CN116351234B - Smoke residence time extension device and marine desulfurizing tower adopting same - Google Patents

Smoke residence time extension device and marine desulfurizing tower adopting same Download PDF

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Publication number
CN116351234B
CN116351234B CN202310290143.XA CN202310290143A CN116351234B CN 116351234 B CN116351234 B CN 116351234B CN 202310290143 A CN202310290143 A CN 202310290143A CN 116351234 B CN116351234 B CN 116351234B
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Prior art keywords
smoke outlet
smoke
outlet pipe
pipe group
residence time
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CN116351234A (en
Inventor
陈志远
杨志富
管延敏
张乐乐
赵远
缪海瑞
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Huige Nantong Environmental Protection Equipment Co ltd
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Huige Nantong Environmental Protection Equipment Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/80Semi-solid phase processes, i.e. by using slurries
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/01Engine exhaust gases
    • B01D2258/012Diesel engines and lean burn gasoline engines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention relates to a smoke residence time extension device, which comprises a smoke outlet connecting device and a plurality of smoke outlet pipes communicated with the smoke outlet connecting device, wherein the smoke outlet ends of the smoke outlet pipes are used for discharging smoke, the smoke outlet residence time extension device comprises a first smoke outlet pipe group and a second smoke outlet pipe group which are arranged at two sides of the smoke outlet connecting device, the smoke outlet connecting device comprises a shell, one end of the shell is a smoke outlet connecting part of a desulfurizing tower, the other end of the shell is a smoke outlet connecting part connected with all the smoke outlet pipes and the tubular smoke outlet connecting part, the smoke outlet connecting part comprises a bottom plate and a side wall, a plurality of first connecting ports are arranged on the side wall, the number of the first connecting ports is the same as that of the smoke outlet pipes, and each first connecting port is connected with one smoke outlet pipe; the bottom plate is provided with a shielding mechanism for alternately shielding part of the first connecting ports. The flue gas residence time extension device can be used for modifying the existing desulfurizing tower at low cost, has longer flue gas residence time, is rapid in mixing of flue gas and slurry liquid drops, and has large contact area and higher absorption efficiency.

Description

Smoke residence time extension device and marine desulfurizing tower adopting same
Technical Field
The invention belongs to the technical field of waste gas treatment, and particularly relates to a smoke residence time extension device and a marine desulfurizing tower adopting the same.
Background
Fossil fuels such as coal and oil are still a main source of current energy sources for human beings, and the influence of the use of a large amount of fossil fuels on the earth environment cannot be ignored; for example, combustion exhaust gas such as coal and oil contains a large amount of sulfur dioxide, which is directly discharged into the atmosphere without treatment, so that serious pollution is caused, and currently, a desulfurizing tower is generally adopted in the industry to carry out desulfurization treatment on sulfur-containing flue gas, especially wet desulfurization equipment with large treatment capacity and relatively low cost is widely used.
The prior desulfurizing tower has different structures, and most of the desulfurizing towers adopt atomizing nozzles to spray and absorb slurry from the upper part of the desulfurizing tower, flue gas enters the desulfurizing tower from a flue gas outlet in the middle part of the desulfurizing tower and reacts with the atomized slurry, so that sulfur dioxide is absorbed, calcium sulfate is formed and is converged in a slurry pool at the bottom of the desulfurizing tower;
the residence time of the flue gas in the desulfurizing tower and the mixing uniformity degree of the flue gas and the slurry, even the flowing speed, the flowing length and the like in the desulfurizing tower can influence the absorption efficiency of the desulfurizing tower; because the height of desulfurizing tower can not be too big, so the residence time of flue gas in the desulfurizing tower is short, flue gas and thick liquid misce bene, can lead to the absorption efficiency of desulfurizing tower to a certain extent not go on, consequently need set up a plurality of desulfurizing towers and carry out repeated purification and make the waste gas of emission reach standard, this will increase place and equipment cost.
