CN116966113A

CN116966113A - Double-dosage-form makeup remover and preparation method thereof

Info

Publication number: CN116966113A
Application number: CN202311037217.5A
Authority: CN
Inventors: 孙云起; 蔡永通; 乔晗; 郭朝万; 聂艳峰; 江川霞; 李鑫宇; 席绍峰; 肖湲
Original assignee: GUANGZHOU QUALITY SUPERVISION AND TESTING INSTITUTE; Guangdong Marubi Biological Technology Co Ltd
Current assignee: GUANGZHOU QUALITY SUPERVISION AND TESTING INSTITUTE; Guangdong Marubi Biological Technology Co Ltd
Priority date: 2023-08-16
Filing date: 2023-08-16
Publication date: 2023-10-31

Abstract

The invention relates to a two-agent type makeup removing preparation and a preparation method thereof. Before the product is used, the two agents are required to be mixed and stirred into gel, and the gel is used, so that the gel has good makeup removing effect and also has the anti-aging effect.

Description

Double-dosage-form makeup remover and preparation method thereof

Technical Field

The invention belongs to the technical field of cosmetics, and relates to a double-agent type makeup removing preparation and a preparation method thereof.

Background

Along with the development of cosmetics, the residues of the cosmetics greatly hurt skin, and if the residues cannot be cleaned up in time, the residues can enter hair follicles to form cysts, so that the makeup removal of the skin is particularly important, and various makeup removal products are generated. Cleansing is an important step in skin care, and selection of a good cleansing product can effectively reduce cosmetic damage to the skin, while poor quality or improper use of cleansing products can cause numerous skin problems.

The cleansing products are mainly divided into 5 types according to the textures, namely cleansing oil, cleansing milk, cleansing cream, cleansing gel and cleansing water. The cleansing gel has better use feeling than cleansing liquid, cleansing cream and cleansing oil. The makeup removing gel and the preparation method thereof have various types, and CN104367516A provides a mild makeup removing gel for the lips of eyes and a preparation method thereof, and the makeup removing gel comprises oil-soluble components and water-soluble components. However, the cleansing force of the eye and lip cleansing gel is general, and the cleansing effect is still not thorough. CN107260586a provides a cleansing emulsion gel and a preparation method thereof, the preparation method comprises the steps of forming a ternary decontamination microcapsule coating, then preparing microemulsion with squalane, and then stabilizing the system with acrylic resin to form a semitransparent cleansing emulsion gel.

Most of the makeup removing gels on the market are manufactured before leaving the factory, and the end consumer can directly use the makeup removing gel in a dosage form state, and the effect is single, so that development of a novel makeup removing preparation with good makeup removing effect and anti-aging effect is needed.

Disclosure of Invention

Aiming at the defects of the prior art, the invention aims to provide a two-dosage form makeup remover, and a preparation method and application thereof.

In order to achieve the aim of the invention, the invention adopts the following technical scheme:

in a first aspect, the present invention provides a two-part makeup remover comprising a powder comprising a thickener and a liquid comprising a makeup remover component and water, which are separately packaged.

The double-agent type makeup removing preparation has good makeup removing and anti-aging effects, the powder agent and the liquid agent are independently packaged and mixed before use, and the anti-aging effects are superior to those of makeup removing gel with the same components and content and manufactured before delivery.

Preferably, the mass ratio of the powder agent to the liquid agent is (0.5-5): 95-99.5.

When the powder and the liquid are mixed in the above specific mass ratio, the cleansing and anti-aging effects are best.

Wherein, the specific point values in (0.5-5) can be selected from 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, etc., and the specific point values in (95-99.5) can be selected from 95, 95.5, 96, 96.5, 97, 97.5, 98, 98.5, 99, 99.5, etc., and other specific point values in the above numerical ranges can be selected, which will not be repeated here.

Preferably, the content of the makeup removing component in the liquid agent is 5-10% by mass, for example, 5%, 5.5%, 6%, 6.5%, 7%, 7.5%, 8%, 8.5%, 9%, 9.5%, 10%, etc., and other specific values in the above numerical ranges are selected, which will not be described in detail herein.

The cleansing effect is best when the cleansing ingredient is added in the above specific mass percent.

Preferably, the liquid agent further comprises any one or a combination of at least two of a moisturizer, a skin conditioner, or a preservative.

