CN116602890B - Anti-dandruff shampoo containing nano-gold and preparation method thereof - Google Patents
Anti-dandruff shampoo containing nano-gold and preparation method thereof Download PDFInfo
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- 239000010931 gold Substances 0.000 title claims abstract description 72
- 229910052737 gold Inorganic materials 0.000 title claims abstract description 72
- 239000002453 shampoo Substances 0.000 title claims abstract description 65
- 208000001840 Dandruff Diseases 0.000 title claims abstract description 57
- 238000002360 preparation method Methods 0.000 title abstract description 11
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 68
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000011780 sodium chloride Substances 0.000 claims abstract description 34
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 claims abstract description 34
- CYMRPDYINXWJFU-UHFFFAOYSA-N 2-carbamoylbenzoic acid Chemical compound NC(=O)C1=CC=CC=C1C(O)=O CYMRPDYINXWJFU-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000003760 tallow Substances 0.000 claims abstract description 31
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- 229940082500 cetostearyl alcohol Drugs 0.000 claims abstract description 24
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002904 solvent Substances 0.000 claims abstract description 20
- 239000004094 surface-active agent Substances 0.000 claims abstract description 17
- 239000002562 thickening agent Substances 0.000 claims abstract description 16
- 239000000725 suspension Substances 0.000 claims abstract description 15
- 238000013329 compounding Methods 0.000 claims abstract description 14
- 239000003381 stabilizer Substances 0.000 claims abstract description 13
- VFKZECOCJCGZQK-UHFFFAOYSA-M 3-hydroxypropyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCO VFKZECOCJCGZQK-UHFFFAOYSA-M 0.000 claims description 23
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 23
- 229940057950 sodium laureth sulfate Drugs 0.000 claims description 22
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 claims description 22
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 19
- 244000007835 Cyamopsis tetragonoloba Species 0.000 claims description 18
- 229920002545 silicone oil Polymers 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 15
- 230000003750 conditioning effect Effects 0.000 claims description 15
- 229940098691 coco monoethanolamide Drugs 0.000 claims description 9
- 239000002131 composite material Substances 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 19
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 30
- 239000000126 substance Substances 0.000 description 24
- 238000003756 stirring Methods 0.000 description 22
- 210000004209 hair Anatomy 0.000 description 21
- 239000000203 mixture Substances 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 239000008367 deionised water Substances 0.000 description 15
- 229910021641 deionized water Inorganic materials 0.000 description 15
- 230000000694 effects Effects 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 13
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 12
- 238000001816 cooling Methods 0.000 description 12
- 210000004761 scalp Anatomy 0.000 description 12
- 239000001913 cellulose Substances 0.000 description 11
- 229920002678 cellulose Polymers 0.000 description 11
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical group CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 10
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 10
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 10
- 229940100242 glycol stearate Drugs 0.000 description 10
- 229920000059 polyethylene glycol stearate Polymers 0.000 description 10
- -1 pH regulators Substances 0.000 description 9
- 238000003860 storage Methods 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 6
- 230000001804 emulsifying effect Effects 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 244000303965 Cyamopsis psoralioides Species 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- 238000005189 flocculation Methods 0.000 description 5
- 230000016615 flocculation Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- 230000001954 sterilising effect Effects 0.000 description 5
- 230000003385 bacteriostatic effect Effects 0.000 description 4
- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 description 4
- 229960000735 docosanol Drugs 0.000 description 4
- 230000002401 inhibitory effect Effects 0.000 description 4
- 229910001629 magnesium chloride Inorganic materials 0.000 description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 230000032683 aging Effects 0.000 description 3
- 210000002510 keratinocyte Anatomy 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 241000555676 Malassezia Species 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000003648 hair appearance Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 241000416536 Euproctis pseudoconspersa Species 0.000 description 1
- 241000555688 Malassezia furfur Species 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000022 bacteriostatic agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229940071160 cocoate Drugs 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 210000003780 hair follicle Anatomy 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 210000003491 skin Anatomy 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 210000000434 stratum corneum Anatomy 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/006—Antidandruff preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/413—Nanosized, i.e. having sizes below 100 nm
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The invention relates to the technical field of shampoo, and in particular discloses an anti-dandruff shampoo containing nano-gold and a preparation method thereof. The anti-dandruff shampoo containing the nano-gold comprises the following components in parts by mass: 71.05-73.34 minutes of solvent; 1.98-2.1 parts of conditioner; 0.03-0.05 part of pH regulator; 1.55-1.7 parts of thickener; 0.75-0.8 part of pearling agent; 20.25-21.8 parts of surfactant; 0.35-0.4 parts of di (hydrogenated tallow) phthalic acid amide; 0.45-0.5 part of suspension stabilizer; 0.9-1.1 parts of nano gold; 0-0.5 part of essence; the thickener is the compounding of cetostearyl alcohol and sodium chloride. The invention has the advantage that the antibacterial effect of the anti-dandruff shampoo containing nano-gold is better and durable and stable.
Description
Technical Field
The invention relates to the field of shampoo, in particular to anti-dandruff shampoo containing nano-gold and a preparation method thereof.
Background
The shampoo is a washing and caring product for cleaning hair and scalp, and is used for cleaning hair and impurities such as grease, dust, dandruff, etc. on scalp, so as to keep hair clean.
Dandruff is keratinocyte that the scalp drops off, under normal state, keratinocyte drops off seldom, very slowly, but under some stimulations, immature keratinocyte can appear the phenomenon that numerous caking drops off, lead to the dandruff to increase.
There are various stimuli that cause dandruff, among them, the most important is the stimulus from bacteria, especially the ubiquitous malassezia, when malassezia on the scalp multiply, it is easy to cause skin superficial stratum corneum and hair follicle infection, thus make the scalp stimulated, and then cause the production of a large amount of dandruff, therefore, in numerous anti-dandruff shampoos, usually add bacteriostats, through inhibiting, eliminating harmful bacteria on the scalp, thus make the ecological environment of the scalp keep healthy, and then realize the effect of inhibiting dandruff production.
The nano gold is a good bacteriostatic agent, and the bacteriostatic effect of the shampoo can be remarkably improved by adding the nano gold into the shampoo, however, flocculation phenomenon easily occurs in the process of storage of the nano gold, so that the bacteriostatic effect of the nano gold is invalid, and the anti-dandruff effect is greatly reduced, and therefore, the shampoo has room for improvement.
Disclosure of Invention
In order to better and permanently keep the antibacterial effect of the anti-dandruff shampoo containing nano-gold stable, the application provides the anti-dandruff shampoo containing nano-gold and a preparation method thereof.
In a first aspect, the present application provides an anti-dandruff shampoo containing nano-gold, which adopts the following technical scheme:
the anti-dandruff shampoo containing the nano gold comprises the following components in parts by weight:
71.05-73.34 minutes of solvent;
1.98-2.1 parts of conditioner;
0.03-0.05 part of pH regulator;
1.55-1.7 parts of thickener;
0.75-0.8 part of pearling agent;
20.25-21.8 parts of surfactant;
0.35-0.4 parts of di (hydrogenated tallow) phthalic acid amide;
0.45-0.5 part of suspension stabilizer;
0.9-1.1 parts of nano gold;
0-0.5 part of essence;
the thickener is the compounding of cetostearyl alcohol and sodium chloride.
By adopting the technical scheme, the shampoo has excellent anti-dandruff and sterilizing effects by adding the nano gold, and the nano gold can be permanently and stably uniformly distributed in the shampoo in the form of nano particles by compounding cetylstearyl alcohol, sodium chloride and di (hydrogenated tallow) phthalic acid amide and then matching with the nano gold, so that flocculation phenomenon is not easy to occur, and the anti-dandruff shampoo containing the nano gold is not easy to cause the reduction of antibacterial effect in long-term storage, can permanently maintain better anti-dandruff effect and has better quality.
Preferably, the mass ratio of the cetostearyl alcohol to the sodium chloride is 0.45-0.5:1.1-1.2.
By adopting the technical scheme, the effect of the combination of the cetylstearyl alcohol and the sodium chloride and the di (hydrogenated tallow) phthalic acid amide is better by specifically selecting the mass ratio of the cetylstearyl alcohol and the sodium chloride, so that the stability of the nano gold is better and permanently improved, flocculation failure of the nano gold is not easy to occur, and the quality of the shampoo is better.
