CN116376645A - Hypochlorous acid type disinfection detergent and preparation method thereof - Google Patents
Hypochlorous acid type disinfection detergent and preparation method thereof Download PDFInfo
- Publication number
- CN116376645A CN116376645A CN202310058292.3A CN202310058292A CN116376645A CN 116376645 A CN116376645 A CN 116376645A CN 202310058292 A CN202310058292 A CN 202310058292A CN 116376645 A CN116376645 A CN 116376645A
- Authority
- CN
- China
- Prior art keywords
- hypochlorous acid
- percent
- detergent
- disinfectant
- decomposer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 title claims abstract description 117
- 239000003599 detergent Substances 0.000 title claims abstract description 34
- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims description 20
- 239000000645 desinfectant Substances 0.000 claims abstract description 44
- 230000001877 deodorizing effect Effects 0.000 claims abstract description 24
- 239000012190 activator Substances 0.000 claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 22
- 229940100530 zinc ricinoleate Drugs 0.000 claims abstract description 21
- GAWWVVGZMLGEIW-GNNYBVKZSA-L zinc ricinoleate Chemical compound [Zn+2].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O.CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O GAWWVVGZMLGEIW-GNNYBVKZSA-L 0.000 claims abstract description 21
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000460 chlorine Substances 0.000 claims abstract description 20
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 20
- 239000004094 surface-active agent Substances 0.000 claims abstract description 17
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229910000403 monosodium phosphate Inorganic materials 0.000 claims abstract description 6
- 235000019799 monosodium phosphate Nutrition 0.000 claims abstract description 6
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims abstract description 6
- CXVGEDCSTKKODG-UHFFFAOYSA-N sulisobenzone Chemical compound C1=C(S(O)(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC=CC=C1 CXVGEDCSTKKODG-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229960000368 sulisobenzone Drugs 0.000 claims abstract description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 20
- 229920002125 Sokalan® Polymers 0.000 claims description 19
- 239000007788 liquid Substances 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 15
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 11
- 229920001577 copolymer Polymers 0.000 claims description 11
- 239000002781 deodorant agent Substances 0.000 claims description 11
- 239000004584 polyacrylic acid Substances 0.000 claims description 11
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 10
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 10
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 10
- 239000011780 sodium chloride Substances 0.000 claims description 10
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 10
- 238000005303 weighing Methods 0.000 claims description 10
- -1 polyethylene oxazolidone Polymers 0.000 claims description 9
- GIYMJJRYEFFRKQ-UHFFFAOYSA-K [Na+].[Na+].[Na+].CNCC(=O)[O-].CNCC(=O)[O-].CNCC(=O)[O-] Chemical compound [Na+].[Na+].[Na+].CNCC(=O)[O-].CNCC(=O)[O-].CNCC(=O)[O-] GIYMJJRYEFFRKQ-UHFFFAOYSA-K 0.000 claims description 8
- 150000002191 fatty alcohols Chemical class 0.000 claims description 8
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 8
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 8
- 239000003945 anionic surfactant Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 239000002736 nonionic surfactant Substances 0.000 claims description 7
- 108010077895 Sarcosine Proteins 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 6
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 6
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 6
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 6
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 6
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- RPZANUYHRMRTTE-UHFFFAOYSA-N 2,3,4-trimethoxy-6-(methoxymethyl)-5-[3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxyoxane;1-[[3,4,5-tris(2-hydroxybutoxy)-6-[4,5,6-tris(2-hydroxybutoxy)-2-(2-hydroxybutoxymethyl)oxan-3-yl]oxyoxan-2-yl]methoxy]butan-2-ol Chemical compound COC1C(OC)C(OC)C(COC)OC1OC1C(OC)C(OC)C(OC)OC1COC.CCC(O)COC1C(OCC(O)CC)C(OCC(O)CC)C(COCC(O)CC)OC1OC1C(OCC(O)CC)C(OCC(O)CC)C(OCC(O)CC)OC1COCC(O)CC RPZANUYHRMRTTE-UHFFFAOYSA-N 0.000 claims description 5
- 229920000805 Polyaspartic acid Polymers 0.000 claims description 5
- 239000002202 Polyethylene glycol Substances 0.000 claims description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 5
- 239000004615 ingredient Substances 0.000 claims description 5
- 108010064470 polyaspartate Proteins 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 5
- 238000004062 sedimentation Methods 0.000 claims description 5
- 239000001509 sodium citrate Substances 0.000 claims description 5
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 5
- 230000001502 supplementing effect Effects 0.000 claims description 5
- 239000004034 viscosity adjusting agent Substances 0.000 claims description 5
- 238000013329 compounding Methods 0.000 claims description 4
- 238000004332 deodorization Methods 0.000 claims description 4
- 239000000796 flavoring agent Substances 0.000 claims description 4
- 235000019634 flavors Nutrition 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 102000029797 Prion Human genes 0.000 claims description 3
- 108091000054 Prion Proteins 0.000 claims description 3
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 3
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 3
- UZVUJVFQFNHRSY-OUTKXMMCSA-J tetrasodium;(2s)-2-[bis(carboxylatomethyl)amino]pentanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC[C@@H](C([O-])=O)N(CC([O-])=O)CC([O-])=O UZVUJVFQFNHRSY-OUTKXMMCSA-J 0.000 claims description 3
- 238000004090 dissolution Methods 0.000 claims description 2
- 238000011012 sanitization Methods 0.000 claims 7
- 230000000249 desinfective effect Effects 0.000 claims 1
- 235000013599 spices Nutrition 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 7
- MLDWGLQSBBCMMO-UHFFFAOYSA-N [Na].[Na].[Na].CNCC(=O)O Chemical compound [Na].[Na].[Na].CNCC(=O)O MLDWGLQSBBCMMO-UHFFFAOYSA-N 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 12
- 230000001954 sterilising effect Effects 0.000 description 12
- 238000005406 washing Methods 0.000 description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 239000000341 volatile oil Substances 0.000 description 6
- 238000005286 illumination Methods 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 235000005979 Citrus limon Nutrition 0.000 description 4
- 244000131522 Citrus pyriformis Species 0.000 description 4
- 229910021645 metal ion Inorganic materials 0.000 description 4
- 244000178870 Lavandula angustifolia Species 0.000 description 3
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 3
- 239000001102 lavandula vera Substances 0.000 description 3
- 235000018219 lavender Nutrition 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2072—Aldehydes-ketones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
- C11D3/485—Halophors, e.g. iodophors
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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Abstract
The invention relates to a hypochlorous acid type disinfection detergent. The anti-stain disinfectant is prepared from, by mass, 15% -25% of a surfactant, 1% -3% of an anti-stain redeposition agent, 0.1% -1% of a hypochlorous acid slowing down decomposer, 0.5% -2% of a viscosity regulator, 0.3% -0.5% of zinc ricinoleate, 0.2% -0.5% of a deodorizing activator, 0.1% -0.3% of essence, and the balance of hypochlorous acid disinfectant (the effective chlorine content of which is 200ppm +/-30 ppm), wherein the hypochlorous acid slowing down decomposer is compounded by trisodium methylglycine diacetate, disodium hydrogen phosphate, sodium dihydrogen phosphate and benzophenone-4 according to a mass ratio of 3:10:5:2. The invention solves the technical restriction of the stability of hypochlorous acid disinfection products, realizes the disinfection detergent of hypochlorous acid derivative products, scientifically endows the product with the functions of deodorizing and the like, and can meet various demands of people on daily disinfection, cleaning and deodorizing.
Description
Technical Field
The invention relates to hypochlorous acid type disinfection detergent and a preparation method thereof.
Background
Hypochlorous acid itself has instability, so that it is stored at normal temperature in the absence of light during storage, and it is necessary to secure sealability. Hypochlorous acid is usually prepared in the prior art, the pH and the available chlorine content of the product are reduced along with the extension of the standing time, the sterilization efficacy is reduced and even gradually disappears due to the reduced performance, and the national chlorine-containing disinfectant standard cannot be met. Hypochlorous acid is difficult to derive from other products than the single product which is used as a disinfectant due to its poor stability.
At present, some so-called hypochlorous acid stabilizers in the industry are basically prepared by adding hypochlorous acid stabilizer into hypochlorous acid solution, and the effect is that the storage time of the hypochlorous acid solution is prolonged as compared with single hypochlorous acid stabilizer, but the problem that the hypochlorous acid needs to be protected from light and sealed and other severe storage conditions during storage is not solved, and the problem that other products are difficult to be derived due to poor stability of the hypochlorous acid is not solved.
Through the query and search related prior art we search for a patent document with a similarity in technology: application number: CN 202210861173.7, name: the document discloses a hypochlorous acid disinfectant and a preparation method thereof, wherein the hypochlorous acid disinfectant comprises the following raw materials in percentage by weight: 70-80% of hypochlorous acid solution, 2-3% of surfactant, 3-5% of washing aid, 2-5% of sodium chloride, 15-20% of ethanol, 2-3% of lemon extract and 0.01-0.03% of inorganic acid.
It was analyzed that we considered the following disadvantages: 1. the most important point is that the product in the technical scheme is still a hypochlorous disinfectant, and the problem of poor hypochlorous acid stability still exists, so that the product still has the problems of light shielding, sealing, short shelf life and the like when being stored. 2. The adjuvants such as surfactant, washing aid and ethanol are added in the product because the greasy dirt on the article can form a water-oil complex, and bacteria can form a water-oil protective film on the surface of the product by utilizing the water-oil complex. The product exhibits very single and very general detergency and therefore is not a laundry product or a disinfectant.
Disclosure of Invention
The invention aims to provide a hypochlorous acid sterilizing detergent and a preparation method thereof, which firstly solve the technical problem of stability of hypochlorous acid sterilizing products, and can ensure that the detergent combined with hypochlorous acid can well utilize the high-efficiency sterilizing performance of hypochlorous acid, the product also has the advantages of more illumination resistance, no need of sealed storage, greatly prolonged effective period of hypochlorous acid, contact with articles with metal ions and the like, and scientifically endows the product with the functions of deodorizing and the like, and the washing capability of the product meets the requirement of washing products on the washing performance, and can simultaneously meet various demands of people on daily sterilization, cleaning and deodorization.
The invention aims at realizing the purposes, and adopts the following technical scheme:
the invention relates to a hypochlorous acid type disinfection detergent which is prepared from the following components in percentage by mass: 15% -25% of surfactant, 1% -3% of anti-stain redeposition agent, 0.1% -1% of hypochlorous acid slow-down decomposer, 0.5% -2% of viscosity regulator, 0.3% -0.5% of zinc ricinoleate, 0.2% -0.5% of deodorizing activator and 0.1% -0.3% of essence, and the balance is complemented by hypochlorous acid disinfectant (the effective chlorine content of which is 200ppm +/-30 ppm), wherein the hypochlorous acid slow-down decomposer is formed by compounding trisodium methylglycinate, disodium hydrogen phosphate, sodium dihydrogen phosphate and benzophenone-4 according to the mass ratio of 3:10:5:2.
Furthermore, the hypochlorous acid type disinfection detergent disclosed by the invention can be added with 0.3% -0.5% of zinc ricinoleate and 0.2% -0.5% of deodorizing activator in the formula, and the balance is complemented by hypochlorous acid disinfectant (the effective chlorine content is 200ppm +/-30 ppm).
Further, the optimized formula composition of the hypochlorous acid type disinfection detergent disclosed by the invention is as follows: 15% -17% of surfactant, 1% -2% of anti-stain redeposition agent, 0.5% -1% of hypochlorous acid slow-down decomposer, 0.5% -2% of viscosity regulator, 0.3% -0.5% of zinc ricinoleate, 0.2% -0.5% of deodorizing activator, 0.1% -0.3% of essence, and the balance of the disinfectant is complemented by hypochlorous acid disinfectant (the effective chlorine content of the disinfectant is 200ppm +/-30 ppm).
Further, the surfactant according to the present invention includes both anionic surfactant and nonionic surfactant.
Further, the surfactant disclosed by the invention comprises two types of sodium dodecyl benzene sulfonate and isomeric fatty alcohol polyoxyethylene ether; the anti-stain redeposition agent is any one of sodium carboxymethyl cellulose (CMC), polyvinylpyrrolidone (PVP), polyvinyl alcohol (PVA), polyacrylic acid (PAA) and acrylic acid/maleic anhydride copolymer (PAA/MA), hydroxypropyl methyl cellulose sodium (HPMC), hydroxybutyl methyl cellulose (HBMC), alcohol-soluble prion (a protein), polyvinylpyrrolidone, polyethylene glycol (PEG) and Polyaspartic Acid (PASP); the deodorizing activator is one of trisodium methylglycinate diacetate and sodium glutamate diacetate; the viscosity regulator is one or two of hydroxypropyl methyl cellulose, hydroxyethyl methyl cellulose and sodium chloride; the essence can be conventional daily chemical essence.
Further, the hypochlorous acid type disinfection detergent disclosed by the invention is prepared from the following components in percentage by mass: 10-15% of sodium dodecyl benzene sulfonate, 5-10% of heterogeneous fatty alcohol polyoxyethylene ether, 1-3% of polyacrylic acid (PAA) and acrylic acid/maleic anhydride copolymer (PAA/MA) (namely anti-stain redeposition agent), 0.5-2% of sodium citrate, 0.5-2% of sodium chloride (namely viscosity modifier), 0.1-1% of hypochlorous acid slow-down decomposer, 0.3-0.5% of zinc ricinoleate, 0.2-0.5% of methyl glycine disodium diacetate (namely deodorization activator), and 0.1-0.3% of essence can be adopted as conventional daily flavors and auxiliary materials, and the balance is complemented by hypochlorous acid disinfectant (the effective chlorine content of which is 200 ppm+/-30 ppm).
Further, the optimal formulation of the hypochlorous acid type disinfection detergent provided by the invention is as follows: 8% -12% of sodium dodecyl benzene sulfonate, 4% -7% of heterogeneous fatty alcohol polyoxyethylene ether, 0.5% -1.0% of polyacrylic acid (PAA) and acrylic acid/maleic anhydride copolymer (PAA/MA) (namely anti-stain redeposition agent), 0.5% -1% of sodium citrate, 0.8% -1.5% of sodium chloride (namely viscosity modifier), 0.5% -1.0% of hypochlorous acid slow-down decomposer, 0.5% of zinc ricinoleate, 0.5% of methyl glycine disodium diacetate (namely deodorizing activator), 0.2% of daily flavor and auxiliary materials, and the balance of the composition is complemented by hypochlorous acid disinfectant (the effective chlorine content of which is 200 ppm+/-30 ppm).
The preparation method of the hypochlorous acid type disinfection detergent comprises the following steps:
weighing ingredients: weighing the components according to the proportion, and respectively placing the components in respective special containers for later use;
prefabricating a deodorant: pre-mixing zinc ricinoleate and a deodorizing activator, and uniformly stirring for later use;
(III) stirring and mixing: firstly adding half amount of hypochlorous acid disinfectant into a kettle, simultaneously starting stirring, adding enough surfactant, adding citric acid after complete dissolution, adjusting the pH of the system to be within 6-7, supplementing the rest hypochlorous acid disinfectant, a prefabricated deodorant, an anti-stain redeposition agent, a hypochlorous acid slow down decomposer, essence and a viscosity regulator, and finally obtaining colorless to yellow transparent viscous liquid;
(IV) standing and settling: after the preparation of the feed liquid is completed, the feed liquid starts to stand still for sedimentation, and the split charging can be carried out after the completion of the preparation.
The beneficial effects of the invention are as follows:
the invention creatively uses hypochlorous acid disinfectant to replace deionized water, and hypochlorous acid is used as a high-efficiency disinfectant, and the sterilizing effect of the hypochlorous acid disinfectant on various bacteria and viruses is far better than that of sterilizing products represented by quaternary ammonium salt low-efficiency bactericides. Hypochlorous acid products have poor chemical stability, which makes it difficult to derive other products than the single product which is a disinfectant product.
The invention maintains the high-efficiency sterilization effect of the hypochlorous acid sterilizing product, solves the technical problem of stability of the hypochlorous acid sterilizing product, innovatively endows the hypochlorous acid sterilizing product with the functions of cleaning and deodorizing, and meets various demands of people on daily sterilization, cleaning and deodorizing.
The cleaning and decontaminating capability of the invention is excellent, the surfactant and the washing auxiliary agent have excellent removing effects on daily dust stains, greasy dirt stains and the like through scientific formula design, and the following data are obtained through test:
table 1 comparative detergency performance
Conclusion: the test results show that the cleaning effect of the detergent on the standard dirty cloth exceeds that of the standard liquid laundry detergent, and the detergent completely meets the demands of people on daily washing.
The invention is also characterized in that the natural component derived from castor oil, namely zinc ricinoleate, is added, and after being activated by an activating agent, the natural component has the capability of capturing various peculiar smell molecules, and other similar products only rely on essence substances to mask peculiar smell, so that the natural source of the peculiar smell cannot be eradicated. The invention has obvious effect on removing amine substances in cigarettes and sulfur substances in human sweat, can remove odor sources from the root by only conventional cleaning operation, and can permanently inhibit the reappearance of the odor, thereby having very good effect.
The main invention points are as follows: solves the technical defect of poor stability of hypochlorous acid, greatly improves the service life of hypochlorous acid products and improves the severe dependence of the hypochlorous acid products on packaging conditions.
For the stability influence factors of hypochlorous acid in the detergent product mixed and compounded with the hypochlorous acid solution, long-term analysis and research show that factors such as illumination intensity, temperature, pH, metal ions and the like have the greatest influence on the stability of hypochlorous acid. Aiming at three influencing factors such as illumination, pH and metal ions, an optimal scheme, namely the hypochlorous acid slowing down decomposer disclosed by the invention is finally determined through research, analysis and screening experiments, and the hypochlorous acid slowing down decomposer has good help on the three influencing factors, and the scheme aims at weakening the influence of the illumination on a product, can stabilize the pH value of the product, and has good wrapping effect on the metal ions introduced into the product in the use process.
The test results of the change condition of the effective chlorine content of each sample under the simulation condition of a laboratory applying the scheme or not are researched:
TABLE 2 variation of available chlorine content for each sample
Note that: 1. the sample 1 is a blank hypochlorous acid sample, and the sample 2 is a hypochlorous acid sample applying the scheme;
2. the experimental conditions are as follows: d65 standard light source, simulated sunlight irradiation condition, constant temperature 54+ -2deg.C, 250ppm hard water.
From the above experimental data, the following conclusions can be drawn: under the ageing condition of the laboratory, after 21 days of experiments, the effective chlorine content reduction rate of the No. 1 sample is 10.08%, and the effective chlorine content reduction rate of the No. 2 sample is 5.15%, and under the conditions of illumination and hard water, the scheme can obviously improve the stability of hypochlorous acid, in other words, the service life and the light resistance of the product are improved, and the severe requirements of the product on the packaging condition are improved. Meanwhile, the method is also greatly suitable for the use habit of consumers, the use habit of the consumers on washing products in daily life is not changed due to the characteristics of the products, the constraint conditions in the use process of the products are reduced, and the use convenience of the products is improved.
Detailed Description
Example 1:
a hypochlorous acid type disinfection detergent is prepared from the following components in percentage by mass: 10% sodium dodecyl benzene sulfonate, 6% isomeric alcohol polyoxyethylene ether, 1% polyacrylic acid (PAA) and acrylic acid/maleic anhydride copolymer (PAA/MA), namely an anti-stain redeposition agent, 0.5% hypochlorous acid slow-down decomposer, 0.3% zinc ricinoleate, 0.2% methyl glycine disodium diacetate, namely a deodorizing activator, 0.1% essence can adopt daily-used perfume and auxiliary materials, such as lavender essential oil, lemon essential oil, propylene glycol and the like, the balance is complemented by hypochlorous acid disinfectant, and the effective chlorine content is 200 ppm+/-30 ppm.
The preparation method of the hypochlorous acid type washing disinfectant disclosed by the embodiment of the invention comprises the following steps of:
weighing ingredients: weighing the components according to the proportion, and respectively placing the components in respective special containers for later use;
prefabricating a deodorant: pre-mixing zinc ricinoleate and a deodorizing activator, and uniformly stirring for later use;
and (III) stirring and mixing: firstly adding half amount of hypochlorous acid disinfectant into a kettle, simultaneously starting stirring, sequentially adding the anionic surfactant and the nonionic surfactant in the formula, adding organic acid after dissolving, controlling the pH of a system within a range of 6-7, sequentially supplementing the rest hypochlorous acid disinfectant, a prefabricated deodorant, an anti-stain redeposition agent, a hypochlorous acid slowing down decomposer, essence and viscosity, and finally obtaining colorless to yellow transparent viscous liquid;
(IV) standing and settling: after the preparation of the feed liquid is completed, the feed liquid starts to stand still for sedimentation, and the split charging can be carried out after the completion of the preparation.
Example 2:
a hypochlorous acid type disinfection detergent is prepared from the following components in percentage by mass: 13% sodium dodecyl benzene sulfonate, 8% isomeric alcohol ether polyoxyethylene ether, 2% polyacrylic acid (PAA) and acrylic acid/maleic anhydride copolymer (PAA/MA) (namely, anti-stain redeposition agent), 1% sodium chloride (namely, viscosity modifier), 0.7% hypochlorous acid slow down decomposer is compounded by trisodium methylglycinate, disodium hydrogen phosphate, sodium dihydrogen phosphate and benzophenone-4 according to the mass ratio of 3:10:5:2, 0.4% zinc ricinoleate, 0.3% trisodium methylglycinate (namely, deodorant activator), 0.2% essence can adopt conventional daily flavors and auxiliary materials, such as lavender essential oil, lemon essential oil, propylene glycol and the like, and the balance is complemented by hypochlorous acid disinfectant (the effective chlorine content of which is 200 ppm+/-30 ppm).
The preparation method of the hypochlorous acid type washing disinfectant disclosed by the embodiment 2 comprises the following steps of:
weighing ingredients: weighing the components according to the proportion, and respectively placing the components in respective special containers for later use;
prefabricating a deodorant: pre-mixing zinc ricinoleate and a deodorizing activator, and uniformly stirring for later use;
and (III) stirring and mixing: firstly adding half amount of hypochlorous acid disinfectant into a kettle, simultaneously starting stirring, sequentially adding an anionic surfactant, an amphoteric surfactant and a nonionic surfactant, after dissolving, adding organic acid, controlling the pH of a system within a range of 6-7, and sequentially supplementing the rest hypochlorous acid disinfectant, a prefabricated deodorant, an anti-stain redeposition agent, a hypochlorous acid slow-down decomposer, essence and a viscosity regulator to finally obtain colorless to yellow transparent viscous liquid;
(IV) standing and settling: after the preparation of the feed liquid is completed, the feed liquid starts to stand still for sedimentation, and the split charging can be carried out after the completion of the preparation.
Example 3:
a hypochlorous acid type disinfection detergent is prepared from the following components in percentage by mass: 15% sodium dodecyl benzene sulfonate, 10% heterogeneous fatty alcohol polyoxyethylene ether, 3% polyacrylic acid (PAA) and acrylic acid/maleic anhydride copolymer (PAA/MA) (namely anti-stain redeposition agent), 2% sodium citrate, 2% sodium chloride (namely viscosity modifier), 1% hypochlorous acid slow-down decomposer which is formed by compounding trisodium methylglycinate, disodium hydrogen phosphate, sodium dihydrogen phosphate and benzophenone-4 according to the mass ratio of 3:10:5:2, 0.5% zinc ricinoleate, 0.5% trisodium methylglycinate (namely deodorizing activator), 0.3% essence can be used as conventional daily fragrances and auxiliary materials, such as lavender essential oil, lemon essential oil, propylene glycol and the like, and the balance is complemented by hypochlorous acid disinfectant (the effective chlorine content of which is 200 ppm+/-30 ppm).
The preparation method of the hypochlorous acid type washing disinfectant disclosed by the embodiment 3 of the invention comprises the following steps of:
weighing ingredients: weighing the components according to the proportion, and respectively placing the components in respective special containers for later use;
prefabricating a deodorant: pre-mixing zinc ricinoleate and a deodorizing activator, and uniformly stirring for later use;
and (III) stirring and mixing: firstly adding half amount of hypochlorous acid disinfectant into a kettle, simultaneously starting stirring, sequentially adding an anionic surfactant and a nonionic surfactant, adding organic acid after dissolving, controlling the pH of a system within a range of 6-7, and sequentially supplementing the rest hypochlorous acid disinfectant, a prefabricated deodorant, an anti-stain redeposition agent, a hypochlorous acid slow down decomposer, essence and a viscosity regulator to obtain colorless to yellow transparent viscous liquid;
(IV) standing and settling: after the preparation of the feed liquid is completed, the feed liquid starts to stand still for sedimentation, and the split charging can be carried out after the completion of the preparation.
The general formula of the hypochlorous acid type disinfection detergent mainly comprises the following components: the anti-stain disinfectant comprises a surfactant, an anti-stain redeposition agent, a hypochlorous acid slowing down decomposer, a viscosity regulator, zinc ricinoleate, a deodorizing activator, essence and the balance hypochlorous acid disinfectant, wherein the hypochlorous acid slowing down decomposer is prepared by compounding trisodium methylglycinate, disodium hydrogen phosphate, sodium dihydrogen phosphate and benzophenone-4 according to a mass ratio of 3:10:5:2. The surfactant comprises an anionic surfactant and a nonionic surfactant.
In practical application, the surfactant disclosed by the invention can be sodium dodecyl benzene sulfonate and isomeric fatty alcohol polyoxyethylene ether, and other anionic surfactants and nonionic surfactants can be adopted, so that basically the effect is similar and the effect is also similar.
In practical application, the anti-stain redeposition agent of the invention can be any one of sodium carboxymethyl cellulose (CMC), polyvinylpyrrolidone (PVP), polyvinyl alcohol (PVA), polyacrylic acid (PAA) and acrylic acid/maleic anhydride copolymer (PAA/MA), hydroxypropyl methyl cellulose sodium (HPMC), hydroxybutyl methyl cellulose (HBMC), alcohol-soluble prion (a protein), polyethylene oxazolidone, polyethylene glycol (PEG) and Polyaspartic Acid (PASP) besides polyacrylic acid (PAA) and acrylic acid/maleic anhydride copolymer (PAA/MA), and basically has similar functions and effects.
In practical application, the deodorizing activator of the invention can adopt sodium glutamate diacetate and the like besides trisodium methylglycine diacetate, and has similar basic functions and effects.
In practical application, the viscosity regulator can adopt sodium chloride, and can also adopt one or two of hydroxypropyl methyl cellulose and hydroxyethyl methyl cellulose, so that the viscosity regulator has similar basic functions and effects.
In practical application, the essence of the invention is prepared by adopting the conventional industry.
The above-described embodiments of the invention are merely some, but not all, embodiments of the invention. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Claims (8)
1. A hypochlorous acid type disinfecting detergent, which is characterized in that: the hypochlorous acid type disinfection detergent is prepared from the following components in percentage by mass: 15% -25% of surfactant, 1% -3% of anti-stain redeposition agent, 0.1% -1% of hypochlorous acid slow-down decomposer, 0.5% -2% of viscosity regulator, 0.3% -0.5% of zinc ricinoleate, 0.2% -0.5% of deodorizing activator, 0.1% -0.3% of essence, and the balance being hypochlorous acid disinfectant, wherein the effective chlorine content is 200ppm +/-30 ppm; the hypochlorous acid slow-down decomposer is prepared by compounding methyl glycine disodium diacetate, disodium hydrogen phosphate, sodium dihydrogen phosphate and benzophenone-4 according to the mass ratio of 3:10:5:2.
2. A hypochlorous acid sanitizing detergent as set forth in claim 1, wherein: the hypochlorous acid type disinfection detergent is characterized in that 0.3-0.5% of zinc ricinoleate and 0.2-0.5% of deodorizing activator are added into the formula, the balance is complemented by hypochlorous acid disinfectant, and the effective chlorine content of the hypochlorous acid disinfectant is 200ppm +/-30 ppm.
3. A hypochlorous acid sanitizing detergent as set forth in claim 2, wherein: the hypochlorous acid type disinfection detergent is prepared from the following components in percentage by mass: 15 to 17 percent of surfactant, 1 to 2 percent of anti-stain redeposition agent, 0.5 to 1 percent of hypochlorous acid slow down decomposer, 0.5 to 2 percent of viscosity regulator, 0.3 to 0.5 percent of zinc ricinoleate, 0.2 to 0.5 percent of deodorizing activator, 0.1 to 0.3 percent of essence, and the balance being complemented by hypochlorous acid disinfectant, wherein the effective chlorine content is 200ppm +/-30 ppm.
