CN1049030C - Antiseptic foulness-preventing fabric and its prodn process and product - Google Patents
Antiseptic foulness-preventing fabric and its prodn process and product Download PDFInfo
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- CN1049030C CN1049030C CN96107666A CN96107666A CN1049030C CN 1049030 C CN1049030 C CN 1049030C CN 96107666 A CN96107666 A CN 96107666A CN 96107666 A CN96107666 A CN 96107666A CN 1049030 C CN1049030 C CN 1049030C
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- fabric
- compound
- antibacterial deodourizing
- amido
- antibacterial
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Abstract
The present invention discloses an antibacterial anti-odor fabric and preparation method thereof. In the preparation method, antibacterial compounds with amido and active compounds are used for processing a fabric, and generate firm permanent cross-linkage with the fabric. The fabric has the advantages of high-temperature resistance, washing fastness, no toxicity, stimulation or allergy to human bodies, safe use to the skin, and antibacterial effect on gonococcus, colibacillus, pseudomonas aeruginosa, dysentery bacillus, bacillus enteritidis, bacillus typhi, red ringworm fungi, flocculent ringworm fungi, etc., and the fabric can be used for producing clothes, decorations, bed textiles, stockings, insoles, shoe uppers, medical dressings, air filtering materials, etc.
Description
The invention relates to antibacterial deodourizing fabric and preparation method thereof and prepared product.
The antibacterial deodourizing fabric has the communicate illness of preventing, guarantees the multifunctionality of human body safety and Health, is subjected to people's popular welcome.The research of antibiotic finish in recent years is increasing, and for example Chinese patent application 87100231 discloses complex copper ion and Viride Nitens 4 on acrylic fibers, thereby obtains antibiotic property, but can only obtain the antibacterial acrylic fibre fabric.And color and luster is green.Chinese patent application CN1048846 also discloses with a kind of quaternary ammonium compound and has handled fabric, thereby obtains antibiotic property, but it just loses antibacterial action to fungies such as Candida albicans, red mentagrophytes, floccus mentagrophytes after washing 40 times.
One of purpose of the present invention provides a kind of new antibacterial deodourizing fabric, and this antibacterial deodourizing fabric expands cotton, real silk, wool, fiber crops, polyamide fibre, acrylic fibers, terylene, polypropylene fibre to separately or on the BLENDED FABRIC, and has a broad antifungal spectrum, and wash resistant reaches more than 200 times.
Two of purpose of the present invention provides a kind of new antibacterial deodourizing process for making such fabric.
Three of purpose of the present invention is that above-mentioned antibacterial deodourizing fabric applications is used textiles, air filting material etc. on interior outerwear trousers, towel, socks, cloth for shoes, bed.
These and other objects of the present invention will embody by following specific descriptions and illustrate further.
In antibacterial deodourizing fabric of the present invention, on fabric, be connected to the antimicrobial compound of band amido and reactive compound group respectively with A-R-B structure, this reactive compound both can with the hydroxyl on the fabric, the amido reaction can be reacted with above-mentioned antimicrobial compound again, and the two amount on fabric is 0.1-10wt%, in reactive compound, A, B be can with hydroxyl, the amido reactive activity group on the fiber, R is alkyl, substituted alkyl, aryl, substituted aryl, cyclic hydrocarbon radical or heterocyclic radical.
Antimicrobial compound can for:
Wherein, R
1, R
2, R
3Be respectively H, the alkyl of 1-12 carbon atom, substituted alkyl, the aryl of 6-12 carbon atom, substituted aryl and heterocyclic radical, carboxyl, ester group, amide groups and guanidine radicals, R
1, R
2, R
3Can be identical or inequality;
X, Y are respectively O, S, N, can be identical or inequality.
Antimicrobial compound can for:
R
1Definition the same.Antimicrobial compound can for:
Wherein, R
3, R
4Be H, the alkyl of 1-12 carbon atom, aryl or halogen.
