CN117099788A - 包含吡唑化合物的农药混合物 - Google Patents
包含吡唑化合物的农药混合物 Download PDFInfo
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-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P3/00—Fungicides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P5/00—Nematocides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P7/00—Arthropodicides
- A01P7/02—Acaricides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P7/00—Arthropodicides
- A01P7/04—Insecticides
Abstract
农药混合物，包含作为活性化合物的1)1‑[(1RS)‑1,2‑二甲基丙基]‑N‑乙基‑5‑甲基‑N‑哒嗪‑4‑基‑1H‑吡唑‑4‑甲酰胺和2)至少一种其他化合物B，选自B.3)选自florylpicoxamid的Qi位点的配合物III抑制剂，B.5)如说明书中所定义的甾醇生物合成中的C14脱甲基酶抑制剂；其中组分1)和组分2)以10:1‑1:10的重量比存在；这些混合物在植物中和植物上防除无脊椎动物害虫如昆虫、蜘蛛、线虫和/或有害真菌的方法和用途以及保护被害虫和/或有害真菌侵染的该类植物的方法和用途。
Description
本申请是申请号为202080014684.4、申请日为2020年2月11日、发明名称为“包含吡唑化合物的农药混合物”的专利申请的分案申请。
本发明涉及包含吡唑化合物和至少一种杀真菌剂或杀虫剂作为活性化合物的协同增效农药混合物。
因此，本发明涉及包含如下化合物作为活性化合物的农药混合物：
1)式I的1-[(1RS)-1,2-二甲基丙基]-N-乙基-5-甲基-N-哒嗪-4-基-1H-吡唑-4-甲酰胺(通用名：嗪虫唑酰胺(dimpropyridaz))：
和
2)至少一种其他化合物B，选自：
B.1)琥珀酸脱氢酶抑制剂，选自a)氟唑菌酰羟胺(pydiflumetofen)，b)联苯吡嗪菌胺(pyraziflumid)，c)inpyrfluxam，d)pyrapropoyne，e)氟茚唑菌胺(fluindapyr)，f)isoflucypram，g)2-二氟甲基-N-(1,1,3-三甲基-2,3-二氢化茚-4-基)吡啶-3-甲酰胺，h)2-二氟甲基-N-[(3R)-1,1,3-三甲基-2,3-二氢化茚-4-基]吡啶-3-甲酰胺，i)2-二氟甲基-N-(3-乙基-1,1-二甲基-2,3-二氢化茚-4-基)吡啶-3-甲酰胺，j)2-二氟甲基-N-[(3R)-3-乙基-1,1-二甲基-2,3-二氢化茚-4-基]吡啶-3-甲酰胺，k)2-二氟甲基-N-(1,1-二甲基-3-丙基-2,3-二氢化茚-4-基)吡啶-3-甲酰胺，l)2-二氟甲基-N-[(3R)-1,1-二甲基-3-丙基-2,3-二氢化茚-4-基]吡啶-3-甲酰胺，m)2-二氟甲基-N-(3-异丁基-1,1-二甲基-2,3-二氢化茚-4-基)吡啶-3-甲酰胺，n)2-二氟甲基-N-[(3R)-3-异丁基-1,1-二甲基-2,3-二氢化茚-4-基]吡啶-3-甲酰胺，o)N-[2-[2-氯-4-(三氟甲基)苯氧基]苯基]-3-二氟甲基-5-氟-1-甲基吡唑-4-甲酰胺和p)(E)-2-[2-[(5-氰基-2-甲基苯氧基)甲基]苯基]-3-甲氧基丙-2-烯酸甲酯；
B.2)氧化甾醇结合蛋白抑制剂，选自a)氟噻唑吡乙酮(oxathiapiprolin)，b)甲磺酸2-{3-[2-(1-{[3,5-二(二氟甲基)-1H-吡唑-1-基]乙酰基}哌啶-4-基)-1,3-噻唑-4-基]-4,5-二氢-1,2-唑-5-基}苯基酯，c)甲磺酸2-{3-[2-(1-{[3,5-二(二氟甲基)-1H-吡唑-1-基]乙酰基}哌啶-4-基)-1,3-噻唑-4-基]-4,5-二氢-1,2-/>唑-5-基}-3-氯苯基酯，d)4-[1-[2-[3-二氟甲基-5-甲基吡唑-1-基]乙酰基]-4-哌啶基]-N-四氢萘-1-基吡啶-2-甲酰胺，e)4-[1-[2-[3,5-二(二氟甲基)吡唑-1-基]乙酰基]-4-哌啶基]-N-四氢萘-1-基吡啶-2-甲酰胺，f)4-[1-[2-[3-二氟甲基-5-(三氟甲基)吡唑-1-基]乙酰基]-4-哌啶基]-N-四氢萘-1-基吡啶-2-甲酰胺，g)4-[1-[2-[5-环丙基-3-(二氟甲基)吡唑-1-基]乙酰基]-4-哌啶基]-N-四氢萘-1-基吡啶-2-甲酰胺，h)4-[1-[2-[5-甲基-3-(三氟甲基)吡唑-1-基]乙酰基]-4-哌啶基]-N-四氢萘-1-基吡啶-2-甲酰胺，i)4-[1-[2-[5-二氟甲基-3-(三氟甲基)吡唑-1-基]乙酰基]-4-哌啶基]-N-四氢萘-1-基吡啶-2-甲酰胺，j)4-[1-[2-[3,5-二(三氟甲基)吡唑-1-基]乙酰基]-4-哌啶基]-N-四氢萘-1-基吡啶-2-甲酰胺和k)4-[1-[2-[5-环丙基-3-(三氟甲基)吡唑-1-基]乙酰基]-4-哌啶基]-N-四氢萘-1-基吡啶-2-甲酰胺；
B.3)Qi位点的配合物III抑制剂，选自a)florylpicoxamid和b)fenpicoxamid；
B.4)嗜球果伞素类(配合物III抑制剂，Qo位点)，选自a)(Z,2E)-5-[1-(2,4-二氯苯基)吡唑-3-基]氧基-2-甲氧亚氨基-N,3-二甲基戊-3-烯酰胺，b)(Z,2E)-5-[1-(4-氯苯基)吡唑-3-基]氧基-2-甲氧亚氨基-N,3-二甲基戊-3-烯酰胺，和c)2-(邻-((2,5-二甲基苯氧基亚甲基)苯基)-3-甲氧基丙烯酸甲酯；
B.5)甾醇生物合成中的C14脱甲基酶抑制剂(DMI杀真菌剂)，选自a)2-(2,4-二氟苯基)-1,1-二氟-3-(四唑-1-基)-1-[5-[4-(2,2,2-三氟乙氧基)苯基]-2-吡啶基]丙-2-醇，b)2-(2,4-二氟苯基)-1,1-二氟-3-(四唑-1-基)-1-[5-[4-(三氟甲氧基)苯基]-2-吡啶基]丙-2-醇，c)2-氯甲基-2-甲基-5-(对甲苯基甲基)-1-(1,2,4-三唑-1-基甲基)环戊醇，d)4-[[6-[2-(2,4-二氟苯基)-1,1-二氟-2-羟基-3-(5-硫基-1,2,4-三唑-1-基)丙基]-3-吡啶基]氧
基]苄腈；