In the chinese patent of application number 2018202523290, the name is a desulfurizing tower, disclose a desulfurizing tower, including desulfurizing tower, totally closed thick liquid pond, the desulfurizing tower top is provided with the air outlet, and the bottom center is provided with the leakage fluid dram, the leakage fluid dram is connected with thick liquid pond pipe connection, and desulfurizing tower upper portion one side is provided with spiral whirlwind pipeline, spiral whirlwind pipeline one end and flue gas admission pipe UNICOM, and desulfurizing tower inside center is provided with an upper end confined toper reaction barrel, has the interval between toper reaction barrel and the desulfurizing tower, forms the flue gas and rises the passageway, and the spiral whirlwind pipeline other end passes toper reaction barrel upper portion, and toper reaction barrel inside center installs the jet column, and toper reaction barrel outer wall upper portion is provided with a plurality of secondary shower nozzles along toper reaction barrel circumference, and this desulfurizing tower simple structure, desulfurization effect is good, operation maintenance cost is low. The problems are that only the arrangement mode of the flue gas and slurry spraying device is changed, the mixing of the flue gas and slurry liquid drops is still relatively low, and the residence time of the flue gas in the desulfurizing tower is relatively short.
In addition, for large ocean vessels, the exhaust gas discharged by the large ocean vessels must be subjected to desulfurization treatment, so that the marine desulfurization tower can be said to be a standard of the large ocean vessels, and the marine desulfurization tower is a considerable and improved problem in terms of cost and space layout under the conditions that the volume of the marine desulfurization tower cannot be too large and the height of the marine desulfurization tower cannot be too high, so that sufficient purification efficiency is ensured, and meanwhile, the space is excessively occupied.
We find that the smoke outlet of the common desulfurizing tower is sprayed out from a great amount of smoke outlet, the area lacks slurry liquid drops, which is unfavorable for desulfurization reaction, and if the smoke discharged from the smoke outlet is quickly and fully mixed with the slurry liquid drops, the working efficiency of the desulfurizing tower can be improved to a certain extent, and the design thought is provided for improving the purifying efficiency of the desulfurizing tower, especially the marine desulfurizing tower.
Disclosure of Invention
The invention aims to provide the flue gas residence time extension device which is suitable for the marine desulfurization tower, can reform the existing desulfurization tower with low cost, has longer flue gas residence time, can quickly mix the flue gas with slurry liquid drops, has large contact area and has higher absorption efficiency.
In order to solve the technical problems, the invention discloses a smoke residence time extension device, which comprises a smoke outlet connecting device and a plurality of smoke outlet pipes which are communicated with the smoke outlet connecting device and are arranged along the inner wall of a desulfurizing tower, wherein the smoke outlet pipe ends are used for discharging smoke, the smoke outlet residence time extension device comprises a first smoke outlet pipe group and a second smoke outlet pipe group which are arranged at two sides of the smoke outlet connecting device, each of the first smoke outlet pipe group and the second smoke outlet pipe group comprises a plurality of smoke outlet pipes which are arranged up and down, the length of the smoke outlet pipe of the first smoke outlet pipe group is sequentially increased from top to bottom, and the length of the smoke outlet pipe of the second smoke outlet pipe group is sequentially decreased from top to bottom;
the smoke outlet connecting device is used for being connected with smoke outlets in the desulfurizing tower, the smoke outlet connecting device comprises a shell, one end of the shell is a smoke outlet connecting part of the desulfurizing tower, the other end of the shell is a smoke outlet connecting part connected with all smoke outlet pipes and a cylindrical smoke outlet pipe, the smoke outlet connecting part comprises a bottom plate and a side wall, a plurality of first connecting ports are arranged on the side wall, the number of the first connecting ports is the same as that of the smoke outlet pipes, and each first connecting port is connected with one smoke outlet pipe;
the bottom plate is provided with a shielding mechanism for shielding part of the first connecting ports alternately, and when the desulfurizing tower operates, flue gas is sprayed out from different smoke outlet pipes regularly under the action of the shielding mechanism.
Preferably, the shutter mechanism comprises a shutter for shielding part of the first connection port and a drive mechanism for rotating the shutter about the housing axis.
Preferably, the shielding piece comprises a supporting rod and arc-shaped blocking pieces arranged at two ends of the supporting rod, the curvature of each arc-shaped blocking piece is matched with the inner wall of the shell, and the size of each arc-shaped blocking piece is not smaller than the area of one first connecting port.
Preferably, the distance between the arc-shaped baffle plate and the inner wall of the shell is not more than 3mm.
Preferably, the device further comprises a third smoke outlet pipe group which is arranged on the outer side of the bottom plate and comprises a plurality of smoke outlet pipes, the third smoke outlet pipe group is arranged around the center of the bottom plate, a plurality of second connectors are arranged on the bottom plate, and the third smoke outlet pipe group is communicated with the smoke outlet connecting device through the second connectors.