Preferably, the liquid agent further comprises any one or a combination of at least two of humectant 1-10%, skin conditioning agent 0.01-10% or preservative 0.1-1% by mass.

The mass percentage of the humectant can be selected to be 1%, 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9%, 10%, etc., the mass percentage of the skin conditioning agent can be selected to be 0.01%, 0.1%, 0.5%, 1%, 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9%, 10%, etc., the mass percentage of the preservative can be selected to be 0.1%, 0.2%, 0.3%, 0.4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1%, etc., and other specific values in the above numerical range can be selected, and will not be repeated here.

Preferably, the thickener comprises sodium carboxymethyl starch.

Preferably, the makeup removing component comprises any one or a combination of at least two of PEG-6 caprylic/capric glycerides, polysorbate-20 or polyglycerol-6 caprylate, and more preferably a combination of PEG-6 caprylic/capric glycerides, polysorbate-20 and polyglycerol-6 caprylate.

The invention discovers that PEG-6 caprylic acid/capric acid glyceride, polysorbate-20 and polyglycerol-6 caprylic acid ester have a certain synergistic effect on the cleansing effect.

Preferably, the skin conditioning agent comprises any one or a combination of at least two of retinol, soluble collagen or ergothioneine, more preferably a combination of retinol, soluble collagen and ergothioneine.

The invention discovers that retinol, soluble collagen and ergothioneine have a certain synergistic effect on the anti-aging effect.

Preferably, the humectant comprises glycerin.

In a second aspect, the present invention provides a method for preparing the two-pack type makeup remover according to the first aspect, wherein the method for preparing the powder in the two-pack type makeup remover comprises the following steps: independently packaging the thickener to obtain the final product;

the preparation method of the liquid agent in the two-agent type makeup removing preparation comprises the following steps: mixing the makeup removing component with water, and independently packaging.

Preferably, the temperature at which the makeup removing component is mixed with water is 40 to 50 ℃, for example 40 ℃, 41 ℃, 42 ℃, 43 ℃, 44 ℃, 45 ℃, 46 ℃, 47 ℃, 48 ℃, 49 ℃, 50 ℃ and the like, and other specific values within the above numerical range can be selected, and will not be described in detail herein.

Preferably, the makeup removing component is mixed with water before the water is mixed with the moisturizing agent, and the water is mixed with the moisturizing agent for heat preservation.

Preferably, the temperature at which the water is mixed with the humectant is 80-85 ℃, for example 80 ℃, 81 ℃, 82 ℃, 83 ℃, 84 ℃, 85 ℃, etc., and other specific values within the above numerical range can be selected, and will not be described in detail herein.

Preferably, the time of the heat preservation is 15-25min, for example, 15min, 16min, 17min, 18min, 19min, 20min, 21min, 22min, 23min, 24min, 25min, etc., and other specific point values in the above numerical range are selectable, which will not be described in detail herein.

Preferably, the makeup removing component, when mixed with water, further comprises mixing with a skin conditioning agent and/or a preservative.

Compared with the prior art, the invention has the following beneficial effects:

Detailed Description

In order to further describe the technical means adopted by the present invention and the effects thereof, the following describes the technical scheme of the present invention in combination with the preferred embodiments of the present invention, but the present invention is not limited to the scope of the embodiments.

The sources of the functional components contained in the products related to the following examples and comparative examples are as follows (only the functional components are represented, and the necessary auxiliary materials contained in other commercial raw materials are not described in detail):

sodium carboxymethyl starch is commercially available from the company of the sciences of the forest, xinxiang, and the company of the science and technology (China) under the trade name COVAGEL;

retinol is a product available from Shanghai Ke Piano technologies Co., ltd under the trade name Anallerg- -Retinol-10C;

the soluble collagen is purchased from Guangzhou open point biotechnology limited company under the trade name of fully human ^TM Collagen products;

ergothioneine is commercially available from Shanghai Keqin technology Co., ltd-the product of Reyouth-5P;

PEG-6 caprylic/capric glycerides commercially available from EVONIK Operations GmbH company under the trade nameGMC 6MB product;

polysorbate-20 is a product commercially available from Croda Singapore Pte Ltd under the trade designation SP TWEEN 20MBAL-LQ- (SG);

polyglycerol-6 caprylate is commercially available from green wood oil company under the trade name GLYSURF 6 MCL;

hydroxypropyl starch phosphate is commercially available from noron chemicals (boxing) limited under the trade name STRUCTURE XL;

aluminum starch octenyl succinate is a product available from nonion chemicals (boxing) company under the trade name DRY-FLO PC;

PEG-7 glycerol cocoate is commercially available from Croda Singapore Pte Ltd under the trade designation SP GLYCEROX HE MBAL-LQ- (SG);

polyglycerol-10 laurate is a product commercially available from LONZA under the trade name Polyaldo 10-1-L KFG;

polyglycerol-4 decanoate is a product available from the company Hydrior a.g. under the trade name Hydriol pgcl.4.

