CN103015167A - Multifunctional cool shirt - Google Patents
Multifunctional cool shirt Download PDFInfo
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- CN103015167A CN103015167A CN2012105674783A CN201210567478A CN103015167A CN 103015167 A CN103015167 A CN 103015167A CN 2012105674783 A CN2012105674783 A CN 2012105674783A CN 201210567478 A CN201210567478 A CN 201210567478A CN 103015167 A CN103015167 A CN 103015167A
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Abstract
The invention relates to the field of clothing, in particular to a medical textile with an antibacterial function. The medical textile is characterized in that a silver ion antibacterial agent, a soil release finishing agent and a permethrin mosquito prevention finishing agent are adopted to treat the textile, so that the textile has antibacterial, soil release and mosquito prevention functions. The processing steps are as follows: fabric is pretreated, a finishing solution with antibacterial, soil release and mosquito prevention functions is prepared, a working solution is padded, and the fabric is dried, baked, packaged, and made into loungewear. The medical textile has a broad-spectrum and efficient antibacterial action on multiple harmful bacteria such as staphylococcus aureus, pneumobacillus, colibacillus, pseudomonas aeruginosa, candida sporogenes and trichophyton mentagrophytes, the antibacterial rate to the harmful bacteria such as staphylococcus aureus is still above 99% after the medical textile is washed for 100 times, the staying and biting of mosquitoes can be reduced effectively, the medical textile has repellent and contact actions on various mosquitoes such as culex, aedes aegypti, ticks and bugs, and the loungewear made of the fabric has obvious antibacterial, deodorization, relieving itching and mosquito prevention functions.
Description
Technical field
The present invention relates to a kind of multifunctional dress, particularly a kind ofly nurse skin, automatically regulate the multi-functional cool feeling shirt of temperature.
Background technology
Medical textile is the important medium of inside-hospital infection, traditional medical textile is the common cotton fabric mostly, in the ward, be flooded with various pathogens, propagate by skin, respiratory tract alimentary canal and genital tract mucous membrane etc., cause cross-infection rate high, especially this problem of Burn Ward, intensive care unit, medical ward and pediatric ward is even more serious.These malignant bacteria reproduction speeds are fast especially, and every 20min breeds once with the speed of geometric progression, and a bacterium just can breed 1,600,000 offsprings in 8 hours.
Germ not only affects patient's rehabilitation, the health that is also threatening we medical personnel simultaneously.When the SARS in 2003 attacks, we how many medical workers ignore individual safety, be punched in the war of resistance one line, but a large amount of medical personnel are infected, let us has to introspect our protected working, what are there as the protective action of the medical care of medical personnel's barrier clothes actually? obviously answer is not fully up to expectations.Medical textile is the important medium of inside-hospital infection, traditional medical textile is the common cotton fabric mostly, although all can satisfy instructions for use at aspects such as anti-sterilization, washing resistance, antistatic behaviour, tear resistance and comfortablenesses, but lack vital every bacterium property, its space is large, and fine hair is many, does not have water, can't stop germ contamination, its top layer fine hair is collected the effect of bacterium in addition.And traditional disinfection, it is aseptic only to guarantee just to have gone out the laundry, can grow a large amount of bacteriums again after several hours.
In the process of propagating pathogen, textiles is one of important medium, infects such as the MRSA in the hospital and is an example.If textiles has the function of killing pathogen, not only blocked the spread of germs approach, also stoped the foul smell that is produced by dirt on its breeding and the decomposition textiles.Secondly, people always think the bacterium on the textiles, after washing can as contamination can remove significantly, actually this is not so, test shows, still has a large amount of bacteriums on the hot wash cloth cover.
In addition, virus, bacterium that the mosquito of hospital, acarid etc. are propagated more increase the probability of cross infection.The multifunctional medical textiles that does not at present also have antibiotic, easy decontamination and mosquito proof.