Preferably, the mass ratio of the di (hydrogenated tallow) phthalic acid amide, cetostearyl alcohol and sodium chloride is 0.38:0.47:1.15.
by adopting the technical scheme, the nano gold has better effect by specifically selecting the mass ratio of di (hydrogenated tallow) phthalic acid amide, cetostearyl alcohol and sodium chloride, and can keep excellent sterilizing and scurf inhibiting effects after long-term storage.
Preferably, the conditioning agent is the compound of guar hydroxypropyl trimethyl ammonium chloride and emulsified silicone oil.
By adopting the technical scheme, the conditioning agent is formed by specifically selecting guar hydroxypropyl trimethyl ammonium chloride and emulsified silicone oil, so that the hair can be better conditioned, the hair is smoother, the hair quality is improved, the hair is not easy to be rough, and the hair is more attractive.
Preferably, the mass ratio of the guar hydroxypropyl trimethyl ammonium chloride to the emulsified silicone oil is 0.08-0.1:1.9-2.
By adopting the technical scheme, the effects of conditioning the hair and the scalp are better by specifically selecting the mass ratio of guar hydroxypropyl trimethyl ammonium chloride and emulsified silicone oil, so that the scalp is more balanced in water and oil, and the hair is more flexible and attractive.
Preferably, the surfactant is the compound of monoethanolamide cocoate, sodium laureth sulfate and cocamidopropyl betaine.
Through adopting above-mentioned technical scheme, through the compound surfactant formulation of concretely selecting coconut acid monoethanolamide, laureth sulfate sodium, cocoamidopropyl betaine, the cleaning performance to the dirt on scalp and the hair is better, can clean the hair better, makes the hair cleaner, and is more pleasing to the eye.
Preferably, the mass ratio of the coco monoethanolamide, sodium laureth sulfate and cocoamidopropyl betaine is 0.75-0.8:15-16:4.5-5.
By adopting the technical scheme, the cleaning effect is better, the hair is cleaner and the quality is better by specifically selecting the mass ratio of the coconut monoethanolamide, the sodium laureth sulfate and the cocoamidopropyl betaine.
In a second aspect, the present application provides a method for preparing an anti-dandruff shampoo containing nano-gold, which adopts the following technical scheme:
a preparation method of anti-dandruff shampoo containing nano-gold comprises the following steps:
step 1), adding 80-90% of solvent and guar hydroxypropyl trimethyl ammonium chloride into an emulsifying pot, uniformly stirring, then adding a pH regulator, and uniformly stirring to obtain a premix;
step 2), adding cetostearyl alcohol, pearling agent, coco monoethanolamide, di (hydrogenated tallow) phthalic acid amide and sodium laureth sulfate into the premix, heating to 85 ℃, uniformly stirring to obtain a mixture, and cooling;
step 3), adding cellulose, nano gold and the rest solvent into another homogenizing pot, homogenizing to obtain a homogeneous substance;
and 4) cooling the mixture to 45 ℃, adding the homogeneous substance, the emulsified silicone oil, the cocamidopropyl betaine and the sodium chloride into the mixture, and uniformly stirring to obtain the anti-dandruff shampoo containing the nano-gold.
By adopting the technical scheme, the prepared shampoo has excellent effects of sterilizing and inhibiting dandruff, has good cleaning effect and hair and scalp care effect, is not easy to be degraded after being stored for a long time, and has more stable quality.
In summary, the present application has the following beneficial effects:
1. the shampoo has excellent anti-dandruff and sterilizing effects by adding the nano gold, and can be permanently and stably uniformly distributed in the shampoo in the form of nano particles by compounding the cetylstearyl alcohol, the sodium chloride and the di (hydrogenated tallow) phthalic acid amide and then matching with the nano gold, so that flocculation phenomenon is not easy to occur, the anti-dandruff shampoo containing the nano gold is not easy to cause the reduction of antibacterial effect in long-term storage, and the good anti-dandruff effect can be permanently maintained, and the quality is good.
2. In the application, the mass ratio of the di (hydrogenated tallow) phthalic acid amide, the cetostearyl alcohol and the sodium chloride is preferably selected, so that the effect of the nano gold is better, and the excellent sterilizing and anti-dandruff effects can be well maintained after the nano gold is stored for a long time.