Example 1

The embodiment provides a two-agent type makeup remover, which comprises a powder agent and a liquid agent which are independently packaged, wherein the mass ratio of the powder agent to the liquid agent is 3:97, the powder agent is sodium carboxymethyl starch, and the liquid agent comprises the following components: 2% of retinol, 2% of soluble collagen, 0.5% of ergothioneine, 5% of glycerol, 3% of PEG-6 caprylic/capric glycerides, 3% of polysorbate-20%, 2% of polyglycerol-6 caprylate and the balance of water.

The preparation method comprises the following steps: mixing water and glycerol at 82 deg.C, maintaining the temperature for 20min, cooling to 45deg.C, mixing with retinol, soluble collagen, ergothioneine, PEG-6 caprylic acid/capric acid glyceride, polysorbate-20, and polyglycerol-6 caprylate, and independently packaging to obtain liquid preparation; and independently subpackaging sodium carboxymethyl starch to obtain powder.

Example 2

The embodiment provides a two-agent type makeup remover, which comprises a powder agent and a liquid agent which are independently packaged, wherein the mass ratio of the powder agent to the liquid agent is 0.5:99.5, the powder agent is sodium carboxymethyl starch, and the liquid agent comprises the following components: 0.5% of retinol, 1% of soluble collagen, 0.1% of ergothioneine, 10% of glycerol, 3% of PEG-6 caprylic/capric glycerides, 3% of polysorbate-20%, 4% of polyglycerol-6 caprylate and the balance of water.

The preparation method comprises the following steps: mixing water and glycerol at 85deg.C, maintaining the temperature for 15min, cooling to 50deg.C, mixing with retinol, soluble collagen, ergothioneine, PEG-6 caprylic acid/capric acid glyceride, polysorbate-20, and polyglycerol-6 caprylate, and independently packaging to obtain liquid preparation; and independently subpackaging sodium carboxymethyl starch to obtain powder.

Example 3

The embodiment provides a two-agent type makeup remover, which comprises a powder agent and a liquid agent which are independently packaged, wherein the mass ratio of the powder agent to the liquid agent is 5:95, the powder agent is sodium carboxymethyl starch, and the liquid agent comprises the following components: 4% of retinol, 5% of soluble collagen, 1% of ergothioneine, 5% of glycerol, 2% of PEG-6 caprylic/capric glycerides, 2% of polysorbate-20%, 1% of polyglycerol-6 caprylate and the balance of water.

The preparation method comprises the following steps: mixing water and glycerol at 80deg.C, maintaining the temperature for 25min, cooling to 45deg.C, mixing with retinol, soluble collagen, ergothioneine, PEG-6 caprylic acid/capric acid glyceride, polysorbate-20, and polyglycerol-6 caprylate, and independently packaging to obtain liquid preparation; and independently subpackaging sodium carboxymethyl starch to obtain powder.

Example 4

This example provides a two-part cleansing formulation that differs from example 1 only in that the liquid formulation does not contain retinol, and its reduced mass is proportioned to the mass of soluble collagen and ergothioneine, with the other ingredients and content remaining unchanged.

The preparation method is described in example 1.

Example 5

This example provides a two-part cleansing formulation that differs from example 1 only in that the liquid formulation does not contain soluble collagen, and the reduced mass is proportioned to the mass of retinol and ergothioneine, with the other ingredients and amounts remaining unchanged.

The preparation method is described in example 1.

Example 6

This example provides a two-part cleansing formulation that differs from example 1 only in that the liquid formulation does not contain ergothioneine, and the reduced mass is proportioned to the mass of retinol and soluble collagen, with the other ingredients and amounts remaining unchanged.

The preparation method is described in example 1.

Example 7

This example provides a two-part cleansing formulation differing from example 1 only in that the liquid formulation does not contain PEG-6 caprylic/capric glycerides, and the reduced mass is proportioned to the mass of polysorbate-20 and polyglycerin-6 caprylate, with the other ingredients and amounts remaining unchanged.

