CN117064784A - Anhydrous cosmetic containing beta-folded fibroin and preparation method thereof - Google Patents
Anhydrous cosmetic containing beta-folded fibroin and preparation method thereof Download PDFInfo
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- CN117064784A CN117064784A CN202311109677.4A CN202311109677A CN117064784A CN 117064784 A CN117064784 A CN 117064784A CN 202311109677 A CN202311109677 A CN 202311109677A CN 117064784 A CN117064784 A CN 117064784A
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- beta
- fibroin
- sheet
- raw materials
- mixed solution
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- 108010022355 Fibroins Proteins 0.000 title claims abstract description 43
- 239000002537 cosmetic Substances 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 38
- 239000000843 powder Substances 0.000 claims abstract description 36
- 239000004519 grease Substances 0.000 claims abstract description 10
- 238000007605 air drying Methods 0.000 claims abstract description 6
- 239000007864 aqueous solution Substances 0.000 claims abstract description 6
- 238000001035 drying Methods 0.000 claims abstract description 6
- 238000004108 freeze drying Methods 0.000 claims abstract description 6
- 229920005573 silicon-containing polymer Polymers 0.000 claims abstract description 5
- 239000011259 mixed solution Substances 0.000 claims description 32
- 239000003921 oil Substances 0.000 claims description 16
- 239000001993 wax Substances 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 6
- 239000003995 emulsifying agent Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 241001465754 Metazoa Species 0.000 claims description 4
- 239000004480 active ingredient Substances 0.000 claims description 4
- 239000012164 animal wax Substances 0.000 claims description 4
- 238000004040 coloring Methods 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- 239000012184 mineral wax Substances 0.000 claims description 4
- 239000002674 ointment Substances 0.000 claims description 4
- 239000003755 preservative agent Substances 0.000 claims description 4
- 229920002545 silicone oil Polymers 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000012178 vegetable wax Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 210000004709 eyebrow Anatomy 0.000 claims description 3
- 239000000686 essence Substances 0.000 claims description 2
- 239000010408 film Substances 0.000 claims description 2
- 230000000052 comparative effect Effects 0.000 description 13
- 238000005303 weighing Methods 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 108090000623 proteins and genes Proteins 0.000 description 5
- 102000004169 proteins and genes Human genes 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000010445 mica Substances 0.000 description 3
- 229910052618 mica group Inorganic materials 0.000 description 3
- -1 polydimethylsiloxane Polymers 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000010306 acid treatment Methods 0.000 description 2
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000011863 silicon-based powder Substances 0.000 description 2
- 235000010215 titanium dioxide Nutrition 0.000 description 2
- 229960001295 tocopherol Drugs 0.000 description 2
- 229930003799 tocopherol Natural products 0.000 description 2
- 235000010384 tocopherol Nutrition 0.000 description 2
- 239000011732 tocopherol Substances 0.000 description 2
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 2
- VDBJCDWTNCKRTF-UHFFFAOYSA-N 6'-hydroxyspiro[2-benzofuran-3,9'-9ah-xanthene]-1,3'-dione Chemical compound O1C(=O)C2=CC=CC=C2C21C1C=CC(=O)C=C1OC1=CC(O)=CC=C21 VDBJCDWTNCKRTF-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004287 Dehydroacetic acid Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- FKIQSOGFDBALHA-UHFFFAOYSA-L aluminum trimagnesium potassium dioxido(oxo)silane oxygen(2-) difluoride Chemical compound [O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[K+].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O FKIQSOGFDBALHA-UHFFFAOYSA-L 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 229940092738 beeswax Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000012745 brilliant blue FCF Nutrition 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000012730 carminic acid Nutrition 0.000 description 1
