CN110538566A - dry desulphurization energy-saving hybrid full-load adjustable system and control method - Google Patents
dry desulphurization energy-saving hybrid full-load adjustable system and control method Download PDFInfo
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- CN110538566A CN110538566A CN201910778580.XA CN201910778580A CN110538566A CN 110538566 A CN110538566 A CN 110538566A CN 201910778580 A CN201910778580 A CN 201910778580A CN 110538566 A CN110538566 A CN 110538566A
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- 238000000034 method Methods 0.000 title claims description 12
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 75
- 239000003546 flue gas Substances 0.000 claims abstract description 75
- 238000006477 desulfuration reaction Methods 0.000 claims abstract description 50
- 230000023556 desulfurization Effects 0.000 claims abstract description 50
- 230000003009 desulfurizing effect Effects 0.000 claims description 19
- 230000001105 regulatory effect Effects 0.000 claims description 14
- 230000008676 import Effects 0.000 claims 2
- 238000001035 drying Methods 0.000 claims 1
- 238000005265 energy consumption Methods 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 5
- 238000006243 chemical reaction Methods 0.000 description 13
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 10
- 239000011575 calcium Substances 0.000 description 9
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 6
- 238000002485 combustion reaction Methods 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/508—Sulfur oxides by treating the gases with solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/81—Solid phase processes
- B01D53/83—Solid phase processes with moving reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
Abstract
The invention discloses a dry desulfurization energy-saving mixed type full-load adjustable system, which relates to the technical field of dry desulfurization and comprises a desulfurization tower, a denitration system, an induced draft fan and a chimney which are sequentially connected through a main flue, wherein flue gas is introduced into the desulfurization tower through the main flue through a throat pipe part, and the dry desulfurization energy-saving mixed type full-load adjustable system also comprises a plurality of load adjustable valves and a clean flue gas circulating system adjusting valve of a clean flue gas circulating system. The dry desulfurization system with all time periods and all working conditions is designed, the purposes of reducing pressure loss, ensuring desulfurization effect, saving energy and reducing consumption are achieved, and the dry desulfurization system is wider in load adaptability and lower in energy consumption.
Description
Technical Field
The invention relates to the technical field of dry desulphurization, in particular to a dry desulphurization energy-saving mixed type full-load adjustable system and a control method.
Background
The flue gas generated during combustion of coal, fuel oil and fuel gas contains harmful gases such as sulfur dioxide and nitrogen oxide, and the harmful gases are discharged into the atmosphere, so that acid rain is easily caused, the ecological environment is damaged, the body health of people is influenced, and the environmental protection regulations related to China provide strict control standard requirements for the allowable emission concentration of the sulfur dioxide and the nitrogen oxide in the flue gas.
there are many methods of controlling coal pollution, and they are generally classified into three categories, i.e., pre-combustion desulfurization, in-combustion desulfurization, and post-combustion desulfurization (flue gas desulfurization), with flue gas post-combustion desulfurization being considered to be the most effective way to control SO2 pollution. Currently, there are four major flue gas desulfurization processes that have been applied and continue to be developed: wet limestone/gypsum absorption, dry spray drying purification, in-furnace calcium spray post-humidification water activation (LIFAC), and circulating fluidized bed flue gas purification (CFB-FGD).
The circulating fluidized bed flue gas purification process is characterized in that Ca (OH)2 powder added into a reaction tower is fully contacted and mixed with SO2 and other components in flue gas, such as SO3, HCl, HF and other acidic gases, atomized water sprayed at the inlet of the reaction tower reduces the temperature of the flue gas and ensures the optimal reaction condition, and liquid phase is formed on the surface of Ca (OH)2 particles, SO that the reaction can be fully and rapidly carried out in the reaction tower with acid and alkali amphoteric substances mixed. In the circulating fluidized bed reaction tower, Ca (OH)2 powder, flue gas and sprayed moisture are fully mixed in a fluidized state, and the Ca (OH)2 powder is recycled for multiple times, SO that the Ca (OH)2 amount participating in the reaction in the bed is far greater than the newly added Ca (OH)2 amount, namely the Ca/S ratio of the actual reaction is far greater than the apparent Ca/S ratio, and thus acid gases such as SO2, SO3 and the like can be fully absorbed, and the high-efficiency desulfurization and the high-efficiency utilization of a desulfurizing agent are realized.
however, the existing circulating fluidized bed reaction tower has the following problems: when the load of the reaction tower designed according to the full load of the boiler and the sintering machine is changed, the pressure loss in the reaction tower is changed greatly, the normal operation of a desulfurization system is influenced, and the desulfurization effect is influenced. Even if the low-energy-consumption load-adjustable circulating fluidized bed desulfurizing tower disclosed in the patent No. 201220343448. Under the condition of extreme low load, the pressure of the desulfurization bed is low, the bed pressure requirement of normal operation of a desulfurization system cannot be met, and bed collapse is easily caused.
At present, another measure exists for the problem that the desulfurization system cannot normally operate due to load fluctuation: the clean flue gas circulation method is characterized in that a pipeline is arranged in front of a chimney and connected to an inlet of a reaction tower, and a valve is arranged on the pipeline. No matter the front end load, the clean flue gas and the flue gas to be treated are mixed and then enter the reaction tower by adjusting a valve of a flue gas circulating pipeline, so that the flue gas load in the tower is ensured to be full load, but the scheme has high operation energy consumption and poor economic benefit. Therefore, the prior art does not have a flue gas adjusting device which can ensure the desulfurization efficiency and save energy and reduce consumption.
The Chinese patent with the application number of 201220343448.X discloses a low-energy-consumption load-adjustable circulating fluidized bed desulfurization tower, wherein a bypass pipeline is connected between an air inlet flue and a tower body, so that the load adaptability is good, the pressure loss in the operation of an empty tower is reduced, and the desulfurization is more efficient. As for how to ensure the normal operation of the full-time and full-working-condition desulfurization system and reduce the energy consumption, the technology still has room for improvement.
Disclosure of Invention
In order to solve the technical problems, the invention provides a dry desulfurization energy-saving mixed type full-load adjustable system which comprises a desulfurization tower, a denitration system, an induced draft fan and a chimney which are sequentially connected through a main flue, wherein the desulfurization tower introduces flue gas through the main flue through a throat part, and also comprises a plurality of load adjustable valves and a clean flue gas circulating system adjusting valve of a clean flue gas circulating system, the inlet of each load adjustable valve is communicated with the main flue for introducing the flue gas through a load adjustable flue, the outlet of the flue gas purification device is communicated with the tower body of the desulfurizing tower through a load-adjustable flue, the inlet of the clean flue gas circulating system regulating valve is communicated with the main flue between the induced draft fan and the chimney through the clean flue gas circulating system regulating flue, the outlet of the flue gas inlet is communicated with the main flue for introducing flue gas through the clean flue gas circulating system adjusting flue, and the interfaces of the flue gas inlet and the main flue are positioned in front of the load adjustable flue.
the technical effects are as follows: the invention designs a full-time and full-working-condition dry desulfurization system, realizes the purposes of reducing pressure loss, ensuring desulfurization effect, saving energy and reducing consumption, and has wider load adaptability and lower energy consumption.
The technical scheme of the invention is further defined as follows:
in the dry desulfurization energy-saving mixed type full-load adjustable system, the number of the load adjustable valves is four.
in the dry desulfurization energy-saving mixed type full-load adjustable system, the outlet of the load-adjustable flue tangentially enters the inside of the desulfurization tower.
in the dry desulfurization energy-saving mixed type full-load adjustable system, the load adjustable flue adopts a spiral structure.
In the dry desulfurization energy-saving mixed type full-load adjustable system, the load adjustable valve is an adjustable valve.
In the dry desulfurization energy-saving mixed type full-load adjustable system, the clean flue gas circulating system regulating valve adopts an adjustable valve.
Another object of the present invention is to provide a control method of a dry desulfurization energy-saving hybrid full-load adjustable system,
When the circulating fluidized bed runs at 0% -40% of full load, the opening size of the regulating valve of the clean flue gas circulating system is determined according to the flue gas flow, and the normal operation of the desulfurization system is ensured;
when the circulating fluidized bed runs at 40-50% of full load, the load adjustable valves are all closed;
When the circulating fluidized bed runs at 50% -110% of full load, part of flue gas directly passes through the throat part through the load-adjustable flue and is introduced into the desulfurizing tower, specifically:
when the circulating fluidized bed runs at 50-80% of full load, determining the opening number and the opening size of the load adjustable valve according to the flue gas flow;
when the circulating fluidized bed runs at 80% -110% of full load, the load adjustable valve is fully opened.
In the control method of the dry desulfurization energy-saving hybrid full-load adjustable system, the load of the desulfurization tower is designed according to the lowest load during operation.
The invention has the beneficial effects that:
(1) The invention adopts the mode of combining the load adjustable system and the clean flue gas circulating system, thereby being capable of meeting the normal operation of the desulfurization system in all time periods and all working conditions;
(2) According to different operation loads, the adjustable valve of the load adjusting system and the clean flue gas circulating system adjusting valve are adjusted to ensure that the amount of flue gas passing through the throat part of the desulfurizing tower is in a design range, so that the flow field in the desulfurizing tower can be stabilized, the operation range of the desulfurizing system is expanded, and the adaptability of the circulating fluidized bed dry-method desulfurization to the loads is improved;
(3) In the invention, the clean flue gas circulating system is used under the condition of extremely low load, so the energy consumption is lower than that of the single clean flue gas circulating system; the sectional area of the circulating flue is smaller than that of an independent clean flue gas circulating system, so that the investment is saved;
(4) when the invention is in operation, the flow field in the desulfurizing tower is stable, the operation resistance is small, the comprehensive energy consumption is low, and the service life of the equipment is prolonged.
drawings
FIG. 1 is a schematic diagram of the system of the present invention;
Wherein: 1. a desulfurizing tower; 2. a denitration system; 3. an induced draft fan; 4. a chimney; 5. a main flue; 6. a load adjustable valve; 7. the load can adjust the flue; 8. a clean flue gas circulating system regulating valve; 9. the clean flue gas circulating system adjusts the flue.
Detailed Description
the energy-saving hybrid full-load adjustable system for dry desulfurization provided by the embodiment has a structure as shown in fig. 1, and comprises a desulfurization tower 1, a denitration system 2, an induced draft fan 3 and a chimney 4 which are sequentially connected through a main flue 5, wherein the desulfurization tower 1 introduces flue gas through the main flue 5 through a throat part, and the load of the desulfurization tower 1 is designed according to the lowest load during operation. The flue gas cleaning device also comprises four load adjustable valves 6 and a clean flue gas circulating system adjusting valve 8 of the clean flue gas circulating system, wherein the load adjustable valves 6 and the clean flue gas circulating system adjusting valve 8 are all adjusting valves. The inlet of the load adjustable valve 6 is communicated with the main flue 5 for introducing flue gas through the load adjustable flue 7, the outlet of the load adjustable valve is communicated with the tower body of the desulfurizing tower 1 through the load adjustable flue 7, the load adjustable flue 7 adopts a spiral structure, and the outlet of the load adjustable flue 7 tangentially enters the desulfurizing tower 1; the inlet of the clean flue gas circulating system regulating valve 8 is communicated with the main flue 5 between the induced draft fan 3 and the chimney 4 through the clean flue gas circulating system regulating flue 9, the outlet of the clean flue gas circulating system regulating valve is communicated with the main flue 5 for introducing flue gas through the clean flue gas circulating system regulating flue 9, and the interface of the clean flue gas circulating system regulating flue 9 and the interface of the main flue 5 for introducing flue gas are positioned in front of the load adjustable.
the control method of the dry desulfurization energy-saving hybrid full-load adjustable system specifically comprises the following steps:
When the circulating fluidized bed runs at 0% -40% of full load, the opening size of the regulating valve 8 of the clean flue gas circulating system is determined according to the flue gas flow, so that the pressure loss of the empty tower running is always stabilized at 400-500 Pa, and the normal running of the desulfurization system is ensured;
When the circulating fluidized bed runs at 40-50% of full load, the load adjustable valves 6 are all closed, so that the pressure loss of empty tower operation is always stabilized at 400-500 Pa;
when the circulating fluidized bed runs at 50% -110% of full load, part of flue gas directly passes through the throat part through the load-adjustable flue 7 and is introduced into the desulfurizing tower 1, specifically:
When the circulating fluidized bed runs at 50-80% of full load, the opening number and the opening degree of the load adjustable valve 6 are determined according to the flow rate of flue gas, so that the pressure loss of the empty tower running is always stabilized at 400-500 Pa;
When the circulating fluidized bed runs at 80% -110% of full load, the load adjustable valves 6 are all opened, so that the pressure loss of empty tower operation is always stabilized at 400-500 Pa.
in actual operation, the operation load percentage of each state can be properly adjusted according to different items.