B.6)细胞分裂和细胞骨架抑制剂，选自a)Pyridachlometyl，b)N-乙基-2-[(3-乙炔基-8-甲基-6-喹啉基)氧基]丁酰胺，c)N-乙基-2-[(3-乙炔基
-8-甲基-6喹啉基)氧基]-2-甲硫基乙酰胺，d)2-[(3-乙炔基-8-甲基-6-喹啉基)氧基]-N-(2-氟乙基)丁酰胺，e)2-[(3-乙炔基-8-甲基-6-喹啉基)氧基]-N-(2-氟乙基)-2-甲氧基乙酰胺，f)2-[(3-乙炔基-8-甲基-6-喹啉基)氧基]-N-丙基丁酰胺，g)2-[(3-乙炔基-8-甲基-6-喹啉基)氧基]-2-甲氧基-N-丙基乙酰胺，h)2-[(3-乙炔基-8-甲基-6-喹啉基)氧基]-2-甲硫基-N-丙基乙酰胺，i)2-[(3-乙炔基-8-甲基-6-喹啉基)氧基]-N-(2-氟乙基)-2-甲硫基乙酰胺，j)4-(2-溴-4-氟苯基)-N-(2-氯-6-氟苯基)-2,5-二甲基吡唑-3-胺，
B.7)未知作用模式的其他化合物，选自a)双氯氰菌胺(diclocymet)，b)杀螟松(fenitropan)，c)超敏蛋白(harpin)，d)picarbutrazox，e)
dichlobentiazox，f)pyrifenamine，g)quinofumelin，h)ipflufenoquin，
i)4-环丙基-N-(2,4-二甲氧基苯基)噻二唑-5-甲酰胺，j)N'-[4-[[3-[(4-氯苯基)甲基]-1,2,4-噻二唑-5-基]氧基]-2,5-二甲基苯基]-N-乙基-N-甲基甲脒，k)N'-(5-溴-6-(2,3-二氢化茚-2-基)氧基-2-甲基-3-吡啶基)-N-乙基-N-甲基甲脒，l)N'-[5-溴-6-[1-(3,5-二氟苯基)乙氧基]-2-甲基-3-吡啶基]-N-乙基-N-甲基甲脒，m)N'-[5-溴-6-(4-异丙基环己氧基)-2-甲基-3-吡啶基]-N-乙基-N-甲基甲脒，n)N'-[5-溴-2-甲基-6-(1-苯基乙氧基)-3-吡啶基]-N-乙基-N-甲基甲脒，o)(Z)-3-氨基-2-氰基-3-苯基丙-2-烯酸乙酯，p)N-[6-[[(Z)-[(1-甲基四唑-5-基)苯基亚甲基]氨基]氧基甲基]-2-吡啶基]氨基甲酸戊酯，q)N-[6-[[(Z)-[(1-甲基四唑-5-基)苯基亚甲基]氨基]氧基甲基]-2-吡啶基]氨基甲酸丁-3-炔基酯(picarbutrazox)，r)2-(6-苄基-2-吡啶基)喹唑啉，s)2-[6-(3-氟-4-甲氧基苯基)-5-甲基-2-吡啶基]
喹唑啉，t)N'-(2,5-二甲基-4-苯氧基苯基)-N-乙基-N-甲基甲脒，和B.8)N-[[2-氟-4-[(2S,3S)-2-羟基-3-(3,4,5-三氯苯基)-3-(三氟甲基)吡咯烷-1-基]苯基]甲基]环丙烷甲酰胺；
其中组分1)和组分2)以1000:1-1:1000的重量比存在。
在害虫防治领域出现的一个典型问题在于需要降低活性成分的剂量率以降低或避免不利的环境或毒理学效果，同时仍允许有效的害虫防治。遇到的另一问题涉及需要具有对宽范围的害虫或作物病害有效的可用杀虫防治剂。
与农药使用相关的另一难点是重复和唯一地施用单一农药化合物在许多情况下导致对所述活性化合物产生天然或适应耐受性的害虫和有害真菌的快速选择。因此，需要有助于防止或克服耐受性的害虫防治剂。
式I化合物由WO 2012/143317已知。提到该化合物可以用于防除无脊椎动物害虫。
因此，本发明的目的是要提供解决了作为降低剂量率、提高活性谱或组合击倒活性和长期防治或者耐受性管理所讨论的问题中至少一个的农药混合物。
已经发现这些目的中的至少一个由开头所定义的活性化合物的组合实现。
此外，还已发现同时，即联合或分开施用嗪虫唑酰胺和一种或多种活性化合物B或者依次施用嗪虫唑酰胺和一种或多种活性化合物B与使用单独化合物可能的防治率相比允许增强害虫和/或有害真菌的防治。
此外，本发明涉及：
-一种包含包含本文所定义的农药混合物和至少一种惰性液体和/或固体可接受载体的农业组合物；
-一种防治或防除无脊椎动物害虫的方法，包括使所述害虫或其食物供应源、栖息地、繁殖地与农药有效量的本文所定义的农药混合物接触；
-本文所定义的农药混合物在保护生长植物或植物繁殖材料以防无脊椎动物害虫侵袭或侵染中的用途；
-一种防治植物病原性有害真菌的方法，其中用有效量的包含嗪虫唑酰胺和至少一种特定化合物B的农药混合物处理真菌、其栖息地或者要保护以防真菌侵袭的植物、土壤或种子；
-一种保护植物以防植物病原性有害真菌的方法，其中用有效量的包含嗪虫唑酰胺和至少一种特定化合物B的农药混合物处理真菌、其栖息地或者要保护以防真菌侵袭的植物、土壤或种子；以及
本发明混合物可以是嗪虫唑酰胺和至少一种化合物B的物理混合物。因此，本发明还提供了一种包含嗪虫唑酰胺和至少一种化合物B的混合物。然而，该组合物也可以是嗪虫唑酰胺与至少一种化合物B的任何组合，其中不要求化合物A和B一起存在于相同配制剂中。
本文所用术语“无脊椎动物害虫”(也称为动物害虫)包括可能侵袭植物，从而对被侵袭植物造成显著损害的动物种群，如昆虫、蜘蛛和线虫。
术语“本发明化合物”或“式I化合物”或“吡唑化合物A”包括如本文所定义的嗪虫唑酰胺及其立体异构体、盐、互变异构体或N-氧化物。
嗪虫唑酰胺具有一个手性中心；它作为对映体混合物存在。本发明提供了纯对映体或非对映体及其混合物二者以及嗪虫唑酰胺的纯对映体或其混合物的本发明用途。
市售的其他化合物B尤其可以在The Pesticide Manual，第17版，British CropProtection Council(2015)及其在线数据库https://www.bcpc.org/product/bcpc-online-pesticide-manual-latest-version中找到。化合物B1-B8及其杀真菌或杀虫作用分别由CN 1456054，WO 2017008583，CN 1907024，WO 2015197530，WO 2016097003，WO2016139189，WO 2016096944，WO 2016096849，WO 2017220491，WO 2018046431，WO2016109257，WO 2016122802，WO 2016187201，WO 2018098216，WO 2018098243，WO2018098245，WO 2014/60177，WO 2013116251，WO 2015036379，WO13127704，WO 2015/65922，WO 2011/80044，WO2012/146125，WO 2009115557，WO 2012045798，WO2012/69652，EP2865265和WO2016/180802已知。