- 239000004106 carminic acid Substances 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 229940082483 carnauba wax Drugs 0.000 description 1
- 239000012185 ceresin wax Substances 0.000 description 1
- OIQPTROHQCGFEF-UHFFFAOYSA-L chembl1371409 Chemical compound [Na+].[Na+].OC1=CC=C2C=C(S([O-])(=O)=O)C=CC2=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 OIQPTROHQCGFEF-UHFFFAOYSA-L 0.000 description 1
- PZTQVMXMKVTIRC-UHFFFAOYSA-L chembl2028348 Chemical compound [Ca+2].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 PZTQVMXMKVTIRC-UHFFFAOYSA-L 0.000 description 1
- 229940080423 cochineal Drugs 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229940061632 dehydroacetic acid Drugs 0.000 description 1
- JEQRBTDTEKWZBW-UHFFFAOYSA-N dehydroacetic acid Chemical group CC(=O)C1=C(O)OC(C)=CC1=O JEQRBTDTEKWZBW-UHFFFAOYSA-N 0.000 description 1
- PGRHXDWITVMQBC-UHFFFAOYSA-N dehydroacetic acid Natural products CC(=O)C1C(=O)OC(C)=CC1=O PGRHXDWITVMQBC-UHFFFAOYSA-N 0.000 description 1
- 235000019258 dehydroacetic acid Nutrition 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- VPWFPZBFBFHIIL-UHFFFAOYSA-L disodium 4-[(4-methyl-2-sulfophenyl)diazenyl]-3-oxidonaphthalene-2-carboxylate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 VPWFPZBFBFHIIL-UHFFFAOYSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- WNIFXKPDILJURQ-JKPOUOEOSA-N octadecyl (2s,4as,6ar,6as,6br,8ar,10s,12as,14br)-10-hydroxy-2,4a,6a,6b,9,9,12a-heptamethyl-13-oxo-3,4,5,6,6a,7,8,8a,10,11,12,14b-dodecahydro-1h-picene-2-carboxylate Chemical compound C1C[C@H](O)C(C)(C)[C@@H]2CC[C@@]3(C)[C@]4(C)CC[C@@]5(C)CC[C@@](C(=O)OCCCCCCCCCCCCCCCCCC)(C)C[C@H]5C4=CC(=O)[C@@H]3[C@]21C WNIFXKPDILJURQ-JKPOUOEOSA-N 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000004482 other powder Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229960003351 prussian blue Drugs 0.000 description 1
- 239000013225 prussian blue Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- WNIFXKPDILJURQ-UHFFFAOYSA-N stearyl glycyrrhizinate Natural products C1CC(O)C(C)(C)C2CCC3(C)C4(C)CCC5(C)CCC(C(=O)OCCCCCCCCCCCCCCCCCC)(C)CC5C4=CC(=O)C3C21C WNIFXKPDILJURQ-UHFFFAOYSA-N 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/08—Preparations containing skin colorants, e.g. pigments for cheeks, e.g. rouge
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/12—Face or body powders for grooming, adorning or absorbing
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/31—Anhydrous
Abstract
The invention relates to the technical field of cosmetics, in particular to an anhydrous cosmetic containing beta-folded fibroin and a preparation method thereof, and the technical scheme is characterized by comprising the following components in percentage by mass: 0.0001-1% of beta-folded fibroin, 0.1-40% of functional powder, 0.3-30% of auxiliary raw materials and the balance of basic raw materials; the beta-sheet fibroin is prepared by drying, air-drying or freeze-drying a beta-sheet fibroin aqueous solution, and the basic raw materials comprise at least one of grease raw materials and silicon-containing polymers. The invention has the advantages of reducing oily feel, improving user experience, reducing powder sticking, and improving skin adhesion and wider applicability.
Description
Technical Field
The invention relates to the technical field of cosmetics, in particular to an anhydrous cosmetic containing beta-folded fibroin and a preparation method thereof.
Background
The cosmetic is used for regulating human body for beautifying, retaining or changing human appearance, and can achieve the effects of beautifying face, protecting skin and correcting defects. With the improvement of the living standard of people, more and more people are enthusiastically making up, and the self-confidence and the personal image are further improved by beautifying the appearance through the cosmetics.
