CN116602908A - Preparation method of plant composition with hair nourishing effect - Google Patents

Abstract

The invention relates to a preparation method of a plant composition with a hair nourishing effect, which belongs to the field of shampoo compositions and comprises the following raw materials in parts by mass: 30-40 parts of modified Pickering emulsion, 15-25 parts of compound surfactant system, 15-30 parts of goat milk, 1-3 parts of avocado seed extract, 5-7 parts of hydroxypropyl methyl cellulose and 80-100 parts of deionized water; the modified starch is used for loading resveratrol, carvacrol, fermentation cyclopia extract, ganoderma lucidum extract, ginger extract and cacumen biotae extract, so that the plant extract can better play a role in a system, and the scalp can be promoted to absorb the plant extract; by adding goat milk and partial plant extracts to cooperate, and simultaneously using a stabilizer, the viscosity and stability of the system are increased, and the denaturation of proteins in the goat milk and the stability of plant extract components are inhibited.

Description

Preparation method of plant composition with hair nourishing effect

Technical Field

The invention belongs to the technical field of shampoo compositions, and particularly relates to a preparation method of a plant composition with a hair nourishing effect.

Background

Shampoo is considered to be one of the most commonly used cosmetics for daily hair and scalp cleansing, and its use is applicable to men and women of all ages. The shampoo has the function of effectively and thoroughly removing dust, superfluous sebum or other grease, so that hair care and hair care are more and more important to people, and some hair or scalp problems frequently occurring in hair care and hair care always plague people, such as excessive grease secretion, dandruff or hair dryness and bifurcation, and the like.

The shampoo in the market at present mostly adopts antifungal agents (such as zinc pyrithione ZPT) as anti-dandruff agents, including salicylic acid, zinc pyrithione, piroctone olamine salt, climbazole and the like, and the anti-dandruff agents belong to chemical anti-dandruff agents, have the problems of sensitization, irritation, instability and the like, have great damage to hair scales of hair, cause hair dryness and bifurcation after long-term use, and especially have more serious influence on damaged hair quality such as scalding and dyeing and the like.

The shampoo has less functionality and lacks maintenance efficacy, and the synthetic shampoo contains toxic chemical agents such as parahydroxybenzoate, sodium dodecyl sulfate and other chemical substances, so that hair can be damaged; preventing the generation of harmful substances when used with other hair care products, such as avoiding the use of ingredients that together produce carcinogenic compounds (e.g., benzene); the foam generated by the shampoo contains washed dirt, the dirt remained in the foam is difficult to wash out and redeposit on the hair, the cleaning quality is reduced, and harmful microorganisms are excessively propagated: the scalp becomes a place where microorganisms excessively multiply, and scalp inflammation is easily caused by the high temperature and humidity in summer, sweat on the surface of the scalp, sebum, moisture in the air, pollutants and the like, and the coverage of the hair.

Disclosure of Invention

The invention aims to provide a preparation method of a plant composition with hair nourishing effect, modified starch loads resveratrol and a composite plant extract to obtain modified pickering emulsion, so that the plant extract can better play a role in a system and promote scalp to absorb the plant extract, wherein the plant extract can stay on hair to achieve the effect of long-term protection, and scalp can absorb nourishing components to strengthen scalp health; the sodium cocoyl glycinate system is mixed with the tea saponin surfactant to obtain a compound surfactant system, and the tea saponin and the sodium cocoyl glycinate system are compounded to form the surfactant system, so that the performance is stable, the viscosity is moderate, the foam is rich and fine, and the surfactant system is mild and has no stimulation; the goat milk component, alpha-hydroxy acid, vitamin and mineral substances in the goat milk are added to help cell nutrition and strengthen hair quality, and the goat milk is added to cooperate with part of plant extracts, and meanwhile, a stabilizer is used to increase the viscosity and stability of the system and inhibit the denaturation of proteins in the goat milk and the stability of the plant extract components.