Preferably, round baffle plates for shielding part of the second connectors are symmetrically arranged on one side of the support rod close to the bottom plate, and the smoke outlet pipes of the third smoke outlet pipe group are staggered, wherein the smoke outlet pipes are identical in length or different in length.
Preferably, when the driving mechanism drives the supporting rod to rotate, under the shielding of the pair of arc-shaped blocking sheets, each smoke outlet pipe in the first smoke outlet pipe group and the second smoke outlet pipe group alternately discharges smoke; under the shielding of a pair of round blocking sheets, each smoke outlet pipe in the third smoke outlet pipe group alternately discharges smoke.
A desulfurizing tower for ship is composed of a fume residence time extender.
The smoke residence time extension device is simple in structure, can reconstruct the existing desulfurizing tower with lower cost, and has short reconstruction period; the flue gas is released from different positions on the inner wall of the desulfurizing tower through the plurality of flue gas outlet pipes of the first flue gas outlet pipe group and the second flue gas outlet pipe group, two larger airflow vortexes are formed in the desulfurizing tower, and the flue gas blown out by the second flue gas outlet pipe group along the radial direction is separated, cut and scattered, so that the flue gas is more widely and regularly diffused on the cross section of the desulfurizing tower, and is more fully and quickly uniformly mixed with slurry drops at the same time, but not diffused in all directions like the flue gas sprayed out from a flue gas outlet of a common desulfurizing tower, compared with the flue gas flowing layout, the flue gas flowing layout can ensure that the flue gas and the slurry drops are more efficiently mixed, the flowing path in the desulfurizing tower is enlarged, the residence time can be prolonged, and the reaction time and the absorption time are correspondingly prolonged; the shielding mechanism is adopted, so that different smoke outlet pipes alternately discharge smoke, a plurality of vortex flows are formed continuously in a large range, the smoke is enabled to rise spirally, the total moving length of the smoke in the desulfurizing tower is prolonged, the residence time of the smoke is increased to a certain extent, the absorption effect of the desulfurizing tower is improved, and the desulfurizing efficiency is enhanced.
Drawings
Fig. 1 is a schematic structural view of a flue gas residence time extension device.
Fig. 2 is a schematic structural view of the smoke outlet pipe connecting part in fig. 1.
Fig. 3 is a schematic structural view of the smoke outlet pipe connecting portion in fig. 2 at another view angle.
Fig. 4 is a schematic view of the construction of the shield of fig. 3.
The reference numerals in the figures are: 1-smoke outlet connecting device, 2-smoke outlet pipe, 21-first smoke outlet pipe group, 22-second smoke outlet pipe group, 3-third smoke outlet pipe group, 31-second connector, 4-desulfurizing tower smoke outlet connecting part, 5-smoke outlet connecting part, 51-bottom plate, 52-side wall, 6-first connector, 7-shielding mechanism, 71-shielding piece, 72-driving mechanism, 711-supporting rod, 712-arc-shaped shielding piece and 713-round shielding piece.
Detailed Description
The present invention is described in further detail below by way of examples to enable those skilled in the art to practice the same by reference to the specification.
It will be understood that terms, such as "having," "including," and "comprising," as used herein, do not preclude the presence or addition of one or more other elements or groups thereof.
Example 1
As shown in fig. 1-4, a smoke residence time extension device comprises a smoke outlet connecting device 1 and a plurality of smoke outlet pipes 2 which are communicated with the smoke outlet connecting device 1 and are arranged along the inner wall of a desulfurizing tower, wherein the smoke outlet pipe ends are used for discharging smoke, the smoke residence time extension device comprises a first smoke outlet pipe group 21 and a second smoke outlet pipe group 22 which are arranged at two sides of the smoke outlet connecting device, each of the first smoke outlet pipe group 21 and the second smoke outlet pipe group 22 comprises a plurality of smoke outlet pipes which are arranged up and down, the length of the smoke outlet pipe of the first smoke outlet pipe group is sequentially increased from top to bottom, and the length of the smoke outlet pipe of the second smoke outlet pipe group is sequentially decreased from top to bottom; this arrangement facilitates the formation of multiple flue gas vortices in different areas.