The cosmetics in the market can be classified into aqueous cosmetics and anhydrous cosmetics according to the water content of the formula, and the conventional anhydrous cosmetics are prepared by taking grease as a base and adding functional powder to modify the face and lips. The anhydrous cosmetic has higher durability and is not easy to wipe off, but the skin feel is easy to be greasy, the state of the cosmetic on the skin is influenced, and the use experience of a user is also influenced.
Disclosure of Invention
Aiming at the defects existing in the prior art, the invention aims to provide an anhydrous cosmetic containing beta-folded fibroin and a preparation method thereof, and the anhydrous cosmetic has the advantages of reducing oily feel and improving use experience of users.
The technical aim of the invention is realized by the following technical scheme: an anhydrous cosmetic containing beta-sheet fibroin is characterized by comprising the following components in percentage by mass:
0.0001-1% of beta-folded fibroin, 0.1-40% of functional powder, 0.3-30% of auxiliary raw materials and the balance of basic raw materials;
the beta-sheet fibroin is prepared by drying, air-drying or freeze-drying a beta-sheet fibroin aqueous solution, and the basic raw materials comprise at least one of grease raw materials and silicon-containing polymers.
In one embodiment, the functional powder includes one or more of a coloring powder, a physical powder, and a pearlescent powder.
In one embodiment, the lipid feedstock comprises at least one of a lipid and a wax.
In one embodiment, the grease comprises one or more of hydrocarbon oil, silicone oil, and fluorinated oil.
In one embodiment, the waxes include one or more of animal and vegetable waxes, mineral waxes, and synthetic waxes.
In one embodiment, the auxiliary raw material comprises at least one of an oil-soluble active ingredient, an emulsifier, a film forming agent, a fragrance, and a preservative.
In one embodiment, the beta-sheet fibroin is 0.0001-0.05% by mass.
In one embodiment, the anhydrous cosmetic is a lipstick, lip glaze, gao Guangbang, eye shadow stick, foundation stick, blush stick, eyebrow pencil, eyeliner, or ointment.
The preparation method of the anhydrous cosmetic containing the beta-folded fibroin comprises the following steps:
s1, obtaining a basic raw material, heating to completely dissolve the basic raw material, and uniformly stirring to obtain a first mixed solution;
s2, obtaining functional powder, adding the functional powder into the first mixed solution, and uniformly mixing to obtain a second mixed solution;
and S3, adding the beta-folded fibroin and the auxiliary raw materials into the second mixed solution, uniformly mixing to obtain a third mixed solution, and cooling to obtain a target product.
In one embodiment, in S3, the third mixed solution is poured into a mold to be cooled.
The anhydrous cosmetic containing the beta-folded fibroin and the preparation method thereof have the following beneficial effects:
firstly, the beta-folded silk protein is prepared by drying, air-drying or freeze-drying the beta-folded silk protein aqueous solution, so that functional powder can be uniformly attached to skin, the oily feel of anhydrous cosmetics is reduced, and the experience of a user is improved;
secondly, the beta-folded fibroin can adjust the wax crystallization process, so that the smoothness and skin adhesion of the product are further improved, and the invention is suitable for preparing anhydrous cosmetics such as lipstick, lip glaze, gao Guangbang, eye shadow stick, foundation stick or ointment, and the like, and has wider applicability.
Drawings
Fig. 1 is a flow chart of the steps of the present invention.
Detailed Description
The present invention will be described in further detail with reference to the following examples, which are intended to facilitate the understanding of the present invention without any limitation thereto. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In case of conflict, the present specification, definitions, will control.
The term "prepared from …" as used herein is synonymous with "comprising". The terms "comprising," "including," "having," "containing," or any other variation thereof, as used herein, are intended to cover a non-exclusive inclusion. For example, a composition, step, method, article, or apparatus that comprises a list of elements is not necessarily limited to only those elements but may include other elements not expressly listed or inherent to such composition, step, method, article, or apparatus.
The conjunction "consisting of …" excludes any unspecified element, step or component. If used in a claim, such phrase will cause the claim to be closed, such that it does not include materials other than those described, except for conventional impurities associated therewith. When the phrase "consisting of …" appears in a clause of the claim body, rather than immediately following the subject, it is limited to only the elements described in that clause; other elements are not excluded from the stated claims as a whole.
