CN116215758A - Sea gas carbon flux observation buoy and working method thereof - Google Patents

Sea gas carbon flux observation buoy and working method thereof Download PDF

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Publication number
CN116215758A
CN116215758A CN202310026694.5A CN202310026694A CN116215758A CN 116215758 A CN116215758 A CN 116215758A CN 202310026694 A CN202310026694 A CN 202310026694A CN 116215758 A CN116215758 A CN 116215758A
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buoy
sea
sensor
observation
flux
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CN116215758B (en
Inventor
贾永刚
王宏威
付玉通
李云辉
许钰洁
宋佳莉
从金月
乔玥
陈天
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Ocean University of China
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Ocean University of China
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63BSHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B22/00Buoys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63BSHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B22/00Buoys
    • B63B22/04Fixations or other anchoring arrangements
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01DMEASURING NOT SPECIALLY ADAPTED FOR A SPECIFIC VARIABLE; ARRANGEMENTS FOR MEASURING TWO OR MORE VARIABLES NOT COVERED IN A SINGLE OTHER SUBCLASS; TARIFF METERING APPARATUS; MEASURING OR TESTING NOT OTHERWISE PROVIDED FOR
    • G01D21/00Measuring or testing not otherwise provided for
    • G01D21/02Measuring two or more variables by means not covered by a single other subclass
    • GPHYSICS
    • G08SIGNALLING
    • G08CTRANSMISSION SYSTEMS FOR MEASURED VALUES, CONTROL OR SIMILAR SIGNALS
    • G08C17/00Arrangements for transmitting signals characterised by the use of a wireless electrical link
    • G08C17/02Arrangements for transmitting signals characterised by the use of a wireless electrical link using a radio link
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02JCIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
    • H02J7/00Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries
    • H02J7/34Parallel operation in networks using both storage and other dc sources, e.g. providing buffering
    • H02J7/35Parallel operation in networks using both storage and other dc sources, e.g. providing buffering with light sensitive cells
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63BSHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B22/00Buoys
    • B63B2022/006Buoys specially adapted for measuring or watch purposes

Abstract

The invention provides a sea carbon flux observation buoy and a working method thereof, wherein a buoy body comprises an above-sea measuring device positioned at the upper part of the buoy body, a sealed cabin positioned in the buoy body, a buoyancy oil bag, an under-sea measuring device positioned at the upper part of the buoy body and an anchor chain connected with the bottom end of the under-sea measuring device from top to bottom, and the tail end of the anchor chain is connected with a fixed anchor, so that the CO above the sea, a sea interface and under the sea can be observed through the technical scheme of the invention 2 Concentration change, realizing carbon flux observation between sea-gas interfaces and CO atmosphere 2 Concentration and marine CO 2 The concentration is related, the observation of high-precision carbon dioxide flux is realized, and in addition, the unattended and long-term in-situ carbon flux observation is realized, so that technical guarantee is provided for researching the ocean carbon fixation capacity, and the national double-carbon industry is assisted.

Description

Sea gas carbon flux observation buoy and working method thereof
Technical Field
The invention relates to the technical field of sea gas observation, in particular to a sea gas carbon flux observation buoy and a working method thereof.
Background
Since 1960, global CO 2 The concentration increased from 280ppm to 410ppm, and the united states inter-government climate change committee (Intergovernmental Panel on Climate Change, IPCC) indicated "the next 20 years will be at a temperature of 1.5 degrees celsius". Climate change is a major problem concerning human survival and development in various countries, and is one of the most serious challenges facing humans in the 21 st century.
The ocean is used as the largest carbon reservoir on the earth, can continuously absorb and fixedly convert carbon dioxide in the atmosphere, and can reduce CO in the atmosphere 2 Content and stable climate change have a prominent contribution. In the vertical direction, CO in the atmosphere 2 Is transferred to the ocean by sea-gas interaction, dissolved CO in the ocean 2 Is immobilized in the ocean by biological absorption and sedimentation, and the total amount of carbon passing through unit area in unit time in the vertical direction is defined as carbon flux, and the carbon flux can be used for quantifying the absorption of atmospheric CO by the ocean 2 And (3) assessing the carbon sequestration capacity of the ocean.