我们已经发现同时，即联合或分开施用嗪虫唑酰胺和至少一种化合物B或者依次施用嗪虫唑酰胺和至少一种化合物B与单独使用各化合物可能的防治相比允许更好地防治动物害虫和/或有害真菌(协同增效混合物)。
嗪虫唑酰胺可以用作不同杀真菌活性化合物的增效剂。通过同时，即联合或分开施用嗪虫唑酰胺和至少一种活性化合物B1-B7，杀真菌活性以超加和方式提高。通过同时，即联合或分开施用嗪虫唑酰胺和化合物B8，杀虫活性以超加和方式提高。
下面关于各变量的优选实施方案所作说明进一步单独以及优选适用的话就嗪虫唑酰胺而言以及就本发明用途和方法及本发明混合物而言相互结合有效。
本发明的特别方面是农药混合物A、B、C、D、E、F、G和H中的任一种：
农药混合物A包含如下化合物作为活性组分：
A1)嗪虫唑酰胺，和
A2)选自如开头所定义的B.2组的琥珀酸脱氢酶抑制剂；
其中组分A1)和组分A2)以1000:1-1:1000，优选100:1-1:100，特别是20:1-1:20的总重量比例存在。在上述比例中，一个实施方案涉及1:1至过量嗪虫唑酰胺的比例；在另一实施方案中，比例为1:1至过量化合物B。
优选的混合物A是嗪虫唑酰胺与选自氟唑菌酰羟胺，inpyrfluxam，pyrapropoyne，isoflucypram，2-二氟甲基-N-(1,1,3-三甲基-2,3-二氢化茚-4-基)吡啶-3-甲酰胺，2-二氟甲基-N-[(3R)-1,1,3-三甲基-2,3-二氢化茚-4-基]吡啶-3-甲酰胺，2-二氟甲基-N-(3-乙基-1,1-二甲基-2,3-二氢化茚-4-基)吡啶-3-甲酰胺，2-二氟甲基-N-[(3R)-3-乙基-1,1-二甲基-2,3-二氢化茚-4-基]吡啶-3-甲酰胺，2-二氟甲基-N-(1,1-二甲基-3-丙基-2,3-二氢化茚-4-基)吡啶-3-甲酰胺，2-二氟甲基-N-[(3R)-1,1-二甲基-3-丙基-2,3-二氢化茚-4-基]吡啶-3-甲酰胺，2-二氟甲基-N-(3-异丁基-1,1-二甲基-2,3-二氢化茚-4-基)吡啶-3-甲酰胺和2-二氟甲基-N-[(3R)-3-异丁基-1,1-二甲基-2,3-二氢化茚-4-基]吡啶-3-甲酰胺的化合物B以如上所述的混合物比例的组合。
在另一实施方案中，优选的混合物A是嗪虫唑酰胺与选自如开头所定义的A2 a)-A2 n)的化合物B以如上所述的混合物比例的组合。
农药混合物B包含如下化合物作为活性组分：
B1)嗪虫唑酰胺，和
B2)选自如开头所定义的B.2组的氧化甾醇结合蛋白抑制剂；
其中组分B1)和组分B2)以1000:1-1:1000，优选100:1-1:100，特别是20:1-1:20的总重量比例存在。在上述比例中，一个实施方案涉及1:1至过量嗪虫唑酰胺的比例；在另一实施方案中，比例为1:1至过量化合物B。
优选的混合物B是嗪虫唑酰胺与选自氟噻唑吡乙酮和甲磺酸2-{3-[2-(1-{[3,5-二(二氟甲基)-1H-吡唑-1-基]乙酰基}哌啶-4-基)-1,3-噻唑-4-基]-4,5-二氢-1,2-唑-5-基}-3-氯苯基酯的化合物B以如上所述的混合物比例的组合。
在另一实施方案中，优选的混合物B是嗪虫唑酰胺与选自如开头所定义的B.2a)-B.2c)的化合物B以如上所述的混合物比例的组合。在再一实施方案中，优选的混合物E是嗪虫唑酰胺与选自如开头所定义的B2 d)、B2 h)和B2 t)的化合物B以如上所述的混合物比例的组合。
农药混合物C包含如下化合物作为活性组分：
C1)嗪虫唑酰胺，和
C2)a)florylpicoxamid或b)fenpicoxamid；
其中组分C1)和组分C2)以1000:1-1:1000，优选100:1-1:100，特别是20:1-1:20的总重量比例存在。在上述比例中，一个实施方案涉及1:1至过量嗪虫唑酰胺的比例；在另一实施方案中，比例为1:1至过量化合物B。
优选的混合物C是嗪虫唑酰胺与florylpicoxamid以如上所述的混合物比例的组合。
农药混合物D包含如下化合物作为活性组分：
D1)嗪虫唑酰胺，和
D2)选自如开头所定义的B.4组的嗜球果伞素类；
其中组分D1)和组分D2)以1000:1-1:1000，优选100:1-1:100，特别是20:1-1:20的总重量比例存在。在上述比例中，一个实施方案涉及1:1至过量嗪虫唑酰胺的比例；在另一实施方案中，比例为1:1至过量化合物B。
优选的混合物D是嗪虫唑酰胺与选自(Z,2E)-5-[1-(2,4-二氯苯基)吡唑-3-基]氧基-2-甲氧亚氨基-N,3-二甲基戊-3-烯酰胺和(Z,2E)-5-[1-(4-氯苯基)吡唑-3-基]氧基-2-甲氧亚氨基-N,3-二甲基戊-3-烯酰胺的化合物B以如上所述的混合物比例的组合。
农药混合物E包含如下化合物作为活性组分：
E1)嗪虫唑酰胺，和
E2)选自如开头所定义的B.5组的DMI杀真菌剂；
其中组分E1)和组分E2)以1000:1-1:1000，优选100:1-1:100，特别是20:1-1:20的总重量比例存在。在上述比例中，一个实施方案涉及1:1至过量嗪虫唑酰胺的比例；在另一实施方案中，比例为1:1至过量化合物B。
优选的混合物E是嗪虫唑酰胺与4-[[6-[2-(2,4-二氟苯基)-1,1-二氟-2-羟基-3-(5-硫基-1,2,4-三唑-1-基)丙基]-3-吡啶基]氧基]苄腈以如上所述的混合物比例的组合。
农药混合物F包含如下化合物作为活性组分：
F1)嗪虫唑酰胺，和
F2)选自如开头所定义的B.6组的细胞分裂和细胞骨架抑制剂；
其中组分F1)和组分F2)以1000:1-1:1000，优选100:1-1:100，特别是20:1-1:20的总重量比例存在。在上述比例中，一个实施方案涉及1:1至过量嗪虫唑酰胺的比例；在另一实施方案中，比例为1:1至过量化合物B。
优选的混合物F是嗪虫唑酰胺与pyridachlometyl以如上所述的混合物比例的组合。
农药混合物G包含如下化合物作为活性组分：
G1)嗪虫唑酰胺，和
G2)选自如开头所定义的B.6组的未知作用模式的其他化合物；
其中组分G1)和组分G2)以1000:1-1:1000，优选100:1-1:100，特别是20:1-1:20的总重量比例存在。在上述比例中，一个实施方案涉及1:1至过量嗪虫唑酰胺的比例；在另一实施方案中，比例为1:1至过量化合物B。
优选的混合物G是嗪虫唑酰胺与选自Picarbutrazox、quinofumelin、ipflufenoquin和N'-(2,5-二甲基-4-苯氧基苯基)-N-乙基-N-甲基甲脒的化合物B以如上所述的混合物比例的组合。
农药混合物H包含如下化合物作为活性组分：
H1)嗪虫唑酰胺，和
H2)N-[[2-氟-4-[(2S,3S)-2-羟基-3-(3,4,5-三氯苯基)-3-(三氟甲基)吡咯烷-1-基]苯基]甲基]环丙烷甲酰胺；