Summary of the invention
The objective of the invention is to overcome above-mentioned the deficiencies in the prior art, provide a kind of when contacting with human body, can produce nice and cool sensation, low 1-2 ℃ of the comparable common cloth of temperature, and can not produce any peculiar smell, have anti-nursing skin, bite by mosquitos function, can effectively reduce the multi-functional cool feeling shirt of bite by mosquitos.
The present invention can reach by following measure:
A kind of multi-functional cool feeling shirt is characterized in that at cotton cloth, silk weaving cloth, chemical fiber fabric and cotton, silk and the mixed material of weaving cotton cloth of chemical fibre behind dyeing or printing technology, dipping, making of drying in Multifunctional finishing liquid, and its processing technology step is:
Step 1, cloth are processed into the semi-products cloth through pre-treatment, dyeing or stamp,
Step 2, the semi-products cloth is being padded Multifunctional finishing liquid, employing one is soaked one and is rolled, liquid carrying rate is 85-95%, Multifunctional finishing liquid is xylitol by main component, fibroin, the endecatylene acid glyceride, hydrophilic silicon oil, Permethrin, the mosquito proof finishing agent, crosslinking agent and softener form, the weight portion of respectively giving into composition is: xylitol 20-30 part, fibroin 3-5 part, endecatylene acid glyceride 5-8 part, hydrophilic silicon oil 5-10 part, Permethrin 3-5 part, mosquito proof finishing agent 40-50 part, crosslinking agent 5-8 part, softener 5-8 part, described mosquito proof finishing agent is by common fig leaf juice, tarragon, rhizoma atractylodis, the root of Dahurain angelica, cloves, eupatorium, wrinkled giant hyssop, sesame oil, calamus, camphorated oil, lavender, aloe, common nepenthes, thunder godvine, Zhu Kui forms, the weight portion of each composition is common fig leaf juice 15-20 part, tarragon 10-20 part, rhizoma atractylodis 3-6 part, root of Dahurain angelica 5-8 part, cloves 7-9 part, eupatorium 3-5 part, wrinkled giant hyssop 2-3 part, sesame oil 1-2 part, calamus 3-6 part, camphorated oil 1-2 part, lavender 5-7 part, aloe powder 10-15 part, common nepenthes 5-7 part, thunder godvine 6-8 part, Zhu Kui 4-6 part
Step 3, oven dry, bake out temperature 100-120 ℃, time 2-3min,
Step 4, with the oven dry fabric make shirt.
The processing technology of mosquito proof finishing agent of the present invention is: get by weight raw material, common fig leaf juice 15-20 part, tarragon 10-20 part, rhizoma atractylodis 3-6 part, root of Dahurain angelica 5-8 part, cloves 7-9 part, eupatorium 3-5 part, wrinkled giant hyssop 2-3 part, sesame oil 1-2 part, calamus 3-6 part, camphorated oil 1-2 part, lavender 5-7 part, aloe powder 10-15 part, common nepenthes 5-7 part, thunder godvine 6-8 part, Zhu Kui 4-6 part is put into container after mixing, add water in the container and do not have raw material, soak after 1-2 hour, after putting into high-pressure bottle 1-2 hour, filter to get extract
Contain the materials such as fumaric acid, butanedioic acid, the third acetic acid, oxalic acid, quininic acid in the common fig leaf juice of the present invention, have the effects such as anti-inflammation detumescence, detoxifcation pain relieving; The tarragon flavor is hot, bitter, warm in nature; Return spleen, liver, kidney channel; The fragrance temperature is loose, can rise and can fall; Has warming channel for arresting bleeding, eliminating cold to stop pain, the effect of wet down desinsection; Rhizoma atractylodis are controlled wet the Sheng and are stranded spleen, burnout is had a liking for sleeping, gastral cavity ruffian abdominal distension, oedema, the time gas flu, wind-cold-dampness arthralgia, has treatment diseases caused by external factors damp-warm syndrome, the effect of painful swelling of joints, the root of Dahurain angelica is hot, and temperature is returned lung, the stomach warp, cure mainly expelling wind and clearing away cold, understand things pain-stopping, the apocenosis of invigorating blood circulation, pruitus, anti-inflammatory, the effects such as antipyretic-antalgic, cloves has in the temperature, warm kidney, contrary effect is fallen, eupatorium has treatment to accumulate in moistening, sweet greasy in mouthful, turbi damp obstructing in middle-JIAO, halitosis, the effect of summer-heat and damp table disease, wrinkled giant hyssop are usually used in the wet turbid poor appetite that causes of stomach of spleen, thick libngual fur is greasy, and peppermint has refrigerant, antipruritic, anti-inflammatory, the effect of pain relieving, energy chafe nerve endings receptor, produce first