CN116815945A - Sealing structure and sealing method for radon leakage of in-situ leaching uranium collection liquid pool - Google Patents
Sealing structure and sealing method for radon leakage of in-situ leaching uranium collection liquid pool Download PDFInfo
- Publication number
- CN116815945A CN116815945A CN202310721504.1A CN202310721504A CN116815945A CN 116815945 A CN116815945 A CN 116815945A CN 202310721504 A CN202310721504 A CN 202310721504A CN 116815945 A CN116815945 A CN 116815945A
- Authority
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- China
- Prior art keywords
- radon
- component
- polyurethane
- polysulfide sealant
- foaming polyurethane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000007789 sealing Methods 0.000 title claims abstract description 39
- 229910052704 radon Inorganic materials 0.000 title claims abstract description 37
- SYUHGPGVQRZVTB-UHFFFAOYSA-N radon atom Chemical compound [Rn] SYUHGPGVQRZVTB-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 229910052770 Uranium Inorganic materials 0.000 title claims abstract description 29
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 239000007788 liquid Substances 0.000 title claims abstract description 27
- 238000002386 leaching Methods 0.000 title claims abstract description 25
- 238000011065 in-situ storage Methods 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title claims abstract description 22
- 229920002635 polyurethane Polymers 0.000 claims abstract description 62
- 239000004814 polyurethane Substances 0.000 claims abstract description 62
- 238000005187 foaming Methods 0.000 claims abstract description 39
- 239000004587 polysulfide sealant Substances 0.000 claims abstract description 39
- 239000003973 paint Substances 0.000 claims abstract description 32
- 239000011148 porous material Substances 0.000 claims abstract description 21
- 238000011049 filling Methods 0.000 claims abstract description 7
- 238000005507 spraying Methods 0.000 claims description 18
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 14
- 238000005065 mining Methods 0.000 claims description 12
- 239000007921 spray Substances 0.000 claims description 7
- 239000003292 glue Substances 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 3
- 239000000084 colloidal system Substances 0.000 claims description 3
- 238000010276 construction Methods 0.000 claims description 3
- 230000001105 regulatory effect Effects 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 238000002791 soaking Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 10
- -1 acrylic ester Chemical class 0.000 abstract description 7
- 229910000831 Steel Inorganic materials 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000010959 steel Substances 0.000 abstract description 3
- 238000009792 diffusion process Methods 0.000 description 5
- 239000003566 sealing material Substances 0.000 description 4
- 238000009854 hydrometallurgy Methods 0.000 description 3
- 229920005830 Polyurethane Foam Polymers 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011496 polyurethane foam Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/92—Protection against other undesired influences or dangers
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D31/00—Protective arrangements for foundations or foundation structures; Ground foundation measures for protecting the soil or the subsoil water, e.g. preventing or counteracting oil pollution
- E02D31/008—Protective arrangements for foundations or foundation structures; Ground foundation measures for protecting the soil or the subsoil water, e.g. preventing or counteracting oil pollution against entry of noxious gases, e.g. Radon
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/92—Protection against other undesired influences or dangers
- E04B2001/925—Protection against harmful electro-magnetic or radio-active radiations, e.g. X-rays
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Structural Engineering (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Electromagnetism (AREA)
- Physics & Mathematics (AREA)
- Toxicology (AREA)
- Hydrology & Water Resources (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Mining & Mineral Resources (AREA)
- Paleontology (AREA)
- General Engineering & Computer Science (AREA)
- Sealing Material Composition (AREA)
Abstract
The invention discloses a sealing structure and a sealing method for radon leakage of an in-situ leaching uranium collection liquid pool. Finally, the acrylic ester paint with better radon-proof performance and the same environmental color is used as the second radon-proof layer and plays an attractive role. The single-component foaming polyurethane is used as a main framework for filling the pores, the single-component polysulfide sealant is used as a main radon-proof material, the acrylic ester paint is used as a two-layer radon-proof and beautifying appearance material, the radon-proof effect of the multi-layer material is excellent, 78.2% of the radon-proof effect is achieved, the multi-layer material has good weather resistance, meanwhile, the deformation of the color steel plate of the liquid collecting pool when encountering strong convection weather can be self-adapted, the innovation and the practical value are very strong, and the application prospect is good.
Description
Technical Field
The invention relates to the technical field of on-site leaching mine environment protection and occupational health protection, in particular to a sealing structure and a sealing method for radon leakage of an on-site leaching uranium collection liquid pool.
Background
In-situ uranium extraction is a continuous process that targets production and treatment of uranium-containing leachate. In the in-situ leaching process, two main production links are well sites and hydrometallurgy plants. Wherein the hydrometallurgical plant is used for treating uranium-bearing leachate.
In the technological process of treating uranium-bearing leaching solution in a hydrometallurgy plant, facilities such as pipeline laying, house shielding and the like inevitably have gaps. Radon is used as a radioactive gas with longer diffusion length, has strong propagation capability in air and strong adhesiveness, and has certain harm to human health and environment. Therefore, in order to meet the sustainable development requirement of uranium mining industry in China, the design of radon protection in the hydrometallurgy process is very necessary to be optimized.
The liquid collecting tank is a place for temporarily storing uranium-containing leaching liquid leached by a well site, is designed to be semi-submerged, and is covered by a common color steel plate at the top. The coverage of the mode is poor in self-sealing performance, and meanwhile, gaps left by a window, an access passage and a pipeline penetrating through the wall of the side wall lead to release of radon from the liquid collecting tank to the environment.
The sealing radon-proof material is prepared by smearing or spraying a plurality of polymer film materials with low radon diffusion coefficient on the wall surface, and the radon-proof material cuts off radon escape channels and has good air tightness, so that the radon exhalation rate is reduced. However, due to the fact that various sealing radon-proof materials are high in viscosity and poor in fluidity, sealing of large gaps of the liquid collecting tank is not facilitated. It is desirable to provide a new method of sealing the in-situ leaching uranium mining sump.
Disclosure of Invention
The invention aims to provide a sealing structure and a sealing method for radon leakage of an in-situ leaching uranium collection liquid pool, which are used for solving the problems in the prior art, and the radon leakage of the liquid collection pool is achieved by adopting a plurality of sealing materials with different properties for multilayer coating.
In order to achieve the above object, the present invention provides the following solutions: the invention provides a sealing structure for radon leakage of an in-situ leaching uranium mining liquid pool, which comprises
The single-component foaming polyurethane is used for filling the pores of the liquid collecting tank; and
the outside of the single-component foaming polyurethane after filling the pores and drying is coated with the single-component polysulfide sealant; and
and the outer side of the single-component polysulfide sealant is sprayed with the acrylic paint.
The invention also provides a sealing method for radon leakage of the in-situ leaching uranium collection liquid pool, which is applied to the sealing structure for radon leakage of the in-situ leaching uranium collection liquid pool, and comprises the following steps:
step one, cleaning the periphery of a pore, removing sundries around the pore, opening a single-component foaming polyurethane sealing cover, and spraying the single-component foaming polyurethane into the pore to enable the single-component foaming polyurethane to be filled among gaps of houses, pipelines and doors and windows;
step two, removing redundant single-component foaming polyurethane protruding out of the surface of a building by using a graver after the polyurethane is solidified, so that a smooth and flat plane convenient for construction is formed, and extruding single-component polysulfide sealant on the surface of the flat single-component foaming polyurethane and the connection part of the single-component polysulfide sealant and the building by using a glue gun;
and thirdly, after the single-component polysulfide sealant is solidified, spraying acrylate paint on the surface of the polysulfide sealant.
Preferably, in the first step, the single-component foaming polyurethane sealing cover is opened, the nozzle and the guide pipe are rotated to the polyurethane bottle body, the bottle body is rocked, and the polyurethane is rocked uniformly and then sprayed out.
Preferably, in the first step, the nozzle guide pipe of the single-component foaming polyurethane is inserted into the hole for 5 cm to 8cm and pressure is applied to the nozzle, so that the pressure to the nozzle is kept after the polyurethane is sprayed, and the polyurethane is sprayed at a constant speed.
Preferably, in the second step, the dosage of the single-component polysulfide sealant is 1g/cm 2 。
Preferably, in the second step, the single-component polysulfide sealant is extruded on the surface of the flat single-component foaming polyurethane and the connection part of the single-component polysulfide sealant and the building, and then the single-component polysulfide sealant is uniformly coated on the surface of the single-component foaming polyurethane by a scraper, so that the surface of the colloid is uniform, smooth and pore-free, and no gap exists between the polyurethane and the building.
Preferably, in the third step, the acrylic paint is arranged in a paint spraying tank, the paint spraying tank is connected with an air pump, the pressure of the air pump is regulated to 0.3MPa, the acrylic paint is uniformly sprayed on the surface of the single-component polysulfide sealant, and the spraying is repeated for 3 times after the first layer of acrylic paint is dried, so that the surface is smooth and free of pores.
Compared with the prior art, the invention has the following beneficial technical effects:
according to the sealing structure and the sealing method for radon leakage of the in-situ leaching uranium collection liquid pool, the pores are filled with the single-component foaming polyurethane, and the dense radon-preventing layer is formed by the single-component polysulfide sealant with low radon diffusion coefficient. Finally, the acrylic ester paint with better radon-proof performance and the same environmental color is used as the second radon-proof layer and plays an attractive role. The single-component foaming polyurethane is used as a main framework for filling the pores, the single-component polysulfide sealant is used as a main radon-proof material, the acrylic ester paint is used as a two-layer radon-proof and beautifying appearance material, the radon-proof effect of the multi-layer material is excellent, 78.2% of the radon-proof effect is achieved, the multi-layer material has good weather resistance, meanwhile, the deformation of the color steel plate of the liquid collecting pool when encountering strong convection weather can be self-adapted, the innovation and the practical value are very strong, and the application prospect is good.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings that are needed in the embodiments will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and other drawings may be obtained according to these drawings without inventive effort for a person skilled in the art.
FIG. 1 is a distribution position diagram of a seal structure for in-situ leaching uranium mining pool radon leakage;
FIG. 2 is a schematic illustration of the position of a one-component foamed polyurethane bottle and spray head;
wherein, 1, single-component foaming polyurethane; 2. single-component polysulfide sealant; 3. acrylic ester paint; 4. a spray head; 5. a polyurethane bottle body; A. the liquid collecting tank is internally provided with a liquid collecting tank.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely with reference to the accompanying drawings, in which it is apparent that the embodiments described are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
The invention aims to provide a sealing structure and a sealing method for radon leakage of an in-situ leaching uranium collection liquid pool, which are used for solving the problems in the prior art, and the radon leakage of the liquid collection pool is achieved by adopting a plurality of sealing materials with different properties for multilayer coating.
In order that the above-recited objects, features and advantages of the present invention will become more readily apparent, a more particular description of the invention will be rendered by reference to the appended drawings and appended detailed description.
As shown in fig. 1-2, the invention provides a sealing structure for radon leakage of an in-situ leaching uranium collecting pool, which takes foamed polyurethane as main aggregate for filling gaps of the collecting pool, polysulfide sealant as a radon-proof sealing main material, polypropylene paint as a two-layer radon-proof sealing material, gives consideration to the effect of beautifying the appearance, and finally realizes radon-proof sealing effect of the collecting pool.
The invention is realized by the following technical scheme: the method of the invention requires the use of the following tools and materials: the paint spraying device comprises a scraper, a graver, a paint spraying tank, an air pump, a glue gun, single-component foaming polyurethane 1, single-component polysulfide sealant 2, acrylic ester paint 3, a spray head 4 and a guide pipe. The pores are filled by the single-component foaming polyurethane 1, and a compact radon-proof layer is formed by the single-component polysulfide sealant 2 with low radon diffusion coefficient. Finally, the acrylic paint 3 with better radon-proof performance and the same environmental color is used as a second radon-proof layer and plays an attractive role.