At present, the observation method of ocean carbon flux mainly comprises remote sensing, a box method, a direct measurement method and the like, and the remote sensing observation method is used for observing atmospheric CO 2 The change of the content is used for calculating the carbon flux, and the ocean CO can not be directly observed 2 Content and observation are easily affected by weather; the box method observation precision is greatly influenced by a measuring instrument, the measuring range is small, and the system error is large; direct measurement cannot be used for long-term in situ carbon flux observation. Therefore, the conventional ocean carbon flux observation equipment cannot realize long-term in-situ, high-resolution and carbon flux observation between the vertical interfaces of the sea and the gas.
Currently, observation devices for carbon flux focus mainly on carbon flux measurements between the atmosphere and the soil and between the atmosphere and the water meter layer. As disclosed in CN104535522A, the invention is named as a wet land CO in intertidal zone 2 Flux measuring device and measuring method thereof, discloses a tidal zone wetland CO 2 Flux measuring device and measuring method thereof, and infrared gas analyzer is adopted to measure CO in carbon flux gas chamber 2 The change of concentration with time gives a flux of carbon dioxide between the atmosphere and the intertidal zone wetland. However, the device only measures the carbon flux in the closed air chamber, and the carbon flux in the environment is changed for a long time, so that the device ignores the interference of the external environment and has a certain limitation. The invention discloses a real-time sea-air coupling observation buoy system based on Beidou iridium double-star communication, which has the publication number of CN110203333A and is characterized in that turbulence pulsation signals are measured by adopting a vortex correlation method flux measurement module to calculate CO 2 Covariance of concentration pulsation and vertical wind speed pulsation to obtain CO 2 Flux. However, the device only measures the carbon flux between the atmosphere and the sea surface, ignores the change of the carbon flux in the sea water, and has certain limitation.
Therefore, the existing observation equipment does not consider the carbon flux change of the sea-gas two-phase medium, the obtained carbon flux data is quite controversial, the accurate observation of sea-gas carbon flux can not be realized, and the technical bottleneck for restricting the evaluation of sea carbon fixing capacity and the development of sea carbon fixing potential is formed.
Disclosure of Invention
In order to make up for the defects of the prior art, the invention provides a sea carbon flux observation buoy and a working method thereof, which can observe CO above sea surface, sea-air interface and below sea surface 2 Concentration change, realizing carbon flux observation between sea-gas interfaces and CO atmosphere 2 Concentration and marine CO 2 The concentration is related, the observation of high-precision carbon dioxide flux is realized, and in addition, the unattended and long-term in-situ carbon flux observation is realized, so that technical guarantee is provided for researching the ocean carbon fixation capacity, and the national double-carbon industry is assisted.
The invention is realized by the following technical scheme: the buoy body comprises a measuring device above the sea surface, a sealed cabin, a buoyancy oil bag, a measuring device below the sea surface and an anchor chain, wherein the measuring device above the sea surface, the sealed cabin, the buoyancy oil bag, the measuring device below the sea surface and the anchor chain are arranged at the upper part of the buoy body, the anchor chain is connected with the bottom end of the measuring device below the sea surface, the end of the anchor chain is connected with a fixed anchor, the measuring device above the sea surface is fixedly arranged on the upper surface of the sealed cabin, and the measuring device above the sea surface comprises a three-dimensional anemometer and air CO 2 The device comprises a sensor, a warning lamp, a communication antenna, a solar panel, a connecting rod, a support frame and a circular ring; three-dimensional anemometer and air CO 2 The sensor, the warning lamp and the communication antenna are arranged at the top of the device and are connected into the sealed cabin through a vertically installed connecting rod, the connecting rod is fixed in the support frame through a semicircular ring part, a circular ring is arranged at the upper end of the support frame, a solar cell panel is installed on the outer wall of the support frame, and a telescopic support rod and a support frame are arranged between the support frame and the solar cell panel;
the measuring device below the sea surface comprises dissolved CO 2 Sensor, chlorophyll a sensor, three-dimensional point type flowmeter, protection architecture include annular groove, annular groove outside nested double-deck cross connecting rod, annular groove and double-deck cross connecting rod fixed mounting are in the sealed cabin outer wall bottom of buoy bottom, and the anchor chain is fixed in the middle part of double-deck cross connecting rod, dissolves CO 2 The sensor, the chlorophyll a sensor and the three-dimensional point type flowmeter are fixedly arranged on the annular groove so as to protect the measuring device;
the sealed cabin is positioned in the hemispherical buoy body, the center of the top of the sealed cabin is provided with a sealing cover, and a limit groove for fixing the data processing core host, the observation data acquisition board and the floating is arranged in the sealed cabinThe buoy controller and the storage battery pack form a buoy circuit integrated design, and are electrically connected with the three-dimensional anemometer and the air CO 2 Sensor, warning lamp, communication antenna, solar panel and dissolved CO 2 A sensor, a chlorophyll a sensor and a three-dimensional point type flowmeter.
As a preferable scheme, a buoyancy oil bag is arranged inside the buoy body and below the sealed cabin, and is communicated with the bottom of the buoy body, so that oil is pumped into the buoyancy oil bag, and the buoyancy of the buoy is increased; oil is pumped out of the buoyancy oil bag, so that the buoyancy of the buoy is reduced, and the buoy hovers at a certain water depth.
As the preferable scheme, the measuring device above the sea surface further comprises an anti-collision fence, wherein the anti-collision fence is fixedly arranged on the upper surface of the sealed cabin and surrounds the outer side of the supporting frame.
As a preferred scheme, the data processing core host sets parameters of an observation data acquisition board, performs primary processing and statistics on acquired data, stores parameter setting information and acquisition information in a self-contained mode, and sets, debugges and detects a buoy controller; the observation data acquisition board is connected with each sensor through a corresponding data channel, performs fixed-frequency acquisition, statistics and storage on sensor data, and transmits the data in each 30 minutes to the base station through the communication antenna to be transmitted back to the user side; the buoy controller monitors cabin temperature and position information of the buoy, transmits monitoring data to the data processing core host for preliminary analysis, and transmits the data to the base station from the communication antenna every 30 minutes to be transmitted back to the user side; setting the working time length of the warning lamp; the storage battery pack and the solar panel provide power for long-term continuous operation of the buoy, and the power supply system consists of the storage battery pack and the solar panel.
The working method of the sea gas carbon flux observation buoy specifically comprises the following steps:
step S1: the method comprises the steps that a sea carbon flux observation buoy body, a support frame and a support frame are connected with a solar cell panel, after sealing of a sealed cabin is completed, when a rear deck A frame geological cable is lifted, the geological cable is symmetrically connected with a circular ring at the upper end of the support frame, after the geological cable is lifted to a certain height, one end of an anchor chain is symmetrically connected with a double-layer cross connecting rod, and the other end of the anchor chain is connected with a fixed anchor;
step S2: the volume of a buoyancy oil bag in the buoy is adjusted so as to adjust the buoyancy, so that the sea gas carbon flux observation buoy operates to a set depth for working;
step S3: when the buoy works, the three-dimensional anemometer monitors and records the change of wind speed, and air CO 2 The sensor monitors and records the change of the concentration of the atmospheric carbon dioxide;
step S4: three-dimensional point type flowmeter for monitoring and recording water flow change and dissolving CO 2 The sensor monitors and records the change of the concentration of the carbon dioxide in the seawater.
Step S5: the vorticity correlation method formula is divided into air and dissolved CO 2 The average flux calculation formula:
Figure SMS_1
(1)
in the method, in the process of the invention,
Figure SMS_2
(μmol·m -2 s -1 ) Is air CO 2 Average flux (typically 30min average),>
Figure SMS_3
is the instantaneous wind speed (m.s) -1 ),/>
Figure SMS_4
Is air CO 2 Instantaneous concentration (mu mol.m) -3 ),/>
Figure SMS_5
Calculate->
Figure SMS_6
And->
Figure SMS_7
Is capable of high frequency measurement (above 10 Hz) of air CO 2 Concentration and vertical wind speed to calculate 30min of CO 2 Average flux.
Figure SMS_8
(2)
In the method, in the process of the invention,
Figure SMS_10
(μmol·m -2 s -1 ) Is to dissolve CO 2 Average flux (typically 30min average),>
Figure SMS_13
is the instantaneous flow velocity (m.s) -1 ),/>
Figure SMS_16
Is to dissolve CO 2 Instantaneous concentration (mu mol.m) -3 ),/>
Figure SMS_11
Calculate->
Figure SMS_14
And->
Figure SMS_15
Can carry out high-frequency measurement (more than 10 Hz) of dissolved CO 2 Concentration and vertical flow rate to calculate 30min of dissolved CO 2 Average flux,/->
Figure SMS_17
Is to dissolve CO 2 Mean flux correction coefficient,/">
Figure SMS_9
Is chlorophyll a concentration,/->
Figure SMS_12
Is the rate of change of chlorophyll a over time, and k is an empirical factor.
Air CO 2 Sensor, dissolved CO 2 The sensors all meet the requirement of monitoring CO 2 The instantaneous concentration c, the three-dimensional anemometer and the three-dimensional point type anemometer of the system meet the requirements of monitoring three-dimensional wind speed and three-dimensional flow speed, the chlorophyll a sensor meets the requirements of monitoring chlorophyll a concentration, and the formula of the method meets the requirements of monitoring CO through a vorticity correlation method 2 Vertical flux from atmosphere into the body of water;
step S5: the acquired data are transmitted to an observation data acquisition board, the observation data acquisition board transmits the data to a communication antenna, and the communication antenna transmits the data to an offshore base station or a land base station to complete a data transmission task.
The invention adopts the technical proposal, and compared with the prior art, the invention has the following beneficial effects:
1. according to the invention, by carrying the on-water and underwater carbon flux observation equipment, the monitoring of the carbon dioxide flux of the sea-air interface is realized, and long-term in-situ carbon flux observation and real-time transmission are realized by means of solar panels, storage battery power supply and 4G network wireless transmission, so that technical support is provided for sea-air carbon flux related research, and the development of related industries of China is assisted.
2. According to the invention, the buoy is used as an instrument carrying platform, so that the device can observe at different positions of the ocean, and the observation of the carbon dioxide flux of the ocean in different horizontal sections is realized, and the distribution rule of the carbon dioxide flux of the ocean horizontal section is obtained.
3. The invention is beneficial to the prevention and recovery, is easy to detach and maintain as a whole, has long service life, and can meet the continuous, rapid and densely arranged offshore work demands of a plurality of sea carbon flux observation buoys in a short time.
Additional aspects and advantages of the invention will be set forth in part in the description which follows, or may be learned by practice of the invention.
Drawings
The foregoing and/or additional aspects and advantages of the invention will become apparent and may be better understood from the following description of embodiments taken in conjunction with the accompanying drawings in which:
FIG. 1 is a schematic diagram of the overall structure of the present invention;
FIG. 2 is a schematic view of the internal structure of the present invention;
FIG. 3 is a schematic diagram of the upper structure of the present invention;
FIG. 4 is a schematic view of a buoyancy platform according to the present invention;
FIG. 5 is a schematic view of the capsule structure of the present invention;
FIG. 6 is a schematic view of the underwater measuring device of the present invention;
FIG. 7 is a schematic view of the underwater measuring device of the present invention;
figure 8 is a flow chart of the design of the buoy circuit of the present invention,
wherein, the correspondence between the reference numerals and the components in fig. 1 to 3 is:
1 sea surface above measuring device, 1-1 three-dimensional anemometer, 1-2 air CO 2 The sensor, 1-3 warning lamp, 1-4 communication antenna, 1-5 solar panel, 1-6 connecting rod, 1-7 support frame, 1-8 circular ring, 2 sealed cabin, 2-1 host, 2-2 observation data acquisition board, 2-3 buoy controller, 2-4 accumulator battery, 3 buoyancy oil bag, 4 measuring device under sea surface, 4-1 dissolved CO 2 The sensor, 4-2 chlorophyll a sensor, 4-3 three-dimensional point type flowmeter, 4-4 protection structure, 4-4-1 annular groove, 4-4-2 double-layer cross connecting rod, 5 anchor chain, 6 anchor, 7 semicircle ring type spare, 8 sealed lid.
Detailed Description
In order that the above-recited objects, features and advantages of the present invention will be more clearly understood, a more particular description of the invention will be rendered by reference to the appended drawings and appended detailed description. It should be noted that, in the case of no conflict, the embodiments of the present application and the features in the embodiments may be combined with each other.
In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present invention, however, the present invention may be practiced otherwise than as described herein, and therefore the scope of the present invention is not limited to the specific embodiments disclosed below.
The following describes a sea-air carbon flux observation buoy and a working method thereof according to an embodiment of the present invention with reference to fig. 1 to 6.
