的合计,伸长性纺粘非织造布中的其它聚合物(热塑性弹性体和烯烃系聚合物以外的热塑性树脂)的含量优选超过0%且小于10质量%,更优选超过0%且为5质量%以下。
在烯烃系聚合物组合物包含丙烯系聚合物和乙烯系聚合物的情况下,相对于烯烃系聚合物组合物的全部量,丙烯系聚合物的含量优选为80质量%~99质量%,更优选为84质量%~96质量%。另一方面,相对于烯烃系聚合物组合物的全部量,上述乙烯系聚合物的含量优选为20质量%~1质量%,更优选为16质量%~4质量%(其中,丙烯系聚合物+乙烯系聚合物=100质量%)。
(伸长性纺粘非织造布的具体例)
作为伸长性纺粘非织造布,优选包含满足下述(1)~(3)的要件的伸长性纺粘非织造布。
(1)使用了包含流动致相分离中的结晶化的诱导时间之差为100秒以上的两种以上的烯烃系聚合物的、芯鞘型复合纤维、并列型复合纤维(side by side型复合纤维)或卷曲复合纤维的纺粘非织造布。
作为上述两种以上的烯烃系聚合物,例如,可以为高熔点的丙烯系聚合物和低熔点的丙烯系聚合物。
(2)使用了含有包含丙烯系聚合物和乙烯系聚合物的烯烃系聚合物组合物的、海岛型复合纤维、芯鞘型复合纤维、并列型复合纤维或卷曲复合纤维的纺粘非织造布。作为上述烯烃系聚合物组合物,特别优选为下述所示的烯烃系聚合物组合物。
(2-1)包含丙烯均聚物80质量%~99质量%和高密度聚乙烯20质量%~1质量%的烯烃系聚合物组合物。
(2-2)包含MFR相同或不同,且熔点处于157℃~165℃的范围内的高熔点的丙烯系聚合物的烯烃系聚合物组合物。
作为上述丙烯系聚合物,例如,可以为将丙烯均聚物,熔点处于130℃~150℃的范围内的低熔点的丙烯与α-烯烃的无规共聚物进行了共聚的丙烯系聚合物。
(3)使用了将芯部设为MFR处于1g/10分钟~200g/10分钟的范围内的低MFR的丙烯系聚合物,将鞘部设为MFR处于16g/10分钟~215g/10分钟的范围内的高MFR的丙烯系聚合物,且上述芯部的MFR与上述鞘部的MFR之差为15g/10分钟以上的同芯的芯鞘复合纤维的纺粘非织造布。
作为满足上述(1)~(3)的要件的伸长性纺粘非织造布,可举出例如,下述(A)和(B)的伸长性纺粘非织造布。
(A)使用了包含将芯部设为MFR处于10g/10分钟~200g/10分钟的范围内,熔点处于157℃~165℃的范围内的低MFR且高熔点的丙烯系聚合物(优选为丙烯均聚物),将鞘部设为MFR处于10g/10分钟~200g/10分钟的范围内,熔点处于130℃~150℃的范围内的高MFR且低熔点的丙烯-α-烯烃无规共聚物,且上述芯部的MFR与上述鞘部的MFR之差为1g/10分钟以上的同芯的芯鞘型复合纤维的芯鞘型复合纤维、并列型复合纤维或卷曲复合纤维的纺粘非织造布。
(B)包含将芯部设为MFR处于1g/10分钟~200g/10分钟的范围内的低MFR的丙烯系聚合物(优选为丙烯均聚物),将鞘部设为MFR处于31g/10分钟~230g/10分钟的范围内的高MFR的丙烯系聚合物(优选为丙烯均聚物),且上述芯部的MFR与上述鞘部的MFR之差为30g/10分钟以上的同芯的芯鞘型复合纤维的纺粘非织造布。
在上述(B)中,可以将芯部设为MFR处于10g/10分钟~50g/10分钟的范围内的低MFR的丙烯系聚合物,将鞘部设为MFR处于50g/10分钟~100g/10分钟的范围内的高MFR的丙烯系聚合物。上述芯部的MFR与上述鞘部的MFR之差可以为30g/10分钟~100g/10分钟,可以为40g/10分钟~80g/10分钟以下。