其中组分H1)和组分H2)以1000:1-1:1000，优选100:1-1:100，特别是20:1-1:20的总重量比例存在。在上述比例中，一个实施方案涉及1:1至过量嗪虫唑酰胺的比例；在另一实施方案中，比例为1:1至过量化合物B。
嗪虫唑酰胺和化合物B的二元混合物是本发明的一个优选实施方案。
本发明混合物特别适合防治鳞翅目(Lepidoptera)、鞘翅目(Coleoptera)、双翅目(Diptera)、缨翅目(Thysanoptera)和半翅目(Hemiptera)。
混合物尤其可以用于防治缨翅目和半翅目，尤其是半翅目。
在优选实施方案中，本发明涉及特别适合防治选自蝽科(Pentatomidae)和/或叶蝉科(Cicadellidae)和/或粉虱科(Aleyrodidae)和/或蚜科(Aphididae)的害虫—它们是大豆植物上的典型害虫—的农药混合物A-H。
在一个优选实施方案中，本发明涉及包括施用如上所定义的农药混合物的用途或方法，其中害虫选自拟绿蝽(Acrosternum hilare)，茶翅蝽(Halyomorpha halys)，红带蝽(Piezodorus guildinii)，大豆褐蝽(Euschistus heros)，褐臭蝽(Euschistus servus)，筛豆龟蝽(Megacopta cribraria)，红肩蝽(Thyanta custator)和暗褐臭蝽(Euschistustristigmus)，稻绿蝽(Nezara viridula)及其组合。
在一个实施方案中，臭虫目标是稻绿蝽(Nezara viridula)，壁蝽属(Piezodorusspp.)，拟绿蝽属(Acrosternum spp.)，美洲蝽属(Euschistus)，优选的目标尤其是大豆褐蝽(Euchistus heros)。更优选将农药混合物用来防治蝽科，包括拟绿蝽(Acrosternumhilare)、茶翅蝽(Halyomorpha halys)、红带蝽(Piezodorus guildinii)、大豆褐蝽(Euschistus heros)、褐臭蝽(Euschistus servus)和筛豆龟蝽(Megacopta cribraria)、红肩蝽(Thyanta custator)、暗褐臭蝽(Euschistus tristigmus)以及稻绿蝽(Nezaraviridula)。
农药混合物A-H优选用于蝶型花亚科(Faboideae)，尤其是大豆上以防治臭虫，例如绿蝽属(Nezara spp.)(例如稻绿蝽(Nezara viridula)、Nezara antennata、Nezarahilaris)，壁蝽属(例如红带蝽(Piezodorus guildinii))，拟绿蝽属(例如拟绿蝽(Acrosternum hilare))，美洲蝽属(Euchistus spp.)(例如大豆褐蝽(Euchistus heros)、褐臭蝽(Euschistus servus))，茶翅蝽(Halyomorpha halys)，筛豆龟蝽(Megacoptacribaria)，珀椿象(Plautia crossota)，豆蜂缘蝽(Riptortus clavatus)，Rhopalusmsculatus，Antestiopsis orbitalus，蛀茎虫(Dectes texanus)，Dichelops spp.(例如Dichelops furcatus、Dichelops melacanthus)，扁盾蝽属(Eurygaster spp.)(例如麦扁盾蝽(Eurygaster intergriceps)、Eurygaster maurd)，稻蝽属(Oebalus spp.)(例如墨西哥稻蝽(Oebalus mexicana)、Oebalus poecilus、美洲稻蝽(Oebalus pugnase))，黑蝽属(Scotinophara spp.)(例如稻黑蝽(Scotinophara lurida)、Scotinophara coarctatd)。
优选的目标包括拟绿蝽(Acrosternum hilare)，Antestiopsis orbitalus，Dichelops furcatus，Dichelops melacanthus，大豆褐蝽(Euchistus heros)，褐臭蝽(Euschistus servus)，筛豆龟蝽(Megacopta cribaria)，稻绿蝽(Nezara viridula)，Nezara hilare，红带蝽(Piezodorus guildinii)，茶翅蝽(Halyomorpha halys)。
根据本发明可以防治的其他蝽科害虫是二星蝽属(Eysarcoris)，尤其是北二星蝽(Eysarcoris aeneus)。
混合物优选用于蝶型花亚科，尤其是大豆上以防治粉虱，例如烟粉虱(Bemisiatabaci)。
混合物优选用于蝶型花亚科，尤其是大豆上以防治蚜虫，例如大豆蚜(Aphisglycines)。
混合物优选用于蝶型花亚科，尤其是大豆上以防治叶蝉，例如马铃薯小绿叶蝉(Empoasca fabae)。
混合物优选用于蝶型花亚科，尤其是大豆上以防治叶蝉，例如Lorito verde(小绿叶蝉)(Empoasca kraemeri)。
农药混合物A-H优选用于防治鳞翅目昆虫(鳞翅目)，如草地夜蛾(Spodopterafrugiperda)，海灰翅夜蛾(Spodoptera littoralis)，斜纹夜蛾(Spodoptera litura)；甲虫(鞘翅目)，如棉铃象甲(Anthonomus grandis)，苹花象(Anthonomus pomorum)，以及蓟马(缨翅目)，如桔硬蓟马(Scirtothrips citri)。
本发明混合物及其组合物分别特别适合防治下列植物病害：观赏植物、蔬菜(例如白锈菌(A.candida))和向日葵(例如婆罗门参白锈菌(A.tragopogonis))上的白锈菌属(Albugo)(白锈病)；蔬菜(例如胡萝卜黑斑病(A.dauci)或大葱紫斑病(A.porri))、油菜(例如芸苔生链格孢(A.brassicola)或芸苔链格孢(A.brassicae))、糖用甜菜(例如细链格孢(A.tenuis))、水果(例如巨链格孢(A.grandis))、稻、大豆、土豆和西红柿(例如早疫链格孢(A.solani)、巨链格孢(A.grandis)或链格孢(A.alternata))、西红柿(例如早疫链格孢或链格孢)和小麦(例如小麦链格孢(A.triticina))上的链格孢属(Alternaria)(链格孢叶斑病)；糖用甜菜和蔬菜上的丝囊霉属(Aphanomyces)；禾谷类和蔬菜上的壳二孢属(Ascochyta)，例如小麦上的A.tritici(炭疽病)和大麦上的大麦壳二孢(A.hordei)；玉米上的玉米北方炭疽病菌(Aureobasidium zeae)(同义词玉米眼斑病菌(Kapatiellazeae))；平脐蠕孢属(Bipolaris)和内脐蠕孢属(Drechslera)(有性型：旋孢腔菌属(Cochliobolus))，例如玉米上的叶斑病(玉蜀黍平脐蠕孢(D.maydis)或玉米生离蠕孢(B.zeicola))，例如禾谷类上的斑枯病(麦根腐平脐蠕孢(B.sorokiniana)以及例如稻和草坪上的稻平脐蠕孢(B.oryzae)；禾谷类(例如小麦或大麦)上的小麦白粉菌(Blumeria(旧名：Erysiphe)graminis)(白粉病)；水果和浆果(例如草莓)、蔬菜(例如莴苣、胡萝卜、根芹菜和卷心菜)(洋葱科上的葱鳞葡萄孢(B.squamosal)或葱腐葡萄孢(B.allii)、油菜、观赏植物(例如百合灰霉病(B eliptica))、葡萄藤、森林植物和小麦上的灰葡萄孢(Botrytiscinerea)(有性型：灰葡萄孢霉(Botryotinia fuckeliana)：灰霉病)；莴苣上的莴苣盘梗霉(Bremia lactucae)(霜霉病)；阔叶树和常绿树上的长喙壳属(Ceratocystis)(同义词线嘴壳属(Ophiostoma))(腐烂病或枯萎病)，例如榆树上的榆枯萎病菌(C.ulmi)(荷兰榆病)；玉米(例如灰叶斑病:玉米尾孢菌(C.zeae-maydis))、稻、糖用甜菜(例如甜菜生尾孢(C.beticola))、甘蔗、蔬菜、咖啡、大豆(例如大豆灰斑病菌(C.sojina)或大豆紫斑病菌(C.kikuchii))和稻上的尾孢属(Cercospora)(尾孢叶斑病)；蘑菇上的Cladobotryum spp.(同义词指孢霉属(Dactylium))(例如C.mycophilum(旧名：树状指孢霉(Dactyliumdendroides)，有性型：Nectria albertinii，Nectria rosella，同义词粉红寄生菌(Hypomyces rosellus))；西红柿(例如番茄叶霉菌(C.fulvum)：叶霉病)和禾谷类(例如小麦上的草芽枝孢(C.herbarum)(穗腐病))上的枝孢属(Cladosporium)；禾谷类上的麦角菌(Claviceps purpurea)(麦角病)；玉米(灰色长蠕孢(C.carbonum))、禾谷类(例如禾旋孢腔菌(C.sativus)，无性型：麦根腐平脐蠕孢)和稻(例如宫部旋孢腔菌(C.miyabeanus)，无性型：水稻长蠕孢(H.oryzae))上的旋孢腔菌属(无性型：长蠕孢属(Helminthosporium)或平脐蠕孢属)(叶斑病)；棉花(例如棉炭疽病菌(C.gossypii))、玉米(例如禾生炭疽病菌(C.graminicola)：炭疽茎腐病)、浆果、土豆(例如西瓜炭疽病菌(C.coccodes)：黑点病)、菜豆(例如菜豆炭疽病菌(C.lindemuthianum))和大豆(例如大豆炭疽病菌(C.truncatum)或毛豆炭疽病菌(C.gloeosporioides))、蔬菜(例如黄瓜炭疽病菌(C.lagenarium)或辣椒炭疽病菌(C.capsici))、水果(例如尖孢炭疽菌(C.acutatum))、咖啡(例如咖啡刺盘孢(C.coffeanum)或卡哈瓦刺盘孢(C.kahawae))和各种作物(胶孢炭疽菌(C.gloeosporioides)上的剌盘孢属(Colletotrichum)(有性型：围小丛壳菌属(Glomerella))(炭疽病)；伏革菌属(Corticium)，例如稻上的笹木伏革菌(C.sasakii)(纹枯病)；大豆和观赏植物上的黄瓜褐斑病菌(Corynespora cassiicola)(叶斑病)；锈斑病菌属(Cycloconium)，例如橄榄树上的油橄榄孔雀斑病(C.oleaginum)；果树、葡萄藤(例如C.liriodendri，有性型：Neonectria liriodendri：乌脚病)和观赏植物上的人参生柱隔孢属(Cylindrocarpon)(例如果树腐烂病或葡萄藤乌脚病，有性型：丛赤壳属(Nectria)或杓兰菌根菌属(Neonectria))；大豆上的白纹羽菌(Dematophora(有性型：Rosellinia)necatrix)(根腐病/茎腐病)；北茎溃疡菌属(Diaporthe)，例如大豆上的大豆北茎溃疡病菌(D.phaseolorum)(立枯疡)；玉米、禾谷类如大麦(例如大麦网斑内脐蠕孢(D.teres)，网斑病)和小麦(例如D.tritici-repentis：褐斑病)、稻和草坪上的内脐蠕孢属(同义词长蠕孢属，有性型：核腔菌属(Pyrenophora))；由斑褐孔菌(Formitiporia(同义词Phellinus)punctata)、地中海嗜蓝孢孔菌(F.mediterranea)、Phaeomoniella chlamydospora(旧名：Phaeoacremonium chlamydosporum)、Phaeoacremonium aleophilum和/或葡萄座腔菌(Botryosphaeria obtusa)引起的葡萄藤上的埃斯卡(Esca)(葡萄藤枯萎病，干枯病)；仁果(E.pyri)、浆果(覆盆子痂囊腔菌(E.veneta)：炭疽病)和葡萄藤(葡萄痂囊腔菌(E.ampelina)：炭疽病)上的痂囊腔菌属(Elsinoe)；稻上的稻叶黑粉菌(Entyloma oryzae)(叶黑粉病)；小麦上的附球菌属(Epicoccum)(黑穗病)；糖用甜菜(甜菜白粉菌(E.betae))、蔬菜(例如豌豆白粉菌(E.pisi))如葫芦科植物(例如二孢白粉菌(E.cichoracearum))、卷心菜、油菜(例如E.cruciferarum)上的白粉菌属(Erysiphe)(白粉病)；果树、葡萄藤和观赏树上的侧弯孢菌(Eutypa lata)(Eutypa溃疡病或枯萎病，无性型：Cytosporina lata，同义词Libertella blepharis)；玉米(例如玉米大斑病菌(E.turcicum))上的突脐蠕孢属(Exserohilum)(同义词长蠕孢属)；各种植物上的镰孢霉属(Fusarium)(有性型：赤霉属(Gibberella))(枯萎病，根腐病或茎腐病)，例如禾谷类(例如小麦或大麦)上的禾本科镰孢(F.graminearum)或大刀镰孢(F.culmorum)(根腐病、黑星病或银尖病)，西红柿上的尖镰孢(F.oxysporum)，大豆上的茄镰孢(F.solani)(甘氨酸镰刀菌(f.sp.glycines)，现在的同义词为北美大豆猝死综合症病菌(F.virguliforme)及各自引起猝死综合症的南美大豆猝死综合症病菌(F.tucumaniae)和巴西镰刀菌(F.brasiliense)以及玉米上的轮枝镰孢(F.verticillioides)；禾谷类(例如小麦或大麦)和玉米上的禾顶囊壳(Gaeumannomycesgraminis)(全蚀病)；禾谷类(例如玉蜀黍赤霉(G.zeae))和稻(例如藤仓赤霉(G.fujikuroi)：恶苗病)上的赤霉属；葡萄藤、仁果和其他植物上的苹果炭疽病菌(Glomerella cingulata)以及棉花上的棉炭疽病菌(G.gossypii)；稻上的Grainstainingcomplex；葡萄藤上的葡萄黑腐病菌(Guignardia bidwellii)(黑腐病)；蔷薇科植物和刺柏上的锈菌属(Gymnosporangium)，例如梨上的G.sabinae(锈病)；玉米、禾谷类、土豆和稻上的长蠕孢属(同义词内脐蠕孢属，有性型：旋孢腔菌属)；驼孢锈菌属(Hemileia)，例如咖啡上的咖啡驼孢锈菌(H.vastatrix)(咖啡叶锈病)；葡萄藤上的褐斑拟棒束孢(Isariopsisclavispora)(同义词Cladosporium vitis)；大豆和棉花上的菜豆壳球孢(Macrophominaphaseolina(同义词phaseoli))(根腐病/茎腐病)；禾谷类(例如小麦或大麦)上的雪霉叶枯菌(Microdochium(同义词Fusarium)nivale(雪霉病)；大豆上的扩散叉丝壳(Microsphaeradiffusa)(白粉病)；丛梗孢属(Monilinia)，例如核果和其他蔷薇科植物上的核果链核盘菌(M.laxa)、桃褐腐菌(M.fructicola)和M.fructigena(同义词丛梗孢属(Monilia spp.)：花腐病和枝腐病，褐腐病)；禾谷类、香蕉、浆果和花生上的球腔菌属(Mycosphaerella)，例如小麦上的禾生球腔菌(M.graminicola)(无性型：叶枯病菌(Zymoseptoria tritici)，旧名：小麦壳针孢(Septoria tritici)，壳针孢叶斑病)或香蕉上的斐济球腔菌(M.fijiensis)(同义词Pseudocercospora fijiensis：Sigatoka黑斑病)和香蕉黄条叶斑病菌(M.musicola)，花生上的花生球腔菌(M.arachidicola)(同义词花生褐斑病菌(M.arachidis)或Cercospora arachidis)，伯克利球腔菌(M.berkeleyi)，豌豆上的M.pisi和芥属植物上的M.brassiciola；卷心菜(例如芸苔霜霉(P.brassicae))、油菜(例如寄生霜霉(P.parasitica))、洋葱(例如大葱霜霉(P.destructor))、烟草(烟草霜霉(P.tabacina))和大豆(例如大豆霜霉病菌(P.manshurica))上的霜霉属(Peronospora)(霜霉病)；大豆上的豆薯层锈菌(Phakopsora pachyrhizi)和山马蟥层锈菌(P.Meibomiae)(大豆锈病)；例如葡萄藤(例如P.Tracheiphila和P.tetraspora)和大豆(例如大豆茎褐腐病菌(P.gregata)：茎病害)上的瓶霉菌属(Phialophora)；油菜和卷心菜上的黑胫茎点霉(Phoma lingam)(同义词黑胫病菌(Leptosphaeria biglobosa)和斑点小球腔菌(L.maculans)：根腐病和茎腐病)，糖用甜菜上的甜菜茎点霉(P.betae)(根腐病、叶斑病和立枯疡)以及玉米上的P.zeae-maydis(同义词Phyllostica zeae)；向日葵、葡萄藤(例如葡萄黑腐病菌(P.viticola)：蔓割病和叶斑病)和大豆(例如茎腐病：菜豆拟茎点霉(P.phaseoli)，有性型：大豆北茎溃疡病菌(Diaporthe phaseolorum))上的拟茎点霉属(Phomopsis)；玉米上的玉米褐斑病菌(Physoderma maydis)(褐斑病)；各种植物如柿子椒和葫芦科植物(例如辣椒疫霉(P.capsici))、大豆(例如大豆疫霉(P.megasperma)，同义词大豆疫霉菌(P.sojae))、土豆和西红柿(例如致病疫霉(P.infestans)：晚疫病)和阔叶树(例如栎树猝死病菌(P.ramorum)：橡树急死病)上的疫霉属(Phytophthora)(枯萎病，根腐病，叶腐病，果树腐烂病和茎腐病)；卷心菜、油菜、小萝卜和其他植物上的芸苔根肿菌(Plasmodiophorabrassicae)(根肿病)；霜霉属(Plasmopara)，例如葡萄藤上的葡萄生单轴霉(P.viticola)(葡萄藤霜霉病)和向日葵上的霍尔斯单轴霉(P.halstedii)；蔷薇科植物、啤酒花、仁果和浆果(例如苹果上的苹果白粉病菌(P.leucotricha))以及葫芦科植物(甜瓜白粉病(P.xanthii))上的叉丝单囊壳属(Podosphaera)(白粉病)；例如禾谷类如大麦和小麦(禾谷多粘菌(P.graminis))以及糖用甜菜(甜菜多粘菌(P.betae))上的多粘菌属(Polymyxa)以及由此传播的病毒病害；禾谷类如小麦或大麦上的小麦基腐病菌(Pseudocercosporellaherpotrichoides)(同义词Oculimacula yallundae，O.acuformis：眼斑病，有性型：Tapesia yallundae)；各种植物上的假霜霉属(Pseudoperonospora)(霜霉病)，例如葫芦科植物上的古巴假霜霉(P.cubensis)或啤酒花上的葎草假霜(P.humili)；葡萄藤上的Pseudopezicula tracheiphila(葡萄角斑叶焦病菌或‘rotbrenner’，无性型：瓶霉属(Phialophora))；各种植物上的柄锈菌属(Puccinia)(锈病)，例如禾谷类如小麦、大麦或黑麦上的小麦柄锈菌(P.triticina)(褐锈病或叶锈病)，条形柄锈病(P.striiformis)(条纹病或黄锈病)，大麦柄锈病(P.hordei)(大麦黄矮叶锈病)，禾柄锈菌(P.graminis)(茎腐病或黑锈病)或小麦叶锈菌(P.recondita)(褐锈病或叶锈病)，甘蔗上的屈恩柄锈菌(P.kuehnii)(橙锈病)和芦笋上的天门冬属柄锈病(P.asparagi)；油菜上的核盘菌属(Pyrenopeziza spp.)