3. In the application, the conditioning agent is preferably formed by compounding guar hydroxypropyl trimethyl ammonium chloride and emulsified silicone oil, so that hair can be better conditioned, the hair is smoother, the hair quality is improved, the hair is not easy to be rough, and the hair is more attractive.
4. In the application, the surfactant is preferably formed by compounding the coconut monoethanolamide, the sodium laureth sulfate and the cocamidopropyl betaine, so that the cleaning effect on dirt on scalp and hair is better, the hair can be better cleaned, and the hair is cleaner and more attractive.
Detailed Description
The present application is described in further detail below with reference to examples.
Example 1
An anti-dandruff shampoo containing nano gold comprises the following components:
solvents, conditioning agents, pH regulators, thickeners, pearling agents, surfactants, di (hydrogenated tallow) phthalic acid amide, suspension stabilizers, nano gold and essence.
Wherein the solvent is deionized water, and the self-made solvent is self-made.
Wherein the conditioning agent is the compound of guar hydroxypropyl trimethyl ammonium chloride and emulsified silicone oil.
Guar hydroxypropyl trimethylammonium chloride is purchased from sorv corporation.
Silicone emulsions were purchased from KCC corporation.
Wherein the pH regulator is citric acid, which is purchased from the chemical company of the ridge.
Wherein, the thickener is the compounding of cetostearyl alcohol and sodium chloride.
Cetyl stearyl alcohol is purchased from De Yuan.
Sodium chloride is purchased from the chemical company of the ridge.
Wherein, the pearling agent is glycol stearate, which is purchased from Basv company.
Wherein the surfactant is the compound of coco monoethanolamide, sodium laureth sulfate and cocamidopropyl betaine.
Coconut monoethanolamide is purchased from basf corporation.
Sodium laureth sulfate was purchased from Huawang corporation.
Cocamidopropyl betaine is purchased from basf corporation.
Among them, bis (hydrogenated tallow) phthalic acid amide was purchased from Kagaku corporation.
Wherein the suspension stabilizer is cellulose, purchased from SAPPI company.
Wherein, the nano gold is purchased from Yu An Nate Fei company and has the particle size of 1-10nm.
Wherein, essence is purchased from Korean Bill company.
The preparation method of the anti-dandruff shampoo containing the nano-gold comprises the following steps:
step 1), 66kg of deionized water and 0.08kg of guar hydroxypropyl trimethyl ammonium chloride are put into an emulsifying pot, uniformly stirred, then 0.03kg of citric acid is added, and uniformly stirred, thus obtaining a premix.
Step 2), adding 0.45kg of cetostearyl alcohol, 0.75kg of glycol stearate, 0.75kg of coconut monoethanolamide, 0.35kg of di (hydrogenated tallow) phthalic acid amide and 15kg of sodium laureth sulfate into the premix, heating to 85 ℃, stirring uniformly to obtain a mixture, and cooling.
Step 3), adding 0.45kg of cellulose, 0.9kg of nano gold and 7.34kg of deionized water into another homogenizing pot, and homogenizing to obtain a homogeneous substance.
And 4) cooling the mixture to 45 ℃, adding the homogeneous substance, 1.9kg of emulsified silicone oil, 4.5kg of cocamidopropyl betaine, 1.1kg of sodium chloride and 0.4kg of essence into the mixture, and uniformly stirring to obtain the anti-dandruff shampoo containing the nano-gold.
Example 2
An anti-dandruff shampoo containing nano gold comprises the following components:
solvents, conditioning agents, pH regulators, thickeners, pearling agents, surfactants, di (hydrogenated tallow) phthalic acid amide, suspension stabilizers, nano gold and essence.
Wherein the solvent is deionized water, and the self-made solvent is self-made.
Wherein the conditioning agent is the compound of guar hydroxypropyl trimethyl ammonium chloride and emulsified silicone oil.
Guar hydroxypropyl trimethylammonium chloride is purchased from sorv corporation.
Silicone emulsions were purchased from KCC corporation.
Wherein the pH regulator is citric acid, which is purchased from the chemical company of the ridge.
Wherein, the thickener is the compounding of cetostearyl alcohol and sodium chloride.
Cetyl stearyl alcohol is purchased from De Yuan.
Sodium chloride is purchased from the chemical company of the ridge.
Wherein, the pearling agent is glycol stearate, which is purchased from Basv company.