4. A hypochlorous acid sanitizing detergent as set forth in claim 1, wherein: the surfactant comprises an anionic surfactant and a nonionic surfactant.
5. A hypochlorous acid sanitizing detergent as set forth in claim 1, wherein: the surfactant comprises sodium dodecyl benzene sulfonate and isomeric fatty alcohol polyoxyethylene ether; the anti-stain redeposition agent is any one of sodium carboxymethyl cellulose, polyvinylpyrrolidone, polyvinyl alcohol, polyacrylic acid and acrylic acid/maleic anhydride copolymer, hydroxypropyl methyl cellulose sodium, hydroxybutyl methyl cellulose, alcohol-soluble prion, polyethylene oxazolidone, polyethylene glycol and polyaspartic acid; the deodorizing activator is one of trisodium methylglycinate diacetate and sodium glutamate diacetate; the viscosity regulator is one or two of hydroxypropyl methyl cellulose, hydroxyethyl methyl cellulose and sodium chloride; the essence adopts conventional daily chemical essence.
6. A hypochlorous acid sanitizing detergent as set forth in claim 5, wherein: the hypochlorous acid type disinfection detergent is prepared from the following components in percentage by mass: 10 to 15 percent of sodium dodecyl benzene sulfonate, 5 to 10 percent of heterogeneous fatty alcohol polyoxyethylene ether, 1 to 3 percent of polyacrylic acid and acrylic acid/maleic anhydride copolymer, namely, anti-stain redeposition agent, 0.5 to 2 percent of sodium citrate, 0.5 to 2 percent of sodium chloride, namely, viscosity modifier, 0.1 to 1 percent of hypochlorous acid slow-down decomposer, 0.3 to 0.5 percent of zinc ricinoleate, 0.2 to 0.5 percent of methyl glycine disodium diacetate, namely, deodorization activator, and 0.1 to 0.3 percent of essence can be adopted as conventional daily flavors and auxiliary materials, the balance is complemented by hypochlorous acid disinfectant, and the effective chlorine content is 200ppm plus or minus 30ppm.
7. A hypochlorous acid sanitizing detergent as set forth in claim 6, wherein: the optimized formula of the hypochlorous acid type disinfection detergent is as follows: 8 to 12 percent of sodium dodecyl benzene sulfonate, 4 to 7 percent of heterogeneous fatty alcohol polyoxyethylene ether, 0.5 to 1.0 percent of polyacrylic acid and acrylic acid/maleic anhydride copolymer, namely an anti-stain redeposition agent, 0.5 to 1 percent of sodium citrate, 0.8 to 1.5 percent of sodium chloride, namely a viscosity regulator, 0.5 to 1.0 percent of hypochlorous acid slow-down decomposer, 0.5 percent of zinc ricinoleate, 0.5 percent of methyl glycine disodium diacetate, namely a deodorization activator, 0.2 percent of daily spice and auxiliary materials, and the balance of the disinfectant is complemented by hypochlorous acid, wherein the effective chlorine content of the disinfectant is 200ppm +/-30 ppm.
8. A process for the preparation of a hypochlorous acid sanitizing detergent as set forth in claim 1 comprising the steps of:
weighing ingredients: weighing the components according to the proportion, and respectively placing the components in respective special containers for later use;
prefabricating a deodorant: pre-mixing zinc ricinoleate and a deodorizing activator, and uniformly stirring for later use;
(III) stirring and mixing: firstly adding half amount of hypochlorous acid disinfectant into a kettle, simultaneously starting stirring, adding enough surfactant, adding citric acid after complete dissolution, adjusting the pH of the system to be within 6-7, supplementing the rest hypochlorous acid disinfectant, a prefabricated deodorant, an anti-stain redeposition agent, a hypochlorous acid slow down decomposer, essence and a viscosity regulator, and finally obtaining colorless to yellow transparent viscous liquid;
(IV) standing and settling: after the preparation of the feed liquid is completed, the feed liquid starts to stand still for sedimentation, and the split charging can be carried out after the completion of the preparation.
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