As shown in fig. 1, 2 and 3, the invention provides a sea carbon flux observation buoy, wherein a buoy body comprises an above-sea surface measuring device 1, a sealed cabin 2, a buoyancy oil bag 3, an under-sea surface measuring device 4 and an under-sea surface measuring device, wherein the above-sea surface measuring device 1 is arranged at the upper part of the buoy body, the sealed cabin 2 is arranged inside the buoy body and serves as a central device, and the under-sea surface measuring device is arranged at the upper part of the buoy body from top to bottomAn anchor chain 5 connected with the bottom end of the device 4 is arranged, the tail end of the anchor chain 5 is connected with a fixed anchor 6, as shown in figure 4, the above-sea surface measuring device 1 is fixedly arranged on the upper surface of the sealed cabin 2, and the above-sea surface measuring device 1 comprises a three-dimensional anemometer 1-1 and air CO 2 The device comprises a sensor 1-2, a warning lamp 1-3, a communication antenna 1-4, a solar panel 1-5, a connecting rod 1-6, a supporting frame 1-7 and a circular ring 1-8; three-dimensional anemometer 1-1, air CO 2 The sensor 1-2, the warning lamp 1-3 and the communication antenna 1-4 are arranged at the top of the device and are connected into the sealed cabin 2 through the connecting rod 1-6 which is vertically arranged, the connecting rod 1-6 is fixed in the supporting frame 1-7 through the semicircular piece 7, the upper end of the supporting frame 1-7 is provided with the circular ring 1-8, the outer wall of the supporting frame 1-7 is provided with the solar cell panel 1-5, and a telescopic supporting rod is arranged between the supporting frame 1-7 and the solar cell panel 1-5, so that the inclination angle of the solar cell panel can be adjusted;
as shown in fig. 6, the below-sea surface measuring device 4 comprises dissolved CO 2 The sensor 4-1, the chlorophyll a sensor 4-2, the three-dimensional point type flowmeter 4-3 and the protection structure 4-4 are shown in fig. 7, the protection structure 4-4 comprises an annular groove 4-4-1, a double-layer cross connecting rod 4-4-2 is nested outside the annular groove 4-4-1, the annular groove 4-4-1 and the double-layer cross connecting rod 4-4-2 are fixedly arranged at the bottom end of the outer wall of the sealed cabin 2 at the bottom of a buoy, an anchor chain 5 is fixed at the middle part of the double-layer cross connecting rod 4-4-2, and CO is dissolved 2 The sensor 4-1, the chlorophyll a sensor 4-2 and the three-dimensional point type flowmeter 4-3 are fixedly arranged on the annular groove 4-4-1 to protect the measuring device;
as shown in FIG. 5, the sealed cabin 2 is located inside the hemispherical buoy body, the top center of the sealed cabin 2 is provided with a sealing cover 8, a limit groove is arranged in the sealed cabin 2 for fixing a data processing core host 2-1, an observation data acquisition board 2-2, a buoy controller 2-3 and a storage battery pack 2-4, the data processing core host 2-1, the observation data acquisition board 2-2, the buoy controller 2-3 and the storage battery pack 2-4 form a buoy circuit integrated design, and the three-dimensional anemometer 1-1 and the air CO are electrically connected 2 Sensor 1-2, warning lamp 1-3, communication antenna 1-4, solar panel 1-5, and dissolved CO 2 Sensor 4-1, chlorophyll a sensor 4-2 and three-dimensional point-type flowmeter 4-3.
The measuring device 1 above the sea surface further comprises an anti-collision fence 1-9, wherein the anti-collision fence 1-9 is fixedly arranged on the upper surface of the sealed cabin 2 and is arranged on the outer side of the supporting frame 1-7 in a surrounding mode.
As shown in fig. 2, a buoyancy oil bag 3 is arranged inside the buoy body and below the sealed cabin 2, the buoyancy oil bag 3 is communicated with the bottom of the buoy body, oil is pumped into the buoyancy oil bag 3, and the buoyancy of the buoy is increased; oil is pumped out of the buoyancy oil bag 3, so that the buoyancy of the buoy is reduced, and the buoy hovers at a certain water depth.
As shown in fig. 8, the data processing core host 2-1 performs parameter setting on the observation data acquisition board 2-2, performs preliminary processing and statistics on acquired data, stores parameter setting information and acquisition information in a self-contained manner, and performs setting, debugging and detection on the buoy controller 2-3; the observation data acquisition board 2-2 is connected with each sensor through a corresponding data channel, performs fixed-frequency acquisition, statistics and storage on sensor data, and transmits the data in each 30 minutes to the base station through the communication antenna 1-4 for transmission back to the user side; the buoy controller 2-3 monitors cabin temperature and position information of the buoy, transmits monitoring data to the data processing core host 2-1 for preliminary analysis, and transmits the data to the base station through the communication antenna every 30 minutes to be transmitted back to the user side; setting the working time length of the warning lamp 1-3; the storage battery pack 2-4 and the solar panel 1-5 provide power for the buoy to continuously work for a long time, and the power supply system consists of the storage battery pack 2-4 and the solar panel 1-5.