Wherein the surfactant is the compound of coco monoethanolamide, sodium laureth sulfate and cocamidopropyl betaine.
Coconut monoethanolamide is purchased from basf corporation.
Sodium laureth sulfate was purchased from Huawang corporation.
Cocamidopropyl betaine is purchased from basf corporation.
Among them, bis (hydrogenated tallow) phthalic acid amide was purchased from Kagaku corporation.
Wherein the suspension stabilizer is cellulose, purchased from SAPPI company.
Wherein, the nano gold is purchased from Yu An Nate Fei company and has the particle size of 1-10nm.
Wherein, essence is purchased from Korean Bill company.
The preparation method of the anti-dandruff shampoo containing the nano-gold comprises the following steps:
step 1), adding 61.36kg of deionized water and 0.09kg of guar hydroxypropyl trimethyl ammonium chloride into an emulsifying pot, uniformly stirring, then adding 0.04kg of citric acid, and uniformly stirring to obtain a premix.
Step 2), adding 0.47kg of cetostearyl alcohol, 0.78kg of glycol stearate, 0.78kg of coconut monoethanolamide, 0.38kg of di (hydrogenated tallow) phthalic acid amide and 15.5kg of sodium laureth sulfate into the premix, heating to 85 ℃, stirring uniformly to obtain a mixture, and cooling.
Step 3), adding 0.47kg of cellulose, 1kg of nano gold and 10.83kg of deionized water into another homogenizing pot, and homogenizing to obtain a homogeneous substance.
And 4) cooling the mixture to 45 ℃, adding the homogeneous substance, 1.95kg of emulsified silicone oil, 4.75kg of cocamidopropyl betaine, 1.15kg of sodium chloride and 0.45kg of essence into the mixture, and uniformly stirring to obtain the anti-dandruff shampoo containing the nano-gold.
Example 3
An anti-dandruff shampoo containing nano gold comprises the following components:
solvents, conditioning agents, pH regulators, thickeners, pearling agents, surfactants, di (hydrogenated tallow) phthalic acid amide, suspension stabilizers, nano gold and essence.
Wherein the solvent is deionized water, and the self-made solvent is self-made.
Wherein the conditioning agent is the compound of guar hydroxypropyl trimethyl ammonium chloride and emulsified silicone oil.
Guar hydroxypropyl trimethylammonium chloride is purchased from sorv corporation.
Silicone emulsions were purchased from KCC corporation.
Wherein the pH regulator is citric acid, which is purchased from the chemical company of the ridge.
Wherein, the thickener is the compounding of cetostearyl alcohol and sodium chloride.
Cetyl stearyl alcohol is purchased from De Yuan.
Sodium chloride is purchased from the chemical company of the ridge.
Wherein, the pearling agent is glycol stearate, which is purchased from Basv company.
Wherein the surfactant is the compound of coco monoethanolamide, sodium laureth sulfate and cocamidopropyl betaine.
Coconut monoethanolamide is purchased from basf corporation.
Sodium laureth sulfate was purchased from Huawang corporation.
Cocamidopropyl betaine is purchased from basf corporation.
Among them, bis (hydrogenated tallow) phthalic acid amide was purchased from Kagaku corporation.
Wherein the suspension stabilizer is cellulose, purchased from SAPPI company.
Wherein, the nano gold is purchased from Yu An Nate Fei company and has the particle size of 1-10nm.
Wherein, essence is purchased from Korean Bill company.
The preparation method of the anti-dandruff shampoo containing the nano-gold comprises the following steps:
step 1), putting 56.84kg of deionized water and 0.1kg of guar hydroxypropyl trimethyl ammonium chloride into an emulsifying pot, uniformly stirring, then adding 0.05kg of citric acid, and uniformly stirring to obtain a premix.
Step 2), adding 0.5kg of cetostearyl alcohol, 0.8kg of glycol stearate, 0.8kg of coconut monoethanolamide, 0.4kg of di (hydrogenated tallow) phthalic acid amide and 16kg of sodium laureth sulfate into the premix, heating to 85 ℃, stirring uniformly to obtain a mixture, and cooling.
Step 3), adding 0.5kg of cellulose, 1.1kg of nano gold and 14.21kg of deionized water into another homogenizing pot, and homogenizing to obtain a homogeneous substance.