cool sensation, can stimulating central nervous system, make telangiectasis on every side and dispel the heat; And promote sweat gland secretion and sweating, and therefore there are the hypothermic effect of falling, sesame oil to contain abundant vitamin e, often be called the vitamin that prevents aging by people again.It is to improving blood circulation, enhance metabolism and produce effect, calamus contains beta-Asarone, α-asarone, amino acid, organic acid and carbohydrate, central inhibitory action is arranged, dermatophyte there is inhibitory action, but camphorated oil Anti-moth-eating, anti-cockroach, healing of wound, the functions such as deodorizing, the pure and fresh gracefulness of lavender fragrance, character is gentle, has calmness, releive, the plant of syngignoscism has the calm mind, calm down pneumostatic, healing of wound, remove scar, anti-inflammatory often is used as beauty treatment and anti-inflammatory articles for use, and aloe is adjusting immunity of human body comprehensively, promote cytothesis, stimulate circulation, get rid of vivotoxin, can also treat scytitis, to acne, freckle, acne and scald, knife wound, insect bites etc. also have good curative effect, and common nepenthes has anti-inflammatory, detoxifcation, insect protected is bitten etc., and thunder godvine has dispels rheumatism, promoting blood circulation and removing obstruction in channels, swelling and pain relieving, the effect of desinsection detoxifcation, Zhu Kui has antibacterial action and kills (pressing down) bacterium effect
Above-mentioned each component has environmental-friendly natural, is specially adapted to make the shirt in summer, has following advantageous effect with its making shirt in summer: the one, have the effect of moistening gentle human skin; The 2nd, cool and comfortable can make skin surface temperature lower about 2 ℃ than traditional shirt, also can obtain the sensation of cool and comfortable in hot summer; The 3rd, mosquito proof is bitten, fragrant odour, and the 4th, function is lasting, and is water-fastness, can not reduce because of repeatedly washing function; The 4th, soft smooth, comfort level is splendid; The 5th, antibiotic anti-peculiar smell can effectively prevent from keeping pure and fresh clothing environment because of various bacteriums and the abnormal smell of body of sweat generation.
The specific embodiment
The invention will be further described below in conjunction with embodiment.
Embodiment 1, a kind of multi-functional cool feeling shirt is characterized in that at the mixed material of weaving cotton cloth of cotton cloth, silk weaving cloth, chemical fiber fabric and cotton, silk and chemical fibre dipping, oven dry are made in Multifunctional finishing liquid behind dyeing or printing technology, and its processing technology step is:
Step 1, cloth are processed into the semi-products cloth through pre-treatment, dyeing or stamp,
Step 2, the semi-products cloth is being padded Multifunctional finishing liquid, employing one is soaked one and is rolled, liquid carrying rate is 85%, Multifunctional finishing liquid is xylitol by main component, fibroin, the endecatylene acid glyceride, hydrophilic silicon oil, Permethrin, the mosquito proof finishing agent, crosslinking agent and softener form, the weight portion of respectively giving into composition is: 20 parts of xylitols, 3 parts of fibroins, 5 parts of endecatylene acid glycerides, 5 parts of hydrophilic silicon oil, 3 parts of Permethrins, 40 parts of mosquito proof finishing agents, 5 parts of crosslinking agents, 5 parts of softeners, described mosquito proof finishing agent is by common fig leaf juice, tarragon, rhizoma atractylodis, the root of Dahurain angelica, cloves, eupatorium, wrinkled giant hyssop, sesame oil, calamus, camphorated oil, lavender, aloe, common nepenthes, thunder godvine, Zhu Kui forms, the weight portion of each composition is 15 parts of common fig leaf juicves, 10 parts of tarragons, 3 parts of rhizoma atractylodis, 5 parts of the roots of Dahurain angelica, 7 parts of cloves, 3 parts of eupatoriums, 2 parts of wrinkled giant hyssops, 1 part in sesame oil, 3 parts of calamus, 1 part of camphorated oil, 5 parts of lavenders, 10 parts of aloe powders, 5 parts of common nepenthes, 6 parts of thunder godvines, 4 parts of Zhu Kui
The processing technology of described mosquito proof finishing agent is: gets by weight raw material, raw material put into container, add water in the container and do not have raw material, soak after 1-2 hour, put into high-pressure bottle after 1 hour, filter to get extract,
Step 3, oven dry, 100 ℃ of bake out temperatures, time 2min,
Step 4, with the oven dry fabric make shirt.