The working method of the sea gas carbon flux observation buoy specifically comprises the following steps:
step S1: the method comprises the steps of connecting a sea carbon flux observation buoy body with a support frame 1-7 and connecting the support frame 1-7 with a solar panel 1-5, after sealing a sealed cabin 2, symmetrically connecting the geological cable with a circular ring 1-8 at the upper end of the support frame 1-7 when a geological cable of a rear deck A is lifted, symmetrically connecting one end of an anchor chain 5 with a double-layer cross connecting rod 4-4-2 after the geological cable is lifted for a certain height, and connecting the other end of the anchor chain with a fixed anchor 6;
step S2: the volume of the buoyancy oil bag 3 in the buoy is adjusted so as to adjust the buoyancy, so that the sea gas carbon flux observation buoy operates to a set depth for working;
step S3: when the buoy works, the three-dimensional anemometer 1-1 monitoring and recording wind speed variation, air CO 2 The sensor 1-2 monitors and records the change of the concentration of the atmospheric carbon dioxide;
step S4: three-dimensional point type flowmeter 4-3 for monitoring and recording water flow change and dissolving CO 2 The sensor 4-1 monitors and records the change of the concentration of the carbon dioxide in the seawater.
Step S5: the vorticity correlation method formula is divided into air and dissolved CO 2 The average flux calculation formula:
Figure SMS_18
(1)
in the method, in the process of the invention,
Figure SMS_19
(μmol·m -2 s -1 ) Is air CO 2 Average flux (typically 30min average),>
Figure SMS_20
is the instantaneous wind speed (m.s) -1 ),/>
Figure SMS_21
Is air CO 2 Instantaneous concentration (mu mol.m) -3 ),/>
Figure SMS_22
Calculate->
Figure SMS_23
And->
Figure SMS_24
Is capable of high frequency measurement (above 10 Hz) of air CO 2 Concentration and vertical wind speed to calculate 30min of CO 2 Average flux. />
Figure SMS_25
(2)
In the method, in the process of the invention,
Figure SMS_28
(μmol·m -2 s -1 ) Is to dissolve CO 2 Average flux (typically 30min average),>
Figure SMS_31
is the instantaneous flow velocity (m.s) -1 ),/>
Figure SMS_33
Is to dissolve CO 2 Instantaneous concentration (mu mol.m) -3 ),/>
Figure SMS_27
Calculate->
Figure SMS_30
And->
Figure SMS_32
Can carry out high-frequency measurement (more than 10 Hz) of dissolved CO 2 Concentration and vertical flow rate to calculate 30min of dissolved CO 2 Average flux,/->
Figure SMS_34
Is to dissolve CO 2 Mean flux correction coefficient,/">
Figure SMS_26
Is chlorophyll a concentration,/->
Figure SMS_29
Is the rate of change of chlorophyll a over time, and k is an empirical factor.
Air CO 2 Sensor 1-2, dissolved CO 2 The sensors 4-1 all meet the requirement of monitoring CO 2 The three-dimensional anemometer 1-1 and the three-dimensional point type anemometer 4-3 meet the requirement of monitoring three-dimensional wind speed and three-dimensional flow velocity, and the formula of the vortex correlation method is adopted to meet the requirement of monitoring CO 2 Vertical flux from atmosphere into the body of water;
step S5: the acquired data are transmitted to the observation data acquisition board 2-2, the observation data acquisition board 2-2 transmits the data to the communication antenna 1-4, and the communication antenna 1-4 transmits the data to the offshore base station or the land base station to complete the data transmission task.
In the description of the present invention, the term "plurality" means two or more, unless explicitly defined otherwise, the orientation or positional relationship indicated by the terms "upper", "lower", etc. are based on the orientation or positional relationship shown in the drawings, merely for convenience of description of the present invention and to simplify the description, and do not indicate or imply that the apparatus or elements referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore should not be construed as limiting the present invention; the terms "coupled," "mounted," "secured," and the like are to be construed broadly, and may be fixedly coupled, detachably coupled, or integrally connected, for example; can be directly connected or indirectly connected through an intermediate medium. The specific meaning of the above terms in the present invention can be understood by those of ordinary skill in the art according to the specific circumstances.
