CN1169488A - Anti-bacterial odour-proof and easy-to-remove-dirt fabric, preparation method and products thereof - Google Patents
Anti-bacterial odour-proof and easy-to-remove-dirt fabric, preparation method and products thereof Download PDFInfo
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- CN1169488A CN1169488A CN 96110108 CN96110108A CN1169488A CN 1169488 A CN1169488 A CN 1169488A CN 96110108 CN96110108 CN 96110108 CN 96110108 A CN96110108 A CN 96110108A CN 1169488 A CN1169488 A CN 1169488A
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Abstract
The present invention discloses an anti-bacterial odour-proof and soil-release finished textile and its preparation method, including: using anti-bacterial compound and fluoroblock copolymer to treat textile to form a layer of fast film which is insoluble in water and general organic solvent on the surface of the textile. Said invented textile possesses the advantages of resisting high-temp., good washability, no toxicity for human body, no irritation and safety effect. Said invented textile can be used for making various textiles, sich as clothing, ornaments, bedclothes, medical dressing, etc.. Said textile can be made of natural, artificial or animal fibres.
Description
The present invention relates to a kind of antibacterial deodourizing easy-to-remove-dirt fabric and preparation method thereof.
The antibacterial deodourizing fabric has the disease-prevention health effect, and easy-to-remove-dirt fabric has antifouling and dirt is easy to cleaning function, and the research of antibiotic finish in recent years and soil-releasing finiss is increasing, but does not occur the antibacterial deodourizing easy-to-remove-dirt fabric as yet.
One of purpose of the present invention provides a kind of new antibacterial deodourizing easy-to-remove-dirt fabric, and this antibacterial deodourizing easy-to-remove-dirt fabric has the antibiotic property of high-efficiency broad spectrum, good antifouling and easy detergency ability, excellent washing performance.
Two of purpose of the present invention provides a kind of preparation method of antibacterial deodourizing easy-to-remove-dirt fabric.
Three of purpose of the present invention is that above-mentioned antibacterial deodourizing easy-to-remove-dirt fabric is applied on interior outerwear trousers, towel, socks, decorating cloth, cloth for shoes, the bed with textiles, carpet, air filting material etc.
These and other objects of the present invention will embody by following specific descriptions and illustrate further.
In the antibacterial deodourizing easy-to-remove-dirt fabric of the present invention, fabric face adhesion type (1) antimicrobial compound and fluorinated block copolymer.
R in the formula
1Be alkyl, amido, carboxylic acid group, ester group, aldehyde radical, amide groups, the heterocyclic radical that replaces.
The amount of formula (1) antimicrobial compound accounts for 0.05～10wt% of fabric weight, is preferably 0.5～5%, and best is 1～4%; The amount of fluorinated block copolymer accounts for 0.05～10wt% of fabric weight, is preferably 0.1～1wt%, and best is 0.2～0.6%.
In this application, formula (1) antimicrobial compound can be selected from following compounds;
N-(5-nitro-2-furfurylidene)-3-amido-2-oxazolidinone, N-(5-nitro-2-furfurylidene)-2-be amino to lift phenol, the amino phonetic ketone of N-(5-nitro-2-furfurylidene)-1-amido glycolyurea, N-(5-nitro-2-furfurylidene)-2-, 5-nitro-2 furan carboxyaldehyde contract biguanides, 5-nitro-2 furan carboxyaldehyde semicarbazones, β-(5-nitro-2-furfurylidene amino) acrylamide, β-(5-nitro-2-furfurylidene amino) benzyl acrylate.
The substituent of above compound, the derivative of above compound can be used alone, and can also use with by several compounds.
Fluorinated block copolymer is selected from formula (2) compound in this application:
Scotchgard FC-218, ScotchgardFC-232 Asahigugrd AG-780 etc. have the fluorinated block copolymer of easy decontamination.
Can be used alone fluorinated copolymer, can also several fluoropolymer immixtures.
The present invention realizes by following mechanism.
Formula of the present invention (1) antimicrobial compound and fluorine block polymer have synergy, after two kinds of compounds are applied on the fabric, by Van der Waals force attached on the fabric, baking through oven dry and high temperature, the two fiber surface at fabric forms a kind of polymeric membrane of water insoluble and common organic solvents securely, thereby makes fabric obtain the durable easy detergency ability of antibacterial deodourizing.
Product of the present invention can prepare as follows.
To account for the about 0.05～10wt% of fabric weight earlier, be preferably 0.5～6wt%, formula (1) antimicrobial compound of best is 1～4wt% and account for the about 0.05～10wt% of fabric weight is preferably 0.1～1wt%, and the fluorine block copolymer of best is 0.2-0.6wt% is mixed with the aqueous solution, execute on the fabric then, at temperature 50-150 ℃, be preferably 80-120 ℃ of oven dry, pass through 150-220 ℃ again, be preferably 160-190 ℃ and bake, can adopt this specialty mode commonly used to dry and bake.
In the present invention, fabric can be by natural fabric, animal fiber, chemical fibre separately or the blending woven fabric or the knitted fabric that form, also can be bondedfibre fabric, can make on interior outerwear trousers, cloth for shoes, shoe-pad, socks, diaper, sanltary towel, cap, gloves, towel, the bed with textiles, decorative textile product, hospital gauze, the cloth that stretches tight, air filting material, carpet etc. with this fabric.
It must be noted that in this application, term " fabric " " speech comprises fiber, yarn, line equally, in other words the present invention includes the manufacture method of anti-bacterial fibre, yarn, line and antibiotic odourproof fiber, yarn, line.
In the present invention, can comprise some additives that spinning post-finishing is normal equally.As softener, spices, antioxidant, uvioresistant photo etching, adhesive etc., they measure adding routinely.
Compare prior art, the present invention has following advantage:
1, the present invention has antibiotic, deodorization, mildew-resistant, antifouling, decontaminable multifunctionality.
2, the kind of fabric expands cotton, fiber crops, wool, real silk, acrylic fibers, polyamide fibre, terylene, polypropylene fibre, polyvinyl to.
3, antimicrobial spectrum expands to: gonococcus, staphylococcus aureus, Staphylococcus epidermidis, Escherichia coli, typhoid bacillus, shigella dysenteriae, Pseudomonas aeruginosa, hay bacillus, Candida albicans, red mentagrophytes, floccus mentagrophyte; Both can be antifouling, decontamination easily again when washing.
4, the antibiotic easy clean effect of the present invention is efficiently durable, washs 100 times, and bacteriostasis rate still reaches 100%; Easily decontamination, still reaches more than 2 grades after washing 50 times by initial 5 grades.
5, the present invention is applied widely, can be used for people's clothing, and decoration and bed are gone up with textiles, medical dressing, air filting material, carpet.
6, security of the present invention is good, to nontoxic, non-stimulated, the no allergic reaction of human body.
Below by three examples the present invention is further elaborated, but embodiment only be used for the explanation, can not place restrictions on not scope of the present invention.Example 1:
Test cloth: 21
s* 21
s108 * 58 38 ＂ bleaching polyester-cotton blend khaki
Technological process: bleaching polyester-cotton blend khaki → leach mill solution → dry → bake
Process conditions:
Solution: 5-nitro-2 furan carboxyaldehyde biguanides 10 grams per liter Asahiguard AG-780 40 grams per liters that contract
The speed of a motor vehicle: 40-50 rice/minute: infrared ray: 2 rows, hot-air seasoning: 80-110 ℃, drying cylinder pressure 2Kg/cm
2(carrying out on the LMH424 padding machine) baked 180 ℃ * 2 minutes.Example 2:
Test cloth: the bright blue plain cloth of 45 * 45 110 * 76 T65/C35 polyester-cotton blend:
Technological process: polyester-cotton blend stained clot-h → leach mill solution → dry → bake → tentering
Process conditions: solution:
β-(5-nitro-2-furyl methene) amino acryl amides 30 grams per liters
Scotchgard FC-218 30 grams per liters
* pest-control finishing agent AI 50 grams per liters
* low temperature sticking agent SC-933 50 grams per liters.
The speed of a motor vehicle: 40-50 rice/minute; Hot-air seasoning 80-110 ℃, drying cylinder pressure 2Kg/Cm
2, baked 170-180 ℃ in high temperature tentering (on the CMH703 rapid resin finishing machine, carrying out) 170 ℃ * 2 minutes.
*: for Shandong Province giant dragon chemical industry Co., Ltd produces.