The working principle of the invention is as follows: in order to prevent radon from damaging human bodies and the environment during uranium mining, the most important method is to prevent radon and daughter from overflowing from gaps between pipelines and houses. The invention has the function of blocking the gaps as much as possible and limiting radon in a fixed space. The single-component foaming polyurethane 1 can expand and solidify in the gaps due to the characteristics of the single-component foaming polyurethane, and can fill the gaps, but the polyurethane foam is a porous material and has poor radon shielding effect. The single-component polysulfide sealant 2 has good air tightness and small diffusion coefficient of radon, can form a compact film after solidification, has good shielding effect on radon, but the single-component polysulfide sealant 2 is difficult to form a film on the surface with larger gaps, so the single-component polysulfide sealant 2 and the single-component foaming polyurethane 1 are considered to form the composite radon-proof material. When a large gap is blocked, the single-component foaming polyurethane 1 is taken as aggregate, and the single-component foaming polyurethane 1 is filled in the gap in advance, so that the gap is fully foamed and expanded and rapidly hardened. The one-component polyurethane foam fills up all gaps and adheres tightly to them. And (3) after the polyurethane surface forms a dry plane, smearing main radon sealing material polysulfide sealant on the surface by using a scraper to achieve the sealing effect. Finally, the acrylic paint 3 is sprayed on the surface of the single-component polysulfide sealant 2 by using a paint spraying tank and an air pump to achieve the functions of resealing and beautifying the appearance.
The sealing method for radon leakage of the in-situ leaching uranium collection liquid pool comprises the following steps:
firstly, cleaning the periphery of a pore, removing sundries around the pore, then opening a single-component foaming polyurethane 1 sealing cover, rotating a spray head 4 and a guide pipe onto a polyurethane bottle body 5, shaking the bottle body, shaking the polyurethane uniformly, and facilitating polyurethane spraying. The guide pipe is inserted into the hole for 5 cm to 8cm, and pressure is slowly applied to the spray head, so that the pressure to the spray head is kept after the polyurethane is sprayed, and the polyurethane is sprayed at a constant speed. The one-component foaming polyurethane 1 is filled between gaps of houses, pipelines and doors and windows, and can expand and solidify in the gaps and even protrude out of the gaps due to the characteristics of the one-component foaming polyurethane 1.
And then removing the excessive foaming polyurethane protruding out of the surface of the building by using a graver after the single-component polyurethane 1 is solidified, so that a smooth and flat plane convenient for construction is formed. Extruding the single-component polysulfide sealant 2 on the surface of flat foaming polyurethane and the building by using a glue gunThe amount of the connecting part is 1g/cm 2 . And then the scraper uniformly coats the single-component polysulfide sealant 2 on the surface of the foaming polyurethane to ensure that the surface of the colloid is uniform and smooth and has no pore, and no gap exists between the polyurethane and the building.
After the single-component polysulfide sealant 2 is solidified, the acrylic paint 3 is arranged in a paint spraying tank, and water can be added to dilute the acrylic paint appropriately according to the viscosity of the acrylic paint 3. The paint spraying tank is connected with an air pump, the pressure of the air pump is regulated to 0.3MPa, the acrylic paint 3 is uniformly sprayed on the surface of the single-component polysulfide sealant 2, and the spraying is repeated for 3 times after the single-component polysulfide sealant is dried, so that the surface is smooth and free of pores.
It should be noted that it will be apparent to those skilled in the art that the present invention is not limited to the details of the above-described exemplary embodiments, but may be embodied in other specific forms without departing from the spirit or essential characteristics thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
The principles and embodiments of the present invention have been described in detail with reference to specific examples, which are provided to facilitate understanding of the method and core ideas of the present invention; also, it is within the scope of the present invention to be modified by those of ordinary skill in the art in light of the present teachings. In view of the foregoing, this description should not be construed as limiting the invention.
Claims (7)
1. A seal structure that is used for soaking collection uranium liquid pool radon to reveal on site, its characterized in that: comprising
The single-component foaming polyurethane is used for filling the pores of the liquid collecting tank; and
the outside of the single-component foaming polyurethane after filling the pores and drying is coated with the single-component polysulfide sealant; and
and the outer side of the single-component polysulfide sealant is sprayed with the acrylic paint.
2. A sealing method for radon leakage of an in-situ leaching uranium mining liquid pool, which is applied to the sealing structure for radon leakage of the in-situ leaching uranium mining liquid pool as claimed in claim 1, and is characterized by comprising the following steps:
step one, cleaning the periphery of a pore, removing sundries around the pore, opening a single-component foaming polyurethane sealing cover, and spraying the single-component foaming polyurethane into the pore to enable the single-component foaming polyurethane to be filled among gaps of houses, pipelines and doors and windows;
step two, removing redundant single-component foaming polyurethane protruding out of the surface of a building by using a graver after the polyurethane is solidified, so that a smooth and flat plane convenient for construction is formed, and extruding single-component polysulfide sealant on the surface of the flat single-component foaming polyurethane and the connection part of the single-component polysulfide sealant and the building by using a glue gun;
and thirdly, after the single-component polysulfide sealant is solidified, spraying acrylate paint on the surface of the polysulfide sealant.
3. The sealing method for radon leakage in an in-situ leaching uranium mining pool of claim 2, wherein: in the first step, a single-component foaming polyurethane sealing cover is opened, a spray head and a guide pipe are rotated to a polyurethane bottle body, the bottle body is rocked, and polyurethane is rocked uniformly and then sprayed out.
4. The sealing method for radon leakage in an in-situ leaching uranium mining pool of claim 2, wherein: in the first step, a nozzle guide pipe of the single-component foaming polyurethane is inserted into the hole for 5 cm to 8cm, and pressure is applied to the nozzle, so that the pressure to the nozzle is kept after the polyurethane is sprayed, and the polyurethane is sprayed at a constant speed.
5. A liquid Chi for in-situ leaching uranium mining according to claim 2The leakage sealing method is characterized in that: in the second step, the dosage of the single-component polysulfide sealant is 1g/cm 2 。
6. The sealing method for radon leakage in an in-situ leaching uranium mining pool of claim 2, wherein: in the second step, the single-component polysulfide sealant is extruded on the surface of the flat single-component foaming polyurethane and the connection part of the single-component polysulfide sealant and the building, and then the single-component polysulfide sealant is uniformly smeared on the surface of the single-component foaming polyurethane by a scraper, so that the surface of the colloid is uniform, smooth and pore-free, and no gap exists between the polyurethane and the building.
7. The sealing method for radon leakage in an in-situ leaching uranium mining pool of claim 2, wherein: in the third step, the acrylic paint is arranged in a paint spraying tank, the paint spraying tank is connected with an air pump, the pressure of the air pump is regulated to 0.3MPa, the acrylic paint is uniformly sprayed on the surface of the single-component polysulfide sealant, and the spraying is repeated for 3 times after the first layer of acrylic paint is dried, so that the surface is smooth and free of pores.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN202310721504.1A CN116815945A (en) | 2023-06-16 | 2023-06-16 | Sealing structure and sealing method for radon leakage of in-situ leaching uranium collection liquid pool |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN202310721504.1A CN116815945A (en) | 2023-06-16 | 2023-06-16 | Sealing structure and sealing method for radon leakage of in-situ leaching uranium collection liquid pool |
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CN116815945A true CN116815945A (en) | 2023-09-29 |
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CN202310721504.1A Pending CN116815945A (en) | 2023-06-16 | 2023-06-16 | Sealing structure and sealing method for radon leakage of in-situ leaching uranium collection liquid pool |
Country Status (1)
Country | Link |
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CN (1) | CN116815945A (en) |
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- 2023-06-16 CN CN202310721504.1A patent/CN116815945A/en active Pending
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