In the description of the present specification, the terms "one embodiment," "some embodiments," "particular embodiments," and the like, mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the present invention. In this specification, schematic representations of the above terms do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The above is only a preferred embodiment of the present invention, and is not intended to limit the present invention, but various modifications and variations can be made to the present invention by those skilled in the art. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (5)

1. The buoy body comprises a measuring device (1) above the sea surface, a sealed cabin (2), a buoyancy oil bag (3), a measuring device (4) below the sea surface and a bottom end of the measuring device (4) below the sea surface, wherein the measuring device (1) above the sea surface is arranged at the upper part of the buoy body, the sealed cabin (2) is arranged inside the buoy body and is used as a central device, and the buoyancy oil bag (3) is arranged at the upper part of the buoy body from top to bottomThe device is characterized in that the above-sea measuring device (1) is fixedly arranged on the upper surface of the sealed cabin (2), and the above-sea measuring device (1) comprises a three-dimensional anemometer (1-1) and air CO 2 The device comprises a sensor (1-2), a warning lamp (1-3), a communication antenna (1-4), a solar panel (1-5), a connecting rod (1-6), a supporting frame (1-7) and a circular ring (1-8); three-dimensional anemometer (1-1), air CO 2 The sensor (1-2), the warning lamp (1-3) and the communication antenna (1-4) are arranged at the top of the device and are connected into the sealed cabin (2) through a connecting rod (1-6) which is vertically arranged, the connecting rod (1-6) is fixed in the supporting frame (1-7) through a semicircular ring-shaped piece (7), a circular ring (1-8) is arranged at the upper end of the supporting frame (1-7), a solar cell panel (1-5) is arranged on the outer wall of the supporting frame (1-7), and a telescopic supporting rod is arranged between the supporting frame (1-7) and the solar cell panel (1-5), so that the inclination angle of the solar cell panel can be adjusted;
the subsurface measurement device (4) comprises dissolved CO 2 Sensor (4-1), chlorophyll a sensor (4-2), three-dimensional point type flowmeter (4-3), protection architecture (4-4) include annular groove (4-4-1), outside nested double-deck cross connecting rod (4-4-2) of annular groove (4-4-1), annular groove (4-4-1) and double-deck cross connecting rod (4-4-2) fixed mounting are in sealed cabin (2) outer wall bottom of buoy bottom, anchor chain (5) are fixed in the middle part of double-deck cross connecting rod (4-4-2), dissolve CO 2 The sensor (4-1), the chlorophyll a sensor (4-2) and the three-dimensional point type flowmeter (4-3) are fixedly arranged on the annular groove (4-4-1) so as to protect the measuring device;
the sealed cabin (2) is positioned in the hemispherical buoy body, the sealing cover (8) is arranged at the center of the top of the sealed cabin (2), a limiting groove used for fixing the data processing core host (2-1), the observation data acquisition board (2-2), the buoy controller (2-3) and the storage battery pack (2-4) is arranged in the sealed cabin (2), and the data processing core host (2-1), the observation data acquisition board (2-2) and the buoy controller (2-3) are arranged in the sealed cabin (2)) And a storage battery pack (2-4) form a buoy circuit integrated design, and are electrically connected with the three-dimensional anemometer (1-1) and the air CO 2 The sensor (1-2), the warning lamp (1-3), the communication antenna (1-4), the solar panel (1-5) and the dissolved CO 2 A sensor (4-1), a chlorophyll a sensor (4-2) and a three-dimensional point type flowmeter (4-3).
2. A sea carbon flux observation buoy according to claim 1, characterized in that the above sea surface measuring device (1) further comprises an anti-collision fence (1-9), wherein the anti-collision fence (1-9) is fixedly arranged on the upper surface of the sealed cabin (2) and surrounds and is arranged outside the supporting frame (1-7).
3. The sea carbon flux observation buoy according to claim 1, wherein a buoyancy oil bag (3) is arranged inside the buoy body and below the sealed cabin (2), and the buoyancy oil bag (3) is communicated with the bottom of the buoy body.
4. A sea-air carbon flux observation buoy according to claim 3, characterized in that the data processing core host (2-1) performs parameter setting on the observation data acquisition board (2-2), performs preliminary processing and statistics on acquired data, stores parameter setting information and acquisition information in a self-contained manner, and performs setting, debugging and detection on the buoy controller (2-3); the observation data acquisition board (2-2) is connected with each sensor through a corresponding data channel, constant frequency acquisition, statistics and storage are carried out on sensor data, and each 30 minutes of subpackage data are sent to the base station by the communication antenna (1-4) and transmitted back to the user side; the buoy controller (2-3) monitors cabin temperature and position information of the buoy, transmits monitoring data to the data processing core host (2-1) for preliminary analysis, and transmits the data to the base station from the communication antenna every 30 minutes to be transmitted back to the user side; setting the working time length of the warning lamp (1-3); the storage battery (2-4) and the solar panel (1-5) provide power for the buoy to continuously work for a long time, and the power supply system comprises the storage battery (2-4) and the solar panel (1-5).