Those skilled in the art can make diversified variation and change according to the disclosed content of the application, for example: change worker's order or the like and all should understand in the application's scope, be subjected to the restriction of claim of the present invention.
Claims (7)
1, a kind of antibacterial deodourizing easy-to-remove-dirt fabric is characterized in that fabric face adhesion type (1) antimicrobial compound and fluorine block copolymer.
R in the formula
1Be alkyl, amido, carboxylic acid group, ester group, aldehyde radical, amide groups, the heterocyclic radical that replaces.
2, a kind of antibacterial deodourizing easy-to-remove-dirt fabric as claimed in claim 1, its Chinese style (1) compound is selected from:
The amino phonetic ketone of N-(5-nitro-2-furfurylidene)-3-amido-2-oxazolidinone, N-(5-nitro-2-furfurylidene)-2-amino-phenol, N-(5-nitro-2-furfurylidene)-1-amido glycolyurea, N-(5-nitro-2-furfurylidene)-2-, 5-nitro-2 furan carboxyaldehyde contract biguanides, 5-nitro-2 furan carboxyaldehyde semicarbazones, β-(5-nitro-2-furfurylidene amino) acrylamide, β-(5-nitro-2-furfurylidene amino) benzyl acrylate.
3, a kind of antibacterial deodourizing easy-to-remove-dirt fabric as claimed in claim 1, wherein fluorinated block copolymer is selected from formula (2) compound:
Scotchgard FC-218, ScotchgardFC-232 Asahiguard AG-780 etc. have the fluorinated block copolymer of easy decontamination.
4, a kind of preparation method of antibacterial deodourizing easy-to-remove-dirt fabric is characterized in that the fluorinated block copolymer that will account for fabric weight 0.5～10wt% is mixed with the aqueous solution, is applied on the fabric, and oven dry between 50-120 ℃ then bakes at 140～190 ℃ again.
5, the antibacterial deodourizing process for making such fabric of claim 4 is characterized in that applying method can be to pad or submersion dehydration, can also be spraying.
6, antibacterial deodourizing easy-to-remove-dirt fabric as claimed in claim 1 is characterized in that described fabric can be by natural fabric, animal fiber, chemical fibre separately or the blending woven fabric or the knitted fabric that form, also can be bondedfibre fabric.
7, antibacterial deodourizing fabric as claimed in claim 1 is characterized in that can making on interior outerwear trousers, cloth for shoes, socks, diaper, sanltary towel, cap, gloves, towel, the bed with textiles, decorative textile product, hospital gauze stretch tight cloth, air filting material, carpet with this fabric.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96110108A CN1113132C (en) | 1996-07-03 | 1996-07-03 | Anti-bacterial odour-proof and easy-to-remove-dirt fabric, preparation method and products thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96110108A CN1113132C (en) | 1996-07-03 | 1996-07-03 | Anti-bacterial odour-proof and easy-to-remove-dirt fabric, preparation method and products thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1169488A true CN1169488A (en) | 1998-01-07 |
| CN1113132C CN1113132C (en) | 2003-07-02 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96110108A Expired - Fee Related CN1113132C (en) | 1996-07-03 | 1996-07-03 | Anti-bacterial odour-proof and easy-to-remove-dirt fabric, preparation method and products thereof |
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| Country | Link |
|---|---|
| CN (1) | CN1113132C (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102978922A (en) * | 2012-12-10 | 2013-03-20 | 杭州富兴地毯有限公司 | Water resistance treatment method and equipment for plant fiber carpet |
| CN103015167A (en) * | 2012-12-24 | 2013-04-03 | 王建波 | Multifunctional cool shirt |
| CN103556466A (en) * | 2013-11-04 | 2014-02-05 | 吴江市祥盛纺织品有限公司 | Composite anti-fouling flannelette |
| CN103717800A (en) * | 2011-05-26 | 2014-04-09 | 吉姆诺布莱恩有限公司 | Method for processing silk fiber |