And 4) cooling the mixture to 45 ℃, adding the homogeneous substance, 2kg of emulsified silicone oil, 5kg of cocamidopropyl betaine, 1.2kg of sodium chloride and 0.5kg of essence into the mixture, and uniformly stirring to obtain the anti-dandruff shampoo containing the nano-gold.
Example 4
An anti-dandruff shampoo containing nano gold comprises the following components:
solvents, conditioning agents, pH regulators, thickeners, pearling agents, surfactants, di (hydrogenated tallow) phthalic acid amide, suspension stabilizers, nano gold and essence.
Wherein the solvent is deionized water, and the self-made solvent is self-made.
Wherein the conditioning agent is the compound of guar hydroxypropyl trimethyl ammonium chloride and emulsified silicone oil.
Guar hydroxypropyl trimethylammonium chloride is purchased from sorv corporation.
Silicone emulsions were purchased from KCC corporation.
Wherein the pH regulator is citric acid, which is purchased from the chemical company of the ridge.
Wherein, the thickener is the compounding of cetostearyl alcohol and sodium chloride.
Cetyl stearyl alcohol is purchased from De Yuan.
Sodium chloride is purchased from the chemical company of the ridge.
Wherein, the pearling agent is glycol stearate, which is purchased from Basv company.
Wherein the surfactant is the compound of coco monoethanolamide, sodium laureth sulfate and cocamidopropyl betaine.
Coconut monoethanolamide is purchased from basf corporation.
Sodium laureth sulfate was purchased from Huawang corporation.
Cocamidopropyl betaine is purchased from basf corporation.
Among them, bis (hydrogenated tallow) phthalic acid amide was purchased from Kagaku corporation.
Wherein the suspension stabilizer is cellulose, purchased from SAPPI company.
Wherein, the nano gold is purchased from Yu An Nate Fei company and has the particle size of 1-10nm.
Wherein, essence is purchased from Korean Bill company.
The preparation method of the anti-dandruff shampoo containing the nano-gold comprises the following steps:
step 1), adding 61.36kg of deionized water and 0.09kg of guar hydroxypropyl trimethyl ammonium chloride into an emulsifying pot, uniformly stirring, then adding 0.04kg of citric acid, and uniformly stirring to obtain a premix.
Step 2), adding 0.27 kg of cetostearyl alcohol, 0.78kg of glycol stearate, 0.78kg of coconut monoethanolamide, 0.38kg of di (hydrogenated tallow) phthalic acid amide and 15.5kg of sodium laureth sulfate into the premix, heating to 85 ℃, stirring uniformly to obtain a mixture, and cooling.
Step 3), adding 0.47kg of cellulose, 1kg of nano gold and 10.83kg of deionized water into another homogenizing pot, and homogenizing to obtain a homogeneous substance.
And 4) cooling the mixture to 45 ℃, adding the homogeneous substance, 1.95kg of emulsified silicone oil, 4.75kg of cocamidopropyl betaine, 1.35kg of sodium chloride and 0.45kg of essence into the mixture, and uniformly stirring to obtain the anti-dandruff shampoo containing the nano-gold.
Example 5
An anti-dandruff shampoo containing nano gold comprises the following components:
solvents, conditioning agents, pH regulators, thickeners, pearling agents, surfactants, di (hydrogenated tallow) phthalic acid amide, suspension stabilizers, nano gold and essence.
Wherein the solvent is deionized water, and the self-made solvent is self-made.
Wherein the conditioning agent is the compound of guar hydroxypropyl trimethyl ammonium chloride and emulsified silicone oil.
Guar hydroxypropyl trimethylammonium chloride is purchased from sorv corporation.
Silicone emulsions were purchased from KCC corporation.
Wherein the pH regulator is citric acid, which is purchased from the chemical company of the ridge.
Wherein, the thickener is the compounding of cetostearyl alcohol and sodium chloride.
Cetyl stearyl alcohol is purchased from De Yuan.
Sodium chloride is purchased from the chemical company of the ridge.
Wherein, the pearling agent is glycol stearate, which is purchased from Basv company.
Wherein the surfactant is the compound of coco monoethanolamide, sodium laureth sulfate and cocamidopropyl betaine.
Coconut monoethanolamide is purchased from basf corporation.