〔其它层〕
在本公开的非织造布层叠体上根据各种用途,可以层叠其它层。在本公开的非织造布层叠体上层叠的其它层没有特别限定,可以根据用途层叠各种层。
作为其它层,具体而言,可举出针织布、机织布、弹性非织造布和伸长性纺粘非织造布以外的非织造布、膜等。在本公开的非织造布层叠体上进一步层叠(贴合)其它层的方法没有特别限制,可以采用热压纹加工、超声波熔合等热熔合法、针刺、水喷射等机械交织法、使用了热熔粘接剂、氨基甲酸酯系粘接剂等粘接剂的方法、挤出层压等各种方法。
作为本公开的非织造布层叠体具有弹性非织造布和伸长性纺粘非织造布以外的非织造布的情况下的非织造布,可举出纺粘非织造布、熔喷非织造布、湿式非织造布、干式非织造布、干式浆粕非织造布、闪蒸纺丝非织造布、开纤非织造布等各种公知的非织造布。这些非织造布可以为伸缩性非织造布,也可以为非伸缩性非织造布。这里所谓非伸缩性非织造布,是指沿MD(非织造布的流向,纵向)或CD(与非织造布的流向垂直的方向,横向)伸长后,不产生恢复应力的非织造布。
作为本公开的非织造布层叠体具有膜的情况下的膜,从保持作为本公开的非织造布层叠体的特征的透气性和亲水性的观点考虑,优选为透气性(透湿性)膜。作为透气性膜,可举出由具有透湿性的聚氨酯系弹性体、聚酯系弹性体、聚酰胺系弹性体等热塑性弹性体形成的膜、将由包含无机微粒或有机微粒的热塑性树脂形成的膜进行拉伸而多孔化形成的多孔膜等各种公知的透气性膜。作为多孔膜所使用的热塑性树脂,优选为高压法低密度聚乙烯、线型低密度聚乙烯(所谓LLDPE)、高密度聚乙烯、聚丙烯、聚丙烯无规共聚物、它们的组合等聚烯烃。然而,在不需要保持非织造布层叠体的透气性和亲水性的情况下,可以使用聚乙烯、聚丙烯、它们的组合等热塑性树脂的膜。
〔非织造布层叠体的制造方法〕
本公开的非织造布层叠体可以使用包含α-烯烃共聚物的弹性非织造布、伸长性纺粘非织造布以及根据需要使用的添加剂,通过公知的非织造布的制造方法来制造。
作为非织造布层叠体的制造方法的一例,对于使用具备至少两列纺丝装置的非织造布制造装置的方法,以下进行说明。下述例为使用烯烃系聚合物作为伸长性纺粘非织造布,使用α-烯烃共聚物作为弹性非织造布的非织造布层叠体的制造方法的一例。
关于本公开的非织造布层叠体,从制造上的观点考虑,优选为在与非织造布制造装置所附带的旋转设备接触的一侧的面上,配置有伸长性纺粘非织造布的方式。
首先,利用第一列纺丝装置所具备的挤出机、根据需要的两个以上的挤出机,将烯烃系聚合物、根据需要的两种以上的烯烃系聚合物进行熔融,导入至具备有多个纺丝孔(喷嘴)的口模(模头)、根据需要的具有芯鞘结构的纺丝孔,并将其排出。然后,将包含经熔融纺丝的烯烃系聚合物的长纤维导入至冷却室,利用冷却风进行冷却之后,利用拉伸空气将长纤维进行拉伸(牵引),使伸长性纺粘非织造布堆积于移动捕集面上。
另一方面,利用第二列纺丝装置所具备的挤出机将包含本公开的α-烯烃共聚物的树脂组合物进行熔融,导入至具有具备有多个纺丝孔(喷嘴)的口模(模头)的纺丝孔,将树脂组合物排出。然后,将包含经熔融纺丝的树脂组合物的长纤维导入至冷却室,利用冷却风进行冷却之后,利用拉伸空气将长纤维进行拉伸(牵引),使其堆积于伸长性纺粘非织造布上,形成弹性非织造布。
根据需要,可以使用第三列纺丝装置,使伸长性纺粘非织造布堆积于弹性非织造布上。
弹性非织造布和伸长性纺粘非织造布中的各聚合物的熔融温度只要为各个聚合物的软化温度或熔化温度以上且小于热分解温度,就没有特别限定。口模的温度取决于所使用的聚合物的种类,例如,在使用乙烯和丙烯的共聚物作为α-烯烃共聚物的情况下,口模的温度优选为180℃~240℃,更优选为190℃~230℃,进一步优选为200℃~225℃。