，例如P.brassicae；小麦上的小麦黄斑叶枯病菌(Pyrenophora(无性型：Drechslera)tritici-repentis)(黄斑病)或大麦上的大麦网斑内脐蠕孢(P.teres)(网斑病)；梨孢属(Pyricularia)，例如稻上的稻瘟病菌(P.oryzae)(有性型：Magnaporthegrisea，稻瘟病)以及草坪和禾谷类上的稻梨孢菌(P.grisea)；草坪、稻、玉米、小麦、棉花、油菜、向日葵、大豆、糖用甜菜、蔬菜和各种其他植物(例如终极腐霉菌(P.ultimum)或瓜果腐霉(P.aphanidermatum))和蘑菇(寡雄腐霉(P.oligandrum))上的腐霉属(Pythium)(立枯病)；柱隔孢属(Ramularia)，例如大麦上的R.collo-cygni(柱隔孢叶斑病，生理叶斑病)和糖用甜菜上的甜菜叶斑病菌(R.Beticola)；棉花、稻、土豆、草坪、玉米、油菜、土豆、糖用甜菜、蔬菜和各种其他植物上的丝核菌属(Rhizoctonia)，例如大豆上的立枯丝核菌(R.solani)(根腐病/茎腐病)，稻上的R.solani(纹枯病)或小麦或大麦上的禾谷丝核菌(R.cerealis)(小麦纹枯病)；草莓、胡萝卜、卷心菜、葡萄藤和西红柿上的葡枝根霉(Rhizopus stolonifer)(黑霉病，软腐病)；大麦、黑麦和小黑麦上的黑麦喙孢(Rhynchosporium secalis)和R.commune(叶斑病)；稻上的稻帚枝霉(Sarocladiumoryzae)和S.attenuatum(叶鞘腐败病)；蔬菜(小核盘菌(S.minor)和核盘菌(S.sclerotiorum))和大田作物如油菜、向日葵(例如核盘菌(S.sclerotiorum))以及大豆、花生、蔬菜、玉米、禾谷类和观赏植物(白绢病(S.rolfsii)(同义词罗耳阿太菌(Atheliarolfsii))上的核盘菌属(Sclerotinia)(茎腐病或白绢病)；各种植物上的壳针孢属(Septoria)，例如大豆上的大豆壳针孢(S.glycines)(褐斑病)，小麦上的小麦壳针孢(S.tritici)(同义词叶枯病菌(Zymoseptoria tritici)，壳针孢叶斑病)和禾谷类上的颖枯壳多孢(S.(同义词Stagonospora)nodorum)(斑枯病)；葡萄藤上的葡萄钩丝壳(Uncinula(同义词Erysiphe)necator)(白粉病，无性型：葡萄粉孢(Oidium tuckeri))；玉米(例如玉米大斑病菌(S.turcicum)，同义词大斑凸脐蠕孢(Helminthosporium turcicum))和草坪上的大斑病菌属(Setosphaeria)(叶枯病)；玉米(例如丝轴黑粉菌(S.reiliana)，同义词Ustilago reiliana：丝黑穗病)、小米和甘蔗上的轴黑粉菌属(Sphacelotheca)(黑穗病)；葫芦科植物上的单丝壳白粉菌(Sphaerotheca fuliginea)(同义词甜瓜白粉病(Podosphaera xanthii)：白粉病)；土豆上的粉痂菌(Spongospora subterranea)(粉痂病)以及由此传播的病毒病害；禾谷类上的壳多孢属(Stagonospora)，例如小麦上的颖枯壳多孢(S.nodorum)(斑枯病，有性型：颖枯球腔菌(Leptosphaeria[同义词Phaeosphaeria]nodorum)，同义词颖枯壳多孢(Septoria nodorum))；土豆上的马铃薯癌肿病菌(Synchytrium endobioticum)(土豆癌肿病)；外囊菌属(Taphrina)，例如桃上的畸形外囊菌(T.deformans)(缩叶病)和李上的李外囊菌(T.pruni)(囊果李)；烟草、仁果、蔬菜、大豆和棉花上的根串珠霉属(Thielaviopsis)(黑色根腐病)，例如黑色根腐病菌(T.basicola)(同义词根黑腐病(Chalara elegans))；禾谷类上的腥黑粉菌属(Tilletia)(腥黑穗病或光腥黑穗病)，例如小麦上的小麦腥黑粉菌(T.tritici)(同义词小麦网腥黑粉菌(T.caries)，小麦腥黑穗病)和小麦矮腥黑穗病(T.controversa)(矮腥黑穗病)；蘑菇上的哈茨木霉菌(Trichoderma harzianum)；大麦或小麦上的肉孢核瑚菌(Typhula incarnata)(灰雪腐病)；黑粉菌属(Urocystis)，例如黑麦上的隐条黑粉菌(U.occulta)(条黑粉病)；蔬菜如菜豆(例如疣顶单胞锈菌(U.appendiculatus)，同义词U.phaseoli)、糖用甜菜(例如甜菜锈病菌(U.betae)或U.beticola))和豆类(例如豇豆锈菌(U.vignae)、豌豆锈菌(U.pisi)、U.viciae-fabae和蚕豆锈菌(U.fabae))上的单孢锈属(Uromyces)(锈病)；禾谷类(例如大麦散黑粉菌(U.nuda)和燕麦散黑粉菌(U.avaenae))、玉米(例如玉蜀黍黑粉菌(U.maydis)：玉米黑穗病)和甘蔗上的黑粉菌属(Ustilago)(黑穗病)；苹果(例如苹果黑星病(V.inaequalis))和梨上的黑星菌属(Venturia)(黑星病)；以及各种植物如果树和观赏树、葡萄藤、浆果、蔬菜和大田作物上的轮生菌属(Verticillium)(枯萎病)，例如油菜上的油菜黄萎菌(V.longisporum)，草莓、油菜、土豆和西红柿上的茄黄萎病菌(V.dahliae)及蘑菇上的蘑菇褐腐病(V.fungicola)；禾谷类上的叶枯病菌(Zymoseptoria tritici)。
本发明混合物可以转化成农业化学组合物常用的类型，例如溶液、乳液、悬浮液、粉剂、粉末、糊、颗粒、模压品、胶囊及其混合物。这些和其他组合物类型在“Catalogue ofpesticide formulation types and international coding system”，TechnicalMonograph，第2期，2008年5月第6版，CropLife International中有定义。
组合物如Mollet和Grubemann，Formulation technology，Wiley VCH，Weinheim，2001；或Knowles，New developments in crop protection product formulation，AgrowReports DS243，T&F Informa，London，2005所述以已知方式制备。
本发明混合物通过用农药有效量的活性化合物处理昆虫、真菌或者要保护以防昆虫或真菌侵袭的植物、植物繁殖材料如种子、土壤、表面、材料或场所而直接或者以组合物形式使用。施用均可在植物、植物繁殖材料如种子、土壤、表面、材料或场所被昆虫感染之前和之后进行。