Sodium laureth sulfate was purchased from Huawang corporation.
Cocamidopropyl betaine is purchased from basf corporation.
Among them, bis (hydrogenated tallow) phthalic acid amide was purchased from Kagaku corporation.
Wherein the suspension stabilizer is cellulose, purchased from SAPPI company.
Wherein, the nano gold is purchased from Yu An Nate Fei company and has the particle size of 1-10nm.
Wherein, essence is purchased from Korean Bill company.
The preparation method of the anti-dandruff shampoo containing the nano-gold comprises the following steps:
step 1), adding 61.36kg of deionized water and 0.09kg of guar hydroxypropyl trimethyl ammonium chloride into an emulsifying pot, uniformly stirring, then adding 0.04kg of citric acid, and uniformly stirring to obtain a premix.
Step 2), adding 0.67 kg of cetostearyl alcohol, 0.78kg of glycol stearate, 0.78kg of coconut monoethanolamide, 0.38kg of di (hydrogenated tallow) phthalic acid amide and 15.5kg of sodium laureth sulfate into the premix, heating to 85 ℃, stirring uniformly to obtain a mixture, and cooling.
Step 3), adding 0.47kg of cellulose, 1kg of nano gold and 10.83kg of deionized water into another homogenizing pot, and homogenizing to obtain a homogeneous substance.
And 4) cooling the mixture to 45 ℃, adding the homogeneous substance, 1.95kg of emulsified silicone oil, 4.75kg of cocamidopropyl betaine, 0.95kg of sodium chloride and 0.45kg of essence into the mixture, and uniformly stirring to obtain the anti-dandruff shampoo containing the nano-gold.
Comparative example 1
An antidandruff shampoo containing nanogold differs from example 2 only in that:
equivalent substitution of bis (hydrogenated tallow) phthalic acid amide with PEG-10 polydimethylsiloxane.
Among them, PEG-10 polydimethylsiloxane is commercially available from CAS number: 68937-54-2.
Comparative example 2
An antidandruff shampoo containing nanogold differs from example 2 only in that:
equal amounts of behenyl alcohol were used instead of cetostearyl alcohol.
Wherein, behenyl alcohol is from commercial, CAS number: 661-19-8.
Comparative example 3
An antidandruff shampoo containing nanogold differs from example 2 only in that:
magnesium chloride was used in place of sodium chloride in equal amounts.
Wherein, magnesium chloride is from commercial market, CAS number: 7786-30-3.
Comparative example 4
An antidandruff shampoo containing nanogold differs from example 2 only in that:
equivalent substitution of bis (hydrogenated tallow) phthalic acid amide with PEG-10 polydimethylsiloxane.
Equal amounts of behenyl alcohol were used instead of cetostearyl alcohol.
Magnesium chloride was used in place of sodium chloride in equal amounts.
Among them, PEG-10 polydimethylsiloxane is commercially available from CAS number: 68937-54-2.
Wherein, behenyl alcohol is from commercial, CAS number: 661-19-8.
Wherein, magnesium chloride is from commercial market, CAS number: 7786-30-3.
Experiment 1
According to the bacteriostasis ring method of QB/T2738-2012 (evaluation method of antibacterial and bacteriostatic effect of daily chemical products) 7.5, the antibacterial effect of the anti-dandruff shampoo containing nano-gold prepared by each example and comparative example is detected, the antibacterial effect is evaluated by the diameter of the bacteriostasis ring, and the larger the diameter of the bacteriostasis ring is, the better the antibacterial effect is, and the diameter of the bacteriostasis ring is larger than 7mm, so that the anti-dandruff shampoo containing nano-gold has the antibacterial effect.
Placing the anti-dandruff shampoo containing the nano gold prepared in each example and comparative example in a transparent glass bottle, opening, keeping the temperature at 45 ℃ and the constant humidity at 90%, performing accelerated aging, standing for 30 days, sampling, detecting according to the QB/T2738-2012 antibacterial and bacteriostatic effect evaluation method of daily chemical products, 7.5 antibacterial ring method, marking as the diameter of the antibacterial ring after storage, and judging the stability of the anti-dandruff shampoo containing the nano gold after storage according to the change of antibacterial effect.
Test strain: malassezia furfur, strain number: ATCC 44344.