冷却风的温度只要为聚合物固化的温度,就没有特别限定,优选为5℃~50℃,更优选为10℃~40℃,进一步优选为15℃~30℃。拉伸空气的风速优选为100m/分钟~10,000m/分钟,更优选为500m/分钟~10,000m/分钟。
本公开的非织造布层叠体优选具有弹性非织造布的至少一部分与伸长性纺粘非织造布的至少一部分热熔合的结构。此时,可以在将弹性非织造布的至少一部分与伸长性纺粘非织造布的至少一部分进行热熔合之前,使用轧辊压紧。
热熔合的方法没有特别限制,能够从各种公知的方法中进行选择。例如,可举出使用了超声波等手段的方法、使用了压纹辊的热压纹加工、使用了热风成型的方法等作为预接合。其中,从拉伸时长纤维被效率良好地拉伸的观点考虑,优选为热压纹加工,其温度范围优选为40℃~115℃。
在通过热压纹加工将层叠体的一部分进行热熔合的情况下,压纹面积率优选为5%~30%,更优选为5%~20%。非压纹单位面积优选为0.5mm2以上,更优选为4mm2~40mm2。所谓非压纹单位面积,表示在四方被压纹部包围的最小单元的非压纹部中,与压纹内接的四边形的最大面积。作为刻印的形状,可举出圆形、椭圆形、长圆形、正方形、菱形、长方形、四边形、以这些形状为基础的连续形状等。
<伸缩性非织造布层叠体>
本公开的伸缩性非织造布层叠体为通过将上述非织造布层叠体进行拉伸而获得的、具有伸缩性的非织造布层叠体。
本公开的伸缩性非织造布层叠体为通过将上述非织造布层叠体进行拉伸加工而获得的非织造布层叠体的拉伸加工物。拉伸加工的方法没有特别限制,能够适用以往公知的方法。拉伸加工的方法可以为部分地拉伸的方法,也可以为整体上拉伸的方法。此外,可以为单轴拉伸的方法,也可以为双轴拉伸的方法。作为沿机械流向(MD)拉伸的方法,可举出例如,使部分地熔合了的混合纤维通过2个以上的轧辊的方法。此时,能够通过将轧辊的旋转速度沿机械流向的顺序加速,从而将部分地熔合了的非织造布层叠体进行拉伸。此外,还能够使用图1所示的齿轮拉伸装置进行齿轮拉伸加工。
拉伸倍率的下限值优选为50%以上,更优选为100%以上,进一步优选为200%以上。另一方面,拉伸倍率的上限值优选为1000%以下,更优选为500%以下。
在单轴拉伸的情况下,机械流向(MD)的拉伸倍率,或与其垂直的方向(CD)的任一者优选满足上述拉伸倍率。在双轴拉伸的情况下,机械流向(MD)和与其垂直的方向(CD)中,至少一者优选满足上述拉伸倍率。
通过以上述那样的拉伸倍率进行拉伸加工,从而形成弹性非织造布和伸长性纺粘非织造布的(长)纤维都被拉伸。形成伸长性纺粘非织造布层的长纤维发生塑性变形,与上述拉伸倍率相应地被伸长(即,变长)。
如果将非织造布层叠体进行拉伸之后,释放应力,则形成弹性非织造布的(长)纤维弹性恢复,形成伸长性纺粘非织造布的长纤维不发生弹性恢复而皱曲,非织造布层叠体表现膨松感。进一步,存在形成伸长性纺粘非织造布的长纤维变细的倾向。因此,认为柔软性和触感变好,并且能够赋予伸长停止的功能。
<纤维制品>
本公开的纤维制品包含本公开的非织造布层叠体或伸缩性非织造布层叠体。纤维制品没有特别限制,可举出一次性尿布、生理用品等吸收性物品、卫生口罩等卫生物品、绷带等医疗物品、衣料原材料、包装材等。本公开的纤维制品优选包含本公开的非织造布层叠体或伸缩性非织造布层叠体作为伸缩构件。
实施例