Embodiment 2, a kind of multi-functional cool feeling shirt is characterized in that at the mixed material of weaving cotton cloth of cotton cloth, silk weaving cloth, chemical fiber fabric and cotton, silk and chemical fibre dipping, oven dry are made in Multifunctional finishing liquid behind dyeing or printing technology, and its processing technology step is:
Step 1, cloth are processed into the semi-products cloth through pre-treatment, dyeing or stamp,
Step 2, the semi-products cloth is being padded Multifunctional finishing liquid, employing one is soaked one and is rolled, liquid carrying rate is 95%, Multifunctional finishing liquid is xylitol by main component, fibroin, the endecatylene acid glyceride, hydrophilic silicon oil, Permethrin, the mosquito proof finishing agent, crosslinking agent and softener form, the weight portion of respectively giving into composition is: 30 parts of xylitols, 5 parts of fibroins, 8 parts of endecatylene acid glycerides, 10 parts of hydrophilic silicon oil, 5 parts of Permethrins, 50 parts of mosquito proof finishing agents, 8 parts of crosslinking agents, 8 parts of softeners, described mosquito proof finishing agent is by common fig leaf juice, tarragon, rhizoma atractylodis, the root of Dahurain angelica, cloves, eupatorium, wrinkled giant hyssop, sesame oil, calamus, camphorated oil, lavender, aloe, common nepenthes, thunder godvine, Zhu Kui forms, the weight portion of each composition is 20 parts of common fig leaf juicves, 20 parts of tarragons, 6 parts of rhizoma atractylodis, 8 parts of the roots of Dahurain angelica, 9 parts of cloves, 5 parts of eupatoriums, 3 parts of wrinkled giant hyssops, 2 parts in sesame oil, 6 parts of calamus, 2 parts of camphorated oils, 7 parts of lavenders, 15 parts of aloe powders, 7 parts of common nepenthes, 8 parts of thunder godvines, 6 parts of Zhu Kui
The processing technology of described mosquito proof finishing agent is: gets by weight raw material, raw material put into container, add water in the container and do not have raw material, soak after 2 hours, put into high-pressure bottle after 2 hours, filter to get extract,
Step 3, oven dry, 120 ℃ of bake out temperatures, time 3min,
Step 4, with the oven dry fabric make shirt.