When an equivalent, concentration, or other value or parameter is expressed as a range, preferred range, or a range bounded by a list of upper preferable values and lower preferable values, this is to be understood as specifically disclosing all ranges formed from any pair of any upper range limit or preferred value and any lower range limit or preferred value, regardless of whether ranges are separately disclosed. For example, when ranges of "1 to 5" are disclosed, the described ranges should be construed to include ranges of "1 to 4", "1 to 3", "1 to 2 and 4 to 5", "1 to 3 and 5", and the like. When a numerical range is described herein, unless otherwise indicated, the range is intended to include its endpoints and all integers and fractions within the range.
The present invention will be described in detail below with reference to the accompanying drawings and examples.
An anhydrous cosmetic containing beta-folded fibroin comprises the following components in percentage by mass:
0.0001-1% of beta-folded fibroin, 0.1-40% of functional powder, 0.3-30% of auxiliary raw materials and the balance of basic raw materials;
the beta-sheet fibroin is prepared by drying, air-drying or freeze-drying a beta-sheet fibroin aqueous solution, and the basic raw materials comprise at least one of grease raw materials and silicon-containing polymers.
According to the invention, the beta-folded silk protein is prepared by drying, air-drying or freeze-drying the beta-folded silk protein aqueous solution, and the beta-folded silk protein and the basic raw materials are compounded to form the skin-adhering film, so that the functional powder is uniformly and firmly adhered to the skin, the oily feel of anhydrous cosmetics is reduced, and the experience of a user is improved. In actual production, the beta-sheet content of the beta-sheet fibroin is more than or equal to 30 percent.
In actual production, the silicon-containing polymer includes one or more of a silicone elastomer, and a silica gel. The silicon shell may be a polydimethylsiloxane cross-linked polymer, and the like.
Specifically, the functional powder includes one or more of coloring powder, physical powder and pearl powder.
In practical applications, the coloring powder is used for color mixing, including titanium white, iron oxide red, iron oxide yellow, iron oxide black, ultramarine blue, prussian blue and other mineral pigments, and the organic pigments such as red 7, red 6, red 33, yellow 6, yellow 7, blue 1, carbon black and the like, and natural extracts or biological compositions such as cochineal and the like; the constitution powder is used for adjusting the spreadability and skin adhesion of the product, providing specific skin feel, make-up feel and function, generally refers to powder with the refractive index smaller than 2.0, mainly comprises titanium dioxide, silicon powder, organic silicon powder, zinc oxide, talcum powder, mica, kaolin or nylon powder, and can also use other powder raw materials subjected to organic or inorganic treatment; the pearl powder is used for increasing gloss and texture, and mainly comprises mica, synthetic fluorophlogopite, mica titanium or fish scale. The functional powder may be subjected to surface treatment such as silicon treatment, amino acid treatment, stearic acid treatment, and multiple treatments.
Specifically, the oil-based material includes at least one of oil and wax.
Further, the grease includes one or more of hydrocarbon oil, silicone oil, and fluorinated oil. Hydrocarbon oil refers to an oil containing primarily hydrogen and carbon atoms; silicone oil refers to oils containing at least one silicon atom, in particular at least one Si-O group; fluorinated oil refers to an oil containing at least one fluorine atom.
Further, the waxes include one or more of animal and vegetable waxes, mineral waxes, and synthetic waxes. In actual production, the animal and vegetable wax may be beeswax, lanolin, carnauba wax, candelilla wax, jojoba wax, etc., and the mineral wax may be paraffin wax, microcrystalline paraffin wax, ceresin wax, etc. The beta-folded fibroin can adjust the wax crystallization process so as to form finer and more stable crystals, and further improve the smoothness and skin adhesion of the product.
Specifically, the auxiliary raw materials comprise at least one of oil-soluble active ingredients, emulsifying agents, film forming agents, essence and preservatives.