以下,基于实施例,进一步详细地说明本发明,但是本发明并不受下述实施例的限定。以下实施例所示的材料、使用量、比例、处理步骤等只要不脱离本公开的宗旨,就能够适当变更。另外,只要没有特别的规定,“份”表示“质量份”。
-材料的准备-
作为弹性非织造布的原料,准备以下材料。
·α-烯烃共聚物1A(丙烯/乙烯共聚物)
埃克森美孚公司制,制品名“VistamaxxTM6202”,MFR(230℃,载荷2.16kg):20g/10分钟,乙烯含量:15质量%,抗拉弹性模量:9.8MPa。
·α-烯烃共聚物1B(丙烯/乙烯共聚物)
埃克森美孚公司制,制品名“VistamaxxTM7050FL”,MFR(230℃,载荷2.16kg):48g/10分钟,乙烯含量:13质量%,抗拉弹性模量:14.4MPa。
·α-烯烃均聚物1C(低结晶性聚丙烯)的合成
在带有搅拌机的内容积0.2m3的不锈钢制反应器中,将正庚烷以20L/h,将三异丁基铝以15mmol/h,进一步,将使二甲基苯铵四(五氟苯基)硼酸盐与(1,2’-二甲基亚甲硅基)(2,1’-二甲基亚甲硅基)-双(3-三甲基甲硅烷基甲基茚基)二氯化锆、三异丁基铝与丙烯预先接触而获得的催化剂成分以单位锆为6μmol/h进行了连续供给。在聚合温度70℃,以使气相部氢浓度为8mol%,反应器内的总压保持于0.7MPa·G的方式,连续供给丙烯和氢。在所得的聚合溶液中,添加SUMILIZER GP(住友化学公司制)而使其达到1000ppm,除去溶剂,从而获得了丙烯聚合物。
获得的丙烯聚合物的重均分子量(Mw)为1.2×104,Mw/Mn=2。此外,由NMR测定求出的[mmmm]为46摩尔%,[rrrr]/(1-[mmmm])为0.038,[rmrm]为2.7摩尔%,[mm]×[rr]/[mr]2为1.5,抗拉弹性模量为32.9MPa。
另外,[mmmm]为内消旋五单元组分率,[rrrr]为外消旋五单元组分率,[rmrm]为外消旋内消旋外消旋内消旋五单元组分率,[mm]、[rr]和[mr]分别为三单元组分率。这些值例如,能够通过国际公开第2016/143834号所记载的方法来求出。
[实施例1]
将MFR(按照ASTM D1238,以温度230℃,载荷2.16kg进行测定)8.5g/10分钟,密度0.91g/cm3,熔点160℃的丙烯均聚物(以下为“聚合物2A”;表1和表2中为“PP”)使用的挤出机进行熔融,与此独立地将MFR(按照ASTM D1238,以温度230℃,载荷2.16kg进行测定)60g/10分钟,密度0.91g/cm3,熔点160℃的丙烯均聚物(以下为“聚合物2B”;表1和表2中为“PP”)使用/>的挤出机进行熔融之后,使用具有能够成型“聚合物2A”成为芯、“聚合物2B”成为鞘那样的同芯的芯鞘复合纤维的喷丝头(模头,孔数2887孔)的纺粘非织造布成型机(捕集面上的与机械流向垂直的方向的长度:800mm),以树脂温度和模头温度都为250℃,冷却风温度20℃,拉伸空气风速3750m/分钟的条件,通过纺粘法进行复合熔融纺丝,使由芯部与鞘部的质量比为10/90的同芯的芯鞘型复合纤维形成的伸长性纺粘非织造布作为第1层堆积于捕集面上。
接着,在该堆积面上,将上述α-烯烃共聚物1A使用螺杆直径的单螺杆挤出机进行熔融之后,使用具有喷丝头(模头,孔数808孔)的纺粘非织造布成型机(捕集面上的与机械流向垂直的方向的长度:800mm),以树脂温度和模头温度都为215℃,冷却风温度20℃,拉伸空气风速3750m/分钟的条件,通过纺粘法进行熔融纺丝,使弹性非织造布(弹性纺粘非织造布)堆积作为第2层。该工序中的、上述α-烯烃共聚物1A的纺丝性非常良好。