Embodiment 3, a kind of multi-functional cool feeling shirt is characterized in that at the mixed material of weaving cotton cloth of cotton cloth, silk weaving cloth, chemical fiber fabric and cotton, silk and chemical fibre dipping, oven dry are made in Multifunctional finishing liquid behind dyeing or printing technology, and its processing technology step is:
Step 1, cloth are processed into the semi-products cloth through pre-treatment, dyeing or stamp,
Step 2, the semi-products cloth is being padded Multifunctional finishing liquid, employing one is soaked one and is rolled, liquid carrying rate is 90%, Multifunctional finishing liquid is xylitol by main component, fibroin, the endecatylene acid glyceride, hydrophilic silicon oil, Permethrin, the mosquito proof finishing agent, crosslinking agent and softener form, the weight portion of respectively giving into composition is: 25 parts of xylitols, 4 parts of fibroins, 6 parts of endecatylene acid glycerides, 7 parts of hydrophilic silicon oil, 4 parts of Permethrins, 45 parts of mosquito proof finishing agents, 6 parts of crosslinking agents, 7 parts of softeners, described mosquito proof finishing agent is by common fig leaf juice, tarragon, rhizoma atractylodis, the root of Dahurain angelica, cloves, eupatorium, wrinkled giant hyssop, sesame oil, calamus, camphorated oil, lavender, aloe, common nepenthes, thunder godvine, Zhu Kui forms, the weight portion of each composition is 18 parts of common fig leaf juicves, 15 parts of tarragons, 5 parts of rhizoma atractylodis, 6 parts of the roots of Dahurain angelica, 8 parts of cloves, 4 parts of eupatoriums, 3 parts of wrinkled giant hyssops, 1 part in sesame oil, 4 parts of calamus, 2 parts of camphorated oils, 6 parts of lavenders, 12 parts of aloe powders, 6 parts of common nepenthes, 7 parts of thunder godvines, 5 parts of Zhu Kui
The processing technology of described mosquito proof finishing agent is: get by weight raw material, raw material put into container, add water in the container and do not have raw material, soak after 1-2 hour, put into high-pressure bottle 1-2 hour after, filter to get extract,
Step 3, oven dry, 150 ℃ of bake out temperatures, time 2min,
Step 4, with the oven dry fabric make nightwear.
Embodiment 4, a kind of multi-functional cool feeling shirt is characterized in that at the mixed material of weaving cotton cloth of cotton cloth, silk weaving cloth, chemical fiber fabric and cotton, silk and chemical fibre dipping, oven dry are made in Multifunctional finishing liquid behind dyeing or printing technology, and its processing technology step is:
Step 1, cloth are processed into the semi-products cloth through pre-treatment, dyeing or stamp,
Step 2, the semi-products cloth is being padded Multifunctional finishing liquid, employing one is soaked one and is rolled, liquid carrying rate is 85%, Multifunctional finishing liquid is xylitol by main component, fibroin, the endecatylene acid glyceride, hydrophilic silicon oil, Permethrin, the mosquito proof finishing agent, crosslinking agent and softener form, the weight portion of respectively giving into composition is: 30 parts of xylitols, 3 parts of fibroins, 8 parts of endecatylene acid glycerides, 5 parts of hydrophilic silicon oil, 5 parts of Permethrins, 40 parts of mosquito proof finishing agents, 8 parts of crosslinking agents, 5 parts of softeners, described mosquito proof finishing agent is by common fig leaf juice, tarragon, rhizoma atractylodis, the root of Dahurain angelica, cloves, eupatorium, wrinkled giant hyssop, sesame oil, calamus, camphorated oil, lavender, aloe, common nepenthes, thunder godvine, Zhu Kui forms, the weight portion of each composition is 15 parts of common fig leaf juicves, 20 parts of tarragons, 3 parts of rhizoma atractylodis, 8 parts of the roots of Dahurain angelica, 7 parts of cloves, 5 parts of eupatoriums, 2 parts of wrinkled giant hyssops, 2 parts in sesame oil, 3 parts of calamus, 2 parts of camphorated oils, 5 parts of lavenders, 15 parts of aloe powders, 5 parts of common nepenthes, 8 parts of thunder godvines, 4 parts of Zhu Kui
The processing technology of described mosquito proof finishing agent is: gets by weight raw material, raw material put into container, add water in the container and do not have raw material, soak after 2 hours, put into high-pressure bottle after 1 hour, filter to get extract,
Step 3, oven dry, 100 ℃ of bake out temperatures, time 2min,
Step 4, with the oven dry fabric make underwear.