In practical application, the functional powder can be uniformly dispersed in different oils and fats by adding the emulsifying agent, and skin feel can be adjusted, preferably lipophilic nonionic emulsifying agent such as cetyl PEG/PPG-10/1 polydimethylsiloxane and the like.
In addition, common oil-soluble active ingredients are tocopherol, tocopherol palmitate and stearyl glycyrrhetinate; the preservative is dehydroacetic acid; typical film formers are acrylic/poly (trimethicone) methacrylate copolymers and bis-diglycerol polyacyl adipate-2, etc. In addition to the above-listed components, other auxiliary materials may be used to provide the above-mentioned properties.
Specifically, the mass percentage of the beta-sheet fibroin is 0.0001-0.05%.
Specifically, the anhydrous cosmetic is lipstick, lip glaze, gao Guangbang, eye shadow stick, foundation stick, blush stick, eyebrow pencil, eyeliner or ointment, which has wide applicability.
Referring to fig. 1, a method for preparing anhydrous cosmetics containing beta-sheet fibroin comprises the following steps:
s1, obtaining a basic raw material, heating to completely dissolve the basic raw material, and uniformly stirring to obtain a first mixed solution;
in actual production, for convenience of process, the base raw material can be added in several times, and the base raw material which needs to be heated and melted and the base raw material which does not need to be heated and melted are usually added separately;
the basic raw materials which need to be heated and melted are mostly sticky grease or solid wax at normal temperature, and the raw materials need to be heated and dissolved at 70-80 ℃ and are uniformly stirred;
the method has the advantages that the heating-free basic raw materials can be weighed and mixed uniformly to obtain the first mixed solution, the weighing standard of the part can meet the grinding and dispersing requirements of the functional powder in S2, the second mixed solution in S2 cannot be too thick and heavy to disperse, and the second mixed solution does not need to be too thin in consistency;
if the content of liquid grease in the basic raw material is very high, the rest part which is not added can be added after the functional powder is dispersed.
S2, obtaining functional powder, adding the functional powder into the first mixed solution, and uniformly mixing to obtain a second mixed solution;
in actual operation, various functional powders can be ground and pretreated by a three-roller grinder and then added into the mixed liquid to be uniformly stirred, and in addition, the toner can be prepared into color paste by pretreatment so as to be convenient to use.
S3, adding the beta-folded fibroin and the auxiliary raw materials into the second mixed solution, uniformly mixing to obtain a third mixed solution, and cooling to obtain a target product.
In step S3, the third mixed solution is poured into a mold to be cooled. The part of anhydrous cosmetics needs a specific shape, and the third mixed liquid needs to be in a solution state and is transferred into a mould to be cooled when the temperature is higher so as to form the specific shape.
Example 1 and comparative example 1
Example 1 and comparative example 1 each provide a lip glaze comprising the components in the mass percentages indicated in the following table, example 1 being added with beta-sheet fibroin (silk extract) as compared to comparative example 1.
The preparation method of example 1 and comparative example 1 comprises the following steps:
s1, weighing the phase B according to a proportion, heating to 70-75 ℃ to uniformly melt, and uniformly stirring to obtain a first mixed solution;
s2, weighing the phase A according to a proportion, uniformly grinding the phase A by using a three-roller grinder, adding the phase A into the first mixed solution, and uniformly mixing the mixed solution to obtain a second mixed solution;
s3, cooling the second mixed solution at 30 ℃ to obtain a target product.
Example 2 and comparative example 2
Example 2 provides lipsticks with comparative example 2, respectively, comprising the components in the mass percentages indicated in the following table, example 2 being added with beta-sheet fibroin (silk extract) in comparison with comparative example 2.
The preparation method of example 2 and comparative example 2 comprises the following steps:
s1, weighing the phase A according to a proportion, heating to dissolve the phase A at 70-80 ℃, and uniformly mixing to obtain a first mixed solution;
s2, weighing the phase B according to a proportion, adding the phase B into the first mixed solution, and uniformly mixing to obtain a second mixed solution;
s3, weighing the phase C according to the proportion, adding the phase C into the second mixed solution, uniformly mixing to obtain a third mixed solution, transferring the third mixed solution into a lipstick die, and rapidly cooling to obtain a target product.