| CN103726295A (en) * | 2013-12-25 | 2014-04-16 | 西安工程大学 | Finishing method of cotton-polyester blended fabric with antibacterial, hydrophobic and antifouling functions |
| CN105755822A (en) * | 2016-02-29 | 2016-07-13 | 苏州印丝特纺织数码科技有限公司 | Preparation method and application of antibacterial easy-decontamination finishing agent |
| CN106149130A (en) * | 2016-08-12 | 2016-11-23 | 山东滨州亚光毛巾有限公司 | A kind of controlled antibacterial towel of argentiferous chelating acrylic fiber and preparation method thereof |
| CN107419366A (en) * | 2017-08-18 | 2017-12-01 | 东华大学 | A kind of coloured anti-bacterial acrylic fibers and preparation method thereof |
| CN107419367A (en) * | 2017-08-18 | 2017-12-01 | 东华大学 | A kind of antibacterial acrylic fibre and preparation method thereof |
| CN107460675A (en) * | 2017-08-07 | 2017-12-12 | 稳健医疗用品股份有限公司 | All cotton non-woven fabric wet cloth functional finishing method |
| CN114685479A (en) * | 2020-12-30 | 2022-07-01 | 南方科技大学 | Oxazolidinone compound and preparation method and application thereof |
-
1996
- 1996-07-03 CN CN96110108A patent/CN1113132C/en not_active Expired - Fee Related
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103717800A (en) * | 2011-05-26 | 2014-04-09 | 吉姆诺布莱恩有限公司 | Method for processing silk fiber |
| CN103717800B (en) * | 2011-05-26 | 2015-08-19 | 吉姆诺布莱恩有限公司 | The processing method of silk fiber |
| CN102978922A (en) * | 2012-12-10 | 2013-03-20 | 杭州富兴地毯有限公司 | Water resistance treatment method and equipment for plant fiber carpet |
| CN102978922B (en) * | 2012-12-10 | 2015-06-03 | 杭州富兴地毯有限公司 | Water resistance treatment method and equipment for plant fiber carpet |
| CN103015167B (en) * | 2012-12-24 | 2016-05-25 | 王建波 | A kind of multi-functional cool feeling shirt |
| CN103015167A (en) * | 2012-12-24 | 2013-04-03 | 王建波 | Multifunctional cool shirt |
| CN103556466A (en) * | 2013-11-04 | 2014-02-05 | 吴江市祥盛纺织品有限公司 | Composite anti-fouling flannelette |
| CN103726295A (en) * | 2013-12-25 | 2014-04-16 | 西安工程大学 | Finishing method of cotton-polyester blended fabric with antibacterial, hydrophobic and antifouling functions |
| CN103726295B (en) * | 2013-12-25 | 2016-03-02 | 西安工程大学 | There is polyester cotton method for sorting that is antibacterial, hydrophobic and anti-pollution function |
| CN105755822A (en) * | 2016-02-29 | 2016-07-13 | 苏州印丝特纺织数码科技有限公司 | Preparation method and application of antibacterial easy-decontamination finishing agent |
| CN105755822B (en) * | 2016-02-29 | 2017-11-28 | 苏州印丝特纺织数码科技有限公司 | A kind of preparation method and application of antibacterial soil-releasing finishing agent |
| CN106149130A (en) * | 2016-08-12 | 2016-11-23 | 山东滨州亚光毛巾有限公司 | A kind of controlled antibacterial towel of argentiferous chelating acrylic fiber and preparation method thereof |
| CN107460675A (en) * | 2017-08-07 | 2017-12-12 | 稳健医疗用品股份有限公司 | All cotton non-woven fabric wet cloth functional finishing method |
| CN107419366A (en) * | 2017-08-18 | 2017-12-01 | 东华大学 | A kind of coloured anti-bacterial acrylic fibers and preparation method thereof |
| CN107419367A (en) * | 2017-08-18 | 2017-12-01 | 东华大学 | A kind of antibacterial acrylic fibre and preparation method thereof |
| CN107419367B (en) * | 2017-08-18 | 2019-08-16 | 东华大学 | A kind of antibacterial acrylic fibre and preparation method thereof |
| CN107419366B (en) * | 2017-08-18 | 2019-08-20 | 东华大学 | A kind of coloured anti-bacterial acrylic fibers and preparation method thereof |
| CN114685479A (en) * | 2020-12-30 | 2022-07-01 | 南方科技大学 | Oxazolidinone compound and preparation method and application thereof |
| CN114685479B (en) * | 2020-12-30 | 2023-11-24 | 南方科技大学 | Oxazolidinone compound as well as preparation method and application thereof |
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| Publication number | Publication date |
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| CN1113132C (en) | 2003-07-02 |
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