The invention aims to solve the technical problems: the shampoo has less functionality and lack of maintenance efficacy, and consumers are more prone to chemical components which may harm physical health, and the synthetic shampoo contains toxic chemical preparations which can damage hair; the foam generated by the shampoo contains washed dirt, the dirt remained in the foam is difficult to wash off and redeposit on the hair, and the cleaning quality is reduced; harmful microorganisms overmultiply: the scalp becomes a place where microorganisms excessively multiply, and scalp inflammation is easily caused by the high temperature and humidity in summer, sweat on the surface of the scalp, sebum, moisture in the air, pollutants and the like, and the coverage of the hair.

The aim of the invention can be achieved by the following technical scheme:

a plant composition with hair nourishing effect comprises the following raw materials in parts by mass: 30-40 parts of modified Pickering emulsion, 15-25 parts of compound surfactant system, 15-30 parts of goat milk, 1-3 parts of avocado seed extract, 5-7 parts of hydroxypropyl methyl cellulose and 80-100 parts of deionized water;

the compound surfactant system comprises a sodium cocoyl glycinate system and a tea saponin surfactant;

further, the modified pickering emulsion is prepared by loading resveratrol and a composite plant extract with modified starch, and the preparation method comprises the following steps:

the method comprises the steps of (1) mixing caprylic/capric glyceride and triacetin according to a mass ratio of 1:1 and hydrogenated castor oil at room temperature to form an oil phase, adding resveratrol and a composite plant extract into the oil phase at 50 ℃ at 400rpm, stirring for 30min, dispersing octenyl succinic anhydride modified starch and glycerol into deionized water (68%, w/w), adding into the oil phase under 1500rpm stirring, and treating the dispersion by a high pressure homogenizer at 500Bar to obtain a modified pickering emulsion.

Further, the compound plant extract comprises carvacrol, fermented herba Cycloxae extract, ganoderma extract, rhizoma Zingiberis recens extract, and folium Platycladi extract.

Further, the dosage ratio of resveratrol to the composite plant extract is (0.1-0.3): 0.6-1.

Further, the ratio of the octenyl succinic anhydride modified starch, glycerol and deionized water is (0.5-1.5): 2-4): 66-70.

Further, the preparation method of the fermentation grass extract comprises the following steps:

the preparation method comprises the steps of drying the cyclocarya paliurus leaves in a hot-air furnace at 60 ℃, crushing the cyclocarya paliurus leaves by using a mortar and pestle, adding 8% sucrose solution and deionized water at a ratio of 0.5:1:10, sterilizing the crushed cyclocarya paliurus leaves under high pressure, inoculating 10% lactobacillus plantarum, culturing the crushed cyclocarya paliurus leaves in an MRS culture medium and Sharpe (MRS) broth for culturing lactobacillus, preserving the fermentation at 37 ℃ and 80rpm for 5 days in a stirrer, and centrifuging the obtained product at 8000rpm for 30min to obtain a fermented cyclocarya paliurus extract.

Further, the dosage ratio of the cyclocarya paliurus leaves, the sucrose solution and the deionized water is (0.3-0.7): (0.5-1.5): (8-12).

Further, the compound surfactant system is formed by mixing a cocoyl sodium glycinate system and a tea saponin surfactant, and the preparation method comprises the following steps:

A1. mixing deionized water, glycerol, disodium ethylenediamine tetraacetate and sodium cocoyl glycinate to obtain a phase A, mixing sodium methyl cocoyl taurate, tris (cetostearyl alcohol polyether-4) phosphate and ethylene glycol distearate to obtain a phase B, mixing citric acid, phenoxyethanol and ethylhexyl glycerol to obtain a phase C, placing the phase A and the phase B in a constant-temperature water bath kettle, emulsifying and homogenizing at an emulsification rate of 1200r/min for 30min until the sodium cocoyl glycinate is completely dissolved, stirring in a cold water bath, and standing for 24h to obtain a sodium cocoyl glycinate system;

A2. and mixing the cocoyl sodium glycinate system with a tea saponin surfactant to obtain a compound surfactant system.