Test comparison:
example 1 and comparative example 1 are both oil-dispersed lip gloss formulations. The products of example 1 and comparative example 1 were applied to the lips in equal amounts and compared, the product of example 1 was more silky and more uniformly applied during application, applied to the lips, and had a significantly reduced oily feel.
Example 2 and comparative example 2 are lipsticks of the oil wax crystallization system. The products of example 2 and comparative example 2 were applied to the lips in equal amounts for comparison, the product of example 2 was smoother and more evenly applied during application, and the wax and sticky feel of example 2 was lower than that of comparative example 2.
The foregoing examples illustrate only a few embodiments of the invention and are described in detail herein without thereby limiting the scope of the invention. It should be noted that it will be apparent to those skilled in the art that several variations and modifications can be made without departing from the spirit of the invention, which are all within the scope of the invention. Accordingly, the scope of protection of the present invention is to be determined by the appended claims.
Claims (10)
1. An anhydrous cosmetic containing beta-sheet fibroin is characterized by comprising the following components in percentage by mass:
0.0001-1% of beta-folded fibroin, 0.1-40% of functional powder, 0.3-30% of auxiliary raw materials and the balance of basic raw materials;
the beta-sheet fibroin is prepared by drying, air-drying or freeze-drying a beta-sheet fibroin aqueous solution, and the basic raw materials comprise at least one of grease raw materials and silicon-containing polymers.
2. An anhydrous cosmetic product comprising beta-sheet fibroin according to claim 1, characterized in that: the functional powder comprises one or more of coloring powder, constitution powder and pearl powder.
3. An anhydrous cosmetic product comprising beta-sheet fibroin according to claim 1, characterized in that: the oil raw material comprises at least one of oil and wax.
4. A non-aqueous cosmetic product containing β -sheet fibroin according to claim 3, characterized in that: the grease includes one or more of hydrocarbon oil, silicone oil, and fluorinated oil.
5. A non-aqueous cosmetic product containing β -sheet fibroin according to claim 3, characterized in that: the waxes include one or more of animal and vegetable waxes, mineral waxes, and synthetic waxes.
6. An anhydrous cosmetic product comprising beta-sheet fibroin according to claim 1, characterized in that: the auxiliary raw materials comprise at least one of oil-soluble active ingredients, emulsifying agents, film forming agents, essence and preservatives.
7. An anhydrous cosmetic product comprising beta-sheet fibroin according to claim 1, characterized in that: the mass percentage of the beta-folded fibroin is 0.0001-0.05%.
8. An anhydrous cosmetic product comprising beta-sheet fibroin according to any one of claims 1-7, characterized in that: the anhydrous cosmetic is lipstick, lip glaze, gao Guangbang, eye shadow stick, foundation stick, blush stick, eyebrow pencil, eyeliner or ointment.
9. The method for preparing anhydrous cosmetics containing beta-sheet fibroin according to claim 8, comprising the steps of:
s1, obtaining a basic raw material, heating to completely dissolve the basic raw material, and uniformly stirring to obtain a first mixed solution;
s2, obtaining functional powder, adding the functional powder into the first mixed solution, and uniformly mixing to obtain a second mixed solution;
and S3, adding the beta-folded fibroin and the auxiliary raw materials into the second mixed solution, uniformly mixing to obtain a third mixed solution, and cooling to obtain a target product.
10. The method for preparing anhydrous cosmetics containing beta-sheet fibroin according to claim 9, wherein: and in the step S3, pouring the third mixed solution into a mould for cooling.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN117357425A (en) * | 2023-11-27 | 2024-01-09 | 美尚(广州)化妆品股份有限公司 | Fragrance composition with long-lasting fragrance, preparation method thereof and application thereof in cosmetics |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN117357425A (en) * | 2023-11-27 | 2024-01-09 | 美尚(广州)化妆品股份有限公司 | Fragrance composition with long-lasting fragrance, preparation method thereof and application thereof in cosmetics |
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