本发明还包括一种防除动物害虫和有害真菌的方法，包括使真菌和/或动物害虫，其栖息地、繁殖地、食物供应源，其中动物害虫生长或可能生长的栽培植物、种子、土壤、区域、材料或环境或者要保护以防动物侵袭或侵染的材料、植物、种子、土壤、表面或空间与农药有效量的本发明混合物接触。
嗪虫唑酰胺和该一种或多种化合物B通常以1000:1-1:1000，优选100:1-1:100或20:1-1:20，尤其是10:1-1:10的重量比施用。
“农药有效量”通常是指对生长获得可观察到的效果所需的本发明混合物或包含该混合物的组合物的量，所述效果包括坏死、死亡、阻滞、预防和去除效果，破坏效果或减少目标生物体的出现和活动的效果。对于在本发明中使用的各种混合物和/或组合物，农药有效量可以变化。混合物和/或组合物的农药有效量也会根据主要条件如所需农药效果及持续时间、气候、目标物种、场所、施用方式等而变化。
实施例
现在通过下列实施例更详细说明本发明。
协同效应可以描述为其中两种或更多种化合物的组合效果大于各化合物的单独效果之和的相互作用。两种混合配对(X和Y)之间就防治百分数或效果而言协同效应的存在可以使用Colby等式(Colby，S.R.，1967，计算除草剂组合的协同增效和拮抗响应，Weeds，15，20-22)计算：
将测量的参数与不含活性化合物的对照方案的生长(100％)以及不含真菌的空白值相比较，以确定病原体在各活性化合物中的相对生长百分数。将这些百分数转化为效力。
效力为0表示病原体的生长水平与未处理对照的相当；效力为100表示病原体没有生长。
活性化合物混合物的预期效力使用Colby等式[R.S.Colby，“计算除草剂组合的协同增效和拮抗响应”，Weeds 15，20-22(1967)]确定并与观察到的效力相比较。
下列测试可以证实本发明混合物或组合物对特定真菌的防治效力。然而，化合物、混合物或组合物所提供的害虫防治保护并不限于这些品种。在一些情况下，发现本发明化合物与其他无脊椎动物害虫防治化合物或试剂的组合对某些重要的无脊椎动物害虫和/或有害真菌显示出协同效应。
将活性化合物分开在二甲亚砜中配制成浓度为10000ppm的储备溶液。
产品氟噻唑吡乙酮以市售成品配制剂使用并且用水稀释至所述活性化合物浓度。
1.在微滴定试验中对晚疫病病原体致病疫霉的活性
将储备溶液根据比例混合，用移液管移到微滴定板(MTP)中并用水稀释至所述浓度。然后加入含有豌豆汁基含水营养培养基或DDC培养基的致病疫霉孢子悬浮液。将各板置于温度为18℃的水蒸气饱和室中。接种7天后使用吸收光度计在405nm下测量MTP。
2.在微滴定板试验中对灰霉病灰葡萄孢的活性
将储备溶液根据比例混合，用移液管移到微滴定板(MTP)中并用水稀释至所述浓度。然后加入灰葡萄孢在生物麦芽或酵母-细菌蛋白胨-乙酸钠水溶液中的孢子悬浮液。将各板置于温度为18℃的水蒸气饱和室中。接种7天后使用吸收光度计在405nm下测量MTP。
3.在小麦上对由小麦壳针孢引起的叶斑病的活性
将储备溶液根据比例混合，用移液管移到微滴定板(MTP)中并用水稀释至所述浓度。然后加入小麦壳针孢在生物麦芽或酵母-细菌蛋白胨-甘油或DOB水溶液中的孢子悬浮液。将各板置于温度为18℃的水蒸气饱和室中。接种7天后使用吸收光度计在405nm下测量MTP。
4.在微滴定试验中对大豆灰斑病菌的活性
将储备溶液根据比例混合，用移液管移到微滴定板(MTP)中并用水稀释至所述浓度。然后加入大豆灰斑病菌在生物麦芽或酵母-细菌蛋白胨-乙酸钠水溶液中的孢子悬浮液。将各板置于温度为18℃的水蒸气饱和室中。
接种7天后使用吸收光度计在405nm下测量MTP。
5.在微滴定板试验中对南瓜炭疽病(Colletotrichum orbiculare)的活性
将储备溶液根据比例混合，用移液管移到微滴定板(MTP)中并用水稀释至所述浓度。然后加入南瓜炭疽病在生物麦芽或酵母-细菌蛋白胨-乙酸钠水溶液中的孢子悬浮液。将各板置于温度为18℃的水蒸气饱和室中。接种7天后使用吸收光度计在405nm下测量MTP。
6.在微滴定板试验中对黑麦喙孢的活性
将储备溶液根据比例混合，用移液管移到微滴定板(MTP)中并用水稀释至所述浓度。然后加入黑麦喙孢在生物麦芽或酵母-细菌蛋白胨-甘油或DOB水溶液中的孢子悬浮液。将各板置于温度为18℃的水蒸气饱和室中。
接种7天后使用吸收光度计在405nm下测量MTP。
7.在微滴定板试验中对核盘菌的活性
将储备溶液根据比例混合，用移液管移到微滴定板(MTP)中并用水稀释至所述浓度。然后加入核盘菌在生物麦芽或酵母-细菌蛋白胨-甘油或DOB水溶液中的孢子悬浮液。将各板置于温度为18℃的水蒸气饱和室中。
接种7天后使用吸收光度计在405nm下测量MTP。
/>
Claims (6)
1.包含如下化合物作为活性组分的农药混合物：
1)式I的1-(1,2-二甲基丙基)-N-乙基-5-甲基-N-哒嗪-4-基吡唑-4-甲酰胺：
和
2)至少一种其他化合物B，选自：
B.3)Qi位点的配合物III抑制剂，为florylpicoxamid；
B.5)甾醇生物合成中的C14脱甲基酶抑制剂(DMI杀真菌剂)，为4-[[6-[2-(2,4-二氟苯基)-1,1-二氟-2-羟基-3-(5-硫基-1,2,4-三唑-1-基)丙基]-3-吡啶基]氧基]苄腈；
其中组分1)和组分2)以10:1-1:10的重量比存在。
2.权利要求1的混合物，包含一种化合物B。
3.权利要求1或2的混合物，其中组分2)为化合物B.3。
4.权利要求1或2的混合物，其中组分2)为化合物B.5。
5.一种防治植物病原性有害真菌的方法，所述方法包括使真菌、其栖息地或者要保护以防真菌侵袭的植物、土壤或种子与有效量的根据权利要求1-4中任一项的农药混合物接触、用其处理。
6.一种保护生长植物或植物繁殖材料以防无脊椎动物害虫侵袭或侵染的方法，所述方法包括使植物、植物繁殖材料或者其中植物生长的土壤或水体与农药有效量的根据权利要求1-4中任一项的农药混合物接触。
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| AR118143A1 (es) | 2021-09-22 |
| MX2021010111A (es) | 2021-09-21 |
| US20220125050A1 (en) | 2022-04-28 |
| BR112021015521A2 (pt) | 2021-10-05 |
| WO2020169414A8 (en) | 2021-09-10 |
| CN113453555B (zh) | 2023-08-08 |
| KR20210131350A (ko) | 2021-11-02 |
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