When the antibacterial effect of the freshly prepared anti-dandruff shampoo containing nano-gold is tested, the concentration of the bacterial suspension for test is 7.9x10 5 The method comprises the steps of carrying out a first treatment on the surface of the When the antibacterial effect of the stored anti-dandruff shampoo containing nano-gold is tested, the concentration of the bacterial suspension for test is 7.8x10 5 。
The specific test data for experiment 1 are detailed in table 1.
TABLE 1
| Diameter of inhibition ring (mm) | Diameter (mm) of bacteriostasis ring after storage | |
| Example 1 | 24.88 | 22.72 |
| Example 2 | 24.95 | 22.77 |
| Example 3 | 24.93 | 22.74 |
| Example 4 | 24.89 | 22.24 |
| Example 5 | 24.94 | 22.33 |
| Comparative example 1 | 24.91 | 6.25 |
| Comparative example 2 | 24.86 | 6.37 |
| Comparative example 3 | 24.92 | 6.19 |
| Comparative example 4 | 24.87 | 6.42 |
According to the data in table 1, the comparison between the examples and the comparative examples shows that when the bis (hydrogenated tallow) phthalic acid amide, cetostearyl alcohol and sodium chloride are adopted for compounding, the stability of the nano gold is higher, the shampoo of each example still maintains good antibacterial effect after being stored for 30 days under the accelerated aging condition, the antibacterial effect of the shampoo of each comparative example is less changed, the antibacterial effect of the shampoo of each comparative example is obviously reduced, and the phenomenon that the antibacterial effect is invalid due to flocculation of the nano gold is caused by changing the compounding system of the bis (hydrogenated tallow) phthalic acid amide, cetylstearyl alcohol and sodium chloride is proved, so that the shampoo of each example has longer lasting stability and better quality.
According to the data in Table 1, the comparison of examples 1-3 with examples 4-5 shows that the effect of maintaining the stability of the nanogold in the shampoo is better when bis (hydrogenated tallow) phthalic acid amide, cetostearyl alcohol, sodium chloride are compounded in a specific ratio, the diameter of the bacteriostasis ring is reduced less after 30 days of storage under accelerated aging conditions, and the shampoo of examples 1-3 has more durable stability and better quality.
The present embodiment is merely illustrative of the present application and is not intended to be limiting, and those skilled in the art, after having read the present specification, may make modifications to the present embodiment without creative contribution as required, but is protected by patent laws within the scope of the claims of the present application.
Claims (6)
1. An anti-dandruff shampoo containing nano-gold, which is characterized in that: the composite material consists of the following components in parts by weight:
71.05-73.34 minutes of solvent;
1.98-2.1 parts of conditioner;
0.03-0.05 part of pH regulator;
1.55-1.7 parts of thickener;
0.75-0.8 part of pearling agent;
20.25-21.8 parts of surfactant;
0.35-0.4 parts of di (hydrogenated tallow) phthalic acid amide;
0.45-0.5 part of suspension stabilizer;
0.9-1.1 parts of nano gold;
0-0.5 part of essence;
the thickener is the compounding of cetostearyl alcohol and sodium chloride;
the mass ratio of the cetostearyl alcohol to the sodium chloride is 0.45-0.5:1.1-1.2.
2. An anti-dandruff shampoo comprising nanogold according to claim 1, wherein: the mass ratio of the di (hydrogenated tallow) phthalic acid amide to the cetostearyl alcohol to the sodium chloride is 0.38:0.47:1.15.
3. an anti-dandruff shampoo comprising nanogold according to claim 1, wherein: the conditioning agent is the compound of guar hydroxypropyl trimethyl ammonium chloride and emulsified silicone oil.
4. A nano-gold containing anti-dandruff shampoo according to claim 3, wherein: the mass ratio of the guar hydroxypropyl trimethyl ammonium chloride to the emulsified silicone oil is 0.08-0.1:1.9-2.
5. An anti-dandruff shampoo comprising nanogold according to claim 1, wherein: the surfactant is the compound of coco monoethanolamide, sodium laureth sulfate and cocamidopropyl betaine.
6. The anti-dandruff shampoo comprising nanogold according to claim 5, wherein: the mass ratio of the coco monoethanolamide to sodium laureth sulfate to the coco amidopropyl betaine is 0.75-0.8:15-16:4.5-5.
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