The smoke outlet connecting device is used for being connected with smoke outlets in the desulfurizing tower, the smoke outlet connecting device comprises a shell, one end of the shell is a smoke outlet connecting part 4 of the desulfurizing tower, the other end of the shell is a tubular smoke outlet connecting part 5 for connecting all smoke outlet pipes, the smoke outlet connecting part 5 comprises a bottom plate 51 and a side wall 52, a plurality of first connecting ports 6 are arranged on the side wall, the number of the first connecting ports 6 is the same as that of the smoke outlet pipes, and each first connecting port is connected with one smoke outlet pipe; in this embodiment, the smoke outlet pipes of the first smoke outlet pipe group 21 and the second smoke outlet pipe group 22 are arc-shaped pipes with lengths not exceeding 1/4 of the circumferential length of the desulfurizing tower, which are too long to be beneficial to the rapid and uniform distribution of the smoke in the desulfurizing tower.
The bottom plate is provided with a shielding mechanism 7 for shielding part of the first connecting ports alternately, and when the desulfurizing tower operates, flue gas is sprayed out from different smoke outlet pipes regularly under the action of the shielding mechanism 7. The smoke outlet pipes on two sides are respectively provided with a temporary smoke outlet pipe, so that instantaneous smoke pressure distribution can be changed, the smoke can generate small-range frequent movement in the transverse direction, and compared with a continuous smoke spraying mode of a common desulfurizing tower, the invention can regularly stop smoke spraying, can form more vortex, increase the residence time of the smoke and the reaction rate with slurry drops, and improve the desulfurizing efficiency.
As shown in fig. 3, the shutter mechanism 7 includes a shutter 71 for shielding part of the first connection port and a drive mechanism 72 for rotating the shutter about the axis of the housing, the drive mechanism 72 being mounted in the middle of the base plate.
As shown in fig. 4, the shielding member includes a supporting rod 711 and arc-shaped blocking pieces 712 disposed at two ends of the supporting rod, wherein the curvature of the arc-shaped blocking pieces is adapted to the inner wall of the housing, and the size of the arc-shaped blocking pieces is not smaller than the area of a first connecting port.
The distance between the arc-shaped baffle plate and the inner wall of the shell is not more than 3mm.
The flue gas desulfurization device is characterized by further comprising a third flue gas outlet pipe group 3 which is arranged on the outer side of the bottom plate and comprises a plurality of flue gas outlet pipes, wherein the third flue gas outlet pipe group 3 is arranged around the center of the bottom plate, a plurality of second connecting ports 31 are formed in the bottom plate, the third flue gas outlet pipe group 3 is communicated with the flue gas outlet connecting device 1 through the second connecting ports 31, and in the embodiment, the length of the flue gas outlet pipe of the third flue gas outlet pipe group is not more than 1/3 of the diameter of the desulfurization tower.
Round baffle plates 713 for shielding part of the second connectors are symmetrically arranged on one side of the support rod close to the bottom plate, and the lengths of smoke outlet pipes of the third smoke outlet pipe group are inconsistent.
When the driving mechanism drives the supporting rod to rotate, under the shielding of the pair of arc-shaped blocking pieces 712, each smoke outlet pipe in the first smoke outlet pipe group 21 and the second smoke outlet pipe group 22 alternately discharges smoke; under the shielding of the pair of circular baffle plates 713, each smoke outlet pipe in the third smoke outlet pipe group 3 alternately discharges smoke.
Example 2
A desulfurizing tower for ship is composed of a fume residence time extender.
Although embodiments of the present invention have been disclosed above, it is not limited to the details and embodiments shown, it is well suited to various fields of use for which the invention is suited, and further modifications may be readily made by one skilled in the art, and the invention is therefore not to be limited to the particular details and examples shown and described herein, without departing from the general concepts defined by the claims and the equivalents thereof.