Antimicrobial compound can for:
Reactive compound can for:
Wherein, n=1-3.
Reactive compound can for:
Wherein, X is Cl, F, R
1For amido, alkoxyl, Cl, F,
Reactive compound can be halogen substituted pyrimidines compound, and the halogen element is got for Evil quinoline compound, many N-methylol compound, many epoxy ethyls compound.
Further, antimicrobial compound for example can be tetrabromo carbanilide, chlorhexidine, pyridine radicals dithiocarbamate ethyl ester, the dichloro carbanilide, N-methyl-N '-(dichloro fluorine methyl mercapto) urea, tetrabromo carbanilide, benzimidazole amido butyl formate, 2-(a fluorine dichloromethane sulfenyl) benzimidazole, 2-(4 '-thiazolyl) benzimidazole, benzimidazole glycine phenyl ester, 2-(dichlorophenyl) benzimidazole; 2-methyl benzo isothiazolinone, 2-methyl-4-acetyl group benzo isothiazolinone, 5-acetyl group isothiazolinone, 5-furyl isothiazolinone, 2,4-dichloro benzo isothiazolinone; The Ciprofloxacin methyl esters, fluorine pyridine acid, fluorine pyridine acid amides; Trimethoprim, furantoin; Sulphadiazine, flamazine, sulfasalazine, NU-445, Ambamide, sulfamethoxypyridazine, sulphathiazole, sulphoamidine.
Active compound can for: hydroxyl is for dimethyl hydroxyl time ethyl urea, ethylene glycol sex change melamine, the equal diazine of dichloro, one fluorine dichloro s-triazine, trichloro-triazine, 2,4-dichloro pyrimidine-5-phosgene, 2,3-dichloro quinoxaline-6-formyl chloride, N-N '-=beta-hydroxyethyl sulfuric ester ethylenediamine, three '-aziridino phosphates, acryloyl chloride, the propylene bromide acyl chlorides, 1,3,5-trimethoxy propionyl perhydro triazine, methylsulfonyl dichloro pyrimidine, difluoro one chlorine pyrimidine etc.
Product of the present invention can prepare as follows.
At first taking by weighing antimicrobial compound by proportional quantity, be made into the aqueous solution, then in the mode of padding, can be to soak one to roll or two soak two and roll, and pick-up rate is 75% to affact on the fabric oven dry then.And then use the reactive compound coating or the spraying of proportional quantity,, baked 2～5 minutes at 160～165 ℃ then, be finished product 80～110 ℃ of oven dry.
In the present invention, fabric can be by natural fabric, animal fiber, chemical fibre is independent or blending forms woven fabric or knitted fabric, also can be bondedfibre fabric, can make on interior outerwear trousers, cloth for shoes, shoe-pad, socks, diaper, sanltary towel, cap, gloves, towel, the bed with textiles, decorative textile product, hospital gauze, bandage, air filting material etc. with this fabric.
It must be noted that in this application, term " fabric " " speech comprises fiber, yarn, line equally, in other words the present invention includes the manufacture method of anti-bacterial fibre, yarn, line and antibiotic odourproof fiber, yarn, line.
In the present invention, can comprise some additives that spinning post-finishing is commonly used equally, as softener, catalyst (as release acidity or release alkali compounds and peroxide), spices, antioxidant, uvioresistant photo etching, adhesive etc., they add with convention amount.
Compare prior art, the present invention has following advantage:
1, the kind of fabric expands to: cotton, fiber crops, wool, real silk, acrylic fibers, polyamide fibre, terylene, polypropylene fibre, polyvinyl etc.
2, antimicrobial spectrum expands to: gonococcus, staphylococcus aureus, Staphylococcus epidermidis, Escherichia coli, typhoid bacillus, shigella dysenteriae, Pseudomonas aeruginosa, hay bacillus, Candida albicans, red mentagrophytes, floccus mentagrophyte etc.