接着,作为第3层,使与第1层同样的芯鞘型复合纤维通过同样的方法进行堆积,制成3层堆积物。将该堆积物利用压纹辊进行加热加压处理(压纹面积率18%,压纹温度70℃),制作出总目付量为30.0g/m2,第1层和第3层的目付量为10.0g/m2,作为第2层的弹性非织造布层的目付量为10.0g/m2的非织造布层叠体(弹性非织造布层相对于整体所占的质量分率为33.3%)。
如上述那样操作而获得的非织造布层叠体几乎没有对于压纹工序中的金属辊表面的附着,成型性良好。此外,在将非织造布层叠体卷绕成卷状态时,也没有发生卷粘连(互相重叠的非织造布相互附着,使卷固结的现象),能够容易地拉出。
[实施例2]
设为使弹性非织造布的原料从α-烯烃共聚物1A变更为α-烯烃共聚物1B的方式,除此以外,通过与实施例1同样的操作,获得了非织造布层叠体。
[比较例1]
设为使弹性非织造布的原料从α-烯烃共聚物1A变更为α-烯烃均聚物1C的方式,除此以外,通过与实施例1同样的操作,获得了非织造布层叠体。
[实施例3]
将第1层和第3层中的伸长性纺粘非织造布的目付以及第2层中的弹性非织造布的目付从10.0g/m2变更为16.7g/m2,除此以外,通过与实施例1同样的操作,获得了非织造布层叠体。
[实施例4]
将第1层和第3层中的伸长性纺粘非织造布的目付从10.0g/m2变更为15.6g/m2,将第2层中的弹性非织造布的目付从10.0g/m2变更为18.8g/m2,除此以外,通过与实施例1同样的操作,获得了非织造布层叠体。
[实施例5]
将第1层和第3层中的伸长性纺粘非织造布的目付以及第2层中的弹性非织造布的目付从10.0g/m2变更为20.0g/m2,除此以外,通过与实施例1同样的操作,获得了非织造布层叠体。
[实施例6]
将第1层和第3层中的伸长性纺粘非织造布的目付以及第2层中的弹性非织造布的目付从10.0g/m2变更为20.0g/m2,除此以外,通过与实施例2同样的操作,获得了非织造布层叠体。
[比较例2]
将第1层和第3层中的伸长性纺粘非织造布的目付以及第2层中的弹性非织造布的目付从10.0g/m2变更为20.0g/m2,除此以外,通过与比较例1同样的操作,获得了非织造布层叠体。
[比较例3]
将第2层中的弹性非织造布的目付从20.0g/m2变更为25.0g/m2,除此以外,通过与比较例2同样的操作,获得了非织造布层叠体。
-评价-
(纺丝性)
对于各例的非织造布,制造时,目视观察纺粘非织造布制造装置的喷嘴面附近的纺丝状况,计算每5分钟的断线次数(单位:次/5分钟)。如果断线次数为0次/5分钟,则评价为“A”,如果发生断线,没有达到非织造布采集的情况,评价为“B”(表1和表2)。
-伸缩特性(50%伸长时应力、50%恢复时应力)的评价-
使用万能拉伸试验机(Intesco公司制,IM-201型),从各例的非织造布层叠体采集50mm(CD)×200mm(MD)的试验片5张。接着,对于采集的各试验片,以样品宽度50mm、夹盘间距离100mm、拉伸速度100mm/分钟的条件将试验片100%伸长之后,立即以相同速度使其恢复至原长。将该操作再实施1个循环,将第2个循环的伸长时拉伸倍率达到50%时的应力设为50%伸长时应力,将第2个循环的恢复时拉伸倍率达到50%时的应力设为50%恢复时应力。接着,作为伸缩特性的尺度,测定〔50%恢复时应力÷50%伸长时应力〕的值,将5张试验片的算术平均值作为伸缩特性进行评价。另外〔50%恢复时应力÷50%伸长时应力〕的值越大,则意味着伸缩特性越优异(表1和表2)。