5. The method for operating a marine carbon flux observation buoy according to claim 1, comprising the steps of:
step S1: the method comprises the steps that a sea carbon flux observation buoy body is connected with a support frame (1-7) and the support frame (1-7) is connected with a solar cell panel (1-5), after sealing of a sealed cabin (2) is completed, when a rear deck A geological cable is lifted, the geological cable is symmetrically connected with a round ring (1-8) at the upper end of the support frame (1-7), after the geological cable is lifted to a certain height, one end of an anchor chain (5) is symmetrically connected with a double-layer cross connecting rod (4-4-2), and the other end of the anchor chain is connected with a fixed anchor (6);
step S2: the volume of a buoyancy oil bag (3) in the buoy is adjusted so as to adjust the buoyancy, and the buoy is observed to operate to a set depth for working by the sea gas carbon flux;
step S3: when the buoy works, the three-dimensional anemometer (1-1) monitors and records the change of wind speed, and the air CO 2 The sensor (1-2) monitors and records the change of the concentration of the atmospheric carbon dioxide;
step S4: three-dimensional point type flowmeter (4-3) for monitoring and recording water flow change and dissolving CO 2 A sensor (4-1) monitors and records the concentration change of the seawater carbon dioxide;
step S5: the formula of the vorticity correlation method is divided into an average flux calculation formula of air and dissolved CO 2:
Figure 980851DEST_PATH_IMAGE001
(1)
in the method, in the process of the invention,
Figure 787133DEST_PATH_IMAGE002
(μmol·m -2 s -1 ) Is air CO 2 Average flux,/->
Figure 837129DEST_PATH_IMAGE003
Is the instantaneous wind speed (m.s) -1 ),/>
Figure 906716DEST_PATH_IMAGE004
Is air CO 2 Instantaneous concentration (mu mol.m) -3 ),/>
Figure 166796DEST_PATH_IMAGE005
Calculate->
Figure 917714DEST_PATH_IMAGE006
And->
Figure 946850DEST_PATH_IMAGE007
Can carry out high-frequency measurement, more than 10 Hz; air CO 2 Concentration and vertical wind speed to calculate 30min of CO 2 Average flux;
Figure 452918DEST_PATH_IMAGE008
(2)
in the method, in the process of the invention,
Figure 807151DEST_PATH_IMAGE009
(μmol·m -2 s -1 ) Is to dissolve CO 2 Average flux,/->
Figure 486394DEST_PATH_IMAGE010
Is the instantaneous flow velocity (m.s) -1 ),/>
Figure 573299DEST_PATH_IMAGE011
Is the instantaneous concentration of dissolved CO2 (. Mu. Mol.m) -3 ),/>
Figure 922372DEST_PATH_IMAGE012
Calculate->
Figure 157044DEST_PATH_IMAGE013
And->
Figure 312082DEST_PATH_IMAGE014
Covariance of (2) can be measured at high frequency of more than 10Hz, and CO is dissolved 2 Concentration and vertical flow rate to calculate 30min of dissolved CO 2 Average flux,/->
Figure 191176DEST_PATH_IMAGE015
Is to dissolve CO 2 Mean flux correction coefficient,/">
Figure 101364DEST_PATH_IMAGE016
Is chlorophyll a concentration,/->
Figure 433119DEST_PATH_IMAGE017
Is the rate of change of chlorophyll a over time, k is an empirical factor;
air CO 2 Sensor (1-2), dissolved CO 2 The sensors (4-1) all meet the requirement of monitoring CO 2 The instantaneous concentration c, the three-dimensional anemometer and the three-dimensional point type anemometer (4-3) meet the requirement of monitoring three-dimensional wind speed and three-dimensional flow velocity, and the formula of the vortex correlation method meets the requirement of monitoring CO 2 Vertical flux from atmosphere into the body of water;
step S5: the collected data is transmitted to a collection center unit, the collection center transmits the data to a communication unit, and the communication unit transmits the data to an offshore base station or a land base station to complete a data transmission task.
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