Claims (2)
1. an antiseptic medical textile is characterized in that with silver ion antimicrobial agent, soil-releasing finishing agent and Permethrin mosquito proof finishing agent textiles being processed, and makes antibiotic, the easy decontamination of its acquisition, anti-mosquito function, and its procedure of processing is:
Arrangement processing after step 1, fabric are waited for after the steps such as pre-treatment, dyeing or stamp are processed into semi-products,
Step 2, prepare antibiotic, easy decontamination and anti-mosquito functions dressing liquid, dressing liquid is by silver ion antimicrobial agent, soil-releasing finishing agent, Permethrin mosquito proof finishing agent and water form, silver ion antimicrobial agent, soil-releasing finishing agent, the percentage by weight of Permethrin mosquito proof finishing agent is: the silver ion antimicrobial agent of 3-5%, the soil-releasing finishing agent of 8-12%, the Permethrin mosquito proof finishing agent of 3-5%, all the other are water, various auxiliary agents are added to the water one by one according to top ratio, the limit edged stirs, be stirred to till the uniform solution, and adjusting working solution pH value is 6-7, the working solution for preparing is injected the groove of padding machine
Step 3, pad working solution, one soaks one rolls, and pick-up is 70%,
Step 4, oven dry, 105 ℃ of temperature, time 1-2min,
Step 5, bake, the fabric of drying is baked, temperature is not more than 140 ℃, and the time is no less than 2min,
Step 6, the fabric that bakes is carried out preshrunk, to obtain better feel, clot packing then,
Step 7, fabric is made home wear miscellaneous.
2.
A kind of multi-functional cool feeling shirt according to claim 1, the processing technology that it is characterized in that the mosquito proof finishing agent is: get by weight raw material, common fig leaf juice 15-20 part, tarragon 10-20 part, rhizoma atractylodis 3-6 part, root of Dahurain angelica 5-8 part, cloves 7-9 part, eupatorium 3-5 part, wrinkled giant hyssop 2-3 part, sesame oil 1-2 part, calamus 3-6 part, camphorated oil 1-2 part, lavender 5-7 part, aloe powder 10-15 part, common nepenthes 5-7 part, thunder godvine 6-8 part, Zhu Kui 4-6 part is put into container after mixing, add water in the container and do not have raw material, soak after 1-2 hour, after putting into high-pressure bottle 1-2 hour, filter to get extract.
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103397520A (en) * | 2013-08-27 | 2013-11-20 | 董海燕 | Vermin-killing mosquito-repellent anti-static biological preparation for fabrics |
| CN103911738A (en) * | 2014-04-11 | 2014-07-09 | 南通龙旗服饰有限公司 | Printed fabric for summer clothes |
| CN105603745A (en) * | 2015-12-22 | 2016-05-25 | 常熟市泽众家用纺织品有限公司 | Jacquard fabric |
| CN106012517A (en) * | 2016-06-24 | 2016-10-12 | 广德毅维纺织有限公司 | Medical-fabric special treating liquid |
| CN106521769A (en) * | 2016-12-22 | 2017-03-22 | 晋江市远大服装织造有限公司 | Cool type fabric weaving process containing xylitol |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1169488A (en) * | 1996-07-03 | 1998-01-07 | 天津服装研究所 | Anti-bacterial odour-proof and easy-to-remove-dirt fabric, preparation method and products thereof |
| CN1548292A (en) * | 2003-05-13 | 2004-11-24 | 上海中大科技发展有限公司 | Multifunctional non-woven composite material and its production process |
| KR20100000549A (en) * | 2008-06-25 | 2010-01-06 | (주)에스엔에스 | Complex agent for wool containing textiles and finishing method using thereby |
| CN101886335A (en) * | 2010-07-15 | 2010-11-17 | 福建鑫华股份有限公司 | Method for manufacturing inflaming-retarding antifouling non-woven decorative material |
| CN102330339A (en) * | 2011-05-25 | 2012-01-25 | 高莉萍 | Functional textile fabric |
| CN102383304A (en) * | 2011-06-22 | 2012-03-21 | 刘骁 | Household textile product with insecticidal effect and processing method thereof |
| CN102628217A (en) * | 2012-04-05 | 2012-08-08 | 王建波 | Antibacterial, mosquito-and-insect-repellent functional loungewear |
-
2012
- 2012-12-24 CN CN201210567478.3A patent/CN103015167B/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1169488A (en) * | 1996-07-03 | 1998-01-07 | 天津服装研究所 | Anti-bacterial odour-proof and easy-to-remove-dirt fabric, preparation method and products thereof |
| CN1548292A (en) * | 2003-05-13 | 2004-11-24 | 上海中大科技发展有限公司 | Multifunctional non-woven composite material and its production process |
| KR20100000549A (en) * | 2008-06-25 | 2010-01-06 | (주)에스엔에스 | Complex agent for wool containing textiles and finishing method using thereby |
| CN101886335A (en) * | 2010-07-15 | 2010-11-17 | 福建鑫华股份有限公司 | Method for manufacturing inflaming-retarding antifouling non-woven decorative material |
| CN102330339A (en) * | 2011-05-25 | 2012-01-25 | 高莉萍 | Functional textile fabric |
| CN102383304A (en) * | 2011-06-22 | 2012-03-21 | 刘骁 | Household textile product with insecticidal effect and processing method thereof |
| CN102628217A (en) * | 2012-04-05 | 2012-08-08 | 王建波 | Antibacterial, mosquito-and-insect-repellent functional loungewear |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103397520A (en) * | 2013-08-27 | 2013-11-20 | 董海燕 | Vermin-killing mosquito-repellent anti-static biological preparation for fabrics |
| CN103397520B (en) * | 2013-08-27 | 2015-07-29 | 董海燕 | Fabric desinsection mosquito-repellent anti-static biologic product |
| CN103911738A (en) * | 2014-04-11 | 2014-07-09 | 南通龙旗服饰有限公司 | Printed fabric for summer clothes |
| CN108697339A (en) * | 2015-12-11 | 2018-10-23 | 健康纺织瑞典公司 | Method and system for monitoring medical garment |
| CN105603745A (en) * | 2015-12-22 | 2016-05-25 | 常熟市泽众家用纺织品有限公司 | Jacquard fabric |
| CN106012517A (en) * | 2016-06-24 | 2016-10-12 | 广德毅维纺织有限公司 | Medical-fabric special treating liquid |
| CN106811961A (en) * | 2016-12-07 | 2017-06-09 | 桐乡市君湖纺织整理有限公司 | A kind of processing method with refreshing function fabric |
| CN106521769B (en) * | 2016-12-22 | 2018-05-01 | 晋江市远大服装织造有限公司 | Cool fabric weaving process containing xylitol |
| CN106521769A (en) * | 2016-12-22 | 2017-03-22 | 晋江市远大服装织造有限公司 | Cool type fabric weaving process containing xylitol |
| CN108824031A (en) * | 2018-07-03 | 2018-11-16 | 常州旭荣针织印染有限公司 | The CDP fabrics fabric dyeing and finishing process with uvioresistant, nice and cool sense of touch, mosquito-proof complex function |
| CN108824031B (en) * | 2018-07-03 | 2023-12-01 | 常州旭荣针织印染有限公司 | Dyeing and finishing process of cation-dyeable polyester fabric with ultraviolet resistance, cool touch and mosquito prevention composite functions |
| CN111395015A (en) * | 2020-04-15 | 2020-07-10 | 淄博大染坊丝绸集团有限公司 | Dyeing and finishing process of real silk fabric for summer wear |
| CN112981663A (en) * | 2021-02-18 | 2021-06-18 | 天津市元生泰科技有限公司 | Novel magnetic balance garment and production method thereof |
| CN115027106A (en) * | 2022-05-19 | 2022-09-09 | 苏州宏洋纺织染整有限公司 | Multifunctional linen-cotton cloth and preparation proportion |
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