Claims (6)

1. The smoke residence time extension device is characterized by comprising a smoke outlet connecting device and a plurality of smoke outlet pipes which are communicated with the smoke outlet connecting device and are arranged along the inner wall of the desulfurizing tower, wherein the smoke outlet pipe ends are used for discharging smoke, the smoke residence time extension device comprises a first smoke outlet pipe group and a second smoke outlet pipe group which are arranged at two sides of the smoke outlet connecting device, each of the first smoke outlet pipe group and the second smoke outlet pipe group comprises a plurality of smoke outlet pipes which are arranged up and down, the length of the smoke outlet pipe of the first smoke outlet pipe group is sequentially increased from top to bottom, and the length of the smoke outlet pipe of the second smoke outlet pipe group is sequentially decreased from top to bottom;
the smoke outlet connecting device is used for being connected with smoke outlets in the desulfurizing tower, the smoke outlet connecting device comprises a shell, one end of the shell is a smoke outlet connecting part of the desulfurizing tower, the other end of the shell is a smoke outlet connecting part connected with all smoke outlet pipes and a cylindrical smoke outlet pipe, the smoke outlet connecting part comprises a bottom plate and a side wall, a plurality of first connecting ports are arranged on the side wall, the number of the first connecting ports is the same as that of the smoke outlet pipes, and each first connecting port is connected with one smoke outlet pipe;
a shielding mechanism for alternately shielding part of the first connection ports is arranged on the bottom plate, and when the desulfurizing tower operates, flue gas is regularly sprayed out from different smoke outlet pipes under the action of the shielding mechanism;
the shielding mechanism comprises a shielding piece for shielding part of the first connecting port and a driving mechanism for rotating the shielding piece around the axis of the shell;
the shielding piece comprises a supporting rod and arc-shaped blocking pieces arranged at two ends of the supporting rod, the curvature of each arc-shaped blocking piece is matched with the inner wall of the shell, and the size of each arc-shaped blocking piece is not smaller than the area of one first connecting port.
2. The smoke-residence time extension device of claim 1, wherein the distance between the arcuate baffle and the inner wall of the housing is no more than 3mm.
3. The smoke residence time extension device of claim 1, further comprising a third smoke outlet pipe group comprising a plurality of smoke outlet pipes and arranged outside the bottom plate, wherein the third smoke outlet pipe group is arranged around the center of the bottom plate, a plurality of second connection ports are arranged on the bottom plate, and the third smoke outlet pipe group is communicated with the smoke outlet connecting device through the second connection ports.
4. The smoke residence time extension device according to claim 3, wherein round baffle plates for shielding part of the second connectors are symmetrically arranged on one side of the support rod close to the bottom plate, and smoke outlet pipes of the third smoke outlet pipe group are staggered, wherein the smoke outlet pipes are identical in length or different in length.
5. The smoke residence time extension device according to claim 4, wherein when the driving mechanism drives the strut to rotate, each smoke outlet pipe in the first smoke outlet pipe group and the second smoke outlet pipe group alternately discharges smoke under the shielding of the pair of arc-shaped blocking sheets; under the shielding of a pair of round blocking sheets, each smoke outlet pipe in the third smoke outlet pipe group alternately discharges smoke.
6. A marine desulfurization tower, characterized in that it employs the flue gas residence time extension apparatus according to any one of claims 1 to 5.
CN202310290143.XA 2023-03-23 2023-03-23 Smoke residence time extension device and marine desulfurizing tower adopting same Active CN116351234B (en)

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CN208678819U (en) * 2018-07-23 2019-04-02 长兴旗滨玻璃有限公司 A kind of denitration of glass furnace fume equipment
CN209696616U (en) * 2018-12-05 2019-11-29 江苏中美华超环保科技有限公司 A kind of catalysis oxidizing tower
CN110180373A (en) * 2019-06-03 2019-08-30 苏州仕净环保科技股份有限公司 A kind of Industrial cleaning facility system removing sulfide gas
CN110538566A (en) * 2019-08-22 2019-12-06 黄震 dry desulphurization energy-saving hybrid full-load adjustable system and control method
CN111346492A (en) * 2020-03-27 2020-06-30 国网山东省电力公司电力科学研究院 Method for prolonging retention time of flue gas in desulfurizing tower
CN111545035A (en) * 2020-05-14 2020-08-18 台州市华杰环保科技有限公司 High-efficiency gas-liquid physicochemical reaction device
CN212701283U (en) * 2020-06-08 2021-03-16 宁夏绿梭肥业科技有限公司 Plasma spiral-flow type desulfurizing tower
CN216972640U (en) * 2022-03-07 2022-07-15 太湖县光华铝业有限公司 Degassing refining pipe for aluminum alloy liquid
CN115006966A (en) * 2022-07-07 2022-09-06 深圳华创生态环境科技有限公司 Waste gas treatment device for waste engine oil regeneration process

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