CN116583631A - 使用液体金属坩埚的用于高熔点金属氧化物的还原系统和方法 - Google Patents
使用液体金属坩埚的用于高熔点金属氧化物的还原系统和方法 Download PDFInfo
- Publication number
- CN116583631A CN116583631A CN202180084249.3A CN202180084249A CN116583631A CN 116583631 A CN116583631 A CN 116583631A CN 202180084249 A CN202180084249 A CN 202180084249A CN 116583631 A CN116583631 A CN 116583631A
- Authority
- CN
- China
- Prior art keywords
- metal
- raw material
- flux
- liquid
- alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910044991 metal oxide Inorganic materials 0.000 title claims abstract description 97
- 150000004706 metal oxides Chemical class 0.000 title claims abstract description 97
- 230000009467 reduction Effects 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims description 113
- 229910001338 liquidmetal Inorganic materials 0.000 title claims description 105
- 239000003870 refractory metal Substances 0.000 title description 3
- 229910052751 metal Inorganic materials 0.000 claims abstract description 217
- 239000002184 metal Substances 0.000 claims abstract description 217
- 239000002994 raw material Substances 0.000 claims description 101
- 229910045601 alloy Inorganic materials 0.000 claims description 91
- 239000000956 alloy Substances 0.000 claims description 91
- 230000004907 flux Effects 0.000 claims description 73
- 230000008569 process Effects 0.000 claims description 64
- 239000010410 layer Substances 0.000 claims description 63
- 238000000465 moulding Methods 0.000 claims description 62
- 239000007787 solid Substances 0.000 claims description 49
- 239000006227 byproduct Substances 0.000 claims description 39
- 239000001301 oxygen Substances 0.000 claims description 39
- 229910052760 oxygen Inorganic materials 0.000 claims description 39
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 38
- 238000006243 chemical reaction Methods 0.000 claims description 30
- 239000012792 core layer Substances 0.000 claims description 30
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 29
- 150000002739 metals Chemical class 0.000 claims description 17
- 230000003647 oxidation Effects 0.000 claims description 17
- 238000007254 oxidation reaction Methods 0.000 claims description 17
- 230000005496 eutectics Effects 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 16
- 230000005484 gravity Effects 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- 229910052721 tungsten Inorganic materials 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 10
- 238000007670 refining Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 8
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 7
- 150000004820 halides Chemical class 0.000 claims description 6
- 239000011261 inert gas Substances 0.000 claims description 6
- 229910052749 magnesium Inorganic materials 0.000 claims description 6
- 229910016036 BaF 2 Inorganic materials 0.000 claims description 5
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- 150000001340 alkali metals Chemical class 0.000 claims description 5
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 5
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 5
- 238000011084 recovery Methods 0.000 claims description 5
- 229910004261 CaF 2 Inorganic materials 0.000 claims description 4
- 229910052770 Uranium Inorganic materials 0.000 claims description 4
- 229910000905 alloy phase Inorganic materials 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 229910052720 vanadium Inorganic materials 0.000 claims description 4
- 238000010924 continuous production Methods 0.000 claims description 3
- 230000002265 prevention Effects 0.000 claims description 3
- 239000010936 titanium Substances 0.000 description 24
- 238000006722 reduction reaction Methods 0.000 description 22
- 239000011777 magnesium Substances 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 11
- 230000007613 environmental effect Effects 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 229910010380 TiNi Inorganic materials 0.000 description 8
- 238000006757 chemical reactions by type Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 239000003638 chemical reducing agent Substances 0.000 description 7
- 239000010949 copper Substances 0.000 description 7
- 239000012467 final product Substances 0.000 description 7
- 229910010413 TiO 2 Inorganic materials 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 230000004888 barrier function Effects 0.000 description 4
- 230000000903 blocking effect Effects 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 229910001510 metal chloride Inorganic materials 0.000 description 4
- 238000004611 spectroscopical analysis Methods 0.000 description 4
- 238000005275 alloying Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 229910020599 Co 3 O 4 Inorganic materials 0.000 description 2
- 229910005191 Ga 2 O 3 Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- -1 oxides Substances 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 229910018068 Li 2 O Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241000275031 Nica Species 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 229910052769 Ytterbium Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/36—Alloys obtained by cathodic reduction of all their ions
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/26—Electrolytic production, recovery or refining of metals by electrolysis of melts of titanium, zirconium, hafnium, tantalum or vanadium
- C25C3/28—Electrolytic production, recovery or refining of metals by electrolysis of melts of titanium, zirconium, hafnium, tantalum or vanadium of titanium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/1263—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds, e.g. by reduction
- C22B34/1268—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds, e.g. by reduction using alkali or alkaline-earth metals or amalgams
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/1263—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds, e.g. by reduction
