JPH0574562B2 - - Google Patents
Info
- Publication number
- JPH0574562B2 JPH0574562B2 JP59139416A JP13941684A JPH0574562B2 JP H0574562 B2 JPH0574562 B2 JP H0574562B2 JP 59139416 A JP59139416 A JP 59139416A JP 13941684 A JP13941684 A JP 13941684A JP H0574562 B2 JPH0574562 B2 JP H0574562B2
- Authority
- JP
- Japan
- Prior art keywords
- aqueous
- mixture
- makeup
- silicone
- viscosity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 claims description 30
- 239000002537 cosmetic Substances 0.000 claims description 19
- 229920002050 silicone resin Polymers 0.000 claims description 13
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 10
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 10
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 10
- 239000000049 pigment Substances 0.000 claims description 9
- 239000000341 volatile oil Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 238000012360 testing method Methods 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 238000009835 boiling Methods 0.000 description 12
- 239000003921 oil Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 8
- 229920001296 polysiloxane Polymers 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 238000005299 abrasion Methods 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 230000008859 change Effects 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229920002545 silicone oil Polymers 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000001993 wax Substances 0.000 description 5
- 238000004220 aggregation Methods 0.000 description 4
- 230000002776 aggregation Effects 0.000 description 4
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 4
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000004200 microcrystalline wax Substances 0.000 description 3
- 235000019808 microcrystalline wax Nutrition 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- 239000004203 carnauba wax Substances 0.000 description 2
- 235000013869 carnauba wax Nutrition 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005562 fading Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 2
- 210000002374 sebum Anatomy 0.000 description 2
- 229940032094 squalane Drugs 0.000 description 2
- 238000009827 uniform distribution Methods 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 241000721047 Danaus plexippus Species 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 208000032400 Retinal pigmentation Diseases 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- MROCJMGDEKINLD-UHFFFAOYSA-N dichlorosilane Chemical compound Cl[SiH2]Cl MROCJMGDEKINLD-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- -1 emulsified Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- UCSUOYMTZRJAIH-UHFFFAOYSA-N iron(2+) oxygen(2-) titanium(4+) Chemical compound [O-2].[O-2].[Ti+4].[Fe+2] UCSUOYMTZRJAIH-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 1
- 239000005052 trichlorosilane Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
<産業上の利用分野>
本発明は、耐水性、耐油性、耐摩擦性に優れ、
また、経時安定性、使用性に秀でた非水系メーク
アツプ化粧料に関するもので、特には非水系タイ
プのアイメーク料として好適なものを提供せんと
するものである。
<従来の技術及び発明が解決しようとする課題>
近年、メークアツプ化粧料に対する需要は多様
化の一途をたどり、これを受ける形でその製品形
態も、口紅、フアンデーシヨン、おしろい、ネイ
ル等の品目構成面のみならず、これをより細分化
する形で液状、粉末状、固型、乳化型等剤型面の
要素が加わつて多岐にわたるものとなつている。
更に、実際のメークアツプ化粧料の使用範囲も
広がり、従来は余りメークをすることの少なかつ
たスポーツ時や夏場の海にてもメークをすること
が日常化してきている。スポーツメークやサマー
メークと呼ばれるこれら商品群を含め、最近のメ
ークアツプ化粧料には従来以上の耐水性、耐汗性
(耐皮脂性)、耐摩擦性等の物理的、化学的諸特性
が要求されるようになつた。
また、これらメークアツプ化粧料の中でも、特
にアイライナー、マスカラ等に代表されるアイメ
ーク料は、その使用される部位が特に敏感であ
り、且つ比較的皮膚の動きが活発であることか
ら、安全性を維持しつつ更に上記諸特性を満足さ
せる必要があり、各種メークアツプ化粧料の中で
最も技術的困難を伴なう製品の1つであつた。
従来、アイメーク料は、その形態から大きく乳
化タイプ、皮膜形成タイプ、非水系タイプに分類
されるが、何れのタイプにおいても、基本的には
処方中に配合されるワツクス、油分やロジン、ポ
リアクリル酸エステル等の樹脂分などの働きによ
り耐水性、耐油性、耐摩擦性を向上させることを
狙いとしていた。そしてこれまで、乳化、皮膜形
成、非水系の3タイプのうちでは、非水系タイプ
のものが最も耐水性に優れ、アイメーク料におけ
る中心タイプとなつているが、未だなお多くの問
題を有するものであつた。すなわち、非水系タイ
プのものは、固型・半固型・液状油分と揮発性油
剤と顔料とを主要成分として構成されるもので、
耐水性は良いものの、耐油性が非常に悪く皮脂に
よる化粧くずれを起し易く、また経時安定性にお
いて分離、ゲル化、顔料沈降、ワツクス等の凝集
や析出等の問題が起るという欠点がある。
この理由としては、微小ワツクス粒子分散構造
を利用して系の粘度を上げ、このゾル中に比重の
大きい顔料を長期間安定に分散しておく方法で
は、系の粘度、温度特性が大きい為、高温度下で
は系が著しく低粘化し、分離、顔料沈降が起り、
使用時の状態が悪く商品価値を失ない、一方、低
温下では、系が固化やゲル化の傾向になり、高粘
性の為に筆への含みが悪く、また肌へスムースに
塗布されないという使用性の悪化を生じるためで
あつた。
<課題を解決するための手段>
そこで、本発明者らはメークアツプ化粧料全般
について要請の高い耐水性、耐油性、耐摩擦性の
改善を考慮しつつ、特には経時安定性の問題をも
含めた前記従来のアイメーク料の抱える問題を解
決すべく鋭意研究を重ねた結果、ある特定のシリ
コーン樹脂とシリコーン油とを含有する混合物を
皮膜形成成分として添加すると、上記諸特性が向
上し、非水系メークアツプ化粧料、特にはアイメ
ーク料として最も効果的なものが得られることを
見出し、本発明の完成に至つた。
すなわち、本発明の構成は顔料を必須成分とし
て含む非水系メークアツプ化粧料において、3次
元網状構造を有するシリコーン樹脂と粘度10万
CS以上のジメチルポリシロキサンとを1:5〜
5:1の比率で含有する混合物を、基材全体に対
して10〜50重量%配合することを特徴とするもの
である。
以下、本発明に係る非水系メークアツプ化粧料
について詳細に述べる。
先ず本発明に適用さえるシリコーン樹脂とは、
重合最終状態で3次元網状構造を有するもので、
別名架橋型シリコーン樹脂とも称される。このも
のは、例えば有機トリクロロシラン(RSiCl3)
と有機ジクロロシラン(R2SiCl2)とを加水分解
した後、縮合し、橋架けさせることにより、下記
に示すような構造を有する樹脂(レジン)とな
る。
<Industrial Application Fields> The present invention has excellent water resistance, oil resistance, and abrasion resistance.
The present invention also relates to non-aqueous makeup cosmetics that are excellent in stability over time and ease of use, and in particular, it is an object of the present invention to provide a non-aqueous eye makeup composition that is suitable as a non-aqueous eye makeup composition. <Problems to be solved by conventional techniques and inventions> In recent years, the demand for makeup cosmetics has continued to diversify, and in response to this, the product format has also expanded to include lipsticks, foundations, face powder, nail polish, etc. In addition to their composition, they are further divided into liquid, powder, solid, emulsified, and other dosage forms, resulting in a wide variety of products. Furthermore, the scope of actual use of make-up cosmetics has expanded, and it has become commonplace for people to wear make-up even when playing sports or going to the beach in the summer, when previously people rarely wore make-up. Recent makeup cosmetics, including these product groups called sports makeup and summer makeup, are required to have better physical and chemical properties than ever before, such as water resistance, sweat resistance (sebum resistance), and abrasion resistance. I started to do that. Furthermore, among these make-up cosmetics, the safety of eye make-up products such as eyeliner and mascara is particularly important because the areas where they are used are particularly sensitive and the skin is relatively active. It was necessary to satisfy the above-mentioned properties while maintaining the above characteristics, and it was one of the most technically difficult products among the various makeup cosmetics. Traditionally, eye makeup products are broadly classified into emulsion types, film-forming types, and non-aqueous types based on their form, but all types basically contain waxes, oils, rosins, and polyacrylics that are blended into the formulation. The aim was to improve water resistance, oil resistance, and abrasion resistance through the action of resin components such as acid esters. Up until now, of the three types (emulsifying, film-forming, and non-aqueous), the non-aqueous type has the best water resistance and has become the main type of eye makeup, but it still has many problems. It was hot. In other words, non-aqueous types are mainly composed of solid, semi-solid, or liquid oils, volatile oils, and pigments.
Although it has good water resistance, it has very poor oil resistance, making it easy for makeup to fade due to sebum, and it also has disadvantages in terms of stability over time, such as separation, gelation, pigment sedimentation, aggregation and precipitation of wax, etc. . The reason for this is that with the method of increasing the viscosity of the system by using the fine wax particle dispersion structure and stably dispersing pigments with high specific gravity in this sol for a long period of time, the viscosity and temperature characteristics of the system are large. At high temperatures, the viscosity of the system becomes significantly lower, separation and pigment precipitation occur.
The product is not in good condition when used, and does not lose its commercial value.On the other hand, at low temperatures, the system tends to solidify or gel, and because of its high viscosity, it does not absorb well into the brush, and it does not apply smoothly to the skin. This was to cause sexual deterioration. <Means for Solving the Problems> Therefore, the present inventors have taken into account improvements in the water resistance, oil resistance, and abrasion resistance that are highly requested for makeup cosmetics in general, and have particularly taken into consideration the issue of stability over time. As a result of extensive research to solve the problems faced by the conventional eye makeup products, we found that when a mixture containing a certain silicone resin and silicone oil was added as a film-forming component, the above properties were improved, and non-aqueous It has been discovered that the most effective make-up cosmetics, particularly eye makeup products, can be obtained, leading to the completion of the present invention. That is, the structure of the present invention is a non-aqueous makeup cosmetic containing a pigment as an essential ingredient, a silicone resin having a three-dimensional network structure, and a viscosity of 100,000 yen.
1:5~ with dimethylpolysiloxane of CS or higher
It is characterized in that the mixture containing the mixture at a ratio of 5:1 is blended in an amount of 10 to 50% by weight based on the entire base material. Hereinafter, the non-aqueous makeup cosmetic according to the present invention will be described in detail. First, the silicone resin applicable to the present invention is
It has a three-dimensional network structure in the final state of polymerization,
Also known as crosslinked silicone resin. This material is, for example, organic trichlorosilane (RSiCl 3 )
After hydrolyzing and organic dichlorosilane (R 2 SiCl 2 ), they are condensed and cross-bridged to produce a resin having the structure shown below.
【式】
(但し、RはC1〜C4のアルキル基もしくはフ
エニル基)
もちろん、上記に示した構造を有するシリコー
ン樹脂としては、従来市販されているシリコーン
重合体(直鎖型)に適宜架橋処理(触媒加熱、放
射線処理)を施したものでも可能である。
そして、上記シリコーン樹脂を非水系メークア
ツプ化粧料に配合する方法としては、架橋型シリ
コーン樹脂と粘度10万CS以上のジメチルポリシ
ロキサンとの混合物を用いる。
尚、上記混合物を用いる場合には、その取扱い
上の利便を図るため、必要に応じて希釈剤として
揮発性の溶剤例えばトルエン、リグロイン等、ま
たは揮発性の油剤例えば低沸点シリコーン油、低
沸点環状シリコーン油、低沸点イソパラフイン等
を加えることができる。また、この様な希釈剤み
の混合物としては、市販のものからも入手が可能
であり、例えば信越シリコーンKR101−10また
はKR114などが例示される。
また、本発明では、耐水性、耐油性、耐摩擦性
等の諸特性と使用性、使用感等とのバランスか
ら、架橋型シリコーン樹脂とジメチルポリシロキ
サンとの混合物中の含有比率が1:5〜5:1の
範囲にあることが必要である。
これは樹脂分がこの配合割合より少なくなると
耐摩擦性が低下し、一方この配合割合より多くな
ると使用性を悪くすると共に経時安定性も低下
し、共に好ましくないからである。
次に、本発明において非水系メークアツプ化粧
料に本発明の混合物を配合する際の配合量として
は、架橋型シリコーン樹脂とジメチルポリシロキ
サンとの混合物重量として、基剤全体に対し10〜
50重量%である。これは10重量%より少ない量で
は未だ系の粘度が低く、顔料分散の安定化が難し
く、一方、50重量%を超えると、他成分とのバラ
ンスが崩れるばかりか、高粘性になり過ぎて使用
性が悪化し、共に好ましくないからである。
本発明の非水系アイメーク料に代表さえる非水
系メークアツプ化粧料には、前記必須成分として
の混合物及び有機、無機、パール剤の各種顔料に
加えて、通常メークアツプ化粧料に使用される有
機、無機の各種粉体、固型・半固型乃至は液状の
油分、低沸点シリコーン油、低沸点環状シリコー
ン油、低沸点イソパラフイン等の揮発性油剤、そ
の他顔料分散剤、可塑剤、繊維、香料、防腐剤等
などが、製品目的に応じて適宜選択され配合され
る。この中でも、特に非水系アイメーク料におい
ては揮発性油剤は重要であり、アイメーク料の乾
燥性を高めるとともに、前記混合物の希釈剤とし
ての働きも示すものである。そして、この揮発性
油剤はアイメーク料中に通常は5〜80重量%好ま
しくは20〜60重量%が配合される。これは5重量
%より少ない量では希釈効果が弱く高粘性となり
使用性が悪く、また乾きが遅くなるし、逆に80重
量%を超える量を用いると希釈効果が強すぎ、系
が顔料を安定に分散するに足る粘性が保てずに分
離を生じてしまい、共に好ましくないからであ
る。
次に本発明によつて得られる非水系メークアツ
プ化粧料を評価するため、後記実施例1で得られ
た本発明のアイライナーと比較品として後記比較
例1に示した従来のアイライナー、また後記実施
例2で得られた本発明のマスカラと比較品として
後記比較例2に示した従来のマスカラとを用い
て、その耐水性、耐油性、皮膜強度、安定性、使
用性の5評価項目について比較試験を行なつた。
その結果を表−1に示す。
(1) 耐水性試験
上記アイライナー、マスカラの各サンプルを樹
脂板上にナイロン筆を用いて塗布。その後室温に
て1時間風乾した後、流水下に10分間浸漬し、色
落ち、にじみ、はがれ等の有無をチエツクした。
サンプル数各10。評価は○:変化なし、△:部分
的に色消え、剥離あり、×:完全に色消えまたは
剥離。
(2) 耐油性試験
上記耐水性試験と同様に調整した各試験板をス
クワランの循環流槽内に10分間浸漬し、上記試験
と同様の評価基準により評価した。
(3) 皮膜強度試験
耐水性試験または耐油性試験を終了した各試験
板について、摩擦試験機を用い含水または含スク
ワランスポンジチツプにて繰り返し摩擦して脱
落、はがれの有無をチエツクした。評価は○:変
化なし、△:部分的に剥離、脱落、×:完全に剥
離、脱落。
(4) 安定性試験
試料アイライナー、マスカラの各サンプルを試
験ガラス瓶に充填し、−10℃、20℃、40℃の恒温
下及び−5℃〜40℃、48hrサイクルのエージング
条件下で1ケ月間放置し、分離、凝集と粘度変化
をチエツクした。評価は○:変化なし、△:若干
の分離、凝集、粘度変化あり、×:著しい分離、
凝集、粘度変化あり。
(5) 使用性試験
アイライナー容器、マスカラ容器に各サンプル
をそれぞれ充填し、40名の女性パネラーにより通
常の使用テスト(各サンプルに付き各10名)を1
ケ月間行ない、描き易さ、にじみ等について総合
評価した。評価は○:良好、△:ほぼ良好、×:
不良。[Formula] (However, R is a C 1 to C 4 alkyl group or a phenyl group) Of course, as a silicone resin having the structure shown above, it is possible to appropriately crosslink a conventional commercially available silicone polymer (linear type). It is also possible to use treated materials (catalyst heating, radiation treatment). As a method for blending the silicone resin into a non-aqueous makeup cosmetic, a mixture of a crosslinked silicone resin and dimethylpolysiloxane having a viscosity of 100,000 CS or more is used. In addition, when using the above mixture, in order to facilitate handling, volatile solvents such as toluene, ligroin, etc., or volatile oils such as low-boiling silicone oil, low-boiling cyclic oil, etc. may be used as diluents, if necessary. Silicone oil, low boiling point isoparaffin, etc. can be added. Further, such a diluent-containing mixture is also commercially available, such as Shin-Etsu Silicone KR101-10 or KR114. In addition, in the present invention, the content ratio in the mixture of crosslinked silicone resin and dimethylpolysiloxane is 1:5 in view of the balance between various properties such as water resistance, oil resistance, and abrasion resistance, usability, and feeling of use. It is necessary that the ratio be in the range of ~5:1. This is because if the resin content is less than this blending ratio, the abrasion resistance will decrease, while if it is more than this blending ratio, the usability will deteriorate and the stability over time will also decrease, both of which are undesirable. Next, in the present invention, when blending the mixture of the present invention into a non-aqueous makeup cosmetic, the amount of the mixture of crosslinked silicone resin and dimethylpolysiloxane is 10 to 10% based on the entire base.
It is 50% by weight. If the amount is less than 10% by weight, the viscosity of the system is still low and it is difficult to stabilize the pigment dispersion.On the other hand, if it exceeds 50% by weight, not only will the balance with other components be disrupted, but the viscosity will become too high for use. This is because the quality deteriorates and both are undesirable. Non-aqueous make-up cosmetics, typified by the non-aqueous eye make-up of the present invention, contain organic, inorganic pigments commonly used in make-up cosmetics, in addition to the above-mentioned mixtures as essential ingredients and various organic, inorganic, and pearlescent pigments. Various powders, solid, semi-solid, and liquid oils, low-boiling point silicone oils, low-boiling point cyclic silicone oils, volatile oils such as low-boiling point isoparaffins, other pigment dispersants, plasticizers, fibers, fragrances, and preservatives. Agents and the like are appropriately selected and blended depending on the purpose of the product. Among these, volatile oil agents are particularly important in non-aqueous eye make-up compositions, as they improve the drying properties of the eye make-up composition and also function as a diluent for the mixture. This volatile oil agent is usually blended into eye makeup in an amount of 5 to 80% by weight, preferably 20 to 60% by weight. If the amount is less than 5% by weight, the dilution effect will be weak and the viscosity will be high, resulting in poor usability and slow drying.On the other hand, if the amount is more than 80% by weight, the dilution effect will be too strong and the system will stabilize the pigment. This is because the viscosity sufficient for dispersion cannot be maintained and separation occurs, both of which are undesirable. Next, in order to evaluate the non-aqueous makeup cosmetics obtained according to the present invention, the eyeliner of the present invention obtained in Example 1 described below, the conventional eyeliner shown in Comparative Example 1 described later, and the conventional eyeliner shown in Comparative Example 1 described later, and Using the mascara of the present invention obtained in Example 2 and the conventional mascara shown in Comparative Example 2 below as a comparative product, the five evaluation items of water resistance, oil resistance, film strength, stability, and usability were evaluated. A comparative test was conducted.
The results are shown in Table-1. (1) Water resistance test Each sample of the eyeliner and mascara above was applied onto a resin board using a nylon brush. After that, it was air-dried for 1 hour at room temperature, and then immersed in running water for 10 minutes to check for discoloration, bleeding, peeling, etc.
Number of samples: 10 each. Evaluation: ○: No change, △: Partial color fading or peeling, ×: Complete color fading or peeling. (2) Oil resistance test Each test plate prepared in the same manner as in the above water resistance test was immersed in a squalane circulating flow tank for 10 minutes, and evaluated using the same evaluation criteria as in the above test. (3) Film strength test Each test plate that had undergone the water resistance test or oil resistance test was repeatedly rubbed with a water-containing or squalane sponge tip using a friction tester to check for any falling off or peeling. Evaluation: ○: No change, △: Partially peeled off and fell off, ×: Completely peeled off and fell off. (4) Stability test Each sample of eyeliner and mascara was filled into a test glass bottle and subjected to constant temperature of -10℃, 20℃, 40℃ and aging condition of -5℃~40℃, 48hr cycle for 1 month. After standing for a while, separation, aggregation and viscosity changes were checked. Evaluation: ○: No change, △: Slight separation, aggregation, viscosity change, ×: Significant separation,
There is aggregation and viscosity change. (5) Usability test Each sample was filled into an eyeliner container and a mascara container, and 40 female panelists conducted a normal usage test (10 people for each sample) once.
It was used for several months, and a comprehensive evaluation was made regarding ease of drawing, blurring, etc. Evaluation is ○: good, △: almost good, ×:
Bad.
【表】【table】
【表】
<実施例>
以下に本発明の好適な実施例及び比較例を示
す。尚、配合割合は重量部である。
実施例1アイライナー
Aシリコーン混合物
Aシリコーン混合物
(シリコーン樹脂:ジメチルポリシロキサン(信越シリ
コーンKE−76)=1:1)
20.0
B[低沸点ジメチルポリシロキサン(1CS)
60.0
C黒酸化鉄
群青15.0
5.0
(方法)
A部とB部の混合物にC部を加え混合攪拌し、
3本ロールで分散均一化する。
比較例1アイライナー
Aマイクロクリスタリンワツクス
コレステロール
ビーズワツクス
ステアリン酸
カルナバワツクス
モクロウ
モノステアリン酸ソルビタン4.0
2.0
4.5
1.0
0.5
1.0
1.0
B[黒酸化鉄 21.0
C[低沸点イソパラフイン 65.0
(方法)
B部とC部の一部を混合し、3本ロールで分散
してペーストとする。A部とC部の残りを80〜90
℃に加温し、攪拌して均一とする。これに先のペ
ーストを加え、高速攪拌しながら冷却する。
実施例2 マスカラ
Aシリコーン混合物
Aシリコーン混合物
(シリコーン樹脂:ジメチルポリシロキサン100万CS=
2:1)
45.0
B[低沸点イソパラフイン 35.0
C黒酸化鉄
黄色4号アルミレーキ
タルク10.0
5.0
5.0
(方法)
A部とB部の混合物にC部を加え混合攪拌し、
3本ロールで分散均一化する。
比較例2マスカラ
Aマイクロクリスタリンワツクス
キヤンデリラワツクス
カルナバワツクス
イソステアリン酸10.0
5.5
12.0
2.5
Bタルク
黒酸化鉄2.0
12.0
C[低沸点イソパラフイン 56.0
(方法)
B部とD部の一部を混合し、3本ロールで分散
してペーストとする。A部とD部の残りを80〜90
℃に加温し、攪拌して均一とする。これに先のペ
ーストを加え高速攪拌しながら80℃以下でC部を
加える。弱攪拌で90℃以上とした後冷却する。
実施例3 フアンデーシヨン
Aシリコーン混合物
Aシリコーン混合物
シリコーン樹脂:ジメチルポリシロキサン100万CS=1
:2
48.5
B低沸点イソパラフイン
低沸点ジメチルポリシロキサン(1CS)38.0
2.0
C黄色酸化鉄
酸化チタン
タルク
ベンガラ1.5
3.0
5.0
0.5
Dミツロウ
マイクロクリスタリンワツクス0.5
1.0
(方法)
A部とB部の混合物にD部を加温溶解し、C部
を加え、混合、分散、攪拌し室温まで冷却する。[Table] <Examples> Preferred examples and comparative examples of the present invention are shown below. Incidentally, the blending ratio is in parts by weight. Example 1 Eyeliner A Silicone mixture A Silicone mixture (Silicone resin: Dimethyl polysiloxane (Shin-Etsu Silicone KE-76) = 1:1) 20.0 B [Low boiling point dimethyl polysiloxane (1CS) 60.0 C Black iron oxide ultramarine 15.0 5.0 ( Method) Add part C to the mixture of parts A and B, mix and stir,
Uniform distribution using 3 rolls. Comparative Example 1 Eyeliner A Microcrystalline wax Cholesterol bead wax Stearic acid carnauba wax Monarch monostearate Sorbitan 4.0 2.0 4.5 1.0 0.5 1.0 1.0 B [Black iron oxide 21.0 C [Low boiling point isoparaffin 65.0 (Method) Part B and Part C is mixed and dispersed using three rolls to form a paste. 80-90 for the rest of Part A and Part C
Warm to ℃ and stir to homogenize. Add the above paste to this and cool while stirring at high speed. Example 2 Mascara A Silicone Mixture A Silicone Mixture (Silicone Resin: Dimethylpolysiloxane 1 million CS=
2:1) 45.0 B [low boiling point isoparaffin 35.0 C black iron oxide yellow No. 4 aluminum lake talc 10.0 5.0 5.0 (Method) Add part C to the mixture of parts A and B, mix and stir,
Uniform distribution using 3 rolls. Comparative Example 2 Mascara A Microcrystalline Wax Scandinavian Wax Carnauba Wax Isostearic Acid 10.0 5.5 12.0 2.5 B Talc Black Iron Oxide 2.0 12.0 C [Low Boiling Point Isoparaffin 56.0 (Method) Part B and Part D were mixed, Disperse with three rolls to make a paste. 80-90 for the rest of Part A and Part D
Warm to ℃ and stir to homogenize. Add the above paste to this and add part C at below 80°C while stirring at high speed. Bring the temperature to 90°C or higher with gentle stirring and then cool. Example 3 Foundation A Silicone Mixture A Silicone Mixture Silicone Resin: Dimethylpolysiloxane 1 million CS=1
:2 48.5 B Low boiling point isoparaffin Low boiling point dimethylpolysiloxane (1CS) 38.0 2.0 C Yellow iron oxide titanium oxide talc red iron oxide 1.5 3.0 5.0 0.5 D Beeswax microcrystalline wax 0.5 1.0 (Method) Add D to the mixture of parts A and B Part C is dissolved by heating, part C is added, mixed, dispersed, stirred, and cooled to room temperature.
Claims (1)
プ化粧料において、3次元網状構造を有するシリ
コーン樹脂と粘度10万CS以上のジメチルポリシ
ロキサンとを1:5〜5:1の比率で含有する混
合物を、基材全体に対して10〜50重量%配合する
ことを特徴とする非水系メークアツプ化粧料。 2 揮発性油剤を含む特許請求の範囲第1項記載
の非水系メークアツプ化粧料。 3 非水系アイメーク料である特許請求の範囲第
1項記載の非水系メークアツプ化粧料。[Scope of Claims] 1. A non-aqueous makeup cosmetic containing pigment as an essential component, comprising a silicone resin having a three-dimensional network structure and dimethylpolysiloxane having a viscosity of 100,000 CS or more in a ratio of 1:5 to 5:1. 1. A non-aqueous make-up cosmetic, characterized in that the mixture is blended in an amount of 10 to 50% by weight based on the entire base material. 2. The non-aqueous makeup cosmetic according to claim 1, which contains a volatile oil agent. 3. The non-aqueous makeup cosmetic according to claim 1, which is a non-aqueous eye makeup composition.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13941684A JPS6118708A (en) | 1984-07-05 | 1984-07-05 | Makeup cosmetic |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13941684A JPS6118708A (en) | 1984-07-05 | 1984-07-05 | Makeup cosmetic |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6118708A JPS6118708A (en) | 1986-01-27 |
JPH0574562B2 true JPH0574562B2 (en) | 1993-10-18 |
Family
ID=15244715
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP13941684A Granted JPS6118708A (en) | 1984-07-05 | 1984-07-05 | Makeup cosmetic |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6118708A (en) |
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JPS51151339A (en) * | 1975-06-18 | 1976-12-25 | Kobayashi Kooc:Kk | Toilet good |
JPS5428832A (en) * | 1977-08-09 | 1979-03-03 | Shiseido Co Ltd | Makeups |
JPS5458756A (en) * | 1977-10-18 | 1979-05-11 | Toshiba Silicone | Organopolysiloxane composition |
JPS5976009A (en) * | 1982-10-23 | 1984-04-28 | Pola Chem Ind Inc | Makeup cosmetic |
-
1984
- 1984-07-05 JP JP13941684A patent/JPS6118708A/en active Granted
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5125070A (en) * | 1974-08-26 | 1976-03-01 | Matsushita Electric Ind Co Ltd | Ryukakadomiumumaku no seizohoho |
JPS51151339A (en) * | 1975-06-18 | 1976-12-25 | Kobayashi Kooc:Kk | Toilet good |
JPS5428832A (en) * | 1977-08-09 | 1979-03-03 | Shiseido Co Ltd | Makeups |
JPS5458756A (en) * | 1977-10-18 | 1979-05-11 | Toshiba Silicone | Organopolysiloxane composition |
JPS5976009A (en) * | 1982-10-23 | 1984-04-28 | Pola Chem Ind Inc | Makeup cosmetic |
Also Published As
Publication number | Publication date |
---|---|
JPS6118708A (en) | 1986-01-27 |
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EXPY | Cancellation because of completion of term |