Because the mode that the load adjustable device and the clean flue gas circulating system are fused is adopted, and the clean flue gas circulating system can be started only under the condition of extremely low load under the general condition, the fused mode not only avoids overlarge energy consumption of the clean flue gas circulating system, but also ensures that the flow field in the desulfurizing tower 1 is stable, the running resistance is small, the comprehensive energy consumption is low during running, and the service life of the equipment is prolonged. The purposes of reducing pressure loss, ensuring the desulfurization effect, saving energy and reducing consumption are achieved.
in addition to the above embodiments, the present invention may have other embodiments. All technical solutions formed by adopting equivalent substitutions or equivalent transformations fall within the protection scope of the claims of the present invention.
Claims (8)
1. the utility model provides an energy-conserving mixed type full load adjustable system of dry process desulfurization, includes desulfurizing tower (1), deNOx systems (2), draught fan (3) and chimney (4) that connect gradually through flue stack (5), flue gas, its characterized in that are introduced through flue stack (5) through the choke position in desulfurizing tower (1): but still include a plurality of load governing valve (6) and a clean flue gas circulation system governing valve (8), but the import of load governing valve (6) is through load adjustable flue (7) and introducing the flue gas flue (5) intercommunication, its export is passed through load adjustable flue (7) with the tower body intercommunication of desulfurizing tower (1), the import of clean flue gas circulation system governing valve (8) through clean flue gas circulation system adjust flue (9) with draught fan (3) between chimney (4) flue (5) intercommunication, its export is passed through clean flue gas circulation system adjust flue (9) and introduce the flue gas flue (5) intercommunication and interface between them are located before load adjustable flue (7).
2. The dry desulphurization energy-saving hybrid full-load adjustable system according to claim 1, characterized in that: the number of the load adjustable valves (6) is four.
3. the dry desulphurization energy-saving hybrid full-load adjustable system according to claim 1, characterized in that: and the outlet of the load-adjustable flue (7) tangentially enters the desulfurizing tower (1).
4. The dry desulphurization energy-saving hybrid full-load adjustable system according to claim 1, characterized in that: the load-adjustable flue (7) adopts a spiral structure.
5. The dry desulphurization energy-saving hybrid full-load adjustable system according to claim 1, characterized in that: the load adjustable valve (6) adopts an adjustable valve.
6. the dry desulphurization energy-saving hybrid full-load adjustable system according to claim 1, characterized in that: the clean flue gas circulating system regulating valve (8) adopts a regulating valve.
7. A control method of the dry desulphurization energy-saving hybrid full-load adjustable system according to any one of claims 1 to 6, characterized by comprising the following steps:
When the circulating fluidized bed runs at 0% -40% of full load, the opening of the clean flue gas circulating system regulating valve (8) is determined according to the flue gas flow, and the normal running of the desulfurization system is ensured;
when the circulating fluidized bed is operated at 40-50% of full load, the load adjustable valve (6) is fully closed;
When the circulating fluidized bed runs at 50% -110% of full load, part of flue gas directly passes through the throat part through the load-adjustable flue (7) and is introduced into the desulfurizing tower (1), and the specific steps are as follows:
When the circulating fluidized bed runs at 50-80% of full load, determining the opening number and the opening degree of the load adjustable valve (6) according to the flow rate of flue gas;
When the circulating fluidized bed is operated at 80-110% of full load, the load adjustable valve (6) is fully opened.
8. The control method of the dry desulphurization energy-saving hybrid full-load adjustable system according to claim 7, characterized in that: the load of the desulfurizing tower (1) is designed according to the lowest load during operation.
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Cited By (2)
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CN116116180A (en) * | 2023-02-09 | 2023-05-16 | 山东泰开环保科技有限公司 | Flue gas inlet control system and control method for desulfurizing tower |
CN116351234A (en) * | 2023-03-23 | 2023-06-30 | 汇舸(南通)环保设备有限公司 | Smoke residence time extension device and marine desulfurizing tower adopting same |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN116116180A (en) * | 2023-02-09 | 2023-05-16 | 山东泰开环保科技有限公司 | Flue gas inlet control system and control method for desulfurizing tower |
CN116116180B (en) * | 2023-02-09 | 2024-02-20 | 山东泰开环保科技有限公司 | Flue gas inlet control system and control method for desulfurizing tower |
CN116351234A (en) * | 2023-03-23 | 2023-06-30 | 汇舸(南通)环保设备有限公司 | Smoke residence time extension device and marine desulfurizing tower adopting same |
CN116351234B (en) * | 2023-03-23 | 2023-10-20 | 汇舸(南通)环保设备有限公司 | Smoke residence time extension device and marine desulfurizing tower adopting same |
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Application publication date: 20191206 |