此外,关于各例中的各温度的储能弹性模量、储能弹性模量之比、最大载荷伸长率和各非织造布的目付,将通过前述的测定方法测定得到的结果示于表1和表2中。
[表1]
[表2]
如表1和表2所示那样,可知实施例的非织造布层叠体与比较例的非织造布层叠体相比,伸缩特性优异,并且应力维持优异。
2018年10月25日申请的日本专利申请2018-201247号的公开内容的整体通过参照引入至本说明书中。
本说明书所记载的全部文献、专利申请和技术标准,以各个文献、专利申请和技术标准通过参照而引入的情况与被具体且逐个记载的情况为同等程度的方式,通过参照引入至本说明书中。

Claims (14)

1.一种非织造布层叠体,其具有:
弹性非织造布,其包含40℃时的储能弹性模量E40与23℃时的储能弹性模量E23之比,即E40/E23为37%以上的α-烯烃共聚物;以及
伸长性纺粘非织造布,其配置于所述弹性非织造布的至少一面侧,
所述α-烯烃共聚物相对于所述弹性非织造布的总量的比例为90质量%~100质量%,所述弹性非织造布中的所述α-烯烃共聚物的熔体流动速率为15g/10分钟~50g/10分钟。
2.根据权利要求1所述的非织造布层叠体,所述α-烯烃共聚物的所述23℃时的储能弹性模量E23为30MPa以下。
3.根据权利要求1或2所述的非织造布层叠体,所述α-烯烃共聚物包含乙烯和丙烯的共聚物。
4.根据权利要求1或2所述的非织造布层叠体,所述α-烯烃共聚物的抗拉弹性模量为30MPa以下。
5.根据权利要求1或2所述的非织造布层叠体,在所述弹性非织造布的两面侧配置有所述伸长性纺粘非织造布。
6.根据权利要求1或2所述的非织造布层叠体,所述伸长性纺粘非织造布的至少一个方向的最大载荷伸长率为45%以上。
7.根据权利要求1或2所述的非织造布层叠体,所述弹性非织造布为弹性纺粘非织造布。
8.根据权利要求1或2所述的非织造布层叠体,所述伸长性纺粘非织造布为包含同芯的芯鞘型复合纤维的伸长性纺粘非织造布,所述同芯的芯鞘型复合纤维中,将芯部设为MFR处于1g/10分钟~1000g/10分钟的范围的低MFR的烯烃系聚合物,将鞘部设为MFR处于1g/10分钟~1000g/10分钟的范围的高MFR的烯烃系聚合物,且所述低MFR的烯烃系聚合物与所述高MFR的烯烃系聚合物的MFR之差为1g/10分钟以上。
9.根据权利要求1或2所述的非织造布层叠体,所述伸长性纺粘非织造布含有烯烃系聚合物组合物,所述烯烃系聚合物组合物包含80质量%~99质量%的结晶性丙烯系聚合物和1质量%~20质量%的高密度聚乙烯。
10.根据权利要求1或2所述的非织造布层叠体,所述弹性非织造布与所述伸长性纺粘非织造布的目付比,即弹性非织造布:伸长性纺粘非织造布处于10:90~90:10的范围内。
11.一种伸缩性非织造布层叠体,其为权利要求1~10中任一项所述的非织造布层叠体的拉伸加工物。
12.一种纤维制品,其包含权利要求1~10中任一项所述的非织造布层叠体或权利要求11所述的伸缩性非织造布层叠体。
13.一种吸收性物品,其包含权利要求1~10中任一项所述的非织造布层叠体或权利要求11所述的伸缩性非织造布层叠体。
14.一种卫生口罩,其包含权利要求1~10中任一项所述的非织造布层叠体或权利要求11所述的伸缩性非织造布层叠体。
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