The preparation method is described in example 1.

Example 8

This example provides a two-part cleansing formulation differing from example 1 only in that the liquid formulation does not contain polysorbate-20, and its reduced mass is proportioned to the mass of PEG-6 caprylic/capric glycerides and polyglycerol-6 caprylate, with the other ingredients and amounts remaining unchanged.

The preparation method is described in example 1.

Example 9

This example provides a two-part cleansing formulation differing from example 1 only in that the liquid formulation does not contain polyglycerol-6 caprylate, and its reduced mass is proportioned to the mass of polysorbate-20 and PEG-6 caprylate/caprate with the other ingredients and amounts remaining unchanged.

The preparation method is described in example 1.

Example 10

This example provides a two-part cleansing formulation which differs from example 1 only in that sodium carboxymethyl starch is replaced by hydroxypropyl starch phosphate in equal amounts in the powder formulation, with the other ingredients and amounts remaining unchanged.

The preparation method is described in example 1.

Example 11

This example provides a two-part cleansing formulation which differs from example 1 only in that sodium carboxymethyl starch is replaced by aluminum starch octenyl succinate in equal amounts in the powder formulation, the other ingredients and content remaining unchanged.

The preparation method is described in example 1.

Example 12

This example provides a two-part makeup remover formulation which differs from example 1 only in that the glycerin is replaced with propylene glycol in equal amounts in the liquid formulation, with the other ingredients and amounts remaining unchanged.

The preparation method is described in example 1.

Example 13

This example provides a two-part makeup remover formulation which differs from example 1 only in that glycerin is replaced with butylene glycol in equal amounts in the liquid formulation, and the other ingredients and contents remain unchanged.

The preparation method is described in example 1.

Example 14

This example provides a two-part make-up remover formulation that differs from example 1 only in that the liquid formulation has the equivalent amount of glycerol replaced with 1, 3-propanediol, with the other ingredients and amounts remaining unchanged.

The preparation method is described in example 1.

Example 15

This example provides a two-part cleansing formulation differing from example 1 only in that the liquid formulation does not contain PEG-6 caprylic/capric glycerides, polysorbate-20 and polyglycerol-6 caprylate, the reduced mass of which is distributed over the mass of PEG-7 glyceryl cocoate, with the other ingredients and amounts remaining unchanged.

The preparation method is described in example 1.

Example 16

This example provides a two-part makeup remover formulation differing from example 1 only in that the liquid formulation does not contain PEG-6 caprylic/capric glycerides, polysorbate-20 and polyglycerin-6 caprylate, and its reduced mass is distributed over the mass of polyglycerin-10 laurate, with the other ingredients and contents remaining unchanged.

The preparation method is described in example 1.

Example 17

This example provides a two-part makeup remover formulation differing from example 1 only in that the liquid formulation does not contain PEG-6 caprylic/capric glycerides, polysorbate-20 and polyglycerin-6 caprylate, and its reduced mass is distributed over the mass of polyglycerin-4 caprate, with the other ingredients and contents remaining unchanged.

The preparation method is described in example 1.

Example 18

This example provides a two-part makeup remover formulation differing from example 1 only in that the liquid formulation does not contain PEG-6 caprylic/capric glycerides, polysorbate-20 and polyglycerin-6 caprylate, and its reduced mass is distributed over the mass of decyl glucoside, with the other ingredients and amounts remaining unchanged.

The preparation method is described in example 1.

Comparative example 1

This comparative example provides a makeup removing gel prepared by mixing a powder and a liquid in the two-agent type makeup removing preparation described in example 1.

Test example 1

Cleansing effect test

Smearing lipstick with the same amount on the inner side of an arm, taking the two-dosage type makeup removing preparation of the embodiment 1-3 and the embodiment 7-18, mixing powder and liquid, wherein the embodiment 10-11 can not form gel, taking the gel obtained by mixing on cosmetic cotton, wiping back and forth for 5 times, and observing lipstick reduction amount by naked eyes to evaluate the makeup removing effect, wherein the higher the score is, the better the makeup removing effect is; the 1 s are the worst and the 10 s are all removable.

TABLE 1

Sample of	Make-up removal effect scoring
		Example 1	10
Example 2	9
		Example 3	9
Example 7	4
		Example 8	5
Example 9	4
		Example 12	8
Example 13	7
		Example 14	7
Example 15	8
		Example 16	7
Example 17	7
		Example 18	7

As can be seen from the data in Table 1, the makeup removing preparation provided by the invention has a good makeup removing effect, and the PEG-6 caprylic acid/capric acid glyceride, polysorbate-20 and polyglycerol-6 caprylate in the makeup removing component have a certain synergistic effect on the makeup removing effect.

Test example 2

Anti-aging efficacy test

The testing method comprises the following steps: evaskin-S5 image acquisition and analysis

Test part: face region

Experimental parameters: volume, number, and area of wrinkles

The testing process comprises the following steps: subject data acquisition was scheduled prior to product use and 28 days after use of an equivalent amount of test sample, with each image acquisition

Test instrument: face image photographing and analyzing system VISIA-CR (Canfield U.S.)

Test sample: the two-pack type cleansing formulations of examples 1 to 6 and examples 12 to 18 were mixed with a liquid to form a gel before use, and the cleansing gel of comparative example 1 was used

The test results are shown in Table 2

TABLE 2

As can be seen from the data in Table 2, the two-agent type makeup remover provided by the invention has a good anti-aging effect, and ergothioneine, retinol and soluble collagen have a certain synergistic effect on the anti-aging effect, and the anti-aging effect of the two-agent type makeup remover mixed before use is better than that of the makeup remover gel.

The applicant states that the present invention is described by way of the above examples as a two-pack type makeup remover and a method of preparing the same, but the present invention is not limited to the above examples, i.e., it is not meant that the present invention must be practiced by relying on the above examples. It should be apparent to those skilled in the art that any modification of the present invention, equivalent substitution of raw materials for the product of the present invention, addition of auxiliary components, selection of specific modes, etc., falls within the scope of the present invention and the scope of disclosure.

The preferred embodiments of the present invention have been described in detail above, but the present invention is not limited to the specific details of the above embodiments, and various simple modifications can be made to the technical solution of the present invention within the scope of the technical concept of the present invention, and all the simple modifications belong to the protection scope of the present invention.

In addition, the specific features described in the above embodiments may be combined in any suitable manner, and in order to avoid unnecessary repetition, various possible combinations are not described further.

Claims

1. The two-agent type makeup removing preparation is characterized by comprising a powder agent and a liquid agent which are independently packaged, wherein the powder agent comprises a thickening agent, and the liquid agent comprises a makeup removing component and water.

2. The two-pack type cleansing preparation according to claim 1, wherein the mass ratio of the powder to the liquid is (0.5-5): 95-99.5.

3. The two-pack type makeup remover according to claim 1 or 2, wherein the mass percentage of the makeup removing component in the liquid agent is 5-10%.

4. The two-part makeup remover formulation according to any one of claims 1-3, wherein the liquid agent further comprises any one or a combination of at least two of a moisturizer, a skin conditioner, or a preservative;

5. The two-part makeup removing formulation according to any one of claims 1 to 4, wherein the thickener comprises sodium carboxymethyl starch.

6. The two-part makeup remover according to any of claims 1-5, characterized in that the makeup removing component comprises any one or a combination of at least two of PEG-6 caprylic/capric glycerides, polysorbate-20 or polyglycerol-6 caprylate, preferably a combination of PEG-6 caprylic/capric glycerides, polysorbate-20 and polyglycerol-6 caprylate.

7. A two-part makeup remover according to any of claims 4-6, characterized in that the skin conditioning agent comprises any one or a combination of at least two of retinol, soluble collagen or ergothioneine, preferably a combination of retinol, soluble collagen and ergothioneine.

8. The two-part makeup removing formulation according to any one of claims 4 to 7, wherein the humectant comprises glycerin.

9. The method for preparing a two-pack type cleansing preparation according to any one of claims 1 to 8, wherein the method for preparing a powder in the two-pack type cleansing preparation comprises: independently packaging the thickener to obtain the final product;

10. The method for preparing a two-pack type makeup removing preparation according to claim 9, characterized in that the temperature at which the makeup removing component is mixed with water is 40 to 50 ℃;

preferably, before the makeup removing component is mixed with water, the water is mixed with a humectant, and the mixture is kept warm;

preferably, the temperature at which the water is mixed with the humectant is 80-85 ℃;

preferably, the time of heat preservation is 15-25min;