3, antibacterial effect of the present invention is efficiently durable, washs 100 times, and bacteriostasis rate still reaches more than 99.9%.
4, the present invention is applied widely, can be used for people's clothing, and decoration and bed are gone up and used textiles, medical dressing, air filting material.
5, security of the present invention is good, to nontoxic, non-stimulated, the no allergic reaction of human body.
In the present invention, if not refer in particular to, all percentage, part all is weight percentage weight portion.
The invention will be further described by the following examples, but embodiment only is used for explanation, can not place restrictions on scope of the present invention.
Example 1:
Test cloth: textile plain " is bleached in 21 ＇ * 21 ＇ 60 * 58 36
Technological process: → 160～165 ℃ of bleached cotton fabric → pad antimicrobial compound solution → oven dry → spraying reactive compound body lotion → 110 ℃ oven dry baked 2～5 minutes.
Antimicrobial compound solution comprises:
Sulphadiazine 3Kg
Benzimidazole amido formamide 2Kg
Water (deionization) 95kg
Active compounds solution comprises:
N ', N '-two beta-hydroxyethyl sulfuric ester phenylenediamine 5Kg
*Coating agent SJ-959 40Kg
*Thickener SJ-958 54.5Kg
* *Softener SJ-950 0.5Kg
*: the strong biochemical worker in Qingdao Co., Ltd produces, and Main Ingredients and Appearance is polyacrylate and polyurethane.
*: the strong biochemical worker in Qingdao Co., Ltd produces, and Main Ingredients and Appearance is the ammonium salt of acrylic acid and methacrylic acid copolymer.
* *: the strong biochemical worker in Qingdao Co., Ltd produces.
The amount of antimicrobial compound on fabric is 8% of fabric gross weight, and the amount of reactive compound on fabric is 7.5% of fabric gross weight.
Example 2:
Test cloth: textile pink towel cloth
Technological process: cotton towel cloth → dipping antimicrobial compound solution → dehydration → 110 ℃, oven dry → dipping active compounds solution → 120 ℃, oven dry in 5 minutes.
Antimicrobial compound solution comprises:
2-(a fluorine dichloromethane sulfenyl) benzimidazole 5Kg
Deionized water 95Kg
Active compounds solution comprises:
2.4-dichloro pyrimidine-5-phosgene 3Kg
Soda ash 1Kg
Water 96Kg
Antimicrobial compound and the reactive compound amount on fabric is respectively 5% of fabric gross weight.
Example 3:
Test cloth: polyester-cotton fabric
Technological process: polyester-cotton fabric → dipping antimicrobial compound solution and active compounds solution → oven dry → tentering → finished product
Pick-up rate is 75%, and the tentering temperature is 170～180 ℃, and the time is 20 seconds.
Solution comprises:
Fluorine pyridine acid methyl esters 6Kg
N-methylolacrylamide 3Kg
*Insect-proof agent AI 5Kg
*Low temperature sticking agent SJ-953 3Kg
Ammonium persulfate 0.5Kg
Deionized water 82.5Kg
Antimicrobial compound and the reactive compound amount on fabric is respectively 9.1% of fabric gross weight.
*, * *Be the strong biochemical plant in Qingdao product.
Claims (9)
1, a kind of antibacterial deodourizing fabric, it is characterized in that on fabric, being connected to respectively the antimicrobial compound of band amido and reactive compound group with A-R-B structure, this reactive compound both can with the hydroxyl on the fabric, the amido reaction can be reacted with above-mentioned antimicrobial compound again, and the two amount on fabric is 0.1-10wt%, in reactive compound, A, B be can with hydroxyl, the amido reactive activity group on the fiber, R is alkyl, substituted alkyl, aryl, substituted aryl, cyclic hydrocarbon radical or heterocyclic radical.
2, antibacterial deodourizing fabric as claimed in claim 1, it is characterized in that described antimicrobial compound can for:
Wherein, R
1, R
2, R
3Be respectively H, the alkyl of 1-12 carbon atom, substituted alkyl, the aryl of 6-12 carbon atom, substituted aryl and heterocyclic radical, carboxyl, ester group, amide groups and guanidine radicals, R
1, R
2, R
3Can be identical or inequality;
X, Y are respectively O, S, N, can be identical or inequality.
3, antibacterial deodourizing fabric as claimed in claim 1, it is characterized in that described antimicrobial compound can for:
R
1Definition the same.
4, antibacterial deodourizing fabric as claimed in claim 1, it is characterized in that described antimicrobial compound can for:
Wherein, R
3, R
4Be H, the alkyl of 1-12 carbon atom, aryl or halogen.
5, antibacterial deodourizing fabric as claimed in claim 1 is characterized in that described antibiotic
6, antibacterial deodourizing fabric as claimed in claim 1, it is characterized in that described reactive compound can for:
Wherein, n=1-3.
7, antibacterial deodourizing fabric as claimed in claim 1 is characterized in that described activity
Wherein, X is Cl, F, R
1For amido, alkoxyl, Cl, F,
8, antibacterial deodourizing fabric as claimed in claim 1 is characterized in that described reactive compound can be halogen substituted pyrimidines compound, and the halogen element is got for Evil quinoline compound, many N-methylol compound, many epoxy ethyls compound.
9, antibacterial deodourizing process for making such fabric as claimed in claim 1 is characterized in that at first antimicrobial compound being affacted on the fabric with the form of padding (pick-up rate 75%), then oven dry; And then use the reactive compound coating,,, baked 2～5 minutes then at 160～165 ℃ 80～110 ℃ of oven dry.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96107666A CN1049030C (en) | 1996-06-17 | 1996-06-17 | Antiseptic foulness-preventing fabric and its prodn process and product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96107666A CN1049030C (en) | 1996-06-17 | 1996-06-17 | Antiseptic foulness-preventing fabric and its prodn process and product |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1147581A CN1147581A (en) | 1997-04-16 |
| CN1049030C true CN1049030C (en) | 2000-02-02 |
Family
ID=5119687
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96107666A Expired - Fee Related CN1049030C (en) | 1996-06-17 | 1996-06-17 | Antiseptic foulness-preventing fabric and its prodn process and product |
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| Country | Link |
|---|---|
| CN (1) | CN1049030C (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW402526B (en) * | 1997-08-07 | 2000-08-21 | Fukusen Industry Co Ltd | The disinfection and anti-bacterial process method and the apparature |
| CN101818453B (en) * | 2009-02-26 | 2013-01-16 | 苏州市职业大学 | Method for protecting silk fabrics |
| CN103015164B (en) * | 2012-12-12 | 2015-10-28 | 嵊州雅戈尔毛纺织有限公司 | A kind of preparation method of antibacterial and deodorizing fabric |
| CN105862218A (en) * | 2016-05-03 | 2016-08-17 | 圣凯诺服饰有限公司 | Processing method of anti-bacterial and odor-removing armpit sweat bag for clothing |
| CN109576999A (en) * | 2018-12-25 | 2019-04-05 | 象山新光针织印染有限公司 | A kind of preparation method of deodorization breathable garment fabric |
| CN113024915A (en) * | 2021-02-14 | 2021-06-25 | 魏燕华 | Preparation method of antibacterial and deodorant thermoplastic rubber shoe material |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1048846A (en) * | 1989-07-17 | 1991-01-30 | 武汉市第三印染厂研究所 | Anti-bacteria health finishing agent, its preparation method is used and technology |
-
1996
- 1996-06-17 CN CN96107666A patent/CN1049030C/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1048846A (en) * | 1989-07-17 | 1991-01-30 | 武汉市第三印染厂研究所 | Anti-bacteria health finishing agent, its preparation method is used and technology |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1147581A (en) | 1997-04-16 |
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Granted publication date: 20000202 Termination date: 20100617 |