Further, in the phase A, the dosage ratio of deionized water, glycerol, disodium ethylenediamine tetraacetate and sodium cocoyl glycinate is 9.6:25:0.1:55; in phase B, sodium methyl cocoyl taurate, tris (cetostearyl alcohol polyether-4) phosphate and ethylene glycol distearate are used in a ratio of 5:1:2; in phase C, the dosage ratio of citric acid, phenoxyethanol and ethylhexyl glycerol is 1.5:0.8.

A plant composition with hair care effect, comprising the steps of:

s1, adding the modified Pickering emulsion into deionized water, and uniformly stirring at 45 ℃ to obtain a mixed solution;

s2, adding the compound surfactant system, the goat milk, the avocado seed extract and the hydroxypropyl methylcellulose into the mixed solution, and uniformly stirring to obtain the composition.

The beneficial effects of the invention are that

(1) In the technical scheme of the invention, carvacrol has an effect of removing mites, and phenolic substances have an antibacterial effect; the cacumen biotae extract can promote proliferation of human dermal papilla cells, prolong the growing period of hair follicles, and has good alopecia preventing effect; the ginger extract has the function of inhibiting reductase, and the shampoo prepared by the ginger extract has a certain alopecia preventing effect; the ganoderma lucidum has good affinity to hair, antigen-antibody reaction can not occur, and nutrient substances of the ganoderma lucidum can be absorbed by the hair and can permeate into the stratum corneum, so that the hair is glossy, and the effects of hairdressing and hair care are achieved; the compound plant extract can achieve sun-proof and hair-proof effects on scalp and hair in different modes.

(2) According to the technical scheme, the modified starch is used for loading resveratrol, carvacrol, fermentation cyclopia extract, ganoderma lucidum extract, ginger extract and cacumen biotae extract, so that the plant extract can better play a role in a system, and promote scalp to absorb the plant extract, wherein the plant extract can stay on hair to achieve the effect of long-term protection, and scalp can absorb nourishing components to strengthen scalp health; the modified starch is used for loading other water insoluble components in resveratrol and plant extracts, so that the addition of a surfactant is reduced, the irritation of the surfactant to scalp is reduced, and in addition, the modified starch has good moisturizing effect and skin itching relieving effect on the hair.

(3) In the technical scheme of the invention, the tea saponin has the functions of decontamination, moisture preservation and ultraviolet resistance, can diminish inflammation, relieve itching and remove dandruff, is compounded with a coco sodium glycine surfactant system with the pH value close to that of scalp, has extremely low irritation, has good foam effect and decontamination capability, and can not take away moisture of the scalp to cause tightening feeling; the tea saponin and the cocoyl sodium glycinate system are compounded to form the surfactant system, so that the surfactant system has stable performance, moderate viscosity, rich and fine foam, and is mild and free of stimulation.

(4) In the technical scheme of the invention, the compound surfactant and the modified pickering emulsion act together, so that the detergent has a mild and effective decontamination effect.

(5) In the technical scheme of the invention, alpha-hydroxy acid, vitamin and mineral substances in goat milk are beneficial to cell nutrition and hair quality enhancement, and goat milk is beneficial to stabilizing the pH value stability of a system, wherein the pH value is responsible for improving hair quality and maximally reducing eye irritation, stabilizing the ecological balance of scalp, and mild acidity can prevent swelling and promote scaling and shaping, so that hair luster is induced and hair damage is maximally reduced; in addition, the addition of goat milk can lead to better dirt dispersion, no dirt exists in the foam,

(6) According to the technical scheme, the goat milk and part of plant extracts are synergized, and meanwhile, the stabilizing agent is used, so that the viscosity and stability of a system are improved, the denaturation of proteins in the goat milk and the stability of plant extract components are inhibited, the surface tension and viscosity of the shampoo are reduced, and good conditioning performance, good cleaning capability, foaming stability, wetting time and brightness are provided.

Detailed Description

The technical solutions of the embodiments of the present invention will be clearly and completely described below in conjunction with the embodiments of the present invention, and it is apparent that the described embodiments are only some embodiments of the present invention, not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.

Example 1

The fermentation of the extract of the Cyclobalm comprises the following steps:

drying 0.5g of Cyclobalm leaves in a hot-air furnace at 60deg.C, pulverizing with a mortar and pestle, adding 1g of sucrose solution and 10g of deionized water, autoclaving, culturing in MRS medium and Sharpe (MRS) broth for culturing lactobacillus, fermenting at 37deg.C and 80rpm for 5 days in a stirrer, and centrifuging at 8000rpm for 30min to obtain fermented Cyclobalm extract.

Example 2

This example differs from example 1 in that the masses of the cyclop grass blades, sucrose solution and deionized water are 0.3g, 0.5g and 8g, respectively.

Example 3

This example differs from example 1 in that the masses of the cyclop grass blades, sucrose solution and deionized water are 0.7g, 1.5g and 12g, respectively.

Example 4

The modified pickering emulsion is prepared by the following steps:

the glyceryl octadecanoate, glyceryl triacetate and hydrogenated castor oil were stirred at room temperature for 10min to form an oil phase, 0.2g resveratrol and 0.8g complex plant extract were added to the oil phase at 50 ℃ at 400rpm, stirred for 30min, 1g octenyl succinic anhydride modified starch and 3g glycerol were dispersed into 68g deionized water, added to the oil phase with stirring at 1500rpm, and the dispersion was treated by a high pressure homogenizer at 500Bar pressure to give a modified pickering emulsion. Wherein the compound plant extract is prepared by mixing carvacrol, fermentation herba Cycloxae extract, ganoderma extract, rhizoma Zingiberis recens extract and folium Platycladi extract according to any ratio.

Comparative example 1

The comparative example was without the addition of the complex plant extract.

Example 5

The compound surfactant system is prepared by the following steps:

A1. 9.6g of deionized water, 25g of glycerol, 0.1g of disodium ethylenediamine tetraacetate and 55g of sodium cocoyl glycinate are mixed to obtain a phase A, 5g of sodium methyl cocoyl taurate, 1g of tris (cetostearyl alcohol polyether-4) phosphate and 2g of ethylene glycol distearate are mixed to obtain a phase B, 1.5g of citric acid, 0.5g of phenoxyethanol and 0.3g of ethylhexyl glycerol are mixed to obtain a phase C, the phase A and the phase B are placed in a constant-temperature water bath kettle, emulsification and homogenization are carried out at an emulsification rate of 1200r/min until the sodium cocoyl glycinate is completely dissolved, and then the mixture is placed in a cold water bath for stirring and standing for 24 hours to obtain a sodium cocoyl glycinate system;

A2. 0.5g of sodium cocoyl glycinate system was mixed with 0.2g of tea saponin surfactant to obtain a complex surfactant system.

Comparative example 2

The comparative example was without the addition of a sodium cocoyl glycinate system.

Example 6

The plant composition with the hair nourishing effect is characterized by comprising the following raw materials in parts by mass: 30 parts of modified Pickering emulsion, 15 parts of compound surfactant system, 15 parts of goat milk, 1 part of avocado seed extract, 5 parts of hydroxypropyl methylcellulose and 80 parts of deionized water;

the preparation method comprises the following steps:

s1, adding the modified Pickering emulsion into deionized water, and uniformly stirring at 45 ℃ to obtain a mixed solution;

s2, adding the compound surfactant system, the goat milk, the avocado seed extract and the hydroxypropyl methylcellulose into the mixed solution, and uniformly stirring to obtain the composition.

Example 7

The plant composition with the hair nourishing effect is characterized by comprising the following raw materials in parts by mass: 35 parts of modified Pickering emulsion, 20 parts of compound surfactant system, 20 parts of goat milk, 2 parts of avocado seed extract, 6 parts of hydroxypropyl methylcellulose and 90 parts of deionized water;

the preparation method comprises the following steps:

s1, adding the modified Pickering emulsion into deionized water, and uniformly stirring at 45 ℃ to obtain a mixed solution;

s2, adding the compound surfactant system, the goat milk, the avocado seed extract and the hydroxypropyl methylcellulose into the mixed solution, and uniformly stirring to obtain the composition.

Example 8

The plant composition with the hair nourishing effect is characterized by comprising the following raw materials in parts by mass: 40 parts of modified Pickering emulsion, 25 parts of compound surfactant system, 30 parts of goat milk, 3 parts of avocado seed extract, 7 parts of hydroxypropyl methylcellulose and 100 parts of deionized water;

the preparation method comprises the following steps:

s1, adding the modified Pickering emulsion into deionized water, and uniformly stirring at 45 ℃ to obtain a mixed solution;

s2, adding the compound surfactant system, the goat milk, the avocado seed extract and the hydroxypropyl methylcellulose into the mixed solution, and uniformly stirring to obtain the composition.

Comparative example 3

This comparative example differs from example 7 in that the modified pickering emulsion was replaced with the material prepared in comparative example 1, and the rest of the procedure and raw materials were synchronized with example 7.

Comparative example 4

This comparative example differs from example 7 in that the formulated surfactant system was replaced with the material prepared in comparative example 2, the remainder of the procedure and starting materials being synchronized with example 7.

Comparative example 5

This comparative example differs from example 7 in that the example does not contain goat milk.

The plant compositions with hair nourishing effects prepared in examples 6 to 8 and comparative examples 3 to 5 were now tested; to evaluate foam formation and foam stability, a dilution of shampoo in 25mL of deionized water was prepared in a 20mL graduated cylinder at room temperature of 25 ℃, covered and shaken 10 times, the volume of foam formed was recorded after 1 min, and the final volume was recorded after 20 min, to determine the stability of the composition;

velvet testing was used to evaluate wettability, cutting velvet discs of 2.54 cm diameter weighing about 0.30g, preparing 100mL of 1% aqueous composition in a 500mL graduated cylinder, placing the discs in the prepared solution and recording the time required for sinking of the discs as wetting time;

selecting 90 mice, dividing the mice into 9 groups at random, weighing Mao Tichu on the backs of the mice, respectively and correspondingly smearing the composition on the dehaired areas of each group of mice once a day, continuously smearing for 14 days, recording the new growing hair of the smeared sample parts of the mice by using an image analyzer after 14 days, and taking the average value of each group;

to quantify the percentage of solids, the evaporation of the liquid portion of the shampoo was measured, 10g of the composition was used in an evaporation pan at 150 ℃ on a heater, the sample was allowed to evaporate all liquid, the sample was weighed again, and the percentage of solids was calculated as follows:

TABLE 1

From the results of Table 1, it is understood that the plant compositions with hair tonic effect prepared in examples 6 to 8 and comparative examples 3 to 5 have better foaming, wetting property and hair loss preventing property, and that the plant composition with hair tonic effect of example 7 has the best effect on foaming, hair loss preventing property and wetting property. As can be seen from the data in comparative example 5, the absence of the addition of the complex plant extract and the goat milk component demonstrates that the complex plant extract and the goat milk component increase foaming, hair loss prevention and wetting properties of the plant composition with hair care efficacy.

In the description of the present specification, the descriptions of the terms "one embodiment," "example," "specific example," and the like, mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the present invention. In this specification, schematic representations of the above terms do not necessarily refer to the same embodiments or examples. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.

The foregoing is merely illustrative and explanatory of the invention, as various modifications and additions may be made to the particular embodiments described, or in a similar manner, by those skilled in the art, without departing from the scope of the invention or exceeding the scope of the invention as defined in the claims.

Claims (10)

1. The plant composition with the hair nourishing effect is characterized by comprising the following raw materials in parts by mass: 30-40 parts of modified Pickering emulsion, 15-25 parts of compound surfactant system, 15-30 parts of goat milk, 1-3 parts of avocado seed extract, 5-7 parts of hydroxypropyl methyl cellulose and 80-100 parts of deionized water;

the modified Pickering emulsion is prepared by loading resveratrol and a composite plant extract with modified starch;

the compound surfactant system comprises a sodium cocoyl glycinate system and a tea saponin surfactant.

2. The plant composition with hair care effect according to claim 1, wherein the compound plant extract comprises carvacrol, fermentation cyclopia extract, ganoderma lucidum extract, ginger extract, biota orientalis extract.

3. The plant composition with hair care effect according to claim 1, wherein the modified pickering emulsion is prepared by the following steps:

the method comprises the steps of (1) mixing caprylic/capric glyceride and triacetin according to a mass ratio of 1:1 and hydrogenated castor oil at room temperature for 10min to form an oil phase, adding resveratrol and a composite plant extract into the oil phase at 50 ℃ at 400rpm, stirring for 30min, dispersing octenyl succinic anhydride modified starch and glycerol into deionized water, adding into the oil phase under 1500rpm stirring, and treating the dispersion by a high-pressure homogenizer at 500Bar pressure to obtain the modified pickering emulsion.

4. The composition of claim 2, wherein the resveratrol and the compound plant extract are used in a ratio of (0.1-0.3) to (0.6-1).

5. A plant composition with hair care effect according to claim 2, wherein the ratio of octenyl succinic anhydride modified starch, glycerol and deionized water is (0.5-1.5): 2-4): 66-70.

6. The plant composition with hair care effect according to claim 2, wherein the fermentation herb extract is prepared by the following steps:

the preparation method comprises drying herba Cyclobaldric leaves in hot air furnace at 60deg.C, pulverizing with mortar and pestle, adding 8% sucrose solution and deionized water at a ratio of 0.5:1:10, autoclaving, culturing in MRS medium and Sharpe (MRS) broth for culturing lactobacillus, fermenting at 37deg.C and 80rpm for 5 days in a stirrer, and centrifuging at 8000rpm for 30min to obtain fermented herba Cyclobaldric extract.

7. The composition of claim 1, wherein the ratio of the amount of the leaf of the cyclocarya paliurus to the sucrose solution to the deionized water is between 0.3 and 0.7 to between 0.5 and 1.5 to between 8 and 12.

8. The plant composition with hair care effect according to claim 4, wherein the compound surfactant system is formed by mixing a sodium cocoyl glycinate system and a tea saponin surfactant, and the preparation method comprises the following steps:

A1. mixing deionized water, glycerol, disodium ethylenediamine tetraacetate and sodium cocoyl glycinate to obtain a phase A, mixing sodium methyl cocoyl taurate, tris (cetostearyl alcohol polyether-4) phosphate and ethylene glycol distearate to obtain a phase B, mixing citric acid, phenoxyethanol and ethylhexyl glycerol to obtain a phase C, placing the phase A and the phase B in a constant-temperature water bath kettle, emulsifying and homogenizing for 30min to complete dissolution at an emulsification rate of 1200r/min, placing in a cold water bath, stirring, and standing for 24h to obtain a sodium cocoyl glycinate system;

A2. and mixing the cocoyl sodium glycinate system with a tea saponin surfactant to obtain a compound surfactant system.

9. The composition of claim 1, wherein the deionized water, glycerin, disodium edetate and sodium cocoyl glycinate are present in a 9.6:25:0.1:55 ratio in phase a; in phase B, sodium methyl cocoyl taurate, tris (cetostearyl alcohol polyether-4) phosphate and ethylene glycol distearate are used in a ratio of 5:1:2; in phase C, the dosage ratio of citric acid, phenoxyethanol and ethylhexyl glycerol is 1.5:0.8.

10. A plant composition having hair care effect as claimed in claim 1, comprising the steps of:

s1, adding the modified Pickering emulsion into deionized water, and uniformly stirring at 45 ℃ to obtain a mixed solution;

s2, adding the compound surfactant system, the goat milk, the avocado seed extract and the hydroxypropyl methylcellulose into the mixed solution, and uniformly stirring to obtain the composition.