- C22B34/1277—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds, e.g. by reduction using other metals, e.g. Al, Si, Mn
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B5/00—General methods of reducing to metals
- C22B5/02—Dry methods smelting of sulfides or formation of mattes
- C22B5/04—Dry methods smelting of sulfides or formation of mattes by aluminium, other metals or silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/04—Refining by applying a vacuum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/05—Refining by treating with gases, e.g. gas flushing also refining by means of a material generating gas in situ
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/10—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals with refining or fluxing agents; Use of materials therefor, e.g. slagging or scorifying agents
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/14—Refining in the solid state
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/26—Electrolytic production, recovery or refining of metals by electrolysis of melts of titanium, zirconium, hafnium, tantalum or vanadium
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/30—Electrolytic production, recovery or refining of metals by electrolysis of melts of manganese
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/34—Electrolytic production, recovery or refining of metals by electrolysis of melts of metals not provided for in groups C25C3/02 - C25C3/32
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/005—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells of cells for the electrolysis of melts
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/06—Operating or servicing
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Electrolytic Production Of Metals (AREA)
- Crucibles And Fluidized-Bed Furnaces (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2020-0154081 | 2020-11-17 | ||
KR1020200154081A KR102386696B1 (ko) | 2020-11-17 | 2020-11-17 | 액상 금속 도가니를 이용한 고융점 금속 산화물의 환원 시스템 및 방법 |
PCT/KR2021/003848 WO2022108006A1 (ko) | 2020-11-17 | 2021-03-29 | 액상 금속 도가니를 이용한 고융점 금속 산화물의 환원 시스템 및 방법 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN116583631A true CN116583631A (zh) | 2023-08-11 |
Family
ID=81212205
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202180084249.3A Pending CN116583631A (zh) | 2020-11-17 | 2021-03-29 | 使用液体金属坩埚的用于高熔点金属氧化物的还原系统和方法 |
Country Status (8)
Country | Link |
---|---|
US (1) | US20240026555A1 (ja) |
EP (1) | EP4249643A1 (ja) |
JP (1) | JP2023549557A (ja) |
KR (1) | KR102386696B1 (ja) |
CN (1) | CN116583631A (ja) |
AU (1) | AU2021382943A1 (ja) |
CA (1) | CA3200992A1 (ja) |
WO (1) | WO2022108006A1 (ja) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102638196B1 (ko) * | 2023-06-23 | 2024-02-16 | 충남대학교산학협력단 | Ⅳ족 전이금속 산화물로부터 저산소 전이금속 분말을 제조하기 위한 열환원 반응 혼합물과 이를 이용한 저산소 전이금속 분말 제조방법 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5035404A (en) | 1990-09-13 | 1991-07-30 | Westinghouse Electric Corp. | Retort assembly for kroll reductions |
JP2000239836A (ja) * | 1999-02-23 | 2000-09-05 | Japan Energy Corp | 高純度銅または銅合金スパッタリングターゲットおよびその製造方法 |
WO2003046258A2 (en) * | 2001-11-22 | 2003-06-05 | Qit - Fer Et Titane Inc. | A method for electrowinning of titanium metal or alloy from titanium oxide containing compound in the liquid state |
JP4955008B2 (ja) * | 2006-10-03 | 2012-06-20 | Jx日鉱日石金属株式会社 | Cu−Mn合金スパッタリングターゲット及び半導体配線 |
KR101878652B1 (ko) * | 2017-07-12 | 2018-07-16 | 충남대학교산학협력단 | 전해환원 및 전해정련 일관공정에 의한 금속 정련 방법 |
KR102004920B1 (ko) * | 2019-01-28 | 2019-07-29 | 한국지질자원연구원 | 액체금속 음극을 이용한 금속 제련 방법 |
-
2020
- 2020-11-17 KR KR1020200154081A patent/KR102386696B1/ko active IP Right Grant
-
2021
- 2021-03-29 EP EP21894785.1A patent/EP4249643A1/en active Pending
- 2021-03-29 CN CN202180084249.3A patent/CN116583631A/zh active Pending
- 2021-03-29 JP JP2023529926A patent/JP2023549557A/ja active Pending
- 2021-03-29 WO PCT/KR2021/003848 patent/WO2022108006A1/ko active Application Filing
- 2021-03-29 US US18/253,346 patent/US20240026555A1/en active Pending
- 2021-03-29 CA CA3200992A patent/CA3200992A1/en active Pending
- 2021-03-29 AU AU2021382943A patent/AU2021382943A1/en active Pending
Also Published As
Publication number | Publication date |
---|---|
WO2022108006A1 (ko) | 2022-05-27 |
AU2021382943A1 (en) | 2023-06-29 |
EP4249643A1 (en) | 2023-09-27 |
KR102386696B1 (ko) | 2022-04-15 |
CA3200992A1 (en) | 2022-05-27 |
US20240026555A1 (en) | 2024-01-25 |
JP2023549557A (ja) | 2023-11-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Fray et al. | Reduction of titanium and other metal oxides using electrodeoxidation | |
EP1957683B1 (en) | Thermal and electrochemical process for metal production | |
EP2109691B1 (en) | Metallothermic reduction of in-situ generated titanium chloride | |
CN108138343B (zh) | 利用电解还原和电解精炼工序的金属精炼方法 | |
Takeda et al. | Rare earth, titanium group metals, and reactive metals production | |
WO2005019501A2 (en) | Thermal and electrochemical process for metal production | |
JP5719972B2 (ja) | 金属回収方法とその方法を行うための電解装置 | |
WO2014207834A1 (ja) | Al-Sc合金の製造方法 | |
KR101878652B1 (ko) | 전해환원 및 전해정련 일관공정에 의한 금속 정련 방법 | |
CN116583631A (zh) | 使用液体金属坩埚的用于高熔点金属氧化物的还原系统和方法 | |
WO2006098199A1 (ja) | 高融点金属の分離回収方法 | |
WO2016176732A1 (en) | Novel synthetic rutile products and processes for their production | |
EA037505B1 (ru) | Способ получения композитного материала с использованием избытка окислителя | |
CN114945692B (zh) | 金属除去方法和金属回收方法 | |
US20230070997A1 (en) | Metal removal agent | |
KR101740424B1 (ko) | 일메나이트 원광을 이용한 금속 티타늄의 제조방법 | |
EP4249644A1 (en) | Reduction method and system for high-melting-point metal oxide, using fluoride-based electrolytes | |
WO2010131970A1 (en) | Process for separating hafnium and zirconium | |
KR20230081581A (ko) | 금속 정련방법 및 금속 전해환원장치 | |
JP2022168438A